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Relevant bibliographies by topics / Methyl phenyl malonate

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Journal articles

Academic literature on the topic 'Methyl phenyl malonate'

Author: Grafiati

Published: 3 June 2025

Last updated: 31 July 2025

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Journal articles on the topic "Methyl phenyl malonate"

1

Šebo, Ľubomír, Ján Šraga, Grety Rihs та Štefan Toma. "Stereoselectivity of Michael Addition to 3-Phenyl-1-(η6-o-tolyltricarbonylchromium)propenone". Collection of Czechoslovak Chemical Communications 59, № 12 (1994): 2621–31. http://dx.doi.org/10.1135/cccc19942621.

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The stereoselectivity of the Michael addition of several C-nucleophiles to 3-phenyl-1-(η6-o-tolyltricarbonylchromium)propenone has been studied. The ratio of diastereoisomers formed varied from 65 : 35 (malonodinitrile), 72 : 28 (methyl cyanoacetate) and 78 : 22 (nitromethane) and to 90 : 10 (dimethyl malonate). The ratio of diastereoisomers 63 : 37 was found even when addition of dimethyl malonate was carried out at 75 °C in methanol using piperidine as the catalyst. The (S,R) or (R,S) configuration of the main pair of isomers was proved by the X-ray analysis of the dimethyl malonate adduct.

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2

Akkurt, Mehmet, Sema Öztürk Yıldırım, Oumaima T. Benjelloun, Najib Ben Larbi, Taibi Ben Hadda, and Orhan Büyükgüngör. "Diethyl 2-[(morpholin-4-yl)(phenyl)methyl]malonate." Acta Crystallographica Section E Structure Reports Online 63, no. 4 (2007): o1656—o1657. http://dx.doi.org/10.1107/s1600536807010380.

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3

Meskini, Ihssan, Maria Daoudi, Jean-Claude Daran, Hafid Zouihri, and Abdelali Kerbal. "Diethyl 2-{(dibenzylamino)[4-(trifluoromethyl)phenyl]methyl}malonate." Acta Crystallographica Section E Structure Reports Online 66, no. 4 (2010): o961—o962. http://dx.doi.org/10.1107/s1600536810010512.

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4

N., D. SHARMA, KUMAR SANTOSH, V. BAKORE P., and C. JOSHI B. "Condensation of 2-Anilino-4-methylquinoline Derivatives with Substituted-diethylmalonate and Studies of Isomerism through Nmr Spectra." Journal of Indian Chemical Society Vol. 64, Aug 1987 (1987): 481–82. https://doi.org/10.5281/zenodo.6199354.

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Department of Chemistry, University of Rajasthan, Jaipur-302 004 <em>Manuscript received 6 February 1979, accepted 22 January 1987</em> 2 [<em>N</em>-(2,2-Dicarbethoxyvinyl)anilino]-4-methyl-quinoline (6), 2-[<em>N</em>-(2,2-dicarbethoxyvinyl)-2-chloroanilino]-4-methylquinoline (7) and 2-N-(2,2-dicarbethoxyvinyl)-4- methylquinoline (8) were prepared by condensing ethoxymethylene diethyl malonate (4) with 2-anilino-4-methyl-quinoline (1), 2-(2-chlorosailino)-4-methylquinoline (2) and 2.(4-methoxyanilino)-4-methyl quinoline (3), respectively. 2-[<em>N</em>-(2-Carbethoxy-2- pbenacetyl)anilin

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5

Shreekanth, Tharangini K., Hemmige S. Yathirajan, Balakrishna Kalluraya, Sabine Foro, and Christopher Glidewell. "Order versus disorder in two isomorphous pyrazolone-substituted diethyl propanedioates prepared using a three-component one-pot reaction under solvent-free conditions." Acta Crystallographica Section E Crystallographic Communications 76, no. 10 (2020): 1605–10. http://dx.doi.org/10.1107/s2056989020011676.

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Two new substituted propanedioate esters have been synthesized using a three-component solvent-free thermal reaction between diethyl propanedioate (diethyl malonate), 5-chloro-3-methyl-1-phenyl-1H-pyrazole-4-carbaldehyde and an aryl azide, forming two new C—C bonds in a single step. The products diethyl (RS)-2-[(4-bromophenyl)(5-methyl-3-oxo-2-phenyl-2,3-dihydro-1H-pyrazol-4-yl)methyl]propanedioate, C24H25BrN2O5 (I), and diethyl (RS)-2-[(4-chlorophenyl)(5-methyl-3-oxo-2-phenyl-2,3-dihydro-1H-pyrazol-4-yl)methyl]propanedioate, C24H25ClN2O5 (II), are isomorphous, with Z′ = 2 in space group P21/n

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6

Tiwari, Abhishek, and Anita Singh. "Synthesis and evaluation of possible mechanism of anti nociceptive potential of novel 2-quinolone fused 3,5-pyrazolidinedione derivatives in experimental animal models." Analele Universitatii "Ovidius" Constanta - Seria Chimie 24, no. 1 (2013): 5–12. http://dx.doi.org/10.2478/auoc-2013-0001.

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AbstractIn the present synthesis a series of 1-(1-methyl-2-oxo-1,2-dihydroquinolin-4-yl)-2-substituted phenylpyrazolidine-3,5-diones were prepared. By the reaction of N-methylbenzenamine with diethyl malonoate 4-hydroxy-1-methylquinolin-2(1H)-one were prepared, which on treatment with posphoryl chloride converted into 4-chloro-1-methylquinolin-2(1H)-one. Subsequently with substituted phenyl hydrazines 1-methyl-4-(2- substitutedphenylhydrazinyl)quinolin-2(1H)-one were obtained, which on reaction with diethyl malonate gave 1- (1-methyl-2-oxo-1,2-dihydroquinolin-4-yl)-2-substituted phenylpyrazoli

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7

Marx, A., S. Saravanan, S. Muthusubramanian, V. Manivannan, and Nigam P. Rath. "Diethyl 2-[(4-nitrophenyl)(4-phenyl-1,2,3-selenadiazol-5-yl)methyl]malonate." Acta Crystallographica Section E Structure Reports Online 64, no. 4 (2008): o729. http://dx.doi.org/10.1107/s160053680800706x.

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8

Korlyukov, Alexander A., Pavel V. Dorovatovskii, and Anna V. Vologzhanina. "N-(4-Methyl-3-((4-(pyridin-3-yl)pyrimidin-2-yl)amino)phenyl)-4-((4-methylpiperazin-1-yl)methyl)benzamide." Molbank 2022, no. 4 (2022): M1461. http://dx.doi.org/10.3390/m1461.

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Imatinib is one of the most used therapeutic agents to treat leukemia, which specifically inhibits the activity of tyrosine kinases. This polytopic molecule has been structurally characterized only in the form of its piperazin-1-ium salt (mesylate, picrate, citrate, fumarate or malonate). Herein we present the crystal structure of the freebase Imatinib which precipitated from a 1:10 mixture with arginine. The molecule realizes an extended conformation and forms infinite H-bonded chains through its amide, amine and pyrimidine groups.

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9

Kavitha, T., M. Thenmozhi, V. Dhayalan, A. K. Mohanakrishnan, and M. N. Ponnuswamy. "Diethyl 2-[(5-methoxy-2-methyl-1-phenylsulfonyl-1H-indol-3-yl)methylene]malonate." Acta Crystallographica Section E Structure Reports Online 65, no. 6 (2009): o1418—o1419. http://dx.doi.org/10.1107/s1600536809019369.

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In the title compound, C24H25NO7S, the sulfonyl-bound phenyl ring is approximately perpendicular to the indole ring system [dihedral angle = 87.72 (5)°]. The methyl group of one of the ester units is disordered over two positions with occupancies of 0.527 (13) and 0.473 (13). An intramolecular C—H...O hydrogen bond is observed. In the crystal structure, molecules are linked into a ribbon structure running along thecaxis by intermolecular C—H...O hydrogen bonds and C—H...π interactions involving the pyrrole ring.

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10

Vah, Luka, Tadej Medved, Uroš Grošelj, et al. "Regioselective Synthesis of 5- and 3-Hydroxy-N-Aryl-1H-Pyrazole-4-Carboxylates and Their Evaluation as Inhibitors of Plasmodium falciparum Dihydroorotate Dehydrogenase." Molecules 27, no. 15 (2022): 4764. http://dx.doi.org/10.3390/molecules27154764.

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In silico evaluation of various regioisomeric 5- and 3-hydroxy-substituted alkyl 1-aryl-1H-pyrazole-4-carboxylates and their acyclic precursors yielded promising results with respect to their binding in the active site of dihydroorotate dehydrogenase of Plasmodium falciparum (PfDHODH). Consequently, four ethyl 1-aryl-5-hydroxy-1H-pyrazole-4-carboxylates and their 3-hydroxy regioisomers were prepared by two-step syntheses via enaminone-type reagents or key intermediates. The synthesis of 5-hydroxy-1H-pyrazoles was carried out using the literature protocol comprising acid-catalyzed transaminatio

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