Academic literature on the topic 'Mixed-valence compound'

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Journal articles on the topic "Mixed-valence compound"

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Lin, Meng Shan, Yi Chong Wu, and Bor Iuan Jan. "Mixed-valence compound-based biosensor." Biotechnology and Bioengineering 62, no. 1 (January 5, 1999): 56–61. http://dx.doi.org/10.1002/(sici)1097-0290(19990105)62:1<56::aid-bit7>3.0.co;2-m.

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Mazumdar, Chandan, R. Nagarajan, S. K. Dhar, L. C. Gupta, R. Vijayaraghavan, and B. D. Padalia. "Ce2Ni3Si5: A mixed-valence cerium compound." Physical Review B 46, no. 14 (October 1, 1992): 9009–12. http://dx.doi.org/10.1103/physrevb.46.9009.

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Streitwieser, Andrew, and David C. Eisenberg. "Reduced biuranocenylene - a mixed valence organouranium compound." Inorganica Chimica Acta 139, no. 1-2 (December 1987): 193–94. http://dx.doi.org/10.1016/s0020-1693(00)84077-3.

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Shimomura, S., S. Nakamura, N. Ikeda, E. Kaneko, K. Kato, and K. Kohn. "Structural properties of a mixed valence compound." Journal of Magnetism and Magnetic Materials 310, no. 2 (March 2007): 793–95. http://dx.doi.org/10.1016/j.jmmm.2006.10.184.

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Gulácsi, Miklós, and Zsolt Gulácsi. "BCS superconductivity in a mixed valence compound." Solid State Communications 90, no. 1 (April 1994): 51–55. http://dx.doi.org/10.1016/0038-1098(94)90961-x.

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Wilamowski, Z., A. Mycielski, W. Jantsch, and G. Hendorfer. "Spin dynamics in the mixed-valence compound HgSe:Fe." Physical Review B 38, no. 5 (August 15, 1988): 3621–24. http://dx.doi.org/10.1103/physrevb.38.3621.

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Jakubcová, Petra, Falko M. Schappacher, Rainer Pöttgen, and Dirk Johrendt. "Structure and Properties of Mixed-valence Compound Eu5Zr3S12." Zeitschrift für anorganische und allgemeine Chemie 635, no. 4-5 (April 2009): 759–63. http://dx.doi.org/10.1002/zaac.200900075.

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Sunatsuki, Yukinari, Yuichi Ikuta, Naohide Matsumoto, Hiromi Ohta, Masaaki Kojima, Seiichiro Iijima, Shinya Hayami, et al. "An Unprecedented Homochiral Mixed-Valence Spin-Crossover Compound." Angewandte Chemie International Edition 42, no. 14 (April 11, 2003): 1614–18. http://dx.doi.org/10.1002/anie.200250399.

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Gupta, B. R. K. "Phonon dispersion in the mixed-valence compound Sm0.75Y0.25S." Philosophical Magazine Letters 55, no. 5 (May 1987): 231–34. http://dx.doi.org/10.1080/09500838708203755.

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Altshuler, T. S., N. S. Altshuler, and M. S. Bresler. "ESR on Sm3 ions in mixed-valence compound." Ferroelectrics 233, no. 1 (September 1999): 31–35. http://dx.doi.org/10.1080/00150199908016993.

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Dissertations / Theses on the topic "Mixed-valence compound"

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Liu, Chun Yuan. "Electronic localization versus delocalization: a dimetal approach." Texas A&M University, 2003. http://hdl.handle.net/1969.1/3903.

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A series of dimolybdenum compounds having a Mo2 4+ core coordinated by various ligands, including formamidinate (e.g. DAniF = N, NN-di-p-ansisylformamidinate ), acetate and/or acetonitrile molecules, have been synthesized as building blocks for the construction of Mo2-containing supramolecular arrays. Compound Mo2(DAniF)3(O2CCH3) was specifically designed for the preparation of dimolybdenum pairs, whereas the others meet the needs of Mo2 4+ units for different geometry settings. Compounds described by a general formula [Mo2]L[Mo2], where [Mo2] = [Mo2(DAniF)3]+, have two dimetal units electronically coupled by the central unit L , which consequently engender significant impact on the redox property and electronic structure of the molecule. It is found that in the weakly coupled complex system, [Mo2]M(OCH3)4[Mo2] (M = Zn and Co), the mixed-valence complexes present asymmetric molecular structures with two distinct [Mo2] units corresponding to be a bond order 4.0 (F2B4*2) and 3.5 (F2B4*1), respectively. EPR and magnetic susceptibility measurements for the doubly oxidized species show that there is no significant antifferromagnetic spin coupling. Electron delocalization occurs in the complex system where a N, N'-dimethyloxamidate binds two [Mo2] units within two fused six-membered rings. In this case, the mixed-valence complex has a symmetric molecular structure, implying that the odd electron is fully delocalized over two [Mo2]units. Strong metal-metal interaction is also evidenced by intervalence charge transfer of the mixed-valence species and the diamanetism of the doubly oxidized complex. Remarkably, two isomers varying in linkage conformation, namely, alpha and beta, have been isolated as diaryloxamidate ligands are used as the linker. Studies on the neutral and the oxidized compounds of the two isomers by employing various techniques consistently show that in the alpha form intramolecular electron transfer is blocked , while in the beta form, the electrons are delocalized over the two [Mo2] units. Thus, the mixed-valence complexes of the two isomers are appropriately described by alpha-[Mo2]0(oxamidate)[Mo2]1+ and beta- [Mo2]0.5+(oxamidate)[Mo2]0.5+ respectively.
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Hashiguchi, Ryota. "Studies on Polynuclear Metal Complexes and Low-Dimensional Mixed-Valence Halogen-Bridged Transition Metal Complexes Based on them." 京都大学 (Kyoto University), 2017. http://hdl.handle.net/2433/225426.

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Macpherson, Brendan P. "Discrete cyano-bridged mixed valence systems /." [St. Lucia, Qld.], 2004. http://www.library.uq.edu.au/pdfserve.php?image=thesisabs/absthe17778.pdf.

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Zhao, Xiaodong. "Studies of extended cyanines and related mixed valence compounds." Diss., Georgia Institute of Technology, 1995. http://hdl.handle.net/1853/28001.

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Read, Nicholas. "Low temperature properties of models for mixed-valence compounds." Thesis, Imperial College London, 1986. http://hdl.handle.net/10044/1/38140.

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Ammarguellat, Chafika. "Contribution à l'étude des propriétés des composés ternaires intermétalliques de type TM2Si2." Paris 6, 1986. http://www.theses.fr/1986PA066007.

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Etude du phénomène de valence intermédiaire dans les composés du type CeM2Si2 (m=métal de transition 3d). Mise en évidence d'anomalies lors de l'absorption x ainsi que dans les propriétés magnétiques et de transport. Mesure des seuils d'absorption l(i)ii et classification des composes sur une échelle de valeurs de la valence. Etude des variations thermiques de la valence. L'instabilité de valence a également été mise en évidence qualitativement par des mesures des paramètres de maille.
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Uebe, Masashi. "Studies on Triphenylamine-Based Organic Functional Materials." Kyoto University, 2018. http://hdl.handle.net/2433/232006.

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Dilley, Neil Ross. "Strongly correlated electrons in Ce- and Yb-intermetallic compounds : the superconducting mixed state of CeRu₂ and intermediate valence in YbFe₄Sb₁₂ /." Diss., Connect to a 24 p. preview or request complete full text in PDF format. Access restricted to UC IP addresses, 1999. http://wwwlib.umi.com/cr/ucsd/fullcit?p9935479.

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Marzin, Jean-Yves. "Effets des deformations sur les proprietes optiques des super-reseaux contraints a base de semi-conducteurs iii-v." Paris 7, 1987. http://www.theses.fr/1987PA077132.

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Etude, par photoluminescence, spectrometrie d'excitation et absorption optique, de plusieurs systemes contraints et en particulier du systeme in::(0,15)ga::(0,85)as/gaas sur gaas; modifications de la structure de bande dues aux contraintes natives. Identification des transitions optiques; bon accord avec un modele de fonctions enveloppes incluant les effets des contraintes. Estimation des discontinuite de bandes; configuration des bandes de valence. Etude de systemes fortement contraintes sur l'exemple de inas/gaas; transitions associees a la presence de monocouche(s) de inas dans une matrice gaas; effets lies a la segregation de in en surface et au passage d'un mode de croissance 2d a un mode 3d
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Li, Yu. "Electron Transport in Ferrocenes Linked by Molecular Wires." Diss., Georgia Institute of Technology, 2007. http://hdl.handle.net/1853/16198.

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A large variety of diferrocenyl compounds bridged by an organic wire fragment in a generic form of -CH=CH-X-CH=CH- were first synthesized, in which the X unit is a functional group/atom. These compounds were studied by structural analysis, electrochemistry, intervalence NIR absorption and other spectroscopic techniques. The results indicated that metal-ligand redox matching is most essential in facilitating long-range electron transfer in the mixed-valence complexes. A series of doubly-bridged diferrocenyl compounds and wire-linked triferrocenes were also synthesized and studied. All doubly-bridged diferrocenyl compounds demonstrated nearly doubled electronic coupling in comparison to their singly-bridged analogues. Thus the use of parallel wires in such systems represents a facile approach to improve communication in molecular electronics. For triferrocenes linked by symmetric wires, the electronic interaction between the redox-active centers was rather dynamic when the bridging component was short or the charge was delocalized among the ligand and metal centers. For triferrocenes bridged by asymmetric wires, depending on the direction of the polar linking chain, the central ferrocene becomes a molecular switch, turning on or off the communication between the two end ferrocenes. Finally, to eliminate the metal-ligand orbital mixing problem, we also bound the wires with two redox-active styrylpyrrole termini, for which the molecules are purely organic. It was found that when the ð-conjugation was maintained, the oligomers were fully delocalized systems.
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Books on the topic "Mixed-valence compound"

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Stine, Ernest Franklin. The study of mixed valence compounds by time domain reflectometry. 1985.

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Brown, D. B. Mixed-Valence Compounds: Theory and Applications in Chemistry, Physics, Geology, and Biology. Springer, 2011.

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Brown, D. B. Mixed-Valence Compounds: Theory and Applications in Chemistry, Physics, Geology,and Biology. Springer, 2011.

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Gray, Thomas James. Mediated oxidations of insulin, sulfur-containing amino acids and related compounds at a mixed-valence ruthenium cyanide electrode. 1990.

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Launay, Jean-Pierre, and Michel Verdaguer. Electrons in Molecules. Oxford University Press, 2018. http://dx.doi.org/10.1093/oso/9780198814597.001.0001.

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The book treats in a unified way electronic properties of molecules (magnetic, electrical, photophysical), culminating with the mastering of electrons, i.e. molecular electronics and spintronics and molecular machines. Chapter 1 recalls basic concepts. Chapter 2 describes the magnetic properties due to localized electrons. This includes phenomena such as spin cross-over, exchange interaction from dihydrogen to extended molecular magnetic systems, and magnetic anisotropy with single-molecule magnets. Chapter 3 is devoted to the electrical properties due to moving electrons. One considers first electron transfer in discrete molecular systems, in particular in mixed valence compounds. Then, extended molecular solids, in particular molecular conductors, are described by band theory. Special attention is paid to structural distortions (Peierls instability) and interelectronic repulsions in narrow-band systems. Chapter 4 treats photophysical properties, mainly electron transfer in the excited state and its applications to photodiodes, organic light emitting diodes, photovoltaic cells and water photolysis. Energy transfer is also treated. Photomagnetism (how a photonic excitation modifies magnetic properties) is introduced. Finally, Chapter 5 combines the previous knowledge for three advanced subjects: first molecular electronics in its hybrid form (molecules connected to electrodes acting as wires, diodes, memory elements, field-effect transistors) or in the quantum computation approach. Then, molecular spintronics, using, besides the charge, the spin of the electron. Finally the theme of molecular machines is presented, with the problem of the directionality control of their motion.
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Book chapters on the topic "Mixed-valence compound"

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Niki, H., R. Mahoe, K. Okamura, M. Yogi, and H. Terao. "BrNQR relaxation of the mixed-valence compound (NH4)4SbIIISbvBr12." In HFI/NQI 2007, 345–51. Berlin, Heidelberg: Springer Berlin Heidelberg, 2008. http://dx.doi.org/10.1007/978-3-540-85320-6_54.

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Lambert, Christoph. "Triarylamine-Based Organic Mixed-Valence Compounds." In Organic Redox Systems, 245–68. Hoboken, NJ: John Wiley & Sons, Inc, 2015. http://dx.doi.org/10.1002/9781118858981.ch7.

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Hirsch, A., and M. Hanack. "Bridged Mixed Valence Phthalocyaninato-Metal Compounds." In Conjugated Polymeric Materials: Opportunities in Electronics, Optoelectronics, and Molecular Electronics, 163–69. Dordrecht: Springer Netherlands, 1990. http://dx.doi.org/10.1007/978-94-009-2041-5_12.

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Wong, K. Y., and P. N. Schatz. "A Dynamic Model for Mixed-Valence Compounds." In Progress in Inorganic Chemistry, 369–449. Hoboken, NJ, USA: John Wiley & Sons, Inc., 2007. http://dx.doi.org/10.1002/9780470166291.ch6.

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Mishra, Suresh G. "High Temperature Specific Heat of Mixed-Valence Compounds." In Theoretical and Experimental Aspects of Valence Fluctuations and Heavy Fermions, 589–92. Boston, MA: Springer US, 1987. http://dx.doi.org/10.1007/978-1-4613-0947-5_97.

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Cooper, Benjamin F. T., and Charles L. B. Macdonald. "Mixed or Intermediate Valence Group 13 Metal Compounds." In The Group 13 Metals Aluminium, Gallium, Indium and Thallium: Chemical Patterns and Peculiarities, 342–401. Chichester, UK: John Wiley & Sons, Ltd, 2011. http://dx.doi.org/10.1002/9780470976548.ch6.

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Pardasani, R. T., and P. Pardasani. "Magnetic properties of octanuclear mixed-valence (CoII, CoIII) cluster." In Magnetic Properties of Paramagnetic Compounds, 1189–90. Berlin, Heidelberg: Springer Berlin Heidelberg, 2017. http://dx.doi.org/10.1007/978-3-662-54231-6_704.

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Pardasani, R. T., and P. Pardasani. "Magnetic properties of tetranuclear mixed valence manganese-oxo aggregate." In Magnetic Properties of Paramagnetic Compounds, 926–27. Berlin, Heidelberg: Springer Berlin Heidelberg, 2017. http://dx.doi.org/10.1007/978-3-662-54228-6_529.

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Trojan, Kathleen L., William E. Hatfield, Keith D. Kepler, and Martin L. Kirk. "BIS(Phthalocyaninato) Lanthanide Sandwich Compounds Exhibiting Mixed Valence Ligands." In Mixed Valency Systems: Applications in Chemistry, Physics and Biology, 383–88. Dordrecht: Springer Netherlands, 1991. http://dx.doi.org/10.1007/978-94-011-3606-8_28.

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Pardasani, R. T., and P. Pardasani. "Magnetic properties of octahedral mixed valence cis-chromium selenide cluster." In Magnetic Properties of Paramagnetic Compounds, 437–38. Berlin, Heidelberg: Springer Berlin Heidelberg, 2017. http://dx.doi.org/10.1007/978-3-662-54228-6_247.

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Conference papers on the topic "Mixed-valence compound"

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Kodama, Katsuaki, Naoki Igawa, Shin-ichi Shamoto, Kazutaka Ikeda, Hidetoshi Ohshita, Naokatsu Kaneko, Toshiya Otomo, Kentaro Suzuya, Akinori Hoshikawa, and Toru Ishigaki. "Local Structural Analysis by Using Atomic Pair Distribution Function on Mixed Valence Compound LiMn2O4." In Proceedings of the International Conference on Strongly Correlated Electron Systems (SCES2013). Journal of the Physical Society of Japan, 2014. http://dx.doi.org/10.7566/jpscp.3.013012.

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Reyes-Ortega, Yasmi, Cándida Pastor Ramírez, Sylvain Bernès, Rafael Zamorano Ulloa, Daniel Ramírez-Rosales, and Samuel Hernández-Anzaldo. "Tetramer compound of manganese ions with mixed valence [Mn2IIMn2IV] and its spatial, electronic and magnetic studies." In The 1st International Electronic Conference on Crystals. Basel, Switzerland: MDPI, 2018. http://dx.doi.org/10.3390/iecc_2018-05245.

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Purkayastha, Tamoghna, Debashis De, Biplab Das, and Tanay Chattapadhyay. "First principle study of molecular quantum dot cellular automata using mixed valence compounds." In 2016 3rd International Conference on Devices, Circuits and Systems (ICDCS). IEEE, 2016. http://dx.doi.org/10.1109/icdcsyst.2016.7570601.

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Organizing Team, IECC. "Retraction: Ramírez, C.P., et al.; Tetramer compound of manganese ions with mixed valence [Mn2IIMn2IV] and its spatial, electronic and magnetic studies. Proceedings of The 1st International Electronic Conference on Crystals, Volume 1, 2018, 05245." In The 1st International Electronic Conference on Crystals. Basel, Switzerland: MDPI, 2018. http://dx.doi.org/10.3390/iecc_2018-05472.

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Shirai, M., and A. Saito. "Electron-phonon interaction and structural instability of mixed valence compounds Cs/sub 2/Au/sub 2/X/sub 6/(X=C1, Br, I)." In International Conference on Science and Technology of Synthetic Metals. IEEE, 1994. http://dx.doi.org/10.1109/stsm.1994.835513.

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