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Dissertations / Theses on the topic 'Mixed ligand Complex'

Author: Grafiati

Published: 3 June 2025

Last updated: 31 July 2025

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1

Erilhan, Ismail. "The Complex Of 2-aminothiophenol Ligand With Platinum: A Novel Platinum Blues Containing Sulfur Donor Ligand." Master's thesis, METU, 2007. http://etd.lib.metu.edu.tr/upload/3/12608414/index.pdf.

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The reaction of potassiumtetrachloroplatinate with 2-aminothiophenol, yielded a dark blue solid product. This work is about the characterization of this dark blue solid and the investigation of its binding interaction to DNA and enzyme activity. The blue solid product or the &ldquo<br>blue complex&rdquo<br>(as we called it in this work) is soluble in acetone, acetonitrile and DMSO yielding a blue solution. It is stable in solution and has a very strong absorption band at 724 nm. The product is paramagnetic and displays one kind of platinum in XPS (platinum binding energies were obtained at 71.

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2

Emhoff, Kylin. "SYNTHESIS, CHARACTERIZATION, AND CATALYTIC AND BIOLOGICAL ACTIVITIES OF A MIXED-LIGAND COBALT(II) BIPYRIDYL/DIPHENYLAZODIOXIDE COMPLEX." Cleveland State University / OhioLINK, 2021. http://rave.ohiolink.edu/etdc/view?acc_num=csu162366954569629.

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3

Delavaux, Béatrice. "Complexes heterobimetalliques hydrures (ru-m) (m=rh,ir,cu) a ligands bisdiphenylphosphinomethane : synthese et reactivite." Toulouse 3, 1986. http://www.theses.fr/1986TOU30078.

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Synthese de complexes hydruro a coordinat dppm : ph::(2) pch::(2) pph::(2). L'etude de la reactivite de certains complexes comme rurhh::(2)cl(cod) (dppm)::(2), conduit a la preparation de nouveaux hydrures dont on etudie les structures

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4

Chabut, Barbara. "Complexes binucléaires à fer non-heminique : activité biomimétique et échange de ligands." Université Joseph Fourier (Grenoble ; 1971-2015), 1997. http://www.theses.fr/1997GRE10234.

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Notre travail s'inscrit dans le cadre de la recherche de complexes modeles de sites actifs binucleaires d'enzymes a fer non heminique et plus particulierement de l'hemerythrine et de la methane monooxygenase. Pour cela, nous avons synthetise des composes dans lesquels le centre binucleaire est dissymetrique, c'est a dire que les deux ions metalliques sont dans des environnements differents. Ainsi lors de la synthese de complexes a valence mixte, fe#i#i#ife#i#i, l'ion ferrique est dans un environnement n#3o#3 alors que l'ion ferreux se trouve dans un environnement n#2o#3x, un ligand exogene com

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5

Etienne, Michel. "Réactivité de complexes dinucléaires hydrure et alcénylidène ponte du fer vis-a-vis d'hydrocarbures cyanes insatures (mono et dicyanoacétylène, tétracyanoethylène)." Brest, 1988. http://www.theses.fr/1988BRES2009.

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Preparation de complexes avec des coordinats cyano-4 butadienyldene portants. On obtient egalement des complexes dinucleaires avec le tricyano-3,4,4 butadienylidene-1,3. Mecanisme ses reactions de migration de l'hydrogene allylique

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6

Cukiernik, Fabio D. "Synthèses, études physicochimiques et structurales de nouveaux matériaux moléculaires mésogènes : les carboxylates binucléaires de ruthénium." Grenoble 1, 1993. http://www.theses.fr/1993GRE10134.

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Nous avons synthetise et caracterise plusieurs series de carboxylates binucleaires de ruthenium a valence mixte de formule generale ru#2(rco#2)#4x, ou x=cl, rco#2, dodecylsulfate et r=ch#3(ch#2)#n, (c#nh#2#n#+#1o)#mph. Une serie de carboxylates de ruthenium divalent de formule ru#2(rco#2)#4 a chaine aliphatique lineaire a aussi ete synthetisee et etudiee. Les proprietes mesomorphes de ces produits ont ete etudiees par microscopie optique en lumiere polarisee, calorimetrie differentielle a balayage et diffraction de rayons x de poudre. Les carboxylates divalents presentent une mesophase colonna

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7

Gomes, de Lima Bernardes Miriam. "Réactivité de complexes organométalliques mono- et dinucléaires : synthèse de thiolato-composés du molybdène, du tungstène et du cobalt : étude de la formation de liaisons c-c dans la sphère de coordination du métal." Brest, 1986. http://www.theses.fr/1986BRES2008.

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Caracterisation des complexes ((c::(5)h::(5))(co)::(2) lwc(cf::(3)) = c(cf::(3))h) et (c::(5)h::(5))(co) lwc(o)c(cf::(3)) = c(cf::(3))h) (l=co,pr::(3),p(or)::(3)) synthese de complexes dinucleaires de mo et w. L'addition oxydante de dialkylsulfure a des derives biportes de mo(ii) et w(ii) a donne lieu a la formation de complexes thiolato triportes ((c::(5)h::(5))(co)m(mu -sr)::(3)m(co)(c::(5)h::(5)))tx**(-)

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8

Chambron, Jean-Claude. "Synthese et etude de complexes du cuivre (i) et du ruthenium (ii) en vue de la separation intramoleculaire des charges photoinduites." Université Louis Pasteur (Strasbourg) (1971-2008), 1986. http://www.theses.fr/1986STR13092.

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Preparation de 2 macrocycles contenant a la fois des sites chelatants diphenyl-2,9 phenanthroline-1,10 et dialkyl-4,4' ou diaryl-4,4' bipyridine-2,2'. Dans le complexe heterodinucleaire il existe une interaction a l'etat excite entre les 2 metaux

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9

Schoettel, Guy. "Complexes alkylidenes du molybdene." Université Louis Pasteur (Strasbourg) (1971-2008), 1988. http://www.theses.fr/1988STR13125.

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Synthese de complexes de mo(vi) de type mo(ntbu)(=chtbu)(or)::(n)(ch::(2)tbu)::(2-n)(n=0,1,2), s'inscrivant dans le cadre de l'activation catalytique des reactions de metathese des olefines. Le type de reaction observee varie selon le complexe et la nature, cyclique, terminale, interne ou fonctionnalisee de l'olefine etudiee

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10

Don, Ming-jaw. "Ligand Substitution Studies in the Tetracobalt Cluster Co₄(CO)₁₀([mu]₄-PPh₂) and Synthesis and Reactivity Studies in the Fe₂Pt and FeCo₂ Mixed-metal Clusters." Thesis, University of North Texas, 1991. https://digital.library.unt.edu/ark:/67531/metadc279335/.

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The kinetics of ligand substitution for CO in Co4(CO)10(mu4-PPh2) , 1, have been investigated for the ligands P(OMe)3, P(OEt)3, PPh2H, P(0-i-Pr)3, P(n-Bu)3, PPh3, P(i-Pr)3, and PCy3 over a wide temperature range.

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11

Onyiriuka, Emmanuel C. "Pyrazolyl ligands in mixed metal complexes." Thesis, University of British Columbia, 1986. http://hdl.handle.net/2429/27178.

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The anions LMo(CO)₃⁻ (L = MeGapz₃ or MeGa(3,5-Me₂pz)₃) have been isolated as the Na⁺, Et₄N⁺ or HAsPh₃⁺ salts and the solution structures of the Na⁺ salts in THF have been defined by analysis of the v[sub CO] ir spectra. Ion-pair interaction of the LMo(CO)₃⁻ anion with Na⁺cation in THF solution is apparent from the spectroscopic evidence obtained. The MeGapz₃Mo(CO)₃ ⁻anion reacted with HCl or EtBr to give the seven-coordinate [MeGapz₃]-Mo(CO)₃R (R = H or Et) complexes. However, with Mel or PhCOCl complexes of the type [MeGapz₃]Mo(CO)₂(n₂-COR) (R = Me or Ph) were obtained. The reactions of the

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12

Nasri, Habib. "Synthese et caracterisation de porphyrines de fe(ii) et fe(iii) : modelisation du site actif du centre p460 present dans l'hydroxylamine oxydoreductase de la bacterie nitrosomonas europaea." Université Louis Pasteur (Strasbourg) (1971-2008), 1987. http://www.theses.fr/1987STR13149.

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Synthese de modeles du site actif du cytochrome p460 a l'etat reduit. Donc synthese et caracterisation d'une serie de complexes (fe(ii) (or)t piv pp)**(-) ou or=ome, oph, ophf::(4), oac; et des complexes fe(iii)cltpivpp, fe(iii)(oac)tpivpp, fe(iii)(so::(3)cf::(3))(h::(2)o)tpivpp

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13

Graham, Todd Warren. "Mixed-metal complexes incorporating polydentate bridging ligands." Thesis, National Library of Canada = Bibliothèque nationale du Canada, 1999. http://www.collectionscanada.ca/obj/s4/f2/dsk1/tape7/PQDD_0028/NQ39533.pdf.

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14

Boukhris, Abdallah. "Étude par diffraction des rayons X des porphyrines de gallium, germanium et indium, synthons potentiels de conducteurs électriques unidimensionnels." Nancy 1, 1986. http://www.theses.fr/1986NAN10038.

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Étude des composés GA(OEP)(SO::(3)CH::(3)), GA(OEP)N::(3), GE(TPMEPP)(N::(3))::(2), GE(OEP)F::(2) et (OEP) IN-MN(CO)::(5). Caractérisation des groupements azido dans les porphyrines de gallium et de germanium. Première liaison simple métat-métal dans la série des métalloporphyrines. Dopage de fluoro-octaethylporphyrines de gallium et d'octaméthylporphyrines de nickel par l'iode moléculaire. Incommensurabilité des réseaux iode et porphyrine, caractère polymérique des métalloporphyrines. Étude de la conductivité électrique

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15

Lachkar, Mohammed. "Contribution a l'etude de nouveaux complexes sandwich a base de phtalocyanines et de porphyrines de cerium trois et quatre." Université Louis Pasteur (Strasbourg) (1971-2008), 1988. http://www.theses.fr/1988STR13074.

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Synthese et caracterisation du premier biplan mixte phtalocyamine porphyrine de cerium. Etude de ce compose par voltammetrie cyclique. Synthese du premier triplan mixte phtalocyamine bis-porphyrines-bis cerium, et de la bis -phtalocyamine de cerium

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16

Brennan, Conor Joseph. "Structural relationships in complexes of mixed donor ligands." Thesis, Queen's University Belfast, 2001. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.394632.

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17

Wood, Andrew John. "Mixed-metal complexes incorporating redox-active cyanomanganese ligands." Thesis, University of Bristol, 2000. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.311404.

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18

Otter, Carl A. "The synthesis and coordination chemistry of mixed donor pyridine/phenol and pyridine/sulfonamide ligands." Thesis, University of Bristol, 1998. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.246241.

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19

Ahmed, Aminu. "Mixed donor carbene pyridyl ligands and their metal complexes." Thesis, Cardiff University, 2008. http://orca.cf.ac.uk/54889/.

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This thesis describes the synthesis of a series of Ag(I), Pd(II), Rh(I) and Ir(I) complexes of quinoline functionalised nucleophilic heterocyclic carbene (NHC) ligands. The transmetallation properties of the Ag(I) complexes were utilised to prepare the corresponding Pd(II), Rh (I) and Ir(I) (NHC) complexes. A series of quinoline based imidazolium, pyrimidinium salts were prepared and characterised as NHC ligand precursors. Ag(I)(NHC) complexes were prepared by the reaction of the quinoline functionalised salts with Ag20 in DCM. All complexes were spectroscopically characterised and the results

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20

Chung, Simon S. M. "Transition metal complexes of new mixed donor tridentate ligands." Thesis, University of Nottingham, 2001. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.367415.

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21

Forder, Robin James. "Transition metal complexes of phosphine and mixed phosphathia ligands." Thesis, University of Southampton, 1997. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.243129.

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22

Moussavi, Mehdi. "Synthese et etude de biplans phtalocyanines et de triplans mixtes porphyrine-phtalocyanines de terres rares." Université Louis Pasteur (Strasbourg) (1971-2008), 1986. http://www.theses.fr/1986STR13116.

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Une synthese en solution a ete mise au point pour les biphtalovyanines de terres rares. Cette famille de composes est tres etudiee pour les proprietes d'electrochromisme et de semi-conduction. Trois des cinq especes colorees, observees dans le processus d'electrochromisme ont ete isolees chimiquement. Le polymorphisme de l'etat solide des biphtalocyanines de terres rares a ete discute. En plus des trois formes signalees dans la litterature, une nouvelle forme a ete caracterisee. Le premier complexe mixte porphyrine bis-phtalocyanines bis-lanthanides du type "sandwich triplan" a ete prepare et

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23

Leibnitz, P., G. Reck, H. J. Pietzsch, and H. Spies. "Structures of technetium and rhenium complexes." Forschungszentrum Dresden, 2010. http://nbn-resolving.de/urn:nbn:de:bsz:d120-qucosa-29787.

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Investigations in the 99mTc chemistry are stimulated by the search for new radiopharmaceuticals for nuclear medical applications. To understand the coordination mode of Tc with various complexing agents, macroscopic studies of technetium coordination chemistry are often performed using the low energy ß-emitting radionuclide 99Tc, which has a much longer half life (t1/2 = 2.12 x 105 years) than 99mTc, in the mg level. Investigations of Re coordination chemistry are done in conjunction with Tc studies because Re possesses chemical properties similar to those of Tc. For some chemical tasks, Re pr

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24

Leibnitz, P., G. Reck, H. J. Pietzsch, and H. Spies. "Structures of technetium and rhenium complexes." Forschungszentrum Rossendorf, 2001. https://hzdr.qucosa.de/id/qucosa%3A21805.

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Investigations in the 99mTc chemistry are stimulated by the search for new radiopharmaceuticals for nuclear medical applications. To understand the coordination mode of Tc with various complexing agents, macroscopic studies of technetium coordination chemistry are often performed using the low energy ß-emitting radionuclide 99Tc, which has a much longer half life (t1/2 = 2.12 x 105 years) than 99mTc, in the mg level. Investigations of Re coordination chemistry are done in conjunction with Tc studies because Re possesses chemical properties similar to those of Tc. For some chemical tasks, Re pr

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25

Hua, Fei. "Synthesis and Photophysics of Platinum (II) Diimine Acetylide Complexes." Bowling Green State University / OhioLINK, 2007. http://rave.ohiolink.edu/etdc/view?acc_num=bgsu1187329346.

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26

Jong, Howard. "Late transition metal complexes incorporating hemilabile mixed-donor N-heterocyclic carbene ligands." Thesis, University of British Columbia, 2010. http://hdl.handle.net/2429/23473.

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The discovery of N-heterocyclic carbenes (NHC) has dramatically affected the world of catalysis. Their inherent properties that make them excellent auxiliary ligands for catalytic processes have countless laboratories worldwide probing and exploiting every notable feature they possess. However, while there is no shortage of attention in this field of research, there has been considerably less interest in NHCs with an ability chelate to metals via a mixed-donor ligand architecture. Thus, this thesis describes the synthesis and application of a ligand set comprised of bidentate mixed-donor NHC l

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27

Legoupy, Stéphanie. "Synthèse et réactivité de nouveaux complexes organométalliques chiraux du rhénium." Rennes 1, 1997. http://www.theses.fr/1997REN10148.

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Le travail présenté dans ce mémoire concerne la synthèse et la réactivité de complexes du rhénium. De nouveaux complexes organométalliques chiraux du rhénium des alcools propargyliques et homoallylique ont été synthétisés. Des alcools allyliques secondaires et 1,2-disubstitues ont été coordonnés à l'entité chirale (#5C#5H#5)Re(No)(Pph#3)#+Bf#4#-. Dans le cas du 3-buten-2-ol complexe, les deux diastéréoisomères ont pu été séparés. L'étude de la réactivité de ces complexes du rhénium a montré qu'ils sont compatibles avec des réactions d'oxydation, de Wittig, de réduction, d'estérification, de ch

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28

Mtongana, Sibusiso. "A multinuclear (1H, 13C, 31P and 195Pt) magnetic resonance spectroscopy study of mixed ligand platinum(II) complexes with new N,N-dialkyl-N'-acyl(aroyl)thioureas as ligands." Thesis, Stellenbosch : Stellenbosch University, 2002. http://hdl.handle.net/10019.1/52649.

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29

Chang, Ho-chol. "Studies on Synthesis and Properties of Molecular Assemblies of Ligand-based Mixed-valence Metal Complexes." 京都大学 (Kyoto University), 2001. http://hdl.handle.net/2433/77890.

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30

Faulmann, Christophe. "Conducteurs derives de metaux de transition : complexes moleculaires, polymeres, oxydes de cuivre." Toulouse 3, 1988. http://www.theses.fr/1988TOU30160.

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31

Couchman, Samantha M. "Syntheses and structural studies of complexes of mixed donor pyridine/phenol and pyridine/pyrazole ligands." Thesis, University of Bristol, 1999. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.299312.

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32

Bowman, Gary Raymond, University of Western Sydney, of Science Technology and Environment College, and of Science Food and Horticulture School. "Studies of Titanium(IV)complexes of mixed nitrogen and oxygen donor macrocycles and related schiff base ligands." THESIS_CSTE_SFH_Bowman_G.xml, 2002. http://handle.uws.edu.au:8081/1959.7/410.

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This work investigated the use of large tetradentate mixed nitrogen and oxygen donor macrocycles as potential ligands for titanium(IV).These large ligands are capable of encapsulating the metal ion, thereby protecting it from reacting further. In addition, titanium complexes of this type had not been reported previously.Molecular modelling was utilised to evaluate and predict the coordinating potential of the macrocycles investigated.An alternative synthetic strategy was needed to achieve coordination complexes with titanium. This involved the use of a benzene based solvent system and rigorous

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33

Tong, Wai-yip, and 唐煒燁. "Luminescent platinum(II) complexes containing dianionic tetradentate ligands having mixed oxygen, nitrogen and carbon donor atoms and platinum(II)-containing phosphorescent polymers : synthesis, photophysical properties and material applications." Thesis, The University of Hong Kong (Pokfulam, Hong Kong), 2014. http://hdl.handle.net/10722/198829.

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34

ESPA, DAVIDE. "Redox Switchable Chromophores based on Metal (Ni, Pd, Pt) Mixed-Ligand Dithiolene Complexes Showing Molecular Second-order NLO Activity." Doctoral thesis, Università degli Studi di Cagliari, 2011. http://hdl.handle.net/11584/265915.

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35

Brown, Douglas J. "Heteroleptic paddlewheel complexes and molecular assemblies of dimolybdenum and ditungsten a study of electronic and structural control /." Columbus, Ohio : Ohio State University, 2006. http://rave.ohiolink.edu/etdc/view?acc%5Fnum=osu1150289057.

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36

Lee, Ho-man, and 李浩文. "Design, synthesis, luminescene and photochromic studies of dithienylethene-containing nitrogen and mixed nitrogen-oxygen donorligands and their complexes." Thesis, The University of Hong Kong (Pokfulam, Hong Kong), 2009. http://hub.hku.hk/bib/B41757890.

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37

Lee, Ho-man. "Design, synthesis, luminescene and photochromic studies of dithienylethene-containing nitrogen and mixed nitrogen-oxygen donor ligands and their complexes." Click to view the E-thesis via HKUTO, 2009. http://sunzi.lib.hku.hk/hkuto/record/B41757890.

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38

Ziehm, Christopher. "Ground State and Excited State Mixed Valency in Metal-Metal Quadruply Bonded Complexes Supported by Extended π Ligands". The Ohio State University, 2016. http://rave.ohiolink.edu/etdc/view?acc_num=osu1469017749.

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39

Bowman, G. R. "Studies of titanium (IV) complexes of mixed nitrogen and oxygen donor macrocycles and related Schiff base ligands /." View thesis, 2002. http://library.uws.edu.au/adt-NUWS/public/adt-NUWS20030721.114851/index.html.

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40

Lai, Wei. "Heavy Metal Complexes of Mixed S,N Donor Ligands: X-Ray Crystallography and Solution-State 1H NMR." W&M ScholarWorks, 2005. https://scholarworks.wm.edu/etd/1539626840.

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41

Mondal, Sudipta [Verfasser], and Wolfgang [Akademischer Betreuer] Kaim. "Transition metal complexes with 1,2-dicarbonylhydrazine : a study on mixed-valency and non-innocent ligand behaviour / Sudipta Mondal ; Betreuer: Wolfgang Kaim." Stuttgart : Universitätsbibliothek der Universität Stuttgart, 2018. http://d-nb.info/1169653715/34.

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42

Käß, Martina [Verfasser], and Karsten [Akademischer Betreuer] Meyer. "Late Transition Metal Complexes of Mixed NHC/Phenolate Tripodal Ligands for Small Molecule Activation / Martina Käß. Gutachter: Karsten Meyer." Erlangen : Friedrich-Alexander-Universität Erlangen-Nürnberg (FAU), 2014. http://d-nb.info/1075477379/34.

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43

Shen, Jingyi. "Density functional theory study on the interstitial chemical shifts of main-group-element centered hexazirconium halide clusters; synthetic control of speciation in [(Zr6ZCl12)] (Z = B, C)-based mixed ligand complexes." Diss., Texas A&M University, 2003. http://hdl.handle.net/1969.1/2444.

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The correlation between NMR chemical shifts of interstitial atoms and electronic structures of boron- and carbon-centered hexazirconium halide clusters was investigated by density functional theory (DFT) calculation. The influences of bridging halide and terminal ligand variations on electronic structure were examined respectively. Inverse proportionality was found between the chemical shifts and the calculated energy gaps between two Kohn-Sham orbitals of t1u symmetry, which arose from the bonding and antibonding interaction between the zirconium cage bonding orbitals and the interstitial 2

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44

Menu, Marie-Joëlle. "Nouveaux reactifs dans la chimie des complexes du rhodium, du chrome et du tungstene : les anions diazo rc(n::(2))**(-)." Toulouse 3, 1988. http://www.theses.fr/1988TOU30068.

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Synthese des complexes de rh, cr et w contenant le coordinat diazo en faisant reagir les sels de li des anions rc(n::(2))**(-) sur les complexes metalliques. On a isole: (pme::(3))::(4) rhc(n::(2))sime::(3) (pet::(3))::(3) rhc(n::(2))sime::(3), (pme::(3))::(2) rhc(n::(2))(s)p(n-ipr::(2))::(2). On a mis en evidence un complexe carbenique dimere possedant un groupe ylure, lors de la photolyse de (pet::(3))::(3) rhc(n::(2))sime::(3)

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45

Mabad, Bouchra. "Modelisation du site d'oxydation de l'eau en photosynthese : complexes du manganese avec des bases de schiff polydentees." Toulouse 3, 1987. http://www.theses.fr/1987TOU30103.

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46

Ezenwa, Emmanuel. "N,N-diethyl-N'-naphthoylacylchalcogourea to metal (II)complexes as precursors for ternary metal chalcogenide thin films via AACVD." Thesis, University of Manchester, 2016. https://www.research.manchester.ac.uk/portal/en/theses/nndiethylnnaphthoylacylchalcogoureatometal-iicomplexes-as-precursors-for-ternary-metal-chalcogenide-thin-films-via-aacvd(85420a4c-89d4-4465-9734-ca40a75ba924).html.

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In this thesis complexes of acylchalcogoureas with cadmium (II), lead (II) and nickel (II) have been synthesised and investigated as single source precursors for the formation of metal chalcogenide thin films viaaerosol assisted chemical vapour deposition (AACVD). Routes to binary thin films have been explored using homoleptic complexes of the general structure bis(N,N-diethyl-N'-naphthoylchalcogoureato)metal(II). Analysis of the thin films produced showed the successful deposition of the binary materials from the synthesised complexes when characterised by powder XRD, ICP-OES, SEM and EDX. Ro

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47

Barry, Sean Thomas. "Compounds with mixed ligand systems as precursors for thermal synthesis of III-V extended solids: Halo-pnictido, alkyl-pnictido, and siloxo-pnictido complexes of gallium and indium." Thesis, University of Ottawa (Canada), 1996. http://hdl.handle.net/10393/9614.

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The compounds MN(SiMe$\rm\sb3)\sb2Cl\sb2\cdot$base (1: M = Ga, base = thf; 2: M = In, base = pyridine) were synthesised. Compound 1 disproportionated to gallium trichloride while 2 did not show any thermal reactivity. The compounds (Ga(R)$\sb2$N(SiMe$\sb3)\sb2\rbrack\sb2$ (3: R = $\rm\sp{n}$Bu, 4: R = $\rm\sp{t}$Bu) were synthesised. Complex 4 decomposed into several products at 400$\sp\circ$C, while 3 thermolysed to form hexagonal GaN at 400$\sp\circ$C, after annealing at 900$\sp\circ$C. Phosphido analogues of these, $\rm\lbrack Ga(\sp{n}Bu)(R)P(SiMe\sb3)\sb2\rbrack\sb2$ (5: R = $\rm\sp{n}$Bu

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48

Barry, Seán Thomas. "Compounds with mixed ligand systems as precursors for thermal synthesis of III-V extended solids, halo-pnictido, alkyl-pnictido, and siloxo-pnictido complexes of gallium and indium." Thesis, National Library of Canada = Bibliothèque nationale du Canada, 1996. http://www.collectionscanada.ca/obj/s4/f2/dsk3/ftp05/nq20991.pdf.

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49

Wu, Yu-Shan. "Studies on self-association, biological activity and DNA binding properties of a series of water soluble, mixed ligand [Pt(diimine)N,N-dihydroxyethyl-N'-benzoylthioureato]CI complexes." Doctoral thesis, University of Cape Town, 2002. http://hdl.handle.net/11427/6976.

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50

Swan, Paul Lombard. "Synthesis of mixed ligand, water soluble square planar platinum (II) complexes and an investigation of their association with haematin and potential to inhibit the formation of synthetic malaria pigment." Master's thesis, University of Cape Town, 2002. http://hdl.handle.net/11427/9782.

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Includes bibliography.<br>To establish their potential as a template for novel anti-malarial drugs, a series of planinum (II) complexes were synthesised, their association with haematin determined in 40 aqueous DMSO, pH 7.4 at 25°C and their ability to inhibit the formation of β-haematin (synthetic malaria pigment) was investigated. The compounds synthesised and investigated contained a platinum (II) ion coordinated to acylthiourea and diimine ligands. The diimines used included both substituted and unsubstituted 2,2’-bipyridines and 1,10-phenanthrolines. 2-phenyl pyridine was also utilised as

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