Academic literature on the topic 'Mixed Ligand Anionic Complexes'

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Journal articles on the topic "Mixed Ligand Anionic Complexes"

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Aly, Aref A. M., and Asma I. El-Said. "Spectral and Thermal Studies on Some New Anionic Mixed Alkyldithiocarbonato-Oxinato Transition Metal Complexes." Zeitschrift für Naturforschung B 44, no. 3 (1989): 323–26. http://dx.doi.org/10.1515/znb-1989-0313.

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The preparation and characterization of some anionic mixed ligand com plexes of Co(II), Ni(II) and Cu(II) containing the two anionic ligands alkyldithiocarbonate and oxinate are reported. The ionic nature of the complexes was inferred from the conductivity data. Alkyldithiocarbonates act in these complexes as bidentate ligands. Based on the spectroscopic and magnetic data the complexes appear to possess pseudo-octahedral metal coordination.
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SARBESHWAR, MISHRA, and M. PUROHIT K. "Studies on some Anionic Complexes of Oxovanadium(IV)." Journal Of Indian Chemical Society Vol. 66, Jan 1989 (1989): 53–54. https://doi.org/10.5281/zenodo.6116425.

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Department of Chemistry, Regional Engineering College,&nbsp;Rourkela-769 008 <em>Manuscript received 10 December 1987, revised 18 September 1988,&nbsp;accepted 4 October 1988</em> THE chemistry of oxovanadium(iv) is of interest&nbsp; from chemical, structural and biological point of&nbsp;view<sup>1-5</sup>. Keeping this in view and our interest in the chemistry of mixed ligand complexes<sup>6-8</sup>, we report here the synthesis and characterisation of some mixed ligand anionic complexes of oxovana&shy;dium(iv) of the type M[VOL<sub>2</sub>X], where M = Na or K ; X=SCN<sup>-</sup> or \(N^-_2\
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R., K. UPADHYAY. "Chemistry of Mixed Ligand Complexes of Copper(II) involving Ketoanil and Thiourea, Ammonia or Anionic Ligands." Journal of Indian Chemical Society Vol. 74, Jul 1997 (1997): 535–37. https://doi.org/10.5281/zenodo.5901493.

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Department of Chemistry. N R. E C. College, Khurja-203 131 <em>Manuscript received 5 September 1994, revised 31 January 1996, accepted 14 May 1996</em> Mixed ligand complexes of Cu<sup>II</sup> involving thiophene-2-glyoxal-2-mercaptyl-, -2-pyridine- or -2-pyrimidine-anil and thiourea, ammonia or anionic ligands, obtained either by direct reaction or by partial or complete replacement of strongly coordinated ammonia of cupric ammine complex, have been synthesised and characterised.
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BIPIN, B. MAHAPATRA, and PANDA DEBENDRA. "Anionic Mixed Ligand Complexes of Cobalt(II) and Copper(II)." Journal of Indian Chemical Society Vol. 63, Sep 1986 (1986): 792–93. https://doi.org/10.5281/zenodo.6298460.

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Department of Chemistry, G. M. College, Sambalpur-768 004 <em>Manuscript received 13 December 1982, revised 6 June 1986, accepted 18 June 1986</em> Anionic mixed ligand complexes of the compositions [ LH<sub>2</sub>[MCI<sub>4</sub>L<em>&#39;</em><sub>2</sub>]. where LH&nbsp;- 2,6-lutidinium cation, L&#39; - pyridine, piperidine for Co<sup><em>II</em></sup>&nbsp;and quinaldine, -\(\gamma\)- and \(\beta\)-picoline for Cu<em><sup>II</sup></em>&nbsp;; [LH]<sub>2</sub>[MCl<sub>4</sub>L-L], where L-L -1,10-phenanthroline, 2.2&#39;-bipy&shy;ridyl for Co<em><sup>Il</sup></em> and 1,10-phenanthroline.
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Chakravorti, M. C., and Gampa V. B. Subrahmanyam. "Electrosynthesis of thiocyanato and mixed ligand thiocyanato complexes of transition metals by the sacrificial dissolution of metal anodes." Canadian Journal of Chemistry 70, no. 3 (1992): 836–38. http://dx.doi.org/10.1139/v92-110.

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A general method for the electrosynthesis of anionic and mixed ligand nonelectrolytic thiocyanato complexes of transition metals has been developed by the oxidation of sacrificial metal anodes in aqueous, or aqueous ethanolic, medium containing ammonium thiocyanate at room temperature and at an applied potential of 2–7 V. The method is rapid and gives good yield with high purity. Keywords: electrosynthesis, thiocyanato complexes, mixed ligand thiocyanato complexes.
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Davidovich, Ruven, Pavel Fedorov, and Arthur Popov. "Structural chemistry of fluoride and mixed-ligand fluoride complexes of gallium(III)." Reviews in Inorganic Chemistry 37, no. 3-4 (2017): 147–84. http://dx.doi.org/10.1515/revic-2017-0010.

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AbstractThis article covers the structural chemistry of fluoride and mixed-ligand fluoride complexes of gallium(III), discusses more than 140 known crystal structures of anionic fluoride and mixed-ligand fluoride complexes and continues the discussion initiated in previous reviews dedicated to the stereochemistry and structural chemistry of group III–V metals fluoride complexes. Most of these structures have been established by single-crystal X-ray diffraction techniques, but some were characterized by powder X-ray diffraction methods. This paper offers a discussion of the geometry of gallium
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Gozzi, Marta, Benedikt Schwarze, and Evamarie Hey-Hawkins. "Half- and mixed-sandwich metallacarboranes for potential applications in medicine." Pure and Applied Chemistry 91, no. 4 (2019): 563–73. http://dx.doi.org/10.1515/pac-2018-0806.

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Abstract Today, medicinal chemistry is still clearly dominated by organic chemistry, and commercially available boron-based drugs are rare. In contrast to hydrocarbons, boranes prefer the formation of polyhedral clusters via delocalized 3c2e bonds, such as polyhedral dicarba-closo-dodecaborane(12) (closo-C2B10H12). These clusters have remarkable biological stability, and the three isomers, 1,2- (ortho), 1,7- (meta), and 1,12-dicarba-closo-dodecaborane(12) (para), have attracted much interest due to their unique structural features. Furthermore, anionic nido clusters ([7,8-C2B9H11]2−), derived
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K., BALAKRISHNAN, and K. ARAVINDAKSHAN K. "Metal Complexes of 3,4-Dimethoxybenzaldehyde Thiosemicarbazone." Journal of Indian Chemical Society Vol. 68, Apr 1991 (1991): 187–90. https://doi.org/10.5281/zenodo.5955082.

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Department of Chemistry. University of Calieut. Calient-673 635 <em>Matausoript received 15 March 1990, revised 1 April 1991, accepted 8 April 1991</em> The reaction of Co<sup>II</sup>, NI<sup>II</sup>, Cu<sup>II</sup>&nbsp;, Zn<sup>II</sup>. Cd<sup>II</sup>&nbsp;and Hg<sup>II</sup>&nbsp;salts with 3,4-dimethoxy&shy;benzaldehyde thiosemicarbazone (LH) in mixed alcohol-water or absolute alcohol yielded complexes of different stoichiometries. Their elemental analyses conduc&shy;tance, magnetic and electronic, ir&nbsp;and <sup>1</sup>H nmr spectral data revealed that the ligand coordinates with t
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Jaćimović, Željko K., Sladjana B. Novaković, Goran A. Bogdanović, Gerald Giester, Milica Kosović, and Eugen Libowitzky. "First crystal structures of metal complexes with a 4-nitropyrazole-3-carboxylic acid ligand and the third crystal form of the ligand." Acta Crystallographica Section C Structural Chemistry 75, no. 3 (2019): 255–64. http://dx.doi.org/10.1107/s2053229619001244.

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Pyrazole (pz)-derived ligands can, besides exhibiting a strong coordination ability toward different metal ions, exhibit a great diversity in their coordination geometry and nuclearity, which can be achieved by varying the type and position of the pz substituents. The present study reports the synthesis and crystal structure of two binuclear complexes, namely bis(μ-4-nitro-1H-imidazol-1-ide-5-carboxylato)-κ3 N 1,O:N 2;κ3 N 2:N 1,O-bis[aqua(dimethylformamide-κO)copper(II)], [Cu2(C4HN3O4)2(C3H7NO)2(H2O)2], (II), and bis(μ-4-nitro-1H-imidazol-1-ide-5-carboxylato)-κ2 N 1,O:N 2;κ2 N 2:N 1,O-bis[tri
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Tukumova, Natalia V., Tatiana R. Usacheva, Tran Thi Dieu Thuan, Valentin A. Sharnin, and Concetta Giancola. "STABILITY OF COORDINATION COMPOUNDS OF SOME d-METAL IONS WITH SUCCINIC ACID ANION IN AQUEOUS-ETHANOL SOLVENTS." IZVESTIYA VYSSHIKH UCHEBNYKH ZAVEDENIY KHIMIYA KHIMICHESKAYA TEKHNOLOGIYA 61, no. 9-10 (2018): 15–22. http://dx.doi.org/10.6060/ivkkt20186109-10.5778.

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The paper provides an overview of own data on complexation of nickel (II), cobalt (II) and cooper (II) ions with succinic acid anion in water-organic mixed solvents. Proper data are compared with data reported in literature for d-metal complexes with anions of maleic and succinic acids. The effect of aqueous ethanol solvent compositions on the stability of coordination compounds of M2+ with succinic acid anion as well as on рК values of stepwise succinic acid dissociation was carried out by a potentiometric titration at ionic strength of 0.1 maintained with sodium perchlorate at 298.15 ± 0.10
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Dissertations / Theses on the topic "Mixed Ligand Anionic Complexes"

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Delavaux, Béatrice. "Complexes heterobimetalliques hydrures (ru-m) (m=rh,ir,cu) a ligands bisdiphenylphosphinomethane : synthese et reactivite." Toulouse 3, 1986. http://www.theses.fr/1986TOU30078.

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Synthese de complexes hydruro a coordinat dppm : ph::(2) pch::(2) pph::(2). L'etude de la reactivite de certains complexes comme rurhh::(2)cl(cod) (dppm)::(2), conduit a la preparation de nouveaux hydrures dont on etudie les structures
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Menu, Marie-Joëlle. "Nouveaux reactifs dans la chimie des complexes du rhodium, du chrome et du tungstene : les anions diazo rc(n::(2))**(-)." Toulouse 3, 1988. http://www.theses.fr/1988TOU30068.

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Synthese des complexes de rh, cr et w contenant le coordinat diazo en faisant reagir les sels de li des anions rc(n::(2))**(-) sur les complexes metalliques. On a isole: (pme::(3))::(4) rhc(n::(2))sime::(3) (pet::(3))::(3) rhc(n::(2))sime::(3), (pme::(3))::(2) rhc(n::(2))(s)p(n-ipr::(2))::(2). On a mis en evidence un complexe carbenique dimere possedant un groupe ylure, lors de la photolyse de (pet::(3))::(3) rhc(n::(2))sime::(3)
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Faulmann, Christophe. "Conducteurs derives de metaux de transition : complexes moleculaires, polymeres, oxydes de cuivre." Toulouse 3, 1988. http://www.theses.fr/1988TOU30160.

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Caro, Catherine F. "N- and C-centred anionic ligand complexes of the alkaline earth metals." Thesis, University of Sussex, 1998. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.263911.

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Nasri, Habib. "Synthese et caracterisation de porphyrines de fe(ii) et fe(iii) : modelisation du site actif du centre p460 present dans l'hydroxylamine oxydoreductase de la bacterie nitrosomonas europaea." Université Louis Pasteur (Strasbourg) (1971-2008), 1987. http://www.theses.fr/1987STR13149.

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Synthese de modeles du site actif du cytochrome p460 a l'etat reduit. Donc synthese et caracterisation d'une serie de complexes (fe(ii) (or)t piv pp)**(-) ou or=ome, oph, ophf::(4), oac; et des complexes fe(iii)cltpivpp, fe(iii)(oac)tpivpp, fe(iii)(so::(3)cf::(3))(h::(2)o)tpivpp
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VAN, QUYNH ALEXANDRA. "Résonance magnétique nucléaire dans la phase mixte des composés organiques de la famille k-(BEDT-TTF)2CuX." Université Joseph Fourier (Grenoble), 1998. http://www.theses.fr/1998GRE10107.

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Nous presentons un ensemble de spectres obtenus par resonance magnetique nucleaire (rmn) du proton dans la phase supraconductrice de deux supraconducteurs organiques de structure voisine : -(bedt-ttf)#2cu(ncs)#2 et -(bedt-ttf)#2cun(cn)#2br. Dans le compose -(bedt-ttf)#2cu(ncs)#2 pour un champ applique perpendiculairement aux couches conductrices nous obtenons, dans la phase mixte, des formes de raie inattendues, tres differentes de celles prevues pour un reseau de vortex abrikosov triangulaire. En particulier, au-dessous d'une temperature t* qui depend de l'intensite du champ, nous observons u
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Hsu, Wei-Hsin. "Mixed anionic and cationic polyphosphazene complexes for effective gene delivery to glioblastoma in vitro and in vivo." Thesis, University of Nottingham, 2018. http://eprints.nottingham.ac.uk/53452/.

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Gene delivery vectors that are safe, efficient and affordable could significantly enhance the prospects for genetic-based therapies. Here we describe an approach to such vectors, using new variants of polyphosphazene materials and describe the synthesis of a series of degradable polyphosphazenes with both cationic and anionic side-chains, and report their use as mixed polyelectrolyte complexes for DNA and RNA delivery to glioblastoma cells in vitro and in vivo. Precursor poly(allylamino-phosphazene)s were converted to cationic and anionic derivatives via a,w-thiolated alkylamines and alkylcarb
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Leibnitz, P., G. Reck, H. J. Pietzsch, and H. Spies. "Structures of technetium and rhenium complexes." Forschungszentrum Dresden, 2010. http://nbn-resolving.de/urn:nbn:de:bsz:d120-qucosa-29787.

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Investigations in the 99mTc chemistry are stimulated by the search for new radiopharmaceuticals for nuclear medical applications. To understand the coordination mode of Tc with various complexing agents, macroscopic studies of technetium coordination chemistry are often performed using the low energy ß-emitting radionuclide 99Tc, which has a much longer half life (t1/2 = 2.12 x 105 years) than 99mTc, in the mg level. Investigations of Re coordination chemistry are done in conjunction with Tc studies because Re possesses chemical properties similar to those of Tc. For some chemical tasks, Re pr
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Leibnitz, P., G. Reck, H. J. Pietzsch, and H. Spies. "Structures of technetium and rhenium complexes." Forschungszentrum Rossendorf, 2001. https://hzdr.qucosa.de/id/qucosa%3A21805.

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Investigations in the 99mTc chemistry are stimulated by the search for new radiopharmaceuticals for nuclear medical applications. To understand the coordination mode of Tc with various complexing agents, macroscopic studies of technetium coordination chemistry are often performed using the low energy ß-emitting radionuclide 99Tc, which has a much longer half life (t1/2 = 2.12 x 105 years) than 99mTc, in the mg level. Investigations of Re coordination chemistry are done in conjunction with Tc studies because Re possesses chemical properties similar to those of Tc. For some chemical tasks, Re pr
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Hua, Fei. "Synthesis and Photophysics of Platinum (II) Diimine Acetylide Complexes." Bowling Green State University / OhioLINK, 2007. http://rave.ohiolink.edu/etdc/view?acc_num=bgsu1187329346.

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Books on the topic "Mixed Ligand Anionic Complexes"

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Gamble, Gary R. Spectroscopic investigations of mixed-ligand complexes of Copper(I). 1989.

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Highland, Ronald G. Spectroscopic properties of mixed-ligand chelates of closed-shell transition metal complexes. 1985.

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Cummings, Randy K. Synthesis and spectroscopic investigations of nitrogen heterocyclic and aromatic thiol mixed ligand platinum(II) complexes. 1985.

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Book chapters on the topic "Mixed Ligand Anionic Complexes"

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Burmeister, J. L. "In Mixed Ligand Complexes." In Inorganic Reactions and Methods. John Wiley & Sons, Inc., 2007. http://dx.doi.org/10.1002/9780470145227.ch103.

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Burmeister, J. L. "In Mixed-Ligand Complexes." In Inorganic Reactions and Methods. John Wiley & Sons, Inc., 2007. http://dx.doi.org/10.1002/9780470145227.ch31.

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Mehreteab, Ammanuel. "Effects of Structure on the Properties of Pseudononionic Complexes of Anionic and Cationic Surfactants." In Mixed Surfactant Systems. American Chemical Society, 1992. http://dx.doi.org/10.1021/bk-1992-0501.ch028.

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David, L., E. Forizs, C. Craciun, O. Cozar, and I. Gergely. "Spectral studies on some mixed-ligand copper (II) complexes of theophylline." In Spectroscopy of Biological Molecules: New Directions. Springer Netherlands, 1999. http://dx.doi.org/10.1007/978-94-011-4479-7_112.

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Christodoulou, Danae, Chris M. Maragos, Clifford George, et al. "Mixed-Ligand, Non-Nitrosyl Cu(II) Complexes as Potential Pharmacological Agents via NO Release." In Bioinorganic Chemistry of Copper. Springer Netherlands, 1993. http://dx.doi.org/10.1007/978-94-011-6875-5_34.

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Day, Peter. "Ligand Bridged Mixed-Valency Metal Chain Complexes: Prototype N-Site, N-Electron Systems with Electron-Phonon Coupling." In Organic and Inorganic Low-Dimensional Crystalline Materials. Springer US, 1987. http://dx.doi.org/10.1007/978-1-4899-2091-1_3.

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Rillema, D. P., and H. B. Ross. "Photophysical and Photochemical Properties of Ruthenium(II) Mixed-Ligand Complexes: Precursors to Homonuclear and Heteronuclear Multimetal Complexes Containing Ruthenium(II), Platinum(II), Rhenium(I) and Rhodium(III)." In Photochemistry and Photophysics of Coordination Compounds. Springer Berlin Heidelberg, 1987. http://dx.doi.org/10.1007/978-3-642-72666-8_26.

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Ojima, I., A. T. Vu, and D. Bonafoux. "Homoleptic, Cationic Norbornadiene Complexes via Anionic Ligand Abstraction." In Compounds with Transition Metal-Carbon pi-Bonds and Compounds of Groups 10-8 (Ni, Pd, Pt, Co, Rh, Ir, Fe, Ru, Os). Georg Thieme Verlag KG, 2001. http://dx.doi.org/10.1055/sos-sd-001-00447.

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Bochmann, Manfred. "Allyl and dienyl complexes." In Organometallics 2. Oxford University Press, 1994. http://dx.doi.org/10.1093/hesc/9780198558132.003.0005.

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This chapter focuses on allyl and dienyl complexes. The allyl ligand is the simplest in a series of non-cyclic conjugated anionic (enyl) ligands. Coordinated allyl is susceptible to nucleophilic attack—a property which has made allyl complexes invaluable in synthesis and is the basis of numerous catalytic reactions. The site of nucleophilic attack depends on the nature of the metal: allyl groups with cationic character are attacked in the 1,3-position, while anionic allyls react in the 2-position. The chapter then looks at the synthesis and reactivity of allyl complexes, before studying enyl c
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Ojima, I., A. T. Vu, and D. Bonafoux. "Homoleptic Cationic Cycloocta-1,5-diene Complexes via Anionic Ligand Abstraction." In Compounds with Transition Metal-Carbon pi-Bonds and Compounds of Groups 10-8 (Ni, Pd, Pt, Co, Rh, Ir, Fe, Ru, Os). Georg Thieme Verlag KG, 2001. http://dx.doi.org/10.1055/sos-sd-001-00442.

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Conference papers on the topic "Mixed Ligand Anionic Complexes"

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Shaw, S. S., and K. S. Sorbie. "Structure and Stoichiometry of Mixed Calcium–Magnesium–Phosphonate Scale Inhibitor Complexes for Application in Precipitation Squeeze Processes." In CORROSION 2014. NACE International, 2014. https://doi.org/10.5006/c2014-3865.

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Abstract Phosphonate scale inhibitors (SIs) applied in downhole squeeze applications may be retained in the near-well formation through adsorption and/or precipitation mechanisms. In this paper, we focus on the properties of precipitated “mixed” calcium and magnesium phosphonate complexes formed by nine common phosphonate species. By “mixed”, we mean anionic SI bound to both calcium and magnesium divalent cations, i.e. the complex SI_Can1_Mgn2 is formed where n1 and n2 are the stoichiometric coefficients for Ca and Mg, respectively. The stoichiometry (n1 and n2 or the Ca2+/P and Mg2+/P molar r
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Dwivedi, Shikha, S. K. Joshi, V. K. Hinge, B. D. Shrivastava, J. Prasad, and K. Srivastava. "XAFS study of benzimidazole mixed ligand complexes of copper." In PROF. DINESH VARSHNEY MEMORIAL NATIONAL CONFERENCE ON PHYSICS AND CHEMISTRY OF MATERIALS: NCPCM 2018. Author(s), 2019. http://dx.doi.org/10.1063/1.5098748.

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Cannizzo, Andrea, Franziska Frei, Thomas Feurer, et al. "Ultrafast Electronic Relaxations in Metal Mixed-Ligand Dithiolene Complexes." In International Conference on Ultrafast Structural Dynamics. OSA, 2012. http://dx.doi.org/10.1364/icusd.2012.im3d.4.

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Tanasković, Slađana, Branka Dražić, and Mirjana Antonijević Nikolić. "Biological activity of new mixed ligand copper(II) complexes." In RAD Conference. RAD Centre, 2022. http://dx.doi.org/10.21175/rad.spr.abstr.book.2022.24.2.

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Joshi, S. K., R. K. Katare, and B. D. Shrivastava. "EXAFS Studies of Some Copper(II) Mixed-Ligand Complexes." In X-RAY ABSORPTION FINE STRUCTURE - XAFS13: 13th International Conference. AIP, 2007. http://dx.doi.org/10.1063/1.2644675.

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Shareef, Nesser Kadham, and Hayder Hamied Mihsen. "Synthesis, characterization of mixed-ligand complexes containing 3-aminopropyltriethoxysilane and imidazole." In THE 7TH INTERNATIONAL CONFERENCE ON APPLIED SCIENCE AND TECHNOLOGY (ICAST 2019). AIP Publishing, 2019. http://dx.doi.org/10.1063/1.5123058.

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Puchta, Ralph, and Dušan Ćoćić. "IRM@Be2+ – quantum chemistry between Bavaria and Šumadija." In 2nd International Conference on Chemo and Bioinformatics. Institute for Information Technologies, University of Kragujevac, 2023. http://dx.doi.org/10.46793/iccbi23.053p.

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Quantum chemical (density functional theory) mechanistic investigations on ligand exchange reactions at a tetrahedrally-coordinated dicationic Beryllium center offer a harmless and alternative way to learn about the traversed reaction pathways compared to experimental studies. Calculations for solvent exchange at [Be(H2O)4]2+, [Be(NH3)]2+, and [Be(HCN)4]2+ showed interchange (I) type mechanisms. To learn about the potential influences of spectator ligands we calculated the water exchange at [Be(L)(H2O)3]n+ (L: neutral ligands, mono-anionic ligands or cationic ligands) and got again consequentl
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Mishra, A., N. Parsai, and B. D. Shrivastava. "K-absorption spectral studies of some mixed ligand copper complexes using synchrotron radiation." In SOLID STATE PHYSICS: Proceedings of the 56th DAE Solid State Physics Symposium 2011. AIP, 2012. http://dx.doi.org/10.1063/1.4709936.

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Crosby, G. A., G. R. Gamble, and K. J. Jordan. "Electronic Excited States Of Copper(I) Substituted-1,10-Phenanthroline And Substituted-Phosphine Mixed-Ligand Complexes." In OE/LASE '89, edited by E. R. Menzel. SPIE, 1989. http://dx.doi.org/10.1117/12.951561.

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Alkhafagi, Z. H., and T. H. Al-Noor. "Synthesis, characterization and antimicrobial studies of mixed ligand from phthalic acid and 1,10-phenanthroline with their complexes." In INTERNATIONAL CONFERENCE OF NUMERICAL ANALYSIS AND APPLIED MATHEMATICS ICNAAM 2019. AIP Publishing, 2020. http://dx.doi.org/10.1063/5.0028226.

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Reports on the topic "Mixed Ligand Anionic Complexes"

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Wallace, Kevin C., Andy H. Liu, John C. Dewan, and Richard R. Schrock. Preparation and Reactions of Tantalum Alkylidene Complexes Containing Bulky Phenoxide or Thiolate Ligands. Controlling Ring-Opening Metathesis Polymerization Activity and Mechanism Through Choice of Anionic Ligand. Defense Technical Information Center, 1988. http://dx.doi.org/10.21236/ada198293.

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