Relevant bibliographies by topics / Mixed valence

Contents

  1. Journal articles
  2. Dissertations / Theses
  3. Books
  4. Book chapters
  5. Conference papers
  6. Reports

Academic literature on the topic 'Mixed valence'

Author: Grafiati
Published: 4 June 2021
Last updated: 10 March 2023

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Journal articles on the topic "Mixed valence"

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Bosi, Ferdinando. "Bond valence at mixed occupancy sites. I. Regular polyhedra." Acta Crystallographica Section B Structural Science, Crystal Engineering and Materials 70, no. 5 (October 1, 2014): 864–70. http://dx.doi.org/10.1107/s2052520614017855.

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Bond valence sum calculations at mixed occupancy sites show the occurrence of systematic errors leading to apparent violations of the Valence Sum Rule (bond valence theory) in regular and unstrained bonding environments. The systematic deviation of the bond valence from the expected value is observed in the long-range structure, and is discussed from geometric and algebraic viewpoints. In the valence–length diagram, such a deviation arises from discrepancies between the intersection points of the long-range bond valences and the theoretical bond valences with the valence–length curves of involved cations. Three factors cause systematic errors in the bond valences: difference in atomic valences, bond valence parametersRi(the length of a bond of unit valence) and bond valence parametersbi(the bond softness) between the involved cations over the same crystallographic site. One important consequence strictly related to the systematic errors is that they lead to erroneous bond strain values for mixed occupancy sites indicating underbonding or overbonding that actually does not exist.
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Larsson, Sven. "Mixed valence and superconductivity." Philosophical Transactions of the Royal Society A: Mathematical, Physical and Engineering Sciences 366, no. 1862 (September 7, 2007): 47–54. http://dx.doi.org/10.1098/rsta.2007.2138.

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Mixed-valence (MV) systems are referred to here as MV-2 and MV-3 depending on whether two or three consecutive valence states are involved. MV-3 systems range from systems with Hubbard U ≫0, corresponding to a single stable, intermediate valence state, and U ≪0, corresponding to stable alternating valences differing by two units. Experiments using inelastic neutron scattering or inelastic X-ray scattering show softening of breathing phonon modes in MV systems compared with related systems with a single valence. It is hypothesized that softening is due to coupling between potential energy surfaces, corresponding to differing localizations of the electron. As predicted, softening is larger in the delocalized case. A mechanism for superconductivity is suggested.
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Salsman, J. Catherine, Clifford P. Kubiak, and Tasuku Ito. "Mixed Valence Isomers." Journal of the American Chemical Society 127, no. 8 (March 2005): 2382–83. http://dx.doi.org/10.1021/ja042351+.

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Wenger, Oliver S. "Photoswitchable mixed valence." Chemical Society Reviews 41, no. 10 (2012): 3772. http://dx.doi.org/10.1039/c2cs15339d.

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Coey, J. M. D., M. Viret, and S. von Molnár. "Mixed-valence manganites." Advances in Physics 58, no. 6 (November 2009): 571–697. http://dx.doi.org/10.1080/00018730903363184.

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Coey, J. M. D., M. Viret, and S. von Molnár. "Mixed-valence manganites." Advances in Physics 48, no. 2 (March 1999): 167–293. http://dx.doi.org/10.1080/000187399243455.

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Hankache, Jihane, and Oliver S. Wenger. "Organic Mixed Valence." Chemical Reviews 111, no. 8 (August 10, 2011): 5138–78. http://dx.doi.org/10.1021/cr100441k.

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Prassides, Kosmas, Yasuhiro Takabayashi, and Takeshi Nakagawa. "Mixed valency in rare-earth fullerides." Philosophical Transactions of the Royal Society A: Mathematical, Physical and Engineering Sciences 366, no. 1862 (September 7, 2007): 151–61. http://dx.doi.org/10.1098/rsta.2007.2147.

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Mixed-valence phenomena associated with the highly correlated narrow-band behaviour of the 4f electrons in rare earths are well documented for a variety of rare-earth chalcogenides, borides and intermetallics (Kondo insulators and heavy fermions). The family of rare-earth fullerides with stoichiometry RE 2.75 C 60 (RE=Sm, Yb, Eu) also displays an analogous phenomenology and a remarkable sensitivity of the rare-earth valency to external stimuli (temperature and pressure) making them the first known molecular-based members of this fascinating class of materials. Using powerful crystallographic and spectroscopic techniques which provide direct indications of what is happening in these materials at the microscopic level, we find a rich variety of temperature- and pressure-driven abrupt or continuous valence transitions—the electronically active fulleride sublattice acts as an electron reservoir that can accept electrons from or donate electrons to the rare-earth 4f/5d bands, thereby sensitively modulating the valence of the rare-earth sublattice.
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Liu, Zhichang, Marco Frasconi, Wei-Guang Liu, Yu Zhang, Scott M. Dyar, Dengke Shen, Amy A. Sarjeant, William A. Goddard, Michael R. Wasielewski, and J. Fraser Stoddart. "Mixed-Valence Superstructure Assembled from a Mixed-Valence Host–Guest Complex." Journal of the American Chemical Society 140, no. 30 (June 27, 2018): 9387–91. http://dx.doi.org/10.1021/jacs.8b05322.

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Kurella, Anna-Sophie, Thomas Bräuninger, and Franz Urban Pappi. "Centripetal and centrifugal incentives in mixed-member proportional systems." Journal of Theoretical Politics 30, no. 3 (May 27, 2018): 306–34. http://dx.doi.org/10.1177/0951629818774855.

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How does competition for first (candidate) and second ballot (party-list) votes affect the strategic positioning of parties in mixed-member proportional systems? We study this question in a simulation study of multiparty competition in the two tiers. In the first step, we use data from elections for the German Bundestag to estimate individual vote function for each tier based on ideology, policy, and valence incentives. We then use these parameter estimates to calibrate a model in which parties compete for either first- or second-tier votes. Results suggest that parties may face a dilemma when adopting a positional strategy. When national parties and their candidates hold significantly different valences, large valence advantages generate centripetal incentives whereas smaller valences exert a centrifugal pull. Overall, centrifugal incentives dominate the German mixed-member system.
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Dissertations / Theses on the topic "Mixed valence"

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Brown, Neil John. "Novel organometallic mixed valence complexes." Thesis, Durham University, 2010. http://etheses.dur.ac.uk/417/.

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Organometallic mixed valence complexes have been studied extensively over the past 30 years providing many synthetic and theoretical challenges. This thesis has sought to provide the field with a unique family of mixed valence complexes through which theories of electron transfer in weakly coupled systems can be tested. The metal fragment Mo(dppe)(η7-C7H7) is unique amongst its half-sandwich counterparts providing low formal oxidation states and a well resolved EPR signal and forms the basis of these studies. Before undertaking a study of the electronic structure of [{(Mo(dppe)(η7-C7H7)}2{μ- C≡CXC≡C}]n+ systems, and associated issues regarding mixed valence characteristics and carbon-chain mediated metal-metal interactions, mono-metallic molybdenum acetylide complexes that serve as model systems were studied in detail and their electronic structure fully rationalised. Thus, in Chapter two, a range of para substituted molybdenum aryl acetylides, Mo(C≡CC6H4X-4)(dppe)(η7-C7H7), featuring a range of electron-donating and -withdrawing substituents, are described. These compounds have been studied using a range of spectroscopic, crystallographic, electrochemical, spectroelectrochemical, and computational techniques establishing metal centred oxidation character. This is a consequence of cycloheptatrienyl ring destabilising the filled dz2 metal d-orbtial which then forms the HOMO. The poor symmetry match of this dz2 orbital and the alkynyl π-system effectively decouples the molybdenum fragment from the alkynyl substituent. As a precursor to the synthesis and understanding of bi-metallic complexes containing all-carbon bridging moieties, a series of mono-metallic compounds containing diynyl and triynyl ligands have been studied in Chapter three. The subsequent elucidation of the influence of the length of the carbon chain on the electronic structure has been studied using a combination of spectroelectrochemical and computational techniques. These studies reveal that the length of the carbon chain, and the identity of the supporting ligand, (bipyridine or dppe) increases the chain character of the frontier orbitals. Homo-bimetallic complexes containing a bis(ethynyl) substituted para-carborane bridging moiety were synthesised (Chapter four) together with the monometallic complex Mo(C≡CC2B10H11)(dppe)(η7-C7H7). The mono-metallic complex was first synthesised and studied to establish how the ethynyl carborane affects the electronic structure of the Mo(dppe)(η7-C7H7) centre and the nature of interaction between the molybdenum centre, the ethynyl fragment and the carborane cage. This preliminary work was followed by the synthesis of the bimetallic complex, [{Mo(dppe)(η7- C7H7)}2{μ-C≡C(C2B10H10)C≡C}]. Using a range of spectroscopic, spectroelectrochemical and computational techniques the electronic structure, and charge transfer process of [{Mo(dppe)(η7-C7H7)}2{μ-C≡C(C2B10H10)C≡C}]n+ (n = 0, 1 or 2) have been explored. The monocation [{Mo(dppe)(η7-C7H7)}2{μ- C≡C(C2B10H10)C≡C}]+ has shown to be a genuine example of a valence trapped, weakly coupled mixed valence complex allowing conventional descriptions of the intervalence transition to be compared with TD-DFT based interpretations. The literature surrounding the area of poly-carbon ligand chemistry indicates that the butadiyndiyl bridging moiety is an efficient conduit for electron transfer, due to its two orthogonal π-systems that span across the entirety of the ligand, leading to systems which are generally delocalised. An investigation of the mixed valence complex, [{Mo(dppe)(η7-C7H7)}2(μ-C≡CC≡C)]+ reveals a weakly coupled, localised mixed valence electronic structure, which is unique amongst its poly-carbon counterparts (Chapter five). Through using a range of spectroscopic timescales (EPR /IR /UV /vis) the rate of electron transfer has been estimated. To fully account for the number of transitions in the NIR region and the shape of the resulting absorption bands, it is necessary to employ a three state approximation (which explicity indicates the bridge state) when describing the electron transfer process. The complex [{Mo(dppe)(η7-C7H7)}2{μ-C≡C(C6H4)C≡C}]n+ has been studied using a range of spectroscopic, electrochemical and computational methods to establish the nature and rate of electron transfer of the mixed valence complex (Chapter six). It has been demonstrated that the 1,4-diethynylbenzene bridge mixes more efficiently with the Mo(dppe)(η7-C7H7) than the 1,3-butadiyndiyl bridge. Spectroscopic analysis revealed a moderately coupled, localised mixed valence complex, where the rate of electron transfer is much faster than the diynyl complex but not faster than the infrared spectroscopy timescale. The application of the three state model in the description of the charge transfer process allows the increased electron transfer rate to be explained through the increased mixing of the bridge with the Mo(dppe)(η7-C7H7) moiety, characterised by the lowering of the LMCT transition in comparison to carboranyl and diynyl containing complexes. Metal complexes containing the cyanoacetylide moiety, C≡CC≡N, have been known for several decades, but despite the obvious synthetic advantages of cyanoacetylide as a bridging moiety compared to a butadiyndiyl bridge, C≡CC≡C, the C≡CC≡N ligand has been largely ignored. Chapter seven summarises attempts made to provide a convenient route to complexes containing the cyanoacetylide moiety so that a greater variety bimetallic complexes can be synthesised, thus allowing the investigation of the charge transfer characteristics of [{LxM}(μ-C≡CC≡N){MLx}]n+ complexes. Reactions of cyanogen bromide with metal acetylide complexes yield novel mono- and di- bromovinylidenes rather than cyano containing complexes. The cyanation reagent of choice is 1-cyano-4-dimethylaminopyridinium tetrafluoroborate ([CAP]BF4) which allows the ready synthesis of mono- and di-cyanovinylidenes, as well as the synthesis of cyanoacetylide containing complexes. The cyanating agent [CAP]BF4 is able to cyanate a range of metal acetylides, thus expanding the number of potential bimetallic complexes. The hetero-bimetallic complex [{Fe(dppe)(η5-C5H5)}(μ- C≡CC≡N){Mo(dppe)(η7-C7H7)}]PF6 has been synthesised and studied using a range of techniques and has demonstrated that the cyanoacetylide bridge promotes a more delocalised electronic structure for dicationic complexes than is found for the other ethynyl based ligands described in this thesis.
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Macpherson, Brendan P. "Discrete cyano-bridged mixed valence systems /." [St. Lucia, Qld.], 2004. http://www.library.uq.edu.au/pdfserve.php?image=thesisabs/absthe17778.pdf.

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Lancaster, Kelly. "Intramolecular electron transfer in mixed-valence triarylamines." Diss., Atlanta, Ga. : Georgia Institute of Technology, 2009. http://hdl.handle.net/1853/31709.

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Thesis (Ph.D)--Chemistry and Biochemistry, Georgia Institute of Technology, 2010.
Committee Chair: Bredas, Jean-Luc; Committee Member: Kippelen, Bernard; Committee Member: Marder, Seth; Committee Member: Orlando, Thomas; Committee Member: Sherrill, David. Part of the SMARTech Electronic Thesis and Dissertation Collection.
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Michaels, Hannes. "Cu(I)/(II) mixed-valence Coordination Polymers." Thesis, Uppsala universitet, Institutionen för fysik och astronomi, 2017. http://urn.kb.se/resolve?urn=urn:nbn:se:uu:diva-330861.

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Tong, Jin. "Homo- and Mixed-valence [2 × 2] Grid Complexes." Doctoral thesis, Niedersächsische Staats- und Universitätsbibliothek Göttingen, 2016. http://hdl.handle.net/11858/00-1735-0000-0028-8736-B.

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Londergan, Casey H. "Electron transfer and delocalization in mixed-valence complexes /." Diss., Connect to a 24 p. preview or request complete full text in PDF format. Access restricted to UC campuses, 2003. http://wwwlib.umi.com/cr/ucsd/fullcit?p3091312.

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Read, Nicholas. "Low temperature properties of models for mixed-valence compounds." Thesis, Imperial College London, 1986. http://hdl.handle.net/10044/1/38140.

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Zhao, Xiaodong. "Studies of extended cyanines and related mixed valence compounds." Diss., Georgia Institute of Technology, 1995. http://hdl.handle.net/1853/28001.

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Whittle, Karl R. "Redox and mixed valence in some solid state systems." Thesis, Open University, 1998. http://oro.open.ac.uk/57915/.

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Lear, Benjamin James. "The effects of electronic delocalization in highly coupled mixed valence systems." Connect to a 24 p. preview or request complete full text in PDF format. Access restricted to UC campuses, 2007. http://wwwlib.umi.com/cr/ucsd/fullcit?p3273182.

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Thesis (Ph. D.)--University of California, San Diego, 2007.
Title from first page of PDF file (viewed August 31, 2007). Available via ProQuest Digital Dissertations. Vita. Includes bibliographical references (p. 138-146).
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Books on the topic "Mixed valence"

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NATO Advanced Workshop on Mixed Valency Compounds: Applications in Chemistry, Physics, and Biology (1990 Hagia Pelagia, Greece). Mixed valency systems: Applications in chemistry, physics, and biology. Dordrecht: Kluwer Academic Publishers, 1991.

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Prassides, Kosmas, ed. Mixed Valency Systems: Applications in Chemistry, Physics and Biology. Dordrecht: Springer Netherlands, 1991. http://dx.doi.org/10.1007/978-94-011-3606-8.

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Prassides, Kosmas. Mixed Valency Systems: Applications in Chemistry, Physics and Biology. Dordrecht: Springer Netherlands, 1991.

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Stine, Ernest Franklin. The study of mixed valence compounds by time domain reflectometry. 1985.

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Zhong, Yuwu, and Chun Yuan Liu. Electron Transfer in Mixed-Valence Compounds: Design, Synthesis, Mechanisms, and Applications. Wiley & Sons, Incorporated, John, 2023.

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Zhong, Y. Electron Transfer in Mixed-Valence Compounds -Design, Synthesis, Mechanisms, and Applications. Wiley & Sons, Limited, John, 2023.

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Zhong, Yuwu, and Chun Yuan Liu. Electron Transfer in Mixed-Valence Compounds: Design, Synthesis, Mechanisms, and Applications. Wiley & Sons, Incorporated, John, 2023.

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Zhong, Yuwu, and Chun Yuan Liu. Electron Transfer in Mixed-Valence Compounds: Design, Synthesis, Mechanisms, and Applications. Wiley & Sons, Incorporated, John, 2023.

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Gray, Thomas James. Mediated oxidations of insulin, sulfur-containing amino acids and related compounds at a mixed-valence ruthenium cyanide electrode. 1990.

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Brown, D. B. Mixed-Valence Compounds: Theory and Applications in Chemistry, Physics, Geology, and Biology. Springer, 2011.

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Book chapters on the topic "Mixed valence"

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Ondrechen, Mary Jo, Saeed Gozashti, Li-Tai Zhang, and Feimeng Zhou. "Bridged Mixed-Valence Systems." In Electron Transfer in Biology and the Solid State, 225–35. Washington, DC: American Chemical Society, 1989. http://dx.doi.org/10.1021/ba-1990-0226.ch012.

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Rao, C. N. R. "Mixed Valence in Chemistry." In Theoretical and Experimental Aspects of Valence Fluctuations and Heavy Fermions, 235–42. Boston, MA: Springer US, 1987. http://dx.doi.org/10.1007/978-1-4613-0947-5_27.

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Bonča, J., S. El Shawish, C. D. Batista, and J. E. Gubernatis. "Itinerant Ferromagnetism for Mixed Valence Systems." In Concepts in Electron Correlation, 317–26. Dordrecht: Springer Netherlands, 2003. http://dx.doi.org/10.1007/978-94-010-0213-4_31.

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García, Joaquín, Gloria Subías, and Javier Blasco. "XAS Studies on Mixed Valence Oxides." In X-Ray Absorption and X-Ray Emission Spectroscopy, 459–84. Chichester, UK: John Wiley & Sons, Ltd, 2016. http://dx.doi.org/10.1002/9781118844243.ch17.

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Hirsch, A., and M. Hanack. "Bridged Mixed Valence Phthalocyaninato-Metal Compounds." In Conjugated Polymeric Materials: Opportunities in Electronics, Optoelectronics, and Molecular Electronics, 163–69. Dordrecht: Springer Netherlands, 1990. http://dx.doi.org/10.1007/978-94-009-2041-5_12.

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Lambert, Christoph. "Triarylamine-Based Organic Mixed-Valence Compounds." In Organic Redox Systems, 245–68. Hoboken, NJ: John Wiley & Sons, Inc, 2015. http://dx.doi.org/10.1002/9781118858981.ch7.

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Ostrovsky, S. "Electron Delocalization in Dimeric Mixed-Valence Systems." In Relaxation Phenomena, 609–26. Berlin, Heidelberg: Springer Berlin Heidelberg, 2003. http://dx.doi.org/10.1007/978-3-662-09747-2_11.

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Clark, Robin J. H. "Optical Spectroscopic Probes of Mixed Valence Systems." In Mixed Valency Systems: Applications in Chemistry, Physics and Biology, 273–82. Dordrecht: Springer Netherlands, 1991. http://dx.doi.org/10.1007/978-94-011-3606-8_15.

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Christou, G. "Mixed Valence Manganese Carboxylates of Various Nuclearities." In Mixed Valency Systems: Applications in Chemistry, Physics and Biology, 371–76. Dordrecht: Springer Netherlands, 1991. http://dx.doi.org/10.1007/978-94-011-3606-8_26.

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Bersuker, I. B., and S. A. Borshch. "Vibronic Interactions in Polynuclear Mixed-Valence Clusters." In Advances in Chemical Physics, 703–82. Hoboken, NJ, USA: John Wiley & Sons, Inc., 2007. http://dx.doi.org/10.1002/9780470141380.ch6.

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Conference papers on the topic "Mixed valence"

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Helal, W., S. Evangelisti, T. Leininger, D. Maynau, Theodore E. Simos, George Maroulis, George Psihoyios, and Ch Tsitouras. "Localized Multi-Reference Approach for Mixed-Valence Systems." In SELECTED PAPERS FROM ICNAAM-2007 AND ICCMSE-2007: Special Presentations at the International Conference on Numerical Analysis and Applied Mathematics 2007 (ICNAAM-2007), held in Corfu, Greece, 16–20 September 2007 and of the International Conference on Computational Methods in Sciences and Engineering 2007 (ICCMSE-2007), held in Corfu, Greece, 25–30 September 2007. AIP, 2008. http://dx.doi.org/10.1063/1.2997308.

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Laidlaw, W. M., Robert G. Denning, Thierry Verbiest, E. Chauchard, and Andre P. Persoons. "Second-order nonlinearity in mixed-valence metal chromophores." In OE/LASE '94, edited by Seth R. Marder and Joseph W. Perry. SPIE, 1994. http://dx.doi.org/10.1117/12.173817.

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Nakanishi, Yoshiki, Shinya Kudo, Kyouhei Kikutani, Mitsuteru Nakamura, Masahito Yoshizawa, and Akihiro Mitsuda. "Ultrasound Investigation of the Eu-based Mixed Valence System EuRh2Si2." In Proceedings of the International Conference on Strongly Correlated Electron Systems (SCES2019). Journal of the Physical Society of Japan, 2020. http://dx.doi.org/10.7566/jpscp.30.011133.

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Nascimben, Mauro, Thomas Zoega Ramsoy, and Luis Emilio Bruni. "User-Independent Classification of Emotions in a Mixed Arousal-Valence Model." In 2019 IEEE 19th International Conference on Bioinformatics and Bioengineering (BIBE). IEEE, 2019. http://dx.doi.org/10.1109/bibe.2019.00086.

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Higashinaka, Ryuji, Akira Yamada, Ryoichi Miyazaki, Yuji Aoki, Masaichiro Mizumaki, Satoshi Tsutsui, Kiyofumi Nitta, Tomoya Uruga, and Hideyuki Sato. "Mixed Valence States in SmTr2Al20(Tr= Ti, V, Cr, and Ta)." In Proceedings of the International Conference on Strongly Correlated Electron Systems (SCES2013). Journal of the Physical Society of Japan, 2014. http://dx.doi.org/10.7566/jpscp.3.011079.

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Saez, Alejandro, Alessandro Conigli, Julien Frison, Gregorio Herdoiza, Carlos Pena, and Javier Ugarrio. "Scale Setting from a Mixed Action with Twisted Mass Valence Quarks." In The 39th International Symposium on Lattice Field Theory. Trieste, Italy: Sissa Medialab, 2022. http://dx.doi.org/10.22323/1.430.0357.

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Bulinski, M., V. Kuncser, Iancu Iova, A. Bela, Hilmar Franke, U. Russo, and G. Filoti. "Mixed-valence ion-doped PVA as potential materials for real-time holography." In SIOEL: Sixth Symposium of Optoelectronics, edited by Teodor Necsoiu, Maria Robu, and Dan C. Dumitras. SPIE, 2000. http://dx.doi.org/10.1117/12.378670.

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Reid, P. J., C. Silva, Y. Dong, J. T. Hupp, and P. F. Barbara. "Direct Measurement of the Nuclear and Solvent Contributions to the Electron-Transfer Dynamics in Mixed Valence Metal Dimers." In International Conference on Ultrafast Phenomena. Washington, D.C.: Optica Publishing Group, 1994. http://dx.doi.org/10.1364/up.1994.tud.20.

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The electron-transfer in mixed valence metal dimers is investigated with sufficient time resolution (20 fs) to unravel coherent and incoherent electronic, vibrational, and solvent motion for the first time. These compounds represent an ideal class of reactions on which to develop condensed-phase electron-transfer (ET) theories. [1, 2] An example in these reactions is the ruthenium-ruthenium mixed valence compound (RuRu): Photoexcitation initiates the migration of an electron between metal centers with internal conversion from the excited state to the ground state corresponding to the back-electron transfer. We have constructed a 20-fs absorption spectrometer based on a Ti:Sapphire oscillator which is capable of measuring the ultrafast reaction dynamics.[3]
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Stoutland, Page O., Stephen K. Doom, R. Brian Dyer, and William H. Woodruff. "Ultrafast Vibrational Energy Relaxation in [(NC)5MIICNMIII(NH3)5]1-(M = Ru, Os) Studied by Picosecond Infrared Spectroscopy." In International Conference on Ultrafast Phenomena. Washington, D.C.: Optica Publishing Group, 1994. http://dx.doi.org/10.1364/up.1994.thd.13.

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Mixed-valence transition metal complexes have long been used to study electron transfer reactions due to the availability of well-defined complexes with favorable spectroscopic properties.1 These studies have resulted in a plethora of information concerning the fundamental aspects of electron transfer reactions. We have recently used complexes of this type to investigate ultrafast electron transfer and vibrational energy relaxation dynamics in cyanide-bridged mixed-valence transition metal dimers. These studies have allowed us to observe, for the first time in the solution phase, the vibrational excitation which accompanies electron transfer reactions. In previous publications2 we have shown that (1) optical excitation into the metal to metal charge transfer (MMCT) transition of a series of mixed-valence transition metal complexes leads to formation of the excited state redox isomer, and that (2) subsequent ultrafast back electron transfer regenerates the original species, with much of the electronic excitation energy being converted into vibrational energy in the product. To date we have discussed the electron transfer and the coupled vibrational excitation. Here, we concentrate on the relaxation of the vibrationally excited molecules produced following the back electron transfer.
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Purkayastha, Tamoghna, Debashis De, Biplab Das, and Tanay Chattapadhyay. "First principle study of molecular quantum dot cellular automata using mixed valence compounds." In 2016 3rd International Conference on Devices, Circuits and Systems (ICDCS). IEEE, 2016. http://dx.doi.org/10.1109/icdcsyst.2016.7570601.

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Reports on the topic "Mixed valence"

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Rak, Stanton F., Charles A. Liberko, and Larry L. Miller. Mixed Valence in Conjugated Anion Radicals. Solution and Solid State Studies. Fort Belvoir, VA: Defense Technical Information Center, May 1991. http://dx.doi.org/10.21236/ada236428.

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2

Shoemaker, Daniel. In Situ Thermodynamics and Kinetics of Mixed-Valence Inorganic Crystal Formation. Office of Scientific and Technical Information (OSTI), July 2015. http://dx.doi.org/10.2172/1855834.

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3

Korte, N. E., M. T. Muck, J. L. Zutman, R. M. Schlosser, L. Liang, B. Gu, R. L. Siegrist, T. C. Houk, and Q. Fernando. In situ treatment of mixed contaminants in groundwater: Application of zero-valence iron and palladized iron for treatment of groundwater contaminated with trichloroethene and technetium-99. Office of Scientific and Technical Information (OSTI), April 1997. http://dx.doi.org/10.2172/631149.

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4

Schlottmann, P. Mixed-valent and heavy fermions and related systems: Second technical progress report, (May 1987--June 1988). Office of Scientific and Technical Information (OSTI), July 1989. http://dx.doi.org/10.2172/5915113.

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5

(Mixed valent behavior in the actinides and the relationship tocerium). Office of Scientific and Technical Information (OSTI), January 1991. http://dx.doi.org/10.2172/5003952.

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