Academic literature on the topic 'Micellar catalysi'

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Journal articles on the topic "Micellar catalysi"

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Khan, Mohammad Niyaz, and Ibrahim Isah Fagge. "Kinetics and Mechanism of Cationic Micelle/Flexible Nanoparticle Catalysis: A Review." Progress in Reaction Kinetics and Mechanism 43, no. 1 (2018): 1–20. http://dx.doi.org/10.3184/146867818x15066862094905.

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The aqueous surfactant (Surf) solution at [Surf] > cmc (critical micelle concentration) contains flexible micelles/nanoparticles. These particles form a pseudophase of different shapes and sizes where the medium polarity decreases as the distance increases from the exterior region of the interface of the Surf/H2O particle towards its furthest interior region. Flexible nanoparticles (FNs) catalyse a variety of chemical and biochemical reactions. FN catalysis involves both positive catalysis ( i.e. rate increase) and negative catalysis ( i.e. rate decrease). This article describes the mechani
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Broxton, Trevor J. "Micellar Catalysis of Organic Reactions. XXXVIII A Study of the Catalytic Effect of Micelles of 3-Hydroxymethyl-1-tetradecylpyridinium Bromide on Amide Hydrolysis and Nucleophilic Aromatic Substitution." Australian Journal of Chemistry 51, no. 7 (1998): 541. http://dx.doi.org/10.1071/c98053.

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The preparation of 3-hydroxymethyl-1-tetradecylpyridinium bromide and its use as a catalyst of nucleophilic aromatic substitution and also amide hydrolysis are reported. It was found that the hydroxydehalogenation of nitro-activated aryl halides was much faster in these micelles than in the presence of cetyl(2-hydroxyethyl)dimethylammonium bromide. It was concluded that the increased catalysis of nucleophilic aromatic substitution by this micelle was due to a faster decomposition of the aryl micellar ether which must occur before the phenolate product is released. No such difference in the two
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Cibulka, Radek, Lenka Baxová, Hana Dvořáková, et al. "Catalytic effect of alloxazinium and isoalloxazinium salts on oxidation of sulfides with hydrogen peroxide in micellar media." Collection of Czechoslovak Chemical Communications 74, no. 6 (2009): 973–93. http://dx.doi.org/10.1135/cccc2009030.

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Three novel amphiphilic alloxazinium salts were prepared: 3-dodecyl-5-ethyl-7,8,10-trimethylisoalloxazinium perchlorate (1c), 1-dodecyl-5-ethyl-3-methylalloxazinium perchlorate (2b), and 3-dodecyl-5-ethyl-1-methylalloxazinium perchlorate (2c). Their catalytic activity in thioanisole (3) oxidation with hydrogen peroxide was investigated in micelles of sodium dodecylsulfate (SDS), hexadecyltrimethylammonium nitrate (CTANO3) and Brij 35. Reaction rates were strongly dependent on the catalyst structure, on the type of micelles, and on pH value. Alloxazinium salts 2 were more effective catalysts th
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Drennan, Catherine E., Rachelle J. Hughes, Vincent C. Reinsborough, and Oladega O. Soriyan. "Article." Canadian Journal of Chemistry 76, no. 2 (1998): 152–57. http://dx.doi.org/10.1139/v97-226.

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Kinetic studies through stopped-flow spectroscopy were undertaken in the dilute solution range of anionic surfactants where pronounced rate enhancement or inhibition of Ni2+-ligand complexations is often observed at surfactant concentrations much below the critical micelle concentration (CMC). The results are interpreted in terms of Ni-surfactant micelles as the agents responsible for the rate changes in dilute surfactant solution. At higher surfactant concentrations these micelles are transformed into mixed micelles (counterion and size changes), eventually becoming normal surfactant micelles
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Broxton, TJ, JR Christie, and RPT Chung. "Micellar Catalysis of Organic Reactions. XXVI. SNAr Reactions of Azide Ions." Australian Journal of Chemistry 42, no. 6 (1989): 855. http://dx.doi.org/10.1071/ch9890855.

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The azidodehalogenation of a number of aromatic compounds has been studied in the presence of micelles of cetyltrimethylammonium bromide (ctab). The variation of the observed rate of reaction with ctab concentration has been treated by using the model of Rodenas and Vera to determine the rate constant for reaction in the micellar pseudo-phase, k2m, the binding constant of the substrate to the micelle, Ks, and the nucleophile-micellar counter ion exchange constant KAzBr :. The ratio of the rate constants in the micellar pseudo-phase and in water varied between 0.9 and 52. For reactions involvin
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Steven, Alan. "Micelle-Mediated Chemistry in Water for the Synthesis of Drug Candidates." Synthesis 51, no. 13 (2019): 2632–47. http://dx.doi.org/10.1055/s-0037-1610714.

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Micellar reaction conditions, in a predominantly aqueous medium, have been developed for transformations commonly used by synthetic chemists working in the pharmaceutical industry to discover and develop drug candidates. The reactions covered in this review are the Suzuki–Miyaura, Miyaura borylation, Sonogashira coupling, transition-metal-catalysed CAr–N coupling, SNAr, amidation, and nitro reduction. Pharmaceutically relevant examples of these applications will be used to show how micellar conditions can offer advantages in yield, operational ease, amount of waste generated, transition-metal
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Oranli, Levent, Pratap Bahadur, and Gérard Riess. "Hydrodynamic studies on micellar solutions of styrene–butadiene block copolymers in selective solvents." Canadian Journal of Chemistry 63, no. 10 (1985): 2691–96. http://dx.doi.org/10.1139/v85-447.

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Hydrodynamic radius of micelles of several block copolymers in different selective solvents (for both types of blocks) was determined from photon correlation spectroscopy. The boundaries of micellar solutions in heptane (good solvent for polybutadiene block) and dimethylformamide (good solvent for polystyrene block) were established for polymers in terms of their molecular mass and block composition. The photon correlation spectroscopy data in combination with intrinsic viscosities of block copolymers in selective solvents were used to determine micellar molecular mass and aggregation number.
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Wasylishen, Roderick E., Jan C. T. Kwak, Zhisheng Gao, Elisabeth Verpoorte, J. Bruce MacDonald, and Ross M. Dickson. "NMR studies of hydrocarbons solubilized in aqueous micellar solutions." Canadian Journal of Chemistry 69, no. 5 (1991): 822–33. http://dx.doi.org/10.1139/v91-122.

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Information concerning the solubilization of hydrocarbons in ionic surfactant micelles was obtained from 2H NMR relaxation, 1H NMR chemical shifts, and 1H NMR paramagnetic relaxation measurements. The rotational motion of deuterated hydrocarbons, which is related to the micellar microviscosity at the location of the hydrocarbons, was probed by 2H NMR relaxation. The relaxation data are interpreted using both the two-step and the single-step models, and the results are discussed in terms of the micellar microviscosity and the location of the hydrocarbons in micelles. The location of the hydroca
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KALLOL, K. GHOSH, and K. SAR SANTOSH. "Kinetic Studies of Alkaline Hydrolysis of N-Phenylbenzohydroxamic Acid in the Presence of Micelles." Journal of Indian Chemical Society Vol. 72, Sep 1995 (1995): 597–601. https://doi.org/10.5281/zenodo.5909403.

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School of Studies in Chemistry, Pt. Ravishankar Shukla University. Raipur-492 010 <em>Manuscript received 14 September 1993, revised 4 January 1994, accepted 1 March 1994</em> The alkaline hydrolysis of <em>N</em>-phenylbenzohydroxamic acid has been studied under micellar (<em>k</em><sub>&Psi;</sub>) and nonmicellar (<em>k</em><sub>w</sub>) conditions using cationic (cetyltrimethylammonium bromide, cetylpyridinium chloride), anionic (sodium lauryl sulphate), and non-ionic (Triton X-100) micellar agents. The results are explained by the pseudophase ion-exchange model. Both the cationic and anio
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Gebicka, Lidia, and Monika Jurgas-Grudzinska. "Activity and Stability of Catalase in Nonionic Micellar and Reverse Micellar Systems." Zeitschrift für Naturforschung C 59, no. 11-12 (2004): 887–91. http://dx.doi.org/10.1515/znc-2004-11-1220.

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Catalase activity and stability in the presence of simple micelles of Brij 35 and entrapped in reverse micelles of Brij 30 have been studied. The enzyme retains full activity in aqueous micellar solution of Brij 35. Catalase exhibits “superactivity” in reverse micelles composed of 0.1 ᴍ Brij 30 in dodecane, n-heptane or isooctane, and significantly lowers the activity in decaline. The incorporation of catalase into Brij 30 reverse micelles enhances its stability at 50 °C. However, the stability of catalase incubated at 37 °C in micellar and reverse micellar solutions is lower than that in homo
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Dissertations / Theses on the topic "Micellar catalysi"

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SANZONE, ALESSANDRO. "Towards the development of sustainable materials for organic electronics." Doctoral thesis, Università degli Studi di Milano-Bicocca, 2019. http://hdl.handle.net/10281/241277.

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La sintesi e la caratterizzazione di semiconduttori organici (OS) è stata un ambito di ricerca molto sviluppato negli ultimi due decenni. La loro potenziale applicazione per dispositivi come transistor a effetto di campo organici (OFET), diodi organici a emissione di luce (OLED) e celle fotovoltaiche organiche (OPV), ha scatenato un'intensa attività di ricerca in questo campo. Sulla base dei recenti progressi nella tecnologia dei materiali e dei processi e del previsto sviluppo tecnologico futuro, gli esperti sono stati in grado di identificare le sfide chiave di questa tecnologia, per le qual
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CERIANI, CHIARA. "Organic Materials for (Opto)electronics introducing Sustainability in Design, Synthesis and Manufacturing." Doctoral thesis, Università degli Studi di Milano-Bicocca, 2022. http://hdl.handle.net/10281/369035.

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Il progetto di ricerca si concentra sullo sviluppo di nuove strategie sintetiche per la preparazione di semiconduttori organici stampabili e scalabili industrialmente. A tal fine, è stato introdotto un nuovo metodo sintetico per una facile, economica ed eco-sostenibile produzione di semiconduttori organici coniugati. Oggigiorno, il concetto di sostenibilità è una questione molto importante per le aziende che si impegnano nel rispettare i principi della Green Chemistry al fine di ridurre l'impatto ambientale dei processi chimici. In questo quadro, la catalisi micellare si è dimostrata un'ottima
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Maximiano, Flavio Antonio. "Micelas mistas de surfatantes zwiteriônicos e catiônicos: propriedades físico-químicas e efeito na cinética de reação unimolecular." Universidade de São Paulo, 2003. http://www.teses.usp.br/teses/disponiveis/46/46132/tde-13052008-153348/.

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O interesse por sistemas formados por misturas de surfatantes se deve ao fato destas misturas apresentarem propriedades diferentes, e algumas vezes superiores, às dos surfatantes puros. Neste trabalho foram realizadas, em água e em soluções aquosas de sal, medidas de CMC, constantes de dissociação iônica, concentrações superficiais de contra-íons e entalpias de micelização para misturas de surfatantes zwiteriônicos e catiônicos. Os surfactantes catiônicos utilizados foram: brometo e cloreto de N- hexadecil - N,N,N - trimetil amônio, CTAB(C), e brometo de N- dodecil N,N,N - trimetil amônio, DTA
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Wang, Qiyan. "Design of solid micellar catalysts for sustainable chemistry." Electronic Thesis or Diss., Université de Lille (2018-2021), 2021. http://www.theses.fr/2021LILUR029.

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L'épuisement des ressources fossiles et les préoccupations environnementales croissantes encouragent la production de produits chimiques et de carburants durables à partir des ressources de la biomasse et du CO2. L'objectif fondamental de ce projet de recherche concerne la conception d'un nouveau système de catalyseur micellaire à un seul atome. Les catalyseurs sont classiquement classés en homogènes et hétérogènes. Les catalyseurs homogènes offrent une efficacité élevée, liée à une utilisation maximale des métaux et des sites actifs hautement accessibles, et une sélectivité élevée, en raison
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Chhatre, A. S. "Microemulsion systems and micellar catalysis." Thesis(Ph.D.), CSIR-National Chemical Laboratory, Pune, 1992. http://dspace.ncl.res.in:8080/xmlui/handle/20.500.12252/3049.

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Gonçalves, Larissa Martins. "Um modelo para detoxificação de organofosforados: efeito de micelas e vesículas na oximólise de p-nitrofenildifenilfosfato." Universidade de São Paulo, 2006. http://www.teses.usp.br/teses/disponiveis/46/46131/tde-02022007-171907/.

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Oximas têm sido extensivamente usadas como antídoto para envenenamento por organofosforados e como desontaminante. Micelas e vesículas, utilizadas como catalisadores e transportadores de drogas, constituem agentes potenciais para tratamento e descontaminação. Neste trabalho descrevemos a reação de p-Nitrofenildifenilfosfato (PNPDPP), um substrato modelo para organofosforado, com: acetofenoxima (I); ácido 10- fenil-10-hidroxiiminodecanóico (II); 4-(9-carboxinonanil)-1-(9-carboxi-1-hidroiimino nonanil) benzeno (III); cloreto de N-dodecilpiridina (IV); cloreto N-metilpiridina 2-aldoxima (V), na p
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Diego-Castro, Michael John. "Micellar media and the catalysis of the Diels-Alder reactions." Thesis, University College London (University of London), 1999. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.312963.

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Gwicana, Sakumzi. "Micellar-enhanced ultrafiltration of palladium and platinum anions." Thesis, Nelson Mandela Metropolitan University, 2007. http://hdl.handle.net/10948/518.

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The project was concerned with studying the capability of a micellar-enhanced ultrafiltration system (MEUF) to remove platinum group metal ions namely Pt (lV) and Pd (ll) chloro anions from aqueous industrial waste effluents. South Africa has the world’s largest reserves of platinum group metals (PGMs) and other valuable metals such as manganese, chrome ores, titanium minerals etc. which are required for new automotive and other technologies, including fuel cells, catalytic converters and lighter components. The consistent loss with the industrial waste stream and the toxicological effects of
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Tondo, Daniel Walker. "Síntese e estudos físico-químicos de surfactantes dipolares iônico." reponame:Repositório Institucional da UFSC, 2012. http://repositorio.ufsc.br/xmlui/handle/123456789/94804.

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Tese (doutorado) - Universidade Federal de Santa Catarina, Centro de Ciências Físicas e Matemáticas, Programa de Pós-Graduação em Química, Florianópolis, 2011<br>Made available in DSpace on 2012-10-25T16:27:48Z (GMT). No. of bitstreams: 1 288270.pdf: 3875174 bytes, checksum: 2d983bc7cb93aa663182a095ae25dc76 (MD5)<br>Este trabalho aborda o estudo físico-químico de surfactantes dipolares iônicos ou zwiteriônicos, tendo como foco a investigação da ligação de íons em micelas dipolares iônicas. Inicialmente, é descrito o estudo de interação entre diversos íons e micelas de sulfobetaínas utilizando
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Couderc, Sabine. "Micelles d'oximates hexadecyltrimethylammonium : propriétés et conjonction des catalyses micellaire et supernucléophile pour la destruction par hydrolyse des triesters phosphoriques." Versailles-St Quentin en Yvelines, 1999. http://www.theses.fr/1999VERS0010.

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L' @hydrolyse des triesters phosphoriques est étudiée au plan cinétique dans l'eau et dans les solutions de sels d'hexadecyltrimethylammonium en présence d'ions oximate catalytiques. En l'absence de tensioactif, les ions oximate sont des nucléophiles catalyseurs plus efficaces que d'autres nucléophiles de même basicité. Cela provient de l'effet dénommé effet. Par suite d'un effet de saturation des nucléophiles, l'extra réactivité est maximale pour des ions oximate dont le pk a est proche de 8. Les micelles cationiques accentuent fortement l'effet catalytique par un facteur atteignant 10 3, l'a
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Books on the topic "Micellar catalysi"

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Peebles, Jason A. Alkane oxidations in a micellar/mitalloporphyrin catalytic system. National Library of Canada, 1994.

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R, Hill Aubrey, and Orgel Leslie E, eds. Catalysis of the oligomerization of o-phospho-serine, aspartic acid, or glutamic acid by cationic micelles. National Aeronautics and Space Administration, 1997.

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Khan, Mohammad Niyaz. Micellar Catalysis. Taylor & Francis Group, 2020.

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Khan, Mohammad Niyaz. Micellar Catalysis. Taylor & Francis Group, 2006.

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Khan, Mohammad Niyaz. Micellar Catalysis. Taylor & Francis Group, 2010.

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Khan, Mohammad Niyaz. Micellar Catalysis. Taylor & Francis Group, 2006.

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Micellar catalysis. CRC/Taylor & Francis, 2007.

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Khan, Mohammad Niyaz. Micellar Catalysis (Surfactant Science). CRC, 2006.

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Fendler, Janos. Catalysis in Micellar and Macromoleular Systems. Elsevier Science & Technology Books, 2012.

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Book chapters on the topic "Micellar catalysi"

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Moroi, Yoshikiyo. "Micellar Catalysis." In Micelles. Springer US, 1992. http://dx.doi.org/10.1007/978-1-4899-0700-4_11.

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Nuyken, Oskar, Ralf Weberskirch, Thomas Kotre, Daniel Schönfelder, and Alexander Wörndle. "Polymers for Micellar Catalysis." In Polymeric Materials in Organic Synthesis and Catalysis. Wiley-VCH Verlag GmbH & Co. KGaA, 2005. http://dx.doi.org/10.1002/3527601856.ch6.

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Kondo, Hiroki. "Micellar Catalysis of Pyridoxal-Dependent Reactions." In Biochemistry of Vitamin B6. Birkhäuser Basel, 1987. http://dx.doi.org/10.1007/978-3-0348-9308-4_61.

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Oehme, G., I. Grassert, and N. Flach. "Asymmetric Complex Catalysis in Micellar Systems." In Aqueous Organometallic Chemistry and Catalysis. Springer Netherlands, 1995. http://dx.doi.org/10.1007/978-94-011-0355-8_24.

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Manoury, Eric, Florence Gayet, Franck D’Agosto та ін. "Core-Cross-Linked Micelles and Amphiphilic Nanogels as Unimolecular Nanoreactors for Micellar-Type, Metal-Based Aqueous Biphasic Catalysis". У Effects of Nanoconfinement on Catalysis. Springer International Publishing, 2017. http://dx.doi.org/10.1007/978-3-319-50207-6_7.

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Orlich, Bernhard, and Reinhard Schomäcker. "Enzyme Catalysis in Reverse Micelles." In History and Trends in Bioprocessing and Biotransformation. Springer Berlin Heidelberg, 2002. http://dx.doi.org/10.1007/3-540-44604-4_6.

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Zuev, Yu F., B. Z. Idiyatullin, V. D. Fedotov, A. B. Mirgorodskaya, L. Ya Zakharova, and L. A. Kudryavtseva. "Structural Factors in Micellar Catalysis: NMR Self-Diffusion Study." In Magnetic Resonance in Colloid and Interface Science. Springer Netherlands, 2002. http://dx.doi.org/10.1007/978-94-010-0534-0_68.

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Sirovski, F. S. "Phase-Transfer and Micellar Catalysis in Two-Phase Systems." In ACS Symposium Series. American Chemical Society, 1997. http://dx.doi.org/10.1021/bk-1997-0659.ch006.

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Gaboriaud, R., J. Lelièvre, G. Charbit, and F. Dorion. "Reaction Rate Control by Salt Effects in Micellar Catalysis." In Surfactants in Solution. Springer US, 1986. http://dx.doi.org/10.1007/978-1-4615-7981-6_7.

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Rubingh, Donn N., and Mark Bauer. "Lipase Catalysis of Reactions in Mixed Micelles." In Mixed Surfactant Systems. American Chemical Society, 1992. http://dx.doi.org/10.1021/bk-1992-0501.ch012.

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Conference papers on the topic "Micellar catalysi"

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Daiguji, Hirofumi. "Transport and Adsorption Phenomena in Mesoporous Silica." In ASME 2012 10th International Conference on Nanochannels, Microchannels, and Minichannels collocated with the ASME 2012 Heat Transfer Summer Conference and the ASME 2012 Fluids Engineering Division Summer Meeting. American Society of Mechanical Engineers, 2012. http://dx.doi.org/10.1115/icnmm2012-73137.

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The analysis and control of transport phenomena in fluidic nanopores and nanochannels is important in applications such as biochemical analysis, power generation and environmental protection. A unique aspect of nanofluidics is that the relevant length scale is comparable to the range of various surface and interfacial forces in liquids (such as electrostatic, van der Waals and steric interactions). Thus, to obtain an adequate description of transport phenomena in nanospace, it is necessary to understand the discreteness of molecules, especially when the size decreases to 2 nm. Micelle-template
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Reports on the topic "Micellar catalysi"

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Betty, Rita G., Mark D. Tucker, Gretchen Taggart, et al. Enhanced Micellar Catalysis LDRD. Office of Scientific and Technical Information (OSTI), 2012. http://dx.doi.org/10.2172/1096958.

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Abrevaya, H. Micelle-derived catalysts for extended Schulz-Flory. Office of Scientific and Technical Information (OSTI), 1986. http://dx.doi.org/10.2172/7191954.

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Abrevaya, H. Micelle-derived catalysts for extended Schulz-Flory. Office of Scientific and Technical Information (OSTI), 1985. http://dx.doi.org/10.2172/7191957.

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Abrevaya, H. Micelle-derived catalysts for extended Schulz-Flory. Office of Scientific and Technical Information (OSTI), 1986. http://dx.doi.org/10.2172/7027360.

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Abrevaya, H. Micelle-derived catalysts for extended Schulz-Flory. Office of Scientific and Technical Information (OSTI), 1986. http://dx.doi.org/10.2172/6945672.

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Abrevaya, H. Micelle-derived catalysts for extended Schulz-Flory. Office of Scientific and Technical Information (OSTI), 1986. http://dx.doi.org/10.2172/6995148.

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Abrevaya, H. Micelle-derived catalysts for extended Schulz-Flory. [Quarterly report], January 1, 1986--March 31, 1986. Office of Scientific and Technical Information (OSTI), 1986. http://dx.doi.org/10.2172/10190418.

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Abrevaya, H. Micelle-derived catalysts for extended Schulz-Flory. [Quarterly report], April 1, 1986--June 30, 1986. Office of Scientific and Technical Information (OSTI), 1986. http://dx.doi.org/10.2172/10190434.

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Author, Not Given. Micelle-derived catalysts for extended Schulz-Flory. Technical progress report, April 1, 1985--June 30, 1985. Office of Scientific and Technical Information (OSTI), 1985. http://dx.doi.org/10.2172/10190247.

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Abrevaya, H. Micelle-derived catalysts for extended Schulz-Flory. Technical progress report, October 1, 1985--12/31/85. Office of Scientific and Technical Information (OSTI), 1985. http://dx.doi.org/10.2172/10190436.

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