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1

Wang, Qi, Yuchuan Shao, Qingfeng Dong, Zhengguo Xiao, Yongbo Yuan, and Jinsong Huang. "Large fill-factor bilayer iodine perovskite solar cells fabricated by a low-temperature solution-process." Energy Environ. Sci. 7, no. 7 (2014): 2359–65. http://dx.doi.org/10.1039/c4ee00233d.

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2

Burkitt, Daniel, Justin Searle, David Worsley, and Trystan Watson. "Sequential Slot-Die Deposition of Perovskite Solar Cells Using Dimethylsulfoxide Lead Iodide Ink." Materials 11, no. 11 (2018): 2106. http://dx.doi.org/10.3390/ma11112106.

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This work demonstrates a sequential deposition of lead iodide followed by methylammonium iodide using the industrially compatible slot-die coating method that produces homogeneous pin-hole free films without the use of the highly toxic dimethylformamide. This is achieved through the careful selection and formulation of the solvent system and coating conditions for both the lead iodide layer and the methylammonium iodide coating. The solvent system choice is found to be critical to achieving good coating quality, conversion to the final perovskite and for the film morphology formed. A range of
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3

Emmanuel Koné, Klègayéré, Amal Bouich, Donafologo Soro, and Bernabé Marí Soucase. "Effect of mixed iodine and bromine on optical properties in methylammonium lead chlorine (MAPbCl3) spin-coated on the zinc oxide film." E3S Web of Conferences 412 (2023): 01066. http://dx.doi.org/10.1051/e3sconf/202341201066.

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The optical influence of mixing methylammonium lead chlorine (MAPbCl3) with iodine and bromine was studied in this work. The spin coating method deposited three layers of perovskites (MAPbCl3, MAPbCl2I, and MAPbCl2Br) on a layer of zinc oxide (ZnO). The zinc oxide solution was prepared by dissolving dehydrated zinc acetate [Zn(CH3COO)2, 2H2O]> 99.5% purity in ethanol to give a 0.5 M solution. The perovskite solutions were prepared using lead chloride (PbCl2), methylammonium chloride (MACl), methylammonium iodide (MAI), and methylammonium bromide (MABr). The precursor containing iodine was d
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4

Ahlawat, Paramvir, Alexander Hinderhofer, Essa A. Alharbi та ін. "A combined molecular dynamics and experimental study of two-step process enabling low-temperature formation of phase-pure α-FAPbI3". Science Advances 7, № 17 (2021): eabe3326. http://dx.doi.org/10.1126/sciadv.abe3326.

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It is well established that the lack of understanding the crystallization process in a two-step sequential deposition has a direct impact on efficiency, stability, and reproducibility of perovskite solar cells. Here, we try to understand the solid-solid phase transition occurring during the two-step sequential deposition of methylammonium lead iodide and formamidinium lead iodide. Using metadynamics, x-ray diffraction, and Raman spectroscopy, we reveal the microscopic details of this process. We find that the formation of perovskite proceeds through intermediate structures and report polymorph
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5

Joo, Sung Hwan, Il Tae Kim, and Hyung Wook Choi. "Characteristics of Perovskite Solar Cells with Methylammonium Iodide-Added Anti-Solvent." Journal of Nanoscience and Nanotechnology 21, no. 8 (2021): 4367–71. http://dx.doi.org/10.1166/jnn.2021.19408.

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The perovskite film—manufactured via a one-step method—was superficially improved through an anti-solvent process to increase solar cell efficiency. Although perovskite synthesis proceeds rapidly, a significant amount of lead iodide residue remains. Well-placed lead iodide in perovskite grains prevents electron–hole recombination; however, when irregularly placed, it interferes with the movement of electron and holes. In this study, we focused on improving the crystallinity of the perovskite layer, as well as reducing lead iodide residues by adding a methylammonium halide material to the anti-
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6

Skurlov, Ivan D., Iurii G. Korzhenevskii, Anastasiia S. Mudrak, et al. "Optical Properties, Morphology, and Stability of Iodide-Passivated Lead Sulfide Quantum Dots." Materials 12, no. 19 (2019): 3219. http://dx.doi.org/10.3390/ma12193219.

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Iodide atomic surface passivation of lead chalcogenides has spawned a race in efficiency of quantum dot (QD)-based optoelectronic devices. Further development of QD applications requires a deeper understanding of the passivation mechanisms. In the first part of the current study, we compare optics and electrophysical properties of lead sulfide (PbS) QDs with iodine ligands, obtained from different iodine sources. Methylammonium iodide (MAI), lead iodide (PbI2), and tetrabutylammonium iodide (TBAI) were used as iodine precursors. Using ultraviolet photoelectron spectroscopy, we show that differ
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7

Handley, C. M., and C. L. Freeman. "Correction: A new potential for methylammonium lead iodide." Physical Chemistry Chemical Physics 19, no. 21 (2017): 14185–86. http://dx.doi.org/10.1039/c7cp90104f.

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8

Lova, Paola, Paolo Giusto, Francesco Di Stasio, et al. "All-polymer methylammonium lead iodide perovskite microcavities." Nanoscale 11, no. 18 (2019): 8978–83. http://dx.doi.org/10.1039/c9nr01422e.

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9

Handley, C. M., and C. L. Freeman. "A new potential for methylammonium lead iodide." Physical Chemistry Chemical Physics 19, no. 3 (2017): 2313–21. http://dx.doi.org/10.1039/c6cp05829a.

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10

Boix, Pablo P., Shweta Agarwala, Teck Ming Koh, Nripan Mathews, and Subodh G. Mhaisalkar. "Perovskite Solar Cells: Beyond Methylammonium Lead Iodide." Journal of Physical Chemistry Letters 6, no. 5 (2015): 898–907. http://dx.doi.org/10.1021/jz502547f.

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11

Senocrate, Alessandro, Tae-Youl Yang, Giuliano Gregori, Gee Yeong Kim, Michael Grätzel, and Joachim Maier. "Charge carrier chemistry in methylammonium lead iodide." Solid State Ionics 321 (August 2018): 69–74. http://dx.doi.org/10.1016/j.ssi.2018.03.029.

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12

Ong, Khuong P., Teck Wee Goh, Qiang Xu, and Alfred Huan. "Structural Evolution in Methylammonium Lead Iodide CH3NH3PbI3." Journal of Physical Chemistry A 119, no. 44 (2015): 11033–38. http://dx.doi.org/10.1021/acs.jpca.5b09884.

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13

Koza, Jakub A., James C. Hill, Ashley C. Demster, and Jay A. Switzer. "Epitaxial Electrodeposition of Methylammonium Lead Iodide Perovskites." Chemistry of Materials 28, no. 1 (2015): 399–405. http://dx.doi.org/10.1021/acs.chemmater.5b04524.

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14

Hermes, Ilka M., Simon A. Bretschneider, Victor W. Bergmann, et al. "Ferroelastic Fingerprints in Methylammonium Lead Iodide Perovskite." Journal of Physical Chemistry C 120, no. 10 (2016): 5724–31. http://dx.doi.org/10.1021/acs.jpcc.5b11469.

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15

Manukyan, K. V., A. V. Yeghishyan, D. O. Moskovskikh, J. Kapaldo, A. Mintairov, and A. S. Mukasyan. "Mechanochemical synthesis of methylammonium lead iodide perovskite." Journal of Materials Science 51, no. 19 (2016): 9123–30. http://dx.doi.org/10.1007/s10853-016-0165-4.

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16

Mydhili, B., Ancy Albert, and C. O. Sreekala. "Mixed Organic Halide Perovskite Energy Harvester for Solar Cells." Journal of Physics: Conference Series 2426, no. 1 (2023): 012044. http://dx.doi.org/10.1088/1742-6596/2426/1/012044.

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Abstract Organic- inorganic hybrid perovskite shows promising properties such as optical, electrical, and magnetic. To address issues in the standard methylammonium lead iodide perovskite such as toxicity and stability, lead was replaced with Cu in metal ion part and iodine replaced by chlorine in the anionic position. In this work, methyl ammonium copper chloride (MA2CuCl4) and phenyl ethyl ammonium copper chloride (PEA2CuCl4) were synthesised. Optical and structural property variations of solution obtained by mixing MA2CuCl4 and PEA2CuCl4 in 1:1 ratio was studied. Methylammonium lead iodide
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17

Röhm, Holger, Tobias Leonhard, Michael J. Hoffmann, and Alexander Colsmann. "Ferroelectric domains in methylammonium lead iodide perovskite thin-films." Energy & Environmental Science 10, no. 4 (2017): 950–55. http://dx.doi.org/10.1039/c7ee00420f.

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18

Eperon, Giles E., Clara E. Beck, and Henry J. Snaith. "Cation exchange for thin film lead iodide perovskite interconversion." Materials Horizons 3, no. 1 (2016): 63–71. http://dx.doi.org/10.1039/c5mh00170f.

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We demonstrate that we can convert hybrid perovskites between methylammonium lead iodide (MAPbI<sub>3</sub>) and formamidinium lead iodide (FAPbI<sub>3</sub>) by immersion in solutions of MA or FA iodide at room temperature. The cations diffuse uniformly throughout the bulk films, forming an alloy rather than a bi-layer. Furthermore, this demonstrates good organic cation mobility in these materials.
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19

Nagabhushana, G. P., Radha Shivaramaiah, and Alexandra Navrotsky. "Direct calorimetric verification of thermodynamic instability of lead halide hybrid perovskites." Proceedings of the National Academy of Sciences 113, no. 28 (2016): 7717–21. http://dx.doi.org/10.1073/pnas.1607850113.

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Hybrid perovskites, especially methylammonium lead iodide (MAPbI3), exhibit excellent solar power conversion efficiencies. However, their application is plagued by poor chemical and structural stability. Using direct calorimetric measurement of heats of formation, MAPbI3 is shown to be thermodynamically unstable with respect to decomposition to lead iodide and methylammonium iodide, even in the absence of ambient air or light or heat-induced defects, thus limiting its long-term use in devices. The formation enthalpy from binary halide components becomes less favorable in the order MAPbCl3, MAP
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20

Roldán-Carmona, Cristina, Olga Malinkiewicz, Rafael Betancur, et al. "High efficiency single-junction semitransparent perovskite solar cells." Energy Environ. Sci. 7, no. 9 (2014): 2968–73. http://dx.doi.org/10.1039/c4ee01389a.

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21

Hill, James C., Jakub A. Koza, and Jay A. Switzer. "Electrodeposition of Epitaxial Lead Iodide and Conversion to Textured Methylammonium Lead Iodide Perovskite." ACS Applied Materials & Interfaces 7, no. 47 (2015): 26012–16. http://dx.doi.org/10.1021/acsami.5b07222.

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22

Hong, Min Ji, Rose Y. Johnson, and John G. Labram. "Impact of Moisture on Mobility in Methylammonium Lead Iodide and Formamidinium Lead Iodide." Journal of Physical Chemistry Letters 11, no. 13 (2020): 4976–83. http://dx.doi.org/10.1021/acs.jpclett.0c01369.

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23

Barnett, Jeremy L., Vivien L. Cherrette, Connor J. Hutcherson, and Monica C. So. "Effects of Solution-Based Fabrication Conditions on Morphology of Lead Halide Perovskite Thin Film Solar Cells." Advances in Materials Science and Engineering 2016 (2016): 1–12. http://dx.doi.org/10.1155/2016/4126163.

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We present a critical review of the effects of processing conditions on the morphology of methylammonium lead iodide (CH3NH3PbI3) perovskite solar cells. Though difficult to decouple from synthetic and film formation effects, a single morphological feature, specifically grain size, has been evidently linked to the photovoltaic performance of this class of solar cells. Herein, we discuss experimental aspects of optimizing the (a) temperature and time of annealing, (b) spin-coating parameters, and (c) solution temperature of methylammonium iodide (MAI) solution.
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24

Harding, Alexander J., Austin G. Kuba, Brian E. McCandless, et al. "The growth of methylammonium lead iodide perovskites by close space vapor transport." RSC Advances 10, no. 27 (2020): 16125–31. http://dx.doi.org/10.1039/d0ra01640c.

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25

MacDonald, Gordon A., Mengjin Yang, Samuel Berweger, et al. "Methylammonium lead iodide grain boundaries exhibit depth-dependent electrical properties." Energy & Environmental Science 9, no. 12 (2016): 3642–49. http://dx.doi.org/10.1039/c6ee01889k.

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26

Gil-Escrig, Lidón, Giulia Longo, Antonio Pertegás, et al. "Efficient photovoltaic and electroluminescent perovskite devices." Chemical Communications 51, no. 3 (2015): 569–71. http://dx.doi.org/10.1039/c4cc07518h.

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Planar diode structures employing hybrid organic–inorganic methylammonium lead iodide perovskites lead to multifunctional devices exhibiting both a high photovoltaic efficiency and good electroluminescence.
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27

Afzaal, M., B. Salhi, A. Al-Ahmed, H. M. Yates, and A. S. Hakeem. "Surface-related properties of perovskite CH3NH3PbI3 thin films by aerosol-assisted chemical vapour deposition." Journal of Materials Chemistry C 5, no. 33 (2017): 8366–70. http://dx.doi.org/10.1039/c7tc02968c.

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28

Gallet, Thibaut, David Grabowski, Thomas Kirchartz, and Alex Redinger. "Fermi-level pinning in methylammonium lead iodide perovskites." Nanoscale 11, no. 36 (2019): 16828–36. http://dx.doi.org/10.1039/c9nr02643f.

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29

Hong, Min Ji, Scott R. Svadlenak, Konstantinos A. Goulas, and John G. Labram. "Thermal stability of mobility in methylammonium lead iodide." Journal of Physics: Materials 3, no. 1 (2019): 014003. http://dx.doi.org/10.1088/2515-7639/ab442e.

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30

Sajedi Alvar, Mohammad, Manasvi Kumar, Paul W. M. Blom, Gert-Jan A. H. Wetzelaer, and Kamal Asadi. "Absence of ferroelectricity in methylammonium lead iodide perovskite." AIP Advances 7, no. 9 (2017): 095110. http://dx.doi.org/10.1063/1.4994957.

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31

Guo, Haiyan, Peixue Liu, Shichao Zheng, Shixian Zeng, Na Liu, and Seungbum Hong. "Re-entrant relaxor ferroelectricity of methylammonium lead iodide." Current Applied Physics 16, no. 12 (2016): 1603–6. http://dx.doi.org/10.1016/j.cap.2016.09.016.

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32

Yudanova, E. S., T. A. Duda, O. E. Tereshchenko, and O. I. Semenova. "Properties of methylammonium lead iodide perovskite single crystals." Journal of Structural Chemistry 58, no. 8 (2017): 1567–72. http://dx.doi.org/10.1134/s0022476617080133.

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33

Röhm, Holger, Tobias Leonhard, Michael J. Hoffmann, and Alexander Colsmann. "Ferroelectric Poling of Methylammonium Lead Iodide Thin Films." Advanced Functional Materials 30, no. 5 (2019): 1908657. http://dx.doi.org/10.1002/adfm.201908657.

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34

De Souza, Roger A., and Denis Barboni. "Iodide-ion conduction in methylammonium lead iodide perovskite: some extraordinary aspects." Chemical Communications 55, no. 8 (2019): 1108–11. http://dx.doi.org/10.1039/c8cc09236b.

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35

Giorgi, Giacomo, Koichi Yamashita, and Hiroshi Segawa. "First-principles investigation of the Lewis acid–base adduct formation at the methylammonium lead iodide surface." Physical Chemistry Chemical Physics 20, no. 16 (2018): 11183–95. http://dx.doi.org/10.1039/c8cp01019f.

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36

Dachauer, Ralph, Oliver Clemens, Kerstin Lakus‐Wollny, Thomas Mayer, and Wolfram Jaegermann. "Characterization of Methylammonium Lead Iodide Thin Films Fabricated by Exposure of Lead Iodide Layers to Methylammonium Iodide Vapor in a Closed Crucible Transformation Process." physica status solidi (a) 216, no. 11 (2019): 1800894. http://dx.doi.org/10.1002/pssa.201800894.

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37

Sadhu, Subha, Kyler Aqueche, Thierry Buffeteau, Jean-Marc Vincent, Lionel Hirsch, and Dario M. Bassani. "Unexpected surface interactions between fluorocarbons and hybrid organic inorganic perovskites evidenced by PM-IRRAS and their application towards tuning the surface potential." Materials Horizons 6, no. 1 (2019): 192–97. http://dx.doi.org/10.1039/c8mh01119b.

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38

Lai, Wei-Chih, Wen-Ming Hsieh, Huai-Cheng Yu, Siou-Huei Yang, Tzung-Fang Guo, and Peter Chen. "Conversion efficiency enhancement of methylammonium lead triiodide perovskite solar cells converted from thermally deposited lead iodide via thin methylammonium iodide interlayer." Organic Electronics 82 (July 2020): 105713. http://dx.doi.org/10.1016/j.orgel.2020.105713.

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39

Park, Myeongkee, Nikolay Kornienko, Sebastian E. Reyes-Lillo, et al. "Critical Role of Methylammonium Librational Motion in Methylammonium Lead Iodide (CH3NH3PbI3) Perovskite Photochemistry." Nano Letters 17, no. 7 (2017): 4151–57. http://dx.doi.org/10.1021/acs.nanolett.7b00919.

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40

Longo, Giulia, Lidón Gil-Escrig, Maarten J. Degen, Michele Sessolo, and Henk J. Bolink. "Perovskite solar cells prepared by flash evaporation." Chemical Communications 51, no. 34 (2015): 7376–78. http://dx.doi.org/10.1039/c5cc01103e.

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41

Tusiime, Rogers, Fatemeh Zabihi, Mike Tebyetekerwa, et al. "High stress-driven voltages in net-like layer-supported organic–inorganic perovskites." Journal of Materials Chemistry C 8, no. 8 (2020): 2643–58. http://dx.doi.org/10.1039/c9tc05468e.

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42

Misra, Ravi K., Sigalit Aharon, Michael Layani, Shlomo Magdassi, and Lioz Etgar. "A mesoporous–planar hybrid architecture of methylammonium lead iodide perovskite based solar cells." Journal of Materials Chemistry A 4, no. 37 (2016): 14423–29. http://dx.doi.org/10.1039/c6ta06960f.

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We report a hybrid mesoporous–planar architecture of methylammonium lead iodide perovskite based solar cells, to combine the benefits of both the mesoporous and planar architectures in a single device.
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43

Hsieh, Tsung-Yu, Tzu-Chien Wei, Kuan-Lin Wu, Masashi Ikegami, and Tsutomu Miyasaka. "Efficient perovskite solar cells fabricated using an aqueous lead nitrate precursor." Chemical Communications 51, no. 68 (2015): 13294–97. http://dx.doi.org/10.1039/c5cc05298j.

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A novel, aqueous precursor system (Pb(NO<sub>3</sub>)<sub>2</sub> + water) is developed to replace conventional (PbI<sub>2</sub> + DMF) for fabricating methylammonium lead iodide (MAPbI<sub>3</sub>) perovskite solar cells (PSCs).
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44

Achoi, Mohd Faizal Bin, Tetsuo Soga, Shunsuke Aiba, Shinya Kato, and Naoki Kishi. "Effect of Methylammonium Iodide on the All-solution Prepared Methylammonium Bismuth Iodide Perovskite Solar Cells Performance." ASM Science Journal 17 (April 20, 2022): 1–13. http://dx.doi.org/10.32802/asmscj.2022.1099.

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The methylammonium bismuth iodide (MBI), a promising lead (Pb)-free perovskite solar cells (PeSC’s) material, is suitable for photovoltaic applications due to less toxic and good stability. Herein, the effect of MAI (methylammonium iodide) on the structural, morphological, optical properties and solar cells performance of bismuth-perovskite solar cells (Bi-PeSC’s) by all-solution processed multi-step spin coating is investigated. The scanning electron microscope (SEM) morphology visually depicts that with the increase of methylammonium iodide (MAI) precursor molar ratio in bismuth (III) iodide
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45

Meyers, Jonathan K., Lorenzo Y. Serafin, Andre D. Orr, and James F. Cahoon. "Amino-Deliquescence and Amino-Efflorescence of Methylammonium Lead Iodide." Chemistry of Materials 33, no. 10 (2021): 3814–22. http://dx.doi.org/10.1021/acs.chemmater.1c00967.

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46

Ji, Jeoungmin, Farjana Haque, Nhu Thi To Hoang, and Mallory Mativenga. "Ambipolar Transport in Methylammonium Lead Iodide Thin Film Transistors." Crystals 9, no. 10 (2019): 539. http://dx.doi.org/10.3390/cryst9100539.

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We report clear room temperature ambipolar transport in ambient-air processed methylammonium lead iodide (MAPbI3) thin-film transistors (TFTs) with aluminum oxide gate-insulators and indium-zinc-oxide source/drain electrodes. The high ionicity of the MAPbI3 leads to p-type and n-type self-doping, and depending on the applied bias we show that simultaneous or selective transport of electrons and/or holes is possible in a single MAPbI3 TFT. The electron transport (n-type), however, is slightly more pronounced than the hole transport (p-type), and the respective channel resistances range from 5–1
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47

Foley, Benjamin J., Daniel L. Marlowe, Keye Sun, et al. "Temperature dependent energy levels of methylammonium lead iodide perovskite." Applied Physics Letters 106, no. 24 (2015): 243904. http://dx.doi.org/10.1063/1.4922804.

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48

Blaszczyk, Oskar, Lethy Krishnan Jagadamma, Arvydas Ruseckas, Muhammad T. Sajjad, Yiwei Zhang, and Ifor D. W. Samuel. "Interface limited hole extraction from methylammonium lead iodide films." Materials Horizons 7, no. 3 (2020): 943–48. http://dx.doi.org/10.1039/c9mh01517e.

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A new method is proposed to determine charge diffusion coefficient and transfer velocity to extraction layers. Hole diffusion coefficient in MAPbI<sub>3</sub> is constant between 10<sup>16</sup> – 10<sup>17</sup> cm<sup>−3</sup>, a hallmark of band transport but overall extraction is interface limited.
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49

Baumann, A., K. Tvingstedt, M. C. Heiber, et al. "Persistent photovoltage in methylammonium lead iodide perovskite solar cells." APL Materials 2, no. 8 (2014): 081501. http://dx.doi.org/10.1063/1.4885255.

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50

Cai, Lang, Limin She, Helin Qin, Li Xu, and Dingyong Zhong. "Monolayer methylammonium lead iodide films deposited on Au(111)." Surface Science 675 (September 2018): 78–82. http://dx.doi.org/10.1016/j.susc.2018.05.006.

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