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1

Shyshkin, A., and D. Brovko. "HIGH-REACTIVE POWDER CONCRETE ON THE BASIS OF ORGANIC NANOMODIFIKATOROV." Slovak international scientific journal, no. 67 (September 8, 2022): 3–6. https://doi.org/10.5281/zenodo.7059525.

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The results of studies of the properties of concrete, which are a composition of Portland cement, fine aggregate and mineral-organic complex, intended for creation of special constructions. It has been shown that the use of the organic component of the mineral-organic complex micelle-forming surfactants or polyols leads to consolidate the inner surfaces of pores which are formed in the concrete, which leads to an increase in the strength of concrete. It is proved that the most efficient use of the mineral as the mineral component of complex organic compounds containing the so-called d-elements
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2

Wang, Ji Hong, Yang Wang, Zhi Dan Zhang, Mei Lan Li, and Lian Sheng Du. "Studies on Organic Carbon Distribution Characteristics of Organic- Mineral Complex in Sediment of Yitong River." Advanced Materials Research 634-638 (January 2013): 117–21. http://dx.doi.org/10.4028/www.scientific.net/amr.634-638.117.

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The sediment in the parts of Yitong river, located at the central of Jilin province, was taken as the research object, and the organic-mineral complex of soil samples was grouped by the improved colloid grouping method described by Qiulin. The distribution characteristics of the organic carbon in sediment organic-mineral complex were studied. The results showed that the organic carbon absolute contents in different groups were G2>G1>G0 group in <10μm and <2μm sediment organic-mineral complexes. The absolute content of organic carbon in G2 group was the highest, but G1 group had the
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3

Makhinov, A. N., A. F. Makhinova, and Sh Liu. "Impact assessment of solid runoff on heavy metals migration during high floods on the Amur river." IOP Conference Series: Earth and Environmental Science 895, no. 1 (2021): 012025. http://dx.doi.org/10.1088/1755-1315/895/1/012025.

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Abstract Inhomogeneity of the concentrations of chemical elements in the cross-section of the Amur River is considered as a function of the state of their soluble and suspended forms. Flooding of wetlands and urbanized areas contributes to the removal of pollutants into the river channel. The wide spread of fens on the left bank contributes to the concentration of organic matter along the left bank of the river. Terrigenous material mostly comes from the right bank, where agricultural fields are concentrated. The ratio of their concentrations is maintained by the duration of the flood. The mec
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4

Liang, Ni, Di Zhang, and Min Wu. "Adsorption of Phenanthrene and Bisphenol A on Organo-Nano Iron Oxide Complexes." Advanced Materials Research 864-867 (December 2013): 1793–97. http://dx.doi.org/10.4028/www.scientific.net/amr.864-867.1793.

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Organo-mineral complexes are important in regulating the transport and retention of hydrophobic organic contaminants in soils/sediments. Humic acid will be fractionated during adsorption on mineral. This study examined the sorption of model compounds with different properties (tannin acid, gallic acid, fumaric acid sodium and sodium oleate) on nanoiron oxide minerals and determined the sorption of phenanthrene and Bisphenol A on these organooxide complexes. The results showed that the sorption of model compounds on nanoFe2O3 followed the order of O > T > G> F. The higher adsorption of
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5

Wei, Chao Xian, and Ni Liang. "Sorption of Phenanthrene by Dissolved Organic Matters and their Complex with Iron Oxide Nanoparticles." Advanced Materials Research 1073-1076 (December 2014): 489–94. http://dx.doi.org/10.4028/www.scientific.net/amr.1073-1076.489.

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The environmental behavior of polycyclic aromatic hydrocarbons (PAHs) has attracted great research attention. However, their sorption mechanisms in organo-mineral complexes are still not specific enough. Batch sorption experiments with humic acid (HA) were carried out with iron oxide and their complexes adsorption phenanthrene (PHE) to determine the adsorption characteristics and mechanisms in this study. These results showed that the weakly polar and aromatic fractions of DOM preferentially adsorbed on the surface of iron oxide minerals. The organic matter (OM) binding on the surface of iron
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6

Huskić, Igor, and Tomislav Friščić. "Understanding geology through crystal engineering: coordination complexes, coordination polymers and metal–organic frameworks as minerals." Acta Crystallographica Section B Structural Science, Crystal Engineering and Materials 74, no. 6 (2018): 539–59. http://dx.doi.org/10.1107/s2052520618014762.

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Recent structural studies of organic minerals, coupled with the intense search for new carbon-containing mineral species, have revealed naturally occurring structures analogous to those of advanced materials, such as coordination polymers and even open metal–organic frameworks exhibiting nanometre-sized channels. While classifying such `non-conventional' minerals represents a challenge to usual mineral definitions, which focus largely on inorganic structures, this overview highlights the striking similarity of organic minerals to artificial organic and metal–organic materials, and shows how th
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7

Axelson, David E., Randy J. Mikula, and Zenon M. Potoczny. "CHARACTERIZATION OF OIL SANDS MINERAL COMPONENTS AND CLAY-ORGANIC COMPLEXES." Fuel Science and Technology International 7, no. 5-6 (1989): 659–73. http://dx.doi.org/10.1080/08843758908962263.

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8

Lopatin, V. N., N. V. Shepelevich, and I. V. Prostakova. "Modelling optical properties of organic–mineral complexes in water ecosystems." Journal of Physics D: Applied Physics 38, no. 15 (2005): 2556–63. http://dx.doi.org/10.1088/0022-3727/38/15/005.

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9

Bansal, O. P. "Adsorption and desorption of three carbamate pesticides by illite, kaolinite and humic acid-clay complexes." JOURNAL OF ADVANCES IN CHEMISTRY 10, no. 4 (2014): 2585–91. http://dx.doi.org/10.24297/jac.v10i4.896.

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In soils organic matter and clay minerals are often so associated that it is not clear that how the presence of organic matter influences the sorptive process of clay minerals. So, in order to factor and quantify component contributions of mineral fractions and humic acid phase to the sorption of pesticides on clay minerals, adsorption and desorption of three carbamate pesticides oxamyl (I), S-Ethyl-N-(methyl carbamoyl)-oxythio acetimidate (II) and N-Phenyl (ethyl cabamoyl) propylcarbamate (III) by Na+, Ca2+ saturated illite, kaolinite and humic acid-clay complexes were investigated by batch e
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10

Joo, Jin Chul, Charles D. Shackelford, and Kenneth F. Reardon. "Sorption of Neutral Organic Compounds in Mixtures to Mineral Surfaces and Humic Acid-Mineral Complexes." Journal of Hazardous, Toxic, and Radioactive Waste 15, no. 3 (2011): 188–98. http://dx.doi.org/10.1061/(asce)hz.1944-8376.0000070.

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11

Fedotov, P. S., R. Kh Dzhenloda, A. A. Drozdov, and V. K. Karandashev. "METAL-ORGANIC COMPLEXES IN ENVIRONMENTAL SOLID SAMPLES: ON THE SELECTIVITY OF PYROPHOSPHATE EXTRACTION." Industrial laboratory. Diagnostics of materials 85, no. 6 (2019): 5–10. http://dx.doi.org/10.26896/1028-6861-2019-85-6-5-10.

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Sequential extraction procedures (SEP) have been widely used for the fractionation of trace elements in soils according to their physicochemical mobility and bioaccessibility. Potassium/sodium pyrophosphate in alkaline medium may be considered as the most appropriate extracting reagent for the recovery of amorphous metal-organic complexes, which play a very important role in biological, physical, and chemical processes in soil. However, the selectivity of pyrophosphate has been poorly studied. In the present work the ability of pyrophosphate to attack mineral inorganic phases of environmental
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12

Mikula, R. J., D. E. Axelson, and D. Sheeran. "MINERAL MATTER AND CLAY-ORGANIC COMPLEXES IN OIL SANDS EXTRACTION PROCESSES." Petroleum Science and Technology 11, no. 12 (1993): 1695–729. http://dx.doi.org/10.1080/08843759308916155.

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13

Lin, Yun, Paul Munroe, Stephen Joseph, and Rita Henderson. "Migration of dissolved organic carbon in biochars and biochar-mineral complexes." Pesquisa Agropecuária Brasileira 47, no. 5 (2012): 677–86. http://dx.doi.org/10.1590/s0100-204x2012000500007.

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The objective of this work was to determine the contribution of dissolved organic carbon (DOC) from a biochar mineral complex (BMC), so as to better understand the interactions between DOC, biochar, clay, and minerals during thermal treatment, and the effects of BMC on amended soils. The BMC was prepared by heating a mixture of a H3PO4-treated saligna biochar from Acacia saligna, clays, other minerals, and chicken manure. The BMC was applied to a sandy loam soil in Western Australia, where wheat was grown. Liquid chromatography-organic carbon detection (LC-OCD) tests were carried out on water
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14

Byrne, Laurann, Michael J. Hynes, Cathal D. Connolly, and Richard A. Murphy. "Influence of the Chelation Process on the Stability of Organic Trace Mineral Supplements Used in Animal Nutrition." Animals 11, no. 6 (2021): 1730. http://dx.doi.org/10.3390/ani11061730.

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The effect of the chelation process on the pH-dependent stability of organic trace minerals (OTMs) used as mineral supplements in animal nutrition was assessed using analytical techniques such as potentiometry, Fourier Transform Infrared Spectroscopy (FTIRS) and amino acid profiling. The aim was to understand the influence and relative importance of the manufacturing conditions on mineral chelation and the subsequent pH stability of OTMs. A selection of OTMs were assessed over a wide pH range to account for the typical environmental changes encountered in the gastrointestinal (GI) tract. In th
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15

Kayler, Z. E., M. Kaiser, A. Gessler, R. H. Ellerbrock та M. Sommer. "Application of δ<sup>13</sup>C and δ<sup>15</sup>N isotopic signatures of organic matter fractions sequentially separated from adjacent arable and forest soils to identify carbon stabilization mechanisms". Biogeosciences 8, № 10 (2011): 2895–906. http://dx.doi.org/10.5194/bg-8-2895-2011.

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Abstract. Identifying the chemical mechanisms behind soil carbon bound in organo-mineral complexes is necessary to determine the degree to which soil organic carbon is stabilized belowground. Analysis of δ13C and δ15N isotopic signatures of stabilized OM fractions along with soil mineral characteristics may yield important information about OM-mineral associations and their processing history. We anlayzed the δ13C and δ15N isotopic signatures from two organic matter (OM) fractions along with soil mineral proxies to identify the likely binding mechanisms involved. We analyzed OM fractions hypot
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16

Drozdova, O. Yu, N. A. Anohina, V. V. Demin, and S. A. Lapitskiy. "Experimental research of photodegradation processes of organic compounds of natural waters." Moscow University Bulletin. Series 4. Geology, no. 4 (August 28, 2018): 75–80. http://dx.doi.org/10.33623/0579-9406-2018-4-75-80.

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In order to study the effect of sunlight on the composition and properties of dissolved organic matter and metal forms in natural waters, the process of photodegradation of organo-mineral complexes in field conditions with samples of soil and swamp waters was studied. Total content of certain aliphatic and aromatic carboxylic acids increased in the studied samples after irradiation. Photodegradation of organic matter of the natural waters that are rich in iron is accompanied by formation of colloidal particles (Fe hydroxides). The amount of negatively-charged complexes of Ni, Cu, Zn and Cd inc
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17

Koppa, Nadhila Adani, Harmita ., and Catur Jatmika. "SYNTHESIS AND ANALYSIS OF ZINC-METHIONINE, ZINC-TRYPTOPHAN, COPPER-LYSINE, AND COPPER-ISOLEUCINE COMPLEXES USING ATOMIC ABSORPTION SPECTROPHOTOMETRY." International Journal of Applied Pharmaceutics 10, no. 1 (2018): 416. http://dx.doi.org/10.22159/ijap.2018.v10s1.92.

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Objective: This study aimed to synthesize an organic form of Zn and Cu to then produce metal complexes with amino acids, as well as to analyze thefree and bound metal content of the complexes.Methods: In this study, the synthesis methods for zinc-methionine (Zn(Met)2), zinc-tryptophan (ZnTrp), copper-lysine (Cu(Lys)2), and copperisoleucine(Cu(Ile)2) complexes were based on previous studies. Sample verification was conducted using Fourier transform infrared spectroscopy,which can determine the stretched spectra produced by the complexes. In addition, atomic absorption spectrophotometry was used
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18

Nikitina, Elena, Irina Tihonova, Angelina Danilova, and Sergey Lednev. "Study of the method of detoxification of mineralised water sediments by natural sorbents." From Chemistry Towards Technology Step-By-Step 4, no. 3 (2023): 95–100. http://dx.doi.org/10.52957/2782-1900-2024-4-3-95-100.

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Sediments after reagent treatment of mineralised water are a rather complex mixture of various substances of mineral and organic composition. It is necessary to recycle these sediments in order to reduce the negative impact on the environment. The article considers the possibility of sediments detoxification by natural sorbents to bind organic and inorganic toxicants into non-toxic complexes and reduce the negative effect on the environment.
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19

Chorover, Jon, Mary Kay Amistadi, and Oliver A. Chadwick. "Surface charge evolution of mineral-organic complexes during pedogenesis in Hawaiian basalt." Geochimica et Cosmochimica Acta 68, no. 23 (2004): 4859–76. http://dx.doi.org/10.1016/j.gca.2004.06.005.

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20

Chia, Chee Hung, Paul Munroe, Stephen Joseph, and Yun Lin. "Microscopic characterisation of synthetic Terra Preta." Soil Research 48, no. 7 (2010): 593. http://dx.doi.org/10.1071/sr10012.

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Amazonian Dark Earths (Terra Preta) are anthropogenic soils with high organic carbon content and the ability to sustain higher fertility than adjacent, intensely weathered, acidic soils. Consequently, the microstructural development of biochar–mineral complexes, termed synthetic Terra Preta (STP), has been investigated. Here, biochar–mineral complexes are produced at elevated temperatures to mimic the structure of Terra Preta. These materials, if added to soils, may then also improve fertility. The raw materials used in STP were organic biowaste, such as sawdust, chicken manure, and blood and
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21

Litvinovich, A. V., O. Yu Pavlova, A. V. Lavrishchev, and A. A. Belimov. "Composition of organic-mineral complexes (OMC) migrating in the reclaimed sod-podzolic soils (Umbric Albeluvisol Abruptic)." E3S Web of Conferences 224 (2020): 04012. http://dx.doi.org/10.1051/e3sconf/202022404012.

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The composition of organo-mineral complexes (OMC) migrating from the arable horizon limed by Umbric Albeluvisol Abruptic was studied. The carbon content in organic-mineral complexes (OMC) ranged from 5.5 to 5.7%. The optical density index (Esmg/ml) varied in the range of values from 2.7 to 3.1, characteristic for fulvic acids (FA). It was established that FAs averaged with bases retain the ability to exert a destructive effect on soil minerals, transferring a significant amount of Al, Mn, and Fe into solution. According to their ability to migrate as part of OMC, the elements studied in the ex
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22

Plante, A. F., I. Virto, and S. S. Malhi. "Pedogenic, mineralogical and land-use controls on organic carbon stabilization in two contrasting soils." Canadian Journal of Soil Science 90, no. 1 (2010): 15–26. http://dx.doi.org/10.4141/cjss09052.

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Organo-mineral complexation in soils is strongly controlled by pedogenesis, but the mechanisms controlling it and its interaction with cultivation are not yet well understood. We compared the mineralogy and quality of organic carbon (C) among organo-mineral fractions from two soils with contrasting pedogenic origin. Sequential density fractionation (SDF; using 1.6, 1.8, 2.1, 2.4 and 2.6 g mL-1 sodium polytungstate solutions) followed by thermal analysis was applied to a Chernozem from Ellerslie, Alberta, and a Luvisol from Breton, Alberta, each under native and cultivated land uses. Similar cl
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23

Efimov, Boris, Ekaterina Mihailik, and Diana Sanko. "Soil stabilization by injection of mineral complexes." E3S Web of Conferences 389 (2023): 03013. http://dx.doi.org/10.1051/e3sconf/202338903013.

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Soil stabilization and strengthening is a necessary complex of engineering measures and can be carried out by introducing organic or mineral substances into the soil which increases soil viscosity and its mechanical characteristics. Soil modification can also be accompanied by mechanical pressure, as well as temperature influence. Judging by the results of the analysis of the state of the issue, a hypothesis was formulated, according to which an improvement in the operational characteristics of the soil is possible as a result of the use of a stabilizer based on quicklime and an active mineral
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N. S. Maan, Vinus, and B. S. Tewatia. "Effect of Dietary Supplementation of Organic Minerals on Growth Performance of Broilers." International Journal of Current Microbiology and Applied Sciences 10, no. 11 (2021): 235–42. http://dx.doi.org/10.20546/ijcmas.2021.1011.027.

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A study was conducted to assess the effects of replacing inorganic ‘zinc’ and ‘manganese’ with different levels of their organic complexes on growth performance and nutrient metabolizability of broilers. Experiment was conducted with 300 broiler chicks randomly divided into six groups, each consisting of 50 broiler chicks. All groups were further subdivided into five replications each containing 10 broiler chicks. The basal ration was formulated as per BIS (2007) specifications to meet energy and protein requirements of birds. In experimental groups, first group was kept as negative control (T
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Cooper, Rebecca Elizabeth, Karin Eusterhues, Carl-Eric Wegner, Kai Uwe Totsche, and Kirsten Küsel. "Ferrihydrite-associated organic matter (OM) stimulates reduction by <i>Shewanella oneidensis</i> MR-1 and a complex microbial consortia." Biogeosciences 14, no. 22 (2017): 5171–88. http://dx.doi.org/10.5194/bg-14-5171-2017.

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Abstract. The formation of Fe(III) oxides in natural environments occurs in the presence of natural organic matter (OM), resulting in the formation of OM–mineral complexes that form through adsorption or coprecipitation processes. Thus, microbial Fe(III) reduction in natural environments most often occurs in the presence of OM–mineral complexes rather than pure Fe(III) minerals. This study investigated to what extent does the content of adsorbed or coprecipitated OM on ferrihydrite influence the rate of Fe(III) reduction by Shewanella oneidensis MR-1, a model Fe(III)-reducing microorganism, in
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26

Arumugam, Krishnamoorthy, and Udo Becker. "Computational Redox Potential Predictions: Applications to Inorganic and Organic Aqueous Complexes, and Complexes Adsorbed to Mineral Surfaces." Minerals 4, no. 2 (2014): 345–87. http://dx.doi.org/10.3390/min4020345.

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27

Meng, Danyang, Hangxin Cheng, Yang Shao, et al. "Progress on the Effect of Nitrogen on Transformation of Soil Organic Carbon." Processes 10, no. 11 (2022): 2425. http://dx.doi.org/10.3390/pr10112425.

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Carbon and nitrogen are the essential elements constituting living organisms and are closely coupled during biogeochemical cycles. Due to the atmospheric nitrogen deposition and increased agricultural nitrogen fertilizer input, the effect of nitrogen on the sequestration of soil organic carbon (SOC) is controversial. To facilitate a comprehensive understanding of this issue, the progress of recent studies on the different SOC stabilization mechanisms is reviewed. Based on the differences in the stability and fate mechanisms of particulate organic carbon (POC) and mineral-associated organic car
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28

Radkowski, Adam, Iwona Radkowska, Karol Wolski, Piotr Kuc, and Henryk Bujak. "Effect of a Mineral-Organic Concentrate on a Yield Increase and Seed Quality of Perennial Ryegrass (Lolium perenne L.)." Agriculture 14, no. 2 (2024): 200. http://dx.doi.org/10.3390/agriculture14020200.

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Treatment of plants with mineral-organic concentrates has developed intensively in recent years. Fertilizers containing, among others, humus, L-amino acids, vitamins, chelates and metal complexes, macro-, micro- and meso-elements, organic matter and humic acids from the top organic layer of leonardite coal have a positive effect on plant growth and quality and seed yield. An experiment was conducted between 2019 and 2022 at the University of Agriculture in Kraków, in which the impact of mineral-organic concentrate on the seed yield and quality of perennial ryegrass (Lolium perenne L.) 2N Bokse
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Chang, Zhaofeng, Luping Tian, Fangfang Li, et al. "Organo-mineral complexes protect condensed organic matter as revealed by benzene-polycarboxylic acids." Environmental Pollution 260 (May 2020): 113977. http://dx.doi.org/10.1016/j.envpol.2020.113977.

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30

Goldstein, Alan H. "Bacterial solubilization of mineral phosphates: Historical perspective and future prospects." American Journal of Alternative Agriculture 1, no. 2 (1986): 51–57. http://dx.doi.org/10.1017/s0889189300000886.

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AbstractMaximum crop yields require sufficient phosphorus fertilization. Only phosphate in a soluble ionic form (Pi) is effective as a mineral nutrient. Current fertilizer technology supplies the soil solution with Pi via the application of large amounts of phosphate salts. Problems with this technology include energy-intensive production processes, the need for large scale mechanical application with associated environmental consequences, and reprecipitation of the phosphate into insoluble mineral complexes. It has been estimated that in some soils up to 75% of applied phosphate fertilizer ma
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31

Sklyarova, Galina. "Prospects of multipurpose and complex use of the most important types of non-metals in the economy of the Far East region." E3S Web of Conferences 56 (2018): 04013. http://dx.doi.org/10.1051/e3sconf/20185604013.

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construction materials. At the territory of the Far East there are geological and economic potential to create raw material bases for development of important economic complexes such as agrochemical (for fertilizer production: phosphoric - apatites, phosphates, potassium - alunites, organic - peat, sapropels; using as structure formers and soil-aggregate stabilizers: carbonate rocks, natural adsorbents, organic raw materials.), metallurgical (refractory clays, alumina slates, alunits), ecological ( natural adsorbents-zeolites, bentonites, perlites, diatomites) as well as others - chemical-fore
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Li, Junxia, Hailing Zhou, Yanxin Wang, Xianjun Xie, and Kun Qian. "Sorption and speciation of iodine in groundwater system: The roles of organic matter and organic-mineral complexes." Journal of Contaminant Hydrology 201 (June 2017): 39–47. http://dx.doi.org/10.1016/j.jconhyd.2017.04.008.

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33

Navrátil, Oldřich, Zbyněk Kobliha, and Emil Halámek. "Solvent Extraction of Mercury Complexes with Diisopropylaminoethanethiol and Other Substances Accompanying Agent VX." Collection of Czechoslovak Chemical Communications 59, no. 9 (1994): 1964–70. http://dx.doi.org/10.1135/cccc19941964.

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The distribution of 2-diisopropylaminoethanethiol (RSH) between aqueous phase containing picric acid at various pH values (ionic strength 0.1) and toluene as the organic phase was investigated. The protonation constant of the reagent is Ka = 106.27. The constants characterizing the formation of the ion-associate with the picrate anion were also determined. The distribution of mercury was also examined between solutions of RSH and its derivatives in low-polar organic solvents and aqueous phases containing mineral acids and/or their sodium salts. The composition of the extractable chelating comp
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34

Kayler, Z. E., M. Kaiser, A. Gessler, R. H. Ellerbrock та M. Sommer. "Application of <i>δ</i><sup>13</sup>C and <i>δ</i><sup>15</sup>N isotopic signatures of organic matter fractions sequentially separated from adjacent arable and forest soils to identify carbon stabilization mechanisms". Biogeosciences Discussions 8, № 2 (2011): 1985–99. http://dx.doi.org/10.5194/bgd-8-1985-2011.

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Abstract. Identifying the chemical mechanisms behind soil carbon bound in organo-mineral complexes is necessary to determine the degree to which soil organic carbon is stabilized belowground. We used the δ13C and δ15N isotopic signatures from two organic matter (OM) fractions from soil to identify the likely binding mechanisms involved. We used OM fractions hypothesized to contain carbon stabilized through organo-mineral complexes: (1) OM separated chemically with sodium pyrophosphate (OM(PY)) and (2) OM stabilized in microstructures found in the chemical extraction residue (OM(ER)). Furthermo
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35

Chabaev, M. G., R. V. Nekrasov, and M. I. Klementiev. "Influence of organic and non-organic microelements on productivity and metabolic processes in growing young pigs." Ukrainian Journal of Ecology 10, no. 5 (2020): 303–10. http://dx.doi.org/10.15421/2020_248.

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The purpose of our research was to determine the effect two different complexes of elements of copper, zinc, iron, manganese, selenium by organic and mineral origin in feeding mixture “SK-4” on growing pigs productivity, metabolic state and mineral deposition in their organs. We formed two groups of growing pigs, 40 heads each, with an average live weight of 13.6 kg at the age of 42 days. In addition to the main diet, the experimental animals were fed by two premixes of enriched mineral (in the form of sulfates) and organic (as chelates) complex of trace elements. In growing period, the pigs f
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36

Anielak, Anna Maria, Katarzyna Styszko, and Justyna Kwaśny. "The Importance of Humic Substances in Transporting “Chemicals of Emerging Concern” in Water and Sewage Environments." Molecules 28, no. 18 (2023): 6483. http://dx.doi.org/10.3390/molecules28186483.

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In this study, we examined the sorption of selected “chemicals of emerging concern” (CEC) on humic substances commonly found in water and municipal wastewater. These were ibuprofen, diclofenac, caffeine, carbamazepine, estrone, triclosan, bisphenol A, and isoproturon. The humic substances (HSs) were synthetic and not contaminated by the tested organic substances. The elemental composition and content of mineral micropollutants, gravimetric curves, and the IR spectrum of HSs were determined. We determined a relationship between the process efficiency and the characteristics of a sorbent and sor
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Pulunggono, Heru Bagus, Moh Zulfajrin, and Fuadi Irsan. "Distribution of nickel (Ni) in peatland situated alongside mineral soil derived from ultrabasic rocks." SAINS TANAH - Journal of Soil Science and Agroclimatology 18, no. 1 (2021): 15. http://dx.doi.org/10.20961/stjssa.v18i1.45417.

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&lt;p&gt;Detailed studies of Ni distribution in peat that is influenced by Ni-rich soil derived from ultrabasic rocks are still limited. The objective of this study was to reveal the characteristics of Ni in peat from Morowali (Central Sulawesi Province, Indonesia) at several depths and distances from the boundary of the ultrabasic mineral soil. Peat was sampled from depths of 0–30, 30–60, and 60–90 cm at distances of 100, 200, 300, 400, 500, and 600 m from the border of the ultrabasic mineral soil in March 2018. Ni characteristics were examined through their total, exchangeable, water-soluble
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38

Undabeytia, Tomas, Uri Shuali, Shlomo Nir, and Baruch Rubin. "Applications of Chemically Modified Clay Minerals and Clays to Water Purification and Slow Release Formulations of Herbicides." Minerals 11, no. 1 (2020): 9. http://dx.doi.org/10.3390/min11010009.

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This review deals with modification of montmorillonite and other clay-minerals and clays by interacting them with organic cations, for producing slow release formulations of herbicides, and efficient removal of pollutants from water by filtration. Elaboration is on incorporating initially the organic cations in micelles and liposomes, then producing complexes denoted micelle- or liposome-clay nano-particles. The material characteristics (XRD, Freeze-fracture electron microscopy, adsorption) of the micelle– or liposome–clay complexes are different from those of a complex of the same composition
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39

Datta, S. C., P. N. Takkar, and U. K. Verma. "Effect of partial removal of adsorbed humus on kinetics of potassium and silica release by tartaric acid from clay - humus complex from two dissimilar soil profiles." Soil Research 47, no. 7 (2009): 715. http://dx.doi.org/10.1071/sr09002.

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The aim of this investigation is to study how adsorbed humus on clay minerals affects kinetics of dissolution of clay mineral by an organic acid in terms of K and Si release. Clay–humus complexes were isolated from soil samples collected from different depths of 2 soil profiles from an Inceptisol of North India under long-term rice–wheat and maize–wheat cropping systems. Clay–humus complexes were subjected to repeat extraction with 100 mg/L of tartaric acid solutions before and after removal of humus with 30% hydrogen peroxide and the resultant release of potassium and silica was measured. Bef
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Il'ina, Galina Viktorovna, Dmitriy Yur'evich Il'in, Anna Andreevna Grishina, and Al'bina Rafael'evna Dashkina. "Functional complex of microorganisms on mineral carrier for cascade enzymatic degradation of poultry waste." Agrarian Bulletin of the 24, no. 05 (2024): 670–81. http://dx.doi.org/10.32417/1997-4868-2024-24-05-670-681.

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Abstract. The purpose of this study is to increase the efficiency of microbial composting of organic poultry waste and to ensure the preservation of nutrients in compost by using a functional complex of microbial destructor cultures integrated with a mineral carrier. Methods. Biomass of functional microorganisms was obtained by submerged cultivation and inoculated into a compostable substrate in a given chronological sequence. Three complexes of microorganisms were used (nitrifiers; thermophilic decomposers of cellulose and lignin of litter material; mesophilic microorganisms - soil formers).
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41

Degodyuk, S. E. "Ecologically recoverable models of farming biology in Ukraine." Interdepartmental thematic scientific collection "Agriculture" 2, no. 93 (2018): 76–78. http://dx.doi.org/10.31073/zem.93.76-78.

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The article presents the modern vision of the development of biologization of agriculture by restoring natural landscapes and agrocenoses in the basins of small rivers of Ukraine with carrying out works on the restoration of the channels, floodplains and watershed basins with the implementation of agro-, chemo-, bio- and phytomelioration. The prospects of implementation of energy-saving and nature-compatible agricultural systems on the restored landscapes, ensuring the cultivation of toxicological products of plant growing, are determined. The universal application of organo-mineral bioactive
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42

Zieger, Antonia, Klaus Kaiser, Pedro Ríos Guayasamín, and Martin Kaupenjohann. "Massive carbon addition to an organic-rich Andosol increased the subsoil but not the topsoil carbon stock." Biogeosciences 15, no. 9 (2018): 2743–60. http://dx.doi.org/10.5194/bg-15-2743-2018.

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Abstract. Andosols are among the most carbon-rich soils, with an average of 254 Mg ha−1 organic carbon (OC) in the upper 100 cm. A current theory proposes an upper limit for OC stocks independent of increasing carbon input, because of finite binding capacities of the soil mineral phase. We tested the possible limits in OC stocks for Andosols with already large OC concentrations and stocks (212 g kg−1 in the first horizon, 301 Mg ha−1 in the upper 100 cm). The soils received large inputs of 1800 Mg OC ha−1 as sawdust within a time period of 20 years. Adjacent soils without sawdust application s
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Sun, Xiao-Long, Yuan Wang, Hao-Qin Xiong, et al. "The Role of Surface Functional Groups of Iron Oxide, Organic Matter, and Clay Mineral Complexes in Sediments on the Adsorption of Copper Ions." Sustainability 15, no. 8 (2023): 6711. http://dx.doi.org/10.3390/su15086711.

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Heavy metal pollution is a global problem affecting the environment and human health. Sediment is the source sink of heavy metals in water. Under certain circumstances, the migration of heavy metals will cause water pollution. Therefore, it is of great significance to study sediment composition and composite complexes in the migration and transformation of heavy metals. To understand the adsorption mechanisms of composite complexes and improve the theoretical understanding of adsorption in multi-component complex systems, this study explored the characteristics and rules of Cu adsorption to or
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Onken, B. M., and S. J. Traina. "The Sorption of Nonionic Organic Solutes to Humic Acid‐Mineral Complexes: Effect of Cosolutes." Journal of Environmental Quality 26, no. 1 (1997): 132–38. http://dx.doi.org/10.2134/jeq1997.00472425002600010020x.

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45

de Junet, Alexis, Isabelle Basile-Doelsch, Daniel Borschneck, et al. "Characterisation of organic matter from organo-mineral complexes in an Andosol from Reunion Island." Journal of Analytical and Applied Pyrolysis 99 (January 2013): 92–100. http://dx.doi.org/10.1016/j.jaap.2012.10.020.

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46

Sakata, Kohei, Minako Kurisu, Yasuo Takeichi, et al. "Iron (Fe) speciation in size-fractionated aerosol particles in the Pacific Ocean: The role of organic complexation of Fe with humic-like substances in controlling Fe solubility." Atmospheric Chemistry and Physics 22, no. 14 (2022): 9461–82. http://dx.doi.org/10.5194/acp-22-9461-2022.

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Abstract. Atmospheric deposition is one of the main sources of dissolved iron (Fe) in the ocean surfaces. Atmospheric processes are recognized as controlling fractional Fe solubility (Fesol%) in marine aerosol particles. However, the impact of these processes on Fesol% remains unclear. One of the reasons for this is the lack of field observations focusing on the relationship between Fesol% and Fe species in marine aerosol particles. In particular, the effects of organic ligands on Fesol% have not been thoroughly investigated in observational studies. In this study, Fe species in size-fractiona
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Jadhav, Kavitha P., Nayan Ahmed, Tapan Jyoti Purakayastha, et al. "Role of Clay-humus Complexes in Soil Organic Carbon Stabilization Across Paddy Soils in Diverse Indian Soil Orders." International Journal of Plant & Soil Science 36, no. 11 (2024): 527–44. http://dx.doi.org/10.9734/ijpss/2024/v36i115168.

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Aims: This study investigates the mechanisms of soil organic carbon (SOC) stabilization within clay-humus complexes across diverse soil orders in Indian paddy soils. By employing FTIR spectroscopy and NaOCl oxidation, it examines how different clay mineral compositions, such as smectite-rich Vertisols, influence SOC stability. Place and Duration of Study: Soil samples were collected from paddy-growing regions in India- Entisol from Nadia (West Bengal), Inceptisol from Sonipat (Haryana), Vertisol from Belgaum (Karnataka), and Alfisol from Davanagere (Karnataka), between June 2019 and July 2020.
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48

Samson Ibukun, Akinsola, Alabi Aderemi Babatunde, and Coppede Nicola. "Comparative characterizations of plant and mineral dye as potential photosensitizer in Dye-Sensitized Solar Cell." Momona Ethiopian Journal of Science 16, no. 2 (2024): 266–80. http://dx.doi.org/10.4314/mejs.v16i2.5.

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The advent of dye-sensitized solar cells (DSSC) has expansively seen more studies as an alternative to silicon-based and thin-film solar cells due to their simple structure and relatively low production cost. In dye-sensitized solar cells, the dye is one of the major components for high power conversion efficiencies. The extracted dyes were characterized by powder x-ray diffraction, x-ray fluorescence, Scanning electron microscopy, UV-visible spectroscopy, and Gas Chromatography-Mass spectrometry analysis. The structure of the mineral dye contains constituents that enhance better absorption of
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Bortolini, Olga, Letanzio Bragante, Fulvio Di Furia, and Giorgio Modena. "Metal catalysis in oxidation by peroxides. 24. Extraction of aqueous peroxomolybdenum species into organic media and their reactivity." Canadian Journal of Chemistry 64, no. 6 (1986): 1189–95. http://dx.doi.org/10.1139/v86-197.

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The effect of the lipophilicity and coordinating ability of neutral ligands, belonging to the classes of phosphoric amides and pyridine oxides, on the extraction of the neutral oxidants molybdenum(VI)–peroxo complexes from an aqueous acidic phase to an organic one, has been studied. The nature of the Mo(VI)–peroxo species present both in aqueous and organic phase has also been investigated. Sizable amounts of mineral acid, added to adjust pH, may be extracted into the organic phase. The various factors affecting this process such as the nature of the acid added, the organic solvent and the neu
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Genest, Stephanie C., Myrna J. Simpson, André J. Simpson, Ronald Soong, and David J. McNally. "Analysis of soil organic matter at the solid–water interface by nuclear magnetic resonance spectroscopy." Environmental Chemistry 11, no. 4 (2014): 472. http://dx.doi.org/10.1071/en14060.

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Environmental context Structural and conformational information on organic matter–clay complexes and whole soils was obtained using different NMR methods. The results show that organic matter interactions with clay mineral surfaces determine the accessibility of specific organic matter components at the soil–water interface. This physical conformation may also play a role in soil biogeochemical processes and binding to pollutants in terrestrial environments. Abstract Organic matter (OM)–mineral interactions play an important role in OM preservation, global carbon cycling and contaminant transp
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