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Journal articles on the topic 'Micro-porous Metal Organic frameworks'

Author: Grafiati

Published: 5 June 2025

Last updated: 2 August 2025

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1

Bradshaw, Darren, Samir El-Hankari, and Lucia Lupica-Spagnolo. "Supramolecular templating of hierarchically porous metal–organic frameworks." Chem. Soc. Rev. 43, no. 16 (2014): 5431–43. http://dx.doi.org/10.1039/c4cs00127c.

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2

Casas-Solvas, Juan M., and Antonio Vargas-Berenguel. "Porous Metal–Organic Framework Nanoparticles." Nanomaterials 12, no. 3 (2022): 527. http://dx.doi.org/10.3390/nano12030527.

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3

Hezekiah, Cherop, and Kanule Jason. "Thermodynamic Parameters for Hydrogen Storage in Metal Organic Frameworks." European Jornal of Theoretical and Sciences 1, no. 5 (2023): 615–21. https://doi.org/10.59324/ejtas.2023.1(5).51.

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The global energy crisis coupled with the rising demand to decarbonize the planet, has escalated research on alternative clean energy in the changing energy mix. Owing to the abundant availability and natural inexhaustibility of hydrogen in nature, the green hydrogen has turned out to be a promising and attractive energy carrier in cars and other mobile applications. However, hydrogen production still faces challenges on storage, distribution and usage. Microporous metal-organic frameworks have become the most promising materials for hydrogen storage since they have high surface areas and chem

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4

Song, Yonghai, Xia Li, Lanlan Sun, and Li Wang. "Metal/metal oxide nanostructures derived from metal–organic frameworks." RSC Advances 5, no. 10 (2015): 7267–79. http://dx.doi.org/10.1039/c4ra12273a.

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MOFs-derived micro/nanostructures have important potential applications. In this review, we describe the use of MOFs as templates in the synthesis of metal/metal oxide micro/nanostructures and composite materials. The applications of the derived materials are also reviewed.

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5

Barbour, Len. "Dynamics of porous metal-organic frameworks." Acta Crystallographica Section A Foundations and Advances 71, a1 (2015): s128. http://dx.doi.org/10.1107/s2053273315098149.

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6

Sun, Lei, Michael G. Campbell, and Mircea Dincă. "Electrically Conductive Porous Metal-Organic Frameworks." Angewandte Chemie International Edition 55, no. 11 (2016): 3566–79. http://dx.doi.org/10.1002/anie.201506219.

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7

Jia, Miaomiao, Lei Mai, Zhanjun Li, and Wanbin Li. "Air-thermal processing of hierarchically porous metal–organic frameworks." Nanoscale 12, no. 26 (2020): 14171–79. http://dx.doi.org/10.1039/d0nr02899a.

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An air-thermal processing strategy is developed to remove residual solvents and uncoordinated linkers for redesigning metal–organic frameworks with improved adsorption proprieties and hierarchically micro/meso/macroporous superstructures.

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8

Belver, Carolina, and Jorge Bedia. "Metal Organic Frameworks for Advanced Applications." Catalysts 11, no. 5 (2021): 648. http://dx.doi.org/10.3390/catal11050648.

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9

Bavykina, Anastasiya, Amandine Cadiau, and Jorge Gascon. "Porous liquids based on porous cages, metal organic frameworks and metal organic polyhedra." Coordination Chemistry Reviews 386 (May 2019): 85–95. http://dx.doi.org/10.1016/j.ccr.2019.01.015.

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10

He, Yabing, Wei Zhou, Guodong Qian, and Banglin Chen. "Methane storage in metal–organic frameworks." Chem. Soc. Rev. 43, no. 16 (2014): 5657–78. http://dx.doi.org/10.1039/c4cs00032c.

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11

Ricco, Raffaele, Constance Pfeiffer, Kenji Sumida, et al. "Emerging applications of metal–organic frameworks." CrystEngComm 18, no. 35 (2016): 6532–42. http://dx.doi.org/10.1039/c6ce01030j.

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12

Li, Ying, Hua Xu, Shuxin Ouyang, and Jinhua Ye. "Metal–organic frameworks for photocatalysis." Physical Chemistry Chemical Physics 18, no. 11 (2016): 7563–72. http://dx.doi.org/10.1039/c5cp05885f.

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Metal–organic frameworks (MOFs) have emerged as novel photocatalysts owing to their inherent structural characteristics of a large surface area and a well-ordered porous structure. In this article, we summarize various strategies carried out over MOFs via either modification of the organic linker/metal clusters or incorporation with metal/complex catalysts to enhance the light absorption, charge separation, reactant adsorption/activation of MOF-based photocatalysis towards the superior photocatalytic performance.

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13

Kim, Hyunwoo, Nayeong Kim, and Jungki Ryu. "Porous framework-based hybrid materials for solar-to-chemical energy conversion: from powder photocatalysts to photoelectrodes." Inorganic Chemistry Frontiers 8, no. 17 (2021): 4107–48. http://dx.doi.org/10.1039/d1qi00543j.

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14

Maji, Tapas Kumar, and Susumu Kitagawa. "Chemistry of porous coordination polymers." Pure and Applied Chemistry 79, no. 12 (2007): 2155–77. http://dx.doi.org/10.1351/pac200779122155.

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Remarkable advances in the recent development of porous compounds based upon coordination polymers have paved the way toward functional chemistry having potential applications such as gas storage, separation, and catalysis. From the synthetic point of view, the advantage is a designable framework, which can readily be constructed from building blocks, the so-called bottom-up assembly. Compared with conventional porous materials such as zeolites and activated carbons, porous inorganic-organic hybrid frameworks have higher potential for adsorption of small molecules because of their designabilit

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15

Redfern, Louis R., and Omar K. Farha. "Mechanical properties of metal–organic frameworks." Chemical Science 10, no. 46 (2019): 10666–79. http://dx.doi.org/10.1039/c9sc04249k.

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16

Zhu, Jie, Laura Samperisi, Mark Kalaj, et al. "Metal-hydrogen-pi-bonded organic frameworks." Dalton Transactions 51, no. 5 (2022): 1927–35. http://dx.doi.org/10.1039/d1dt04278e.

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We report the synthesis and characterization of a new series of permanently porous, three-dimensional metal–organic frameworks (MOFs), M-HAF-2 (M = Fe, Ga, or In), constructed from tetratopic, hydroxamate-based, chelating linkers.

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17

Chen, Yao, and Shengqian Ma. "Microporous lanthanide metal-organic frameworks." Reviews in Inorganic Chemistry 32, no. 2-4 (2012): 81–100. http://dx.doi.org/10.1515/revic-2012-0003.

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AbstractMicroporous metal-organic frameworks (MOFs) based on lanthanide metal ions or clusters represent a group of porous materials, featuring interesting coordination, electronic, and optical properties. These attractive properties in combination with the porosity make microporous lanthanide MOFs (Ln-MOFs) hold the promise for various applications. This review is to provide an overview of the current status of the research in microporous Ln-MOFs, and highlight their potential as types of multifunctional materials for applications in gas/solvent adsorption and separation, luminescence and che

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18

Oliver, Clive. "Porous metal-organic frameworks incorporating mixed ligands." Acta Crystallographica Section A Foundations and Advances 70, a1 (2014): C1476. http://dx.doi.org/10.1107/s2053273314085234.

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Metal-organic frameworks (MOFs), infinite systems built up of metal ions and organic ligands have been extensively studied in materials and supramolecular chemistry due their structural diversity and application as porous materials, in catalysis, ion exchange, gas storage and purification. [1] A novel, 2-fold interpenetrated, pillared, cadmium metal-organic framework was synthesized using trimesic acid and 1,2-bis(4-pyridyl)ethane.[2] Single crystal X-ray analysis revealed a 2-fold interpenetrated, 3-dimensional framework which exhibits a 3,5-connected network with the Schläfli symbol of [(6^3

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19

Li, Jun-Hong, Yi-Sen Wang, Yu-Chuan Chen, and Chung-Wei Kung. "Metal–Organic Frameworks Toward Electrocatalytic Applications." Applied Sciences 9, no. 12 (2019): 2427. http://dx.doi.org/10.3390/app9122427.

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Metal–organic frameworks (MOFs) are a class of porous materials constructed from metal-rich inorganic nodes and organic linkers. Because of their regular porosity in microporous or mesoporous scale and periodic intra-framework functionality, three-dimensional array of high-density and well-separated active sites can be built in various MOFs; such characteristics render MOFs attractive porous supports for a range of catalytic applications. Furthermore, the electrochemically addressable thin films of such MOF materials are reasonably considered as attractive candidates for electrocatalysis and r

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20

He, Yabing, Fengli Chen, Bin Li, Guodong Qian, Wei Zhou, and Banglin Chen. "Porous metal–organic frameworks for fuel storage." Coordination Chemistry Reviews 373 (October 2018): 167–98. http://dx.doi.org/10.1016/j.ccr.2017.10.002.

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21

Ozturk, Zeynel, Dursun Ali Kose, Zarife Sibel Sahin, Goksel Ozkan, and Abdurrahman Asan. "Novel 2D micro-porous Metal-Organic Framework for hydrogen storage." International Journal of Hydrogen Energy 41, no. 28 (2016): 12167–74. http://dx.doi.org/10.1016/j.ijhydene.2016.05.170.

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22

Jayaramulu, Kolleboyina, Florian Geyer, Andreas Schneemann, et al. "Hydrophobic Metal–Organic Frameworks." Adv. Mater. 31 (June 3, 2019): 1900820. https://doi.org/10.1002/adma.201900820.

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Metal–organic frameworks (MOFs) have diverse potential applications in catalysis, gas storage, separation, and drug delivery because of their nanoscale periodicity, permanent porosity, channel functionalization, and structural diversity. Despite these promising properties, the inherent structural features of even some of the best-performing MOFs make them moisture-sensitive and unstable in aqueous media, limiting their practical usefulness. This problem could be overcome by developing stable hydrophobic MOFs whose chemical composition is tuned to ensure that their metal–ligand bond

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23

Thaggard, Grace, Kyoung Chul Park, and Natalia Shustova. "(Invited) Stimuli-Responsive Metal-Organic Frameworks." ECS Meeting Abstracts MA2023-01, no. 37 (2023): 2165. http://dx.doi.org/10.1149/ma2023-01372165mtgabs.

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Development of stimuli-responsive materials is crucial for the next advancements in the technology and energy sectors. For instance, reversible tuning photophysical profiles of materials or modulation of energy transfer processes are key aspects for the development of next generation of logic gates, spatially- and temporally-resolved sensors, and on-demand drug delivery systems. Our recent efforts have focused on employment of metal-organic frameworks (MOFs) as a versatile platform for the material development, which contain photochromic moieties, allowing for tailoring MOF electronic and phot

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24

Ma, Shengqian. "Gas adsorption applications of porous metal–organic frameworks." Pure and Applied Chemistry 81, no. 12 (2009): 2235–51. http://dx.doi.org/10.1351/pac-con-09-07-09.

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Porous metal–organic frameworks (MOFs) represent a new type of functional materials and have recently become a hot research field due to their great potential in various applications. In this review, recent progress of gas adsorption applications of porous MOFs, mainly including hydrogen storage, methane storage, and selective gas adsorption will be briefly summarized.

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25

Administrator, Open Journal Systems TPU. "METAL-ORGANIC FRAMEWORKS APPLIED FOR WATER PURIFICATION." Resource-Efficient Technologies, no. 1 (March 14, 2018): 1–16. http://dx.doi.org/10.18799/24056537/2018/1/177.

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Metal-organic frameworks (MOFs) which are materials constructed from metal ions/clusters bridged with organic linkers have emerged as an important family of porous materials for widely varying applications. The purification of water polluted with both of organic and inorganic contaminants is a potentially promising application of MOFs since the chemical and thermal properties of the porous materials are easily tunable, e.g. ligand modification, different metal, etc. The demonstration of alignment and the obtained insights facilitate the direction of designing ideal MOF materials with improved

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26

Chaemchuen, Somboon, Ji Chao Wang, Ali G. Gilani, and Francis Verpoort Francis. "METAL-ORGANIC FRAMEWORKS APPLIED FOR WATER PURIFICATION." Resource-Efficient Technologies, no. 1 (March 14, 2018): 1–16. http://dx.doi.org/10.18799/24056529/2018/1/177.

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Metal-organic frameworks (MOFs) which are materials constructed from metal ions/clusters bridged with organic linkers have emerged as an important family of porous materials for widely varying applications. The purification of water polluted with both of organic and inorganic contaminants is a potentially promising application of MOFs since the chemical and thermal properties of the porous materials are easily tunable, e.g. ligand modification, different metal, etc. The demonstration of alignment and the obtained insights facilitate the direction of designing ideal MOF materials with improved

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27

Nyakuchena, James, and Jier Huang. "(Invited) Exploring Metal Organic Frameworks Intrinsic Photocatalytic Materials." ECS Meeting Abstracts MA2023-01, no. 37 (2023): 2167. http://dx.doi.org/10.1149/ma2023-01372167mtgabs.

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Porous crystalline materials such as metal organic frameworks (MOFs) represent a novel class of materials for catalysis due to their inherent porous nature, exceptional thermal and chemical stability, structural flexibility. While many photocatalytic systems based on these materials have been developed in the past decade, a significant gap exists in our understanding of the correlation of photophysical and photocatalytic properties of MOFs with their structure, which hinders accurate prediction and informed design. We aim to address this challenge using an interdisciplinary approach that combi

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28

Seidi, Farzad, Maryam Jouyandeh, Mohsen Taghizadeh, et al. "Metal-Organic Framework (MOF)/Epoxy Coatings: A Review." Materials 13, no. 12 (2020): 2881. http://dx.doi.org/10.3390/ma13122881.

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Epoxy coatings are developing fast in order to meet the requirements of advanced materials and systems. Progress in nanomaterial science and technology has opened a new era of engineering for tailoring the bulk and surface properties of organic coatings, e.g., adhesion to the substrate, anti-corrosion, mechanical, flame-retardant, and self-healing characteristics. Metal-organic frameworks (MOFs), a subclass of coordinative polymers with porous microstructures, have been widely synthesized in recent years and applied in gas and energy storage, separation, sensing, environmental science and tech

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29

Zhang, Wanxia, Ruting Huang, Liyan Song, and Xianyang Shi. "Cobalt-based metal–organic frameworks for the photocatalytic reduction of carbon dioxide." Nanoscale 13, no. 20 (2021): 9075–90. http://dx.doi.org/10.1039/d1nr00617g.

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30

Fu, Hongru, Yuying Jiang, Fei Wang, and Jian Zhang. "The Synthesis and Properties of TIPA-Dominated Porous Metal-Organic Frameworks." Nanomaterials 11, no. 11 (2021): 2791. http://dx.doi.org/10.3390/nano11112791.

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Metal-Organic Frameworks (MOFs) as a class of crystalline materials are constructed using metal nodes and organic spacers. Polydentate N-donor ligands play a mainstay-type role in the construction of metal−organic frameworks, especially cationic MOFs. Highly stable cationic MOFs with high porosity and open channels exhibit distinct advantages, they can act as a powerful ion exchange platform for the capture of toxic heavy-metal oxoanions through a Single-Crystal to Single-Crystal (SC-SC) pattern. Porous luminescent MOFs can act as nano-sized containers to encapsulate guest emitters and constru

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31

RANA, ABHINANDAN. "A Review on Metal-Organic Frameworks: Synthesis and Applications." Asian Journal of Chemistry 33, no. 2 (2021): 245–52. http://dx.doi.org/10.14233/ajchem.2021.23057.

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Metal-organic frameworks (MOFs) are inorganic-organic hybrid porous materials that are composed of positively charged metal ions and organic linkers. The metal ions form nodes that connect the arms of the linkers together to form one-, two-, or three-dimensional structures. Due to this void structure, MOFs have an unusually large internal surface area. They have received enormous interest in recent years particularly as newly developed porous materials. They possess a wide range of potential applications like gas storage, catalysis, sensors, drug delivery, adsorption, etc. In present review ar

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32

Wen, Xinxin, Lili Lin, and Siwei Li. "Current Trends in MOF (Metal-Organic Framework) and Metal X-ides." International Journal of Molecular Sciences 24, no. 13 (2023): 11188. http://dx.doi.org/10.3390/ijms241311188.

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Metal–organic frameworks (MOFs) are a class of porous two- or three-dimensional infinite structure materials consisting of metal ions or clusters and organic linkers, which are connected via coordination bonds [...]

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33

Saeb, Mohammad Reza, Navid Rabiee, Masoud Mozafari, and Ebrahim Mostafavi. "Metal-Organic Frameworks (MOFs)-Based Nanomaterials for Drug Delivery." Materials 14, no. 13 (2021): 3652. http://dx.doi.org/10.3390/ma14133652.

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The composition and topology of metal-organic frameworks (MOFs) are exceptionally tailorable; moreover, they are extremely porous and represent an excellent Brunauer–Emmett–Teller (BET) surface area (≈3000–6000 m2·g−1). Nanoscale MOFs (NMOFs), as cargo nanocarriers, have increasingly attracted the attention of scientists and biotechnologists during the past decade, in parallel with the evolution in the use of porous nanomaterials in biomedicine. Compared to other nanoparticle-based delivery systems, such as porous nanosilica, nanomicelles, and dendrimer-encapsulated nanoparticles, NMOFs are mo

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34

Khan, Mohammad Mansoob, Ashmalina Rahman, and Shaidatul Najihah Matussin. "Recent Progress of Metal-Organic Frameworks and Metal-Organic Frameworks-Based Heterostructures as Photocatalysts." Nanomaterials 12, no. 16 (2022): 2820. http://dx.doi.org/10.3390/nano12162820.

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In the field of photocatalysis, metal-organic frameworks (MOFs) have drawn a lot of attention. MOFs have a number of advantages over conventional semiconductors, including high specific surface area, large number of active sites, and an easily tunable porous structure. In this perspective review, different synthesis methods used to prepare MOFs and MOFs-based heterostructures have been discussed. Apart from this, the application of MOFs and MOFs-based heterostructures as photocatalysts for photocatalytic degradation of different types of pollutants have been compiled. This paper also highlight

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35

Sapchenko, Sergey A., Danil N. Dybtsev, and Vladimir P. Fedin. "Cage amines in the metal–organic frameworks chemistry." Pure and Applied Chemistry 89, no. 8 (2017): 1049–64. http://dx.doi.org/10.1515/pac-2016-1206.

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AbstractNitrogen-rich porous materials have outstanding gas sorption and separation capacity. Using cage amines in the synthesis of metal–organic frameworks is a simple approach for generating the free nitrogen donor centers within the channels of porous materials without the post-synthetic modification. 1,4-Diazabicyclo[2.2.2]octane has a linear arrangement of nitrogen centers and can be used as a linear linker for the design of porous MOF materials. Urotropine has four nitrogen atoms and can act as a tetrahedral four-connected, pyramidal three-connected or bent two-connected linker. Such a d

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36

Horcajada, Patricia. "Porous metal-organic frameworks: from synthesis to applications." Acta Crystallographica Section A Foundations of Crystallography 65, a1 (2009): s100. http://dx.doi.org/10.1107/s0108767309098067.

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37

Butler, Keith T., Christopher H. Hendon, and Aron Walsh. "Electronic Chemical Potentials of Porous Metal–Organic Frameworks." Journal of the American Chemical Society 136, no. 7 (2014): 2703–6. http://dx.doi.org/10.1021/ja4110073.

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38

UEMURA, Takashi. "Precision Polymer Synthesis in Porous Metal-Organic Frameworks." KOBUNSHI RONBUNSHU 72, no. 5 (2015): 191–98. http://dx.doi.org/10.1295/koron.2014-0080.

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39

Lin, Wenbin. "Homochiral porous metal-organic frameworks: Why and how?" Journal of Solid State Chemistry 178, no. 8 (2005): 2486–90. http://dx.doi.org/10.1016/j.jssc.2005.06.013.

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40

Zhao, Min, Sha Ou, and Chuan-De Wu. "Porous Metal–Organic Frameworks for Heterogeneous Biomimetic Catalysis." Accounts of Chemical Research 47, no. 4 (2014): 1199–207. http://dx.doi.org/10.1021/ar400265x.

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41

Yamada, Teppei, Shoji Iwakiri, Takafumi Hara, Katsuhiko Kanaizuka, Mohamedally Kurmoo, and Hiroshi Kitagawa. "Porous Interpenetrating Metal−Organic Frameworks with Hierarchical Nodes." Crystal Growth & Design 11, no. 5 (2011): 1798–806. http://dx.doi.org/10.1021/cg1017278.

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42

Lin, Wenbin. "Asymmetric Catalysis with Chiral Porous Metal–Organic Frameworks." Topics in Catalysis 53, no. 13-14 (2010): 869–75. http://dx.doi.org/10.1007/s11244-010-9519-3.

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43

Clearfield, Abraham. "Unconventional metal organic frameworks: porous cross-linked phosphonates." Dalton Transactions, no. 44 (2008): 6089. http://dx.doi.org/10.1039/b807676f.

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Serre, Christian. "Superhydrophobicity in Highly Fluorinated Porous Metal-Organic Frameworks." Angewandte Chemie International Edition 51, no. 25 (2012): 6048–50. http://dx.doi.org/10.1002/anie.201201440.

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45

Costa Gomes, Margarida, Laure Pison, Ctirad Červinka, and Agilio Padua. "Porous Ionic Liquids or Liquid Metal-Organic Frameworks?" Angewandte Chemie 130, no. 37 (2018): 12085–88. http://dx.doi.org/10.1002/ange.201805495.

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Costa Gomes, Margarida, Laure Pison, Ctirad Červinka, and Agilio Padua. "Porous Ionic Liquids or Liquid Metal-Organic Frameworks?" Angewandte Chemie International Edition 57, no. 37 (2018): 11909–12. http://dx.doi.org/10.1002/anie.201805495.

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47

Gao, Xiang, Wen-Hui Yan, Bo-Yang Hu, Yu-Xin Huang, and Shi-Mei Zheng. "Porous Metal–Organic Frameworks for Light Hydrocarbon Separation." Molecules 28, no. 17 (2023): 6337. http://dx.doi.org/10.3390/molecules28176337.

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The separation of light hydrocarbon compounds is an important process in the chemical industry. Currently, its separation methods mainly include distillation, membrane separation, and physical adsorption. However, these traditional methods or materials have some drawbacks and disadvantages, such as expensive equipment costs and high energy consumption, poor selectivity, low separation ratios, and separation efficiencies. Therefore, it is important to develop novel separation materials for light hydrocarbon separation. As a new type of organic–inorganic hybrid crystalline material, metal–organi

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48

Britt, David, Chain Lee, Fernando J. Uribe-Romo, Hiroyasu Furukawa, and Omar M. Yaghi. "Ring-Opening Reactions within Porous Metal−Organic Frameworks." Inorganic Chemistry 49, no. 14 (2010): 6387–89. http://dx.doi.org/10.1021/ic100652x.

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49

Ma, Shengqian, and Le Meng. "Energy-related applications of functional porous metal–organic frameworks." Pure and Applied Chemistry 83, no. 1 (2010): 167–88. http://dx.doi.org/10.1351/pac-con-10-09-20.

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As a new type of functional materials, porous metal–organic frameworks (MOFs) have experienced tremendous development in the past decade. Their amenability to design, together with the functionalizable nanospace inside their frameworks, has afforded them great potential for various applications. In this review, we provide a brief summary of the current status of porous MOFs in energy-related applications, mainly, energy gas storage, CO2 capture, gas separation, catalysis, and fuel cells.

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50

Bachinin, Semyon, Venera Gilemkhanova, Maria Timofeeva, Yuliya Kenzhebayeva, Andrei Yankin, and Valentin A. Milichko. "Metal-Organic Frameworks for Metal-Ion Batteries: Towards Scalability." Chimica Techno Acta 8, no. 3 (2021): 20210304. http://dx.doi.org/10.15826/chimtech.2021.8.3.04.

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Metal-organic frameworks (MOFs), being a family of highly crystalline and porous materials, have attracted particular attention in material science due to their unprecedented chemical and structural tunability. Next to their application in gas adsorption, separation, and storage, MOFs also can be utilized for energy transfer and storage in batteries and supercapacitors. Based on recent studies, this review describes the latest developments about MOFs as structural elements of metal-ion battery with a focus on their industry-oriented and large-scale production.

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