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Journal articles on the topic 'Modified hydrotalcites'

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1

Zhang, Chen-Yang, Wen-Li Shao, Wei-Xia Zhou, et al. "Biodiesel Production by Esterification Reaction on K+ Modified MgAl-Hydrotalcites Catalysts." Catalysts 9, no. 9 (2019): 742. http://dx.doi.org/10.3390/catal9090742.

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K+ modified hydrotalcites and its activity as a solid base catalyst for ultrasonic wave- assisted biodiesel conversion was investigated. The solid alkaline catalysts of the MgAl-hydrotalcites (HT) was prepared by co-precipitation and modified with K+ by impregnation. The influence of K+ incorporation on the performance of Mg-Al hydrotalcites catalysts was investigated by SmartLab X-ray powder diffractometer (XRD), infrared spectrum (IR), thermogravimetric-differential thermal analysis (TG–DTA), CO2 temperature programmed desorption (CO2-TPD), scanning electron microscopy (SEM), and N2 adsorpti
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2

Su, Ji Xin, Fei Fei Dong, Ming Bo Zhang, and Shen Ping Zhang. "Fluorescent Properties of Zn-Al Hydrotalcite and its Modified Products." Advanced Materials Research 148-149 (October 2010): 1087–90. http://dx.doi.org/10.4028/www.scientific.net/amr.148-149.1087.

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Zn-Al hydrotalcite exhibited fluorescence property without fluorescent substances intercalation. Its maximum excitation wavelength was 406nm and maximum emission wavelength was 523nm. In this study citric acid and adipic acid were introduced into the interlayer of LDH, which enlarged the interlayer spacing. It was found that the fluorescence property was influenced by anions in the interlayer of hydrotalcites. And it would be favorable to bind with other organic compounds to get photocatalysis materials for citric acid modified Zn-Al hydrotalcite. Meanwhile, the fluorescence intensity was enha
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3

Wang, Songlin, Xuxu Yang, Fei Wang, Zongjia Song, Hehe Dong, and Luqing Cai. "Effect of modified hydrotalcites on flame retardancy and physical properties of paper." BioResources 14, no. 2 (2019): 3991–4005. http://dx.doi.org/10.15376/biores.14.2.3991-4005.

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Functionalized layered double hydroxides (LDHs) based on a multi-modifier system composed of itaconic acid (ITA) and titanate coupling agent (NDZ-201) were designed and fabricated in this paper with the aim to develop high-performance fire retardant paper. The structure of LDHs were characterized using Fourier transform infrared spectroscopic analysis, X-ray diffraction analysis, thermogravimetric analysis (TGA), scanning electron microscopic analysis, cone calorimetry, and laser particle size analysis. The results showed that carbonate anions were partially replaced by ITA, whereas the titana
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4

Le, Diep Thi Hong, and Rachnarin Nitisoravut. "Modified hydrotalcites for enhancement of biohydrogen production." International Journal of Hydrogen Energy 40, no. 36 (2015): 12169–76. http://dx.doi.org/10.1016/j.ijhydene.2015.06.142.

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5

Klumpp, E., C. Contreras-Ortega, P. Klahre, et al. "Sorption of 2,4-dichlorophenol on modified hydrotalcites." Colloids and Surfaces A: Physicochemical and Engineering Aspects 230, no. 1-3 (2003): 111–16. http://dx.doi.org/10.1016/j.colsurfa.2003.09.018.

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6

Oliveira, Eduardo L. G., Carlos A. Grande, and Alírio E. Rodrigues. "CO2 sorption on hydrotalcite and alkali-modified (K and Cs) hydrotalcites at high temperatures." Separation and Purification Technology 62, no. 1 (2008): 137–47. http://dx.doi.org/10.1016/j.seppur.2008.01.011.

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7

Yang, Zheng Xian, Hartmut Fischer, and Rob Polder. "The Effect of Modified Hydrotalcites on Mechanical Properties and Chloride Penetration Resistance in Cement Mortar." Key Engineering Materials 629-630 (October 2014): 156–61. http://dx.doi.org/10.4028/www.scientific.net/kem.629-630.156.

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In this paper, two types of modified hydrotalcites (MHT) were incorporated into cement mortars with two dosage levels (replacing 5% and 10% cement by mass). Designated testing programme including strength test, porosity test, and rapid chloride migration and diffusion test were employed to investigate the effect of modified hydrotalcites on chloride penetration in cement mortar. The results based on these tests showed the incorporation of MHT-pAB at 5% dosage in mortar specimens produced a notably improved chloride diffusion resistance with no or minor influence on the development of mechanica
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8

Zhu, Jianxi, Peng Yuan, Hongping He, et al. "In situ synthesis of surfactant/silane-modified hydrotalcites." Journal of Colloid and Interface Science 319, no. 2 (2008): 498–504. http://dx.doi.org/10.1016/j.jcis.2007.11.037.

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9

Silva, Joel M., R. Trujillano, V. Rives, M. A. Soria, and Luis M. Madeira. "High temperature CO 2 sorption over modified hydrotalcites." Chemical Engineering Journal 325 (October 2017): 25–34. http://dx.doi.org/10.1016/j.cej.2017.05.032.

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10

Ionescu, Rodica, Octavian Dumitru Pavel, Ruxandra Bîrjega, Rodica Zăvoianu, and Emilian Angelescu. "Epoxidation of Cyclohexene With H2O2 and Acetonitrile Catalyzed by Mg–Al Hydrotalcite and Cobalt Modified Hydrotalcites." Catalysis Letters 134, no. 3-4 (2009): 309–17. http://dx.doi.org/10.1007/s10562-009-0238-y.

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11

Coral, Natasha, Henrique Brasil, Elizabeth Rodrigues, Carlos E. F. da Costa, and Victor Rumjanek. "Microwave-modified hydrotalcites for the transesterification of soybean oil." Sustainable Chemistry and Pharmacy 11 (March 2019): 49–53. http://dx.doi.org/10.1016/j.scp.2019.01.002.

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12

Scavetta, E., B. Ballarin, M. Berrettoni, I. Carpani, M. Giorgetti, and D. Tonelli. "Electrochemical sensors based on electrodes modified with synthetic hydrotalcites." Electrochimica Acta 51, no. 11 (2006): 2129–34. http://dx.doi.org/10.1016/j.electacta.2005.03.092.

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13

Costantino, U., A. Gallipoli, M. Nocchetti, G. Camino, F. Bellucci, and A. Frache. "New nanocomposites constituted of polyethylene and organically modified ZnAl-hydrotalcites." Polymer Degradation and Stability 90, no. 3 (2005): 586–90. http://dx.doi.org/10.1016/j.polymdegradstab.2005.05.019.

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14

Soares Dias, Ana Paula, Joana Bernardo, Pedro Felizardo, and Maria Joana Neiva Correia. "Biodiesel production over thermal activated cerium modified Mg-Al hydrotalcites." Energy 41, no. 1 (2012): 344–53. http://dx.doi.org/10.1016/j.energy.2012.03.005.

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15

Nieto-Zambrano, Sorelis, Esthela Ramos-Ramίrez, Francisco Tzompantzi Morales, et al. "ZnAl hydrotalcites modified with nanocomposites nZVI–PAA for environmental remediation." Journal of Materials Research and Technology 14 (September 2021): 2243–56. http://dx.doi.org/10.1016/j.jmrt.2021.06.055.

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16

Cornejo, Alfonso, Fernando Bimbela, Rui Moreira, et al. "Production of Aromatic Compounds by Catalytic Depolymerization of Technical and Downstream Biorefinery Lignins." Biomolecules 10, no. 9 (2020): 1338. http://dx.doi.org/10.3390/biom10091338.

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Lignocellulosic materials are promising alternatives to non-renewable fossil sources when producing aromatic compounds. Lignins from Populus salicaceae. Pinus radiata and Pinus pinaster from industrial wastes and biorefinery effluents were isolated and characterized. Lignin was depolymerized using homogenous (NaOH) and heterogeneous (Ni-, Cu- or Ni-Cu-hydrotalcites) base catalysis and catalytic hydrogenolysis using Ru/C. When homogeneous base catalyzed depolymerization (BCD) and Ru/C hydrogenolysis were combined on poplar lignin, the aromatics amount was ca. 11 wt.%. Monomer distributions chan
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17

Önkal-Engin, G., R. Wibulswas, and D. A. White. "Humic Acid Uptake from Aqueous Media Using Hydrotalcites and Modified Montmorillonite." Environmental Technology 21, no. 2 (2000): 167–75. http://dx.doi.org/10.1080/09593330.2000.9618897.

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18

Pérez, A., R. Otero, A. Romero Esquinas, J. R. Jiménez, and J. M. Fernández. "Potential use of modified hydrotalcites as adsorbent of Bentazon and Metazachlor." Applied Clay Science 141 (June 2017): 300–307. http://dx.doi.org/10.1016/j.clay.2017.03.007.

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19

Mastalir, Á., Á. Patzkó, B. Frank, R. Schomäcker, T. Ressler, and R. Schlögl. "Steam reforming of methanol over Cu/ZnO/Al2O3 modified with hydrotalcites." Catalysis Communications 8, no. 11 (2007): 1684–90. http://dx.doi.org/10.1016/j.catcom.2007.01.031.

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20

Szymaszek, Agnieszka, Monika Motak, and Bogdan Samojeden. "The application of modified layered double hydroxides in selective catalytic reduction of nitrogen oxides by ammonia (NH3-SCR)." Polish Journal of Chemical Technology 22, no. 1 (2020): 61–67. http://dx.doi.org/10.2478/pjct-2020-0009.

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AbstractSelective catalytic reduction with ammonia (NH3-SCR) is very efficient DeNOx technique. According to some problems with the commercial catalyst, novel one should be prepared. Hydrotalcites are potential precursors of the new catalysts of NH3-SCR. In this paper, several attempts to apply these materials in NH3-SCR are presented.
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21

Finn, M., N. An, and A. Voutchkova-Kostal. "Immobilization of imidazolium ionic liquids on hydrotalcites using silane linkers: retardation of memory effect." RSC Advances 5, no. 17 (2015): 13016–20. http://dx.doi.org/10.1039/c4ra13839b.

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We report a new covalent surface immobilization of silane-modified imidazolium ionic liquids on hydrotalcite-like materials (HTs) and provide detailed characterization of the resulting surface chemistry using PXRD, CP-MAS, TGA and FT-IR.
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22

Angelescu, E., R. Ionescu, O. D. Pavel, et al. "Epoxidation of cyclohexene with O2 and isobutyraldehyde catalysed by cobalt modified hydrotalcites." Journal of Molecular Catalysis A: Chemical 315, no. 2 (2010): 178–86. http://dx.doi.org/10.1016/j.molcata.2009.09.009.

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23

Pilch-Pitera, Barbara, Michał Kędzierski, Ewa Olejnik, and Szczepan Zapotoczny. "Structure and properties of polyurethane-based powder clear coatings systems modified with hydrotalcites." Progress in Organic Coatings 95 (June 2016): 120–26. http://dx.doi.org/10.1016/j.porgcoat.2016.03.009.

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24

Bîrjega, R., O. D. Pavel, G. Costentin, M. Che, and E. Angelescu. "Rare-earth elements modified hydrotalcites and corresponding mesoporous mixed oxides as basic solid catalysts." Applied Catalysis A: General 288, no. 1-2 (2005): 185–93. http://dx.doi.org/10.1016/j.apcata.2005.04.030.

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25

Bankauskaite, Agne, Kestutis Baltakys, and Gundars Mezinskis. "Modified hydrotalcites application as precursors for (Na,K)Mg/Al spinel-type compounds formation." Journal of Thermal Analysis and Calorimetry 118, no. 2 (2014): 711–18. http://dx.doi.org/10.1007/s10973-014-3737-z.

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26

Graus, Javier, Carlos Bueno-Alejo, and Jose Hueso. "In-Situ Deposition of Plasmonic Gold Nanotriangles and Nanoprisms onto Layered Hydroxides for Full-Range Photocatalytic Response towards the Selective Reduction of p-Nitrophenol." Catalysts 8, no. 9 (2018): 354. http://dx.doi.org/10.3390/catal8090354.

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In this work, we present photocatalysis as a greener alternative to conventional catalysis where harsh reaction conditions, temperature and/or pressure are needed. Photodegradation of organic pollutants is a cost-effective, eco-friendly solution for the decontamination of water and air, and is a field that has been continuously growing over the last decade. Plasmonic metal nanoparticles absorb light irradiation that is transferred to the chemical reaction in a different fashion. Furthermore, plasmonic nanostructures can be combined with other materials, such as semiconductors or a basic suppor
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27

Palin, Luca, Eleonora Conterosito, Marco Milanesio, et al. "Structural characterization of the of inorganic and organic hydrotalcites." Acta Crystallographica Section A Foundations and Advances 70, a1 (2014): C238. http://dx.doi.org/10.1107/s2053273314097617.

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Layered double hydroxides are versatile materials used for intercalating bioactive molecules, both in pharmaceutical and cosmetic fields, with the purpose of protecting them from degradation, enhancing their water solubility to increase bioavailability, and/or obtaining modified release properties. Hydrotalcite is commercially available in its carbonate form, which is usually transformed into the nitrate form and finally exchanged by organic anions to obtain or regulate bioactivity or photo-activity effects (1). In this study all the steps of these transformations were characterized from the s
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28

Jadhav, Amarsinh L., and Ganapati D. Yadav. "A Green Process for Selective Hydrolysis of Cinnamaldehyde in Water to Natural Benzaldehyde by Using Ti and Zn Modified Hydrotalcites as Catalysts." Current Green Chemistry 6, no. 3 (2019): 242–54. http://dx.doi.org/10.2174/2213346106666191021105244.

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Hydrolysis of Cinnamaldehyde (CNM) is one of the important processes for the production of industrially essential natural benzaldehyde. Benzaldehyde is a vital precursor in the production of perfumes, cosmetics, food, beverages, and pharmaceutical intermediates. As homogeneous base catalysts are polluting and difficult to separate, heterogeneous catalysts should be used. Hydrolysis of cinnamaldehyde to benzaldehyde was studied over modified hydrotalcite (HT) base catalysts wherein HT was activated with either zinc or titanium, by combustion synthesis using glycine or glycerol as fuel. Both the
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29

Barbosa, Graciele Vieira, Maria Aparecida Zaghete, Rafael Aparecido Ciola Amoresi, Margarete Soares da Silva, Alberto Adriano Cavalheiro, and Rogério Cesar de Lara da Silva. "Structural Analysis of Magnesium-Aluminium Hydrotalcites Modified with Iron III Obtained by Hydroxide Precipitation Method." Materials Sciences and Applications 08, no. 11 (2017): 784–97. http://dx.doi.org/10.4236/msa.2017.811057.

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30

Kishore, Dasari, and Srinivasan Kannan. "Double bond migration of eugenol to isoeugenol over as-synthesized hydrotalcites and their modified forms." Applied Catalysis A: General 270, no. 1-2 (2004): 227–35. http://dx.doi.org/10.1016/j.apcata.2004.05.008.

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31

Kolena, Jiří, Lenka Soukupová, Jaroslav Kocík, and Jaromír Lederer. "Modified hydrotalcites as precursors for catalysts effective in the hydrogenolysis of glycerol to 1,2-propanediol." Reaction Kinetics, Mechanisms and Catalysis 122, no. 2 (2017): 803–16. http://dx.doi.org/10.1007/s11144-017-1239-2.

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32

Yang, Zhengxian, H. Fischer, J. Cerezo, J. M. C. Mol, and R. Polder. "Aminobenzoate modified MgAl hydrotalcites as a novel smart additive of reinforced concrete for anticorrosion applications." Construction and Building Materials 47 (October 2013): 1436–43. http://dx.doi.org/10.1016/j.conbuildmat.2013.06.049.

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33

Albuquerque, Dantiele W. S., Elisângela S. Costa, Jussara L. de Miranda, Rosana Drumond Gonçalves, and Luiza Cristina de Moura. "Evaluation of the Behavior of Hydrotalcite Like-Materials for CO2 Capture." Applied Mechanics and Materials 830 (March 2016): 3–10. http://dx.doi.org/10.4028/www.scientific.net/amm.830.3.

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Several compounds are being investigated for CO2 capture, besides alkolamines, including solid materials as activated charcoal, zeolites, metal organic frameworks, metal oxides and hydrotalcites. Hydrotalcites, also called layered double hydroxides (LDHs), present some characteristics that are very interesting for CO2 capture, including their speed to achieve equilibrium and their high regeneration. These compounds can be represented by the general formula [M1-x2+Mx3+(OH)2]x+ [(An-)x/n.yH2O]x, where M2+ and M3+ are divalent metals and trivalent cations, respectively, and An- is an anion of val
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34

Nguyen, Duong Thuy, Hang Thi Xuan To, Julien Gervasi, Yoann Paint, Maurice Gonon, and Marie-Georges Olivier. "Corrosion inhibition of carbon steel by hydrotalcites modified with different organic carboxylic acids for organic coatings." Progress in Organic Coatings 124 (November 2018): 256–66. http://dx.doi.org/10.1016/j.porgcoat.2017.12.006.

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35

Kong, Xiangjin, Wenxiu Li, Xiaole Li, Lin Liu, Weijie Geng, and Liying Liu. "Hydrothermal depolymerization of alkali lignin to high-yield monomers over nickel nitrate modified commercial hydrotalcites catalyst." Journal of the Energy Institute 93, no. 2 (2020): 658–65. http://dx.doi.org/10.1016/j.joei.2019.05.014.

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36

Lecomte, Jérôme, Annie Finiels, and Claude Moreau. "Kinetic Study of the Isomerization of Glucose into Fructose in the Presence of Anion-modified Hydrotalcites." Starch - Stärke 54, no. 2 (2002): 75–79. http://dx.doi.org/10.1002/1521-379x(200202)54:2<75::aid-star75>3.0.co;2-f.

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37

Ren, Xiaoqian, Xi Hu, Feng Zhang, et al. "Synthesis of sulphur-modified bifunctional hydrotalcites and study of their surface characteristics by inverse gas chromatography." Catalysis Science & Technology 5, no. 10 (2015): 4813–20. http://dx.doi.org/10.1039/c5cy00765h.

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38

Cabrera-Munguia, Denis A., Horacio González, Mónica Barreto-Gutiérrez, Aída Gutiérrez-Alejandre, José L. Rico, and Dora A. Solís-Casados. "Tuning the Basic Properties of ZnAl Hydrotalcites Modified with Ce Applied to Transesterification of Soybean Oil." Catalysis Letters 150, no. 7 (2020): 1957–69. http://dx.doi.org/10.1007/s10562-020-03099-x.

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39

Pavel, O. D., B. Cojocaru, E. Angelescu, and V. I. Pârvulescu. "The activity of yttrium-modified Mg,Al hydrotalcites in the epoxidation of styrene with hydrogen peroxide." Applied Catalysis A: General 403, no. 1-2 (2011): 83–90. http://dx.doi.org/10.1016/j.apcata.2011.06.017.

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40

Yang, Zhengxian, Rob Polder, J. M. C. Mol, and Carmen Andrade. "The effect of two types of modified Mg-Al hydrotalcites on reinforcement corrosion in cement mortar." Cement and Concrete Research 100 (October 2017): 186–202. http://dx.doi.org/10.1016/j.cemconres.2017.06.004.

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41

Viterbo, Davide, Eleonora Conterosito, Gianluca Croce, et al. "Carbonate contamination in nitrate and organic hydrotalcites by XRPD/TGA-GC-MS." Acta Crystallographica Section A Foundations and Advances 70, a1 (2014): C955. http://dx.doi.org/10.1107/s2053273314090445.

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Layered double hydroxides are versatile materials used for intercalating bioactive molecules, both in pharmaceutical and cosmetic fields, with the purpose of protecting them from degradation, enhancing their water solubility to increase bioavailability, and/or obtaining modified release properties. The crystal chemistry of hydrotalcite-like compounds is investigated by X-ray powder diffraction (XRPD) and hyphenated TGA-GC-MS to shed light on the mechanisms involved in ion exchange and absorption of contaminants, mainly carbonate anions. XRPD demonstrated that the presence of carbonate is able
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42

Filez, Matthias, Evgeniy A. Redekop, Hilde Poelman, et al. "Unravelling the Formation of Pt–Ga Alloyed Nanoparticles on Calcined Ga-Modified Hydrotalcites by in Situ XAS." Chemistry of Materials 26, no. 20 (2014): 5936–49. http://dx.doi.org/10.1021/cm502658d.

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43

Zhai, Shaoyan, Weiyou Zhou, Xuan Dai та ін. "Efficient Synthesis of α,β -Unsaturated Ketones from Primary Alcohols and Ketones over Mg2+ -Modified NiGa Hydrotalcites". ChemistrySelect 3, № 40 (2018): 11284–92. http://dx.doi.org/10.1002/slct.201801862.

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44

Yang, Zhengxian, Hartmut Fischer, and Rob Polder. "Laboratory investigation of the influence of two types of modified hydrotalcites on chloride ingress into cement mortar." Cement and Concrete Composites 58 (April 2015): 105–13. http://dx.doi.org/10.1016/j.cemconcomp.2014.12.016.

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45

Kolena, Jiří, Lenka Soukupová, Jaroslav Kocík, and Jaromír Lederer. "Erratum to: Modified hydrotalcites as precursors for catalysts effective in the hydrogenolysis of glycerol to 1,2-propanediol." Reaction Kinetics, Mechanisms and Catalysis 122, no. 2 (2017): 817. http://dx.doi.org/10.1007/s11144-017-1250-7.

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46

Coelho, Christian, Thomas Stimpfling, Fabrice Leroux, and Vincent Verney. "Inorganic-Organic Hybrid Materials Based on Amino Acid Modified Hydrotalcites Used as UV-Absorber Fillers for Polybutylene Succinate." European Journal of Inorganic Chemistry 2012, no. 32 (2012): 5252–58. http://dx.doi.org/10.1002/ejic.201200525.

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47

Yang, Zhengxian, Hartmut Fischer, and Rob Polder. "Synthesis and characterization of modified hydrotalcites and their ion exchange characteristics in chloride-rich simulated concrete pore solution." Cement and Concrete Composites 47 (March 2014): 87–93. http://dx.doi.org/10.1016/j.cemconcomp.2013.03.008.

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48

Suescum-Morales, David, David Cantador-Fernández, José Ramón Jiménez, and José María Fernández. "Potential CO2 capture in one-coat limestone mortar modified with Mg3Al–CO3 calcined hydrotalcites using ultrafast testing technique." Chemical Engineering Journal 415 (July 2021): 129077. http://dx.doi.org/10.1016/j.cej.2021.129077.

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49

Rodríguez, Augusto, Lenys Fernández, José R. Domínguez, Gema González, Omar Martínez, and Patricio Espinoza-Montero. "Mg and Ni nano-hydrotalcites modified with gold nanoparticles as platform of enzymatic electrochemical sensors for H2O2 detection." Sensing and Bio-Sensing Research 33 (August 2021): 100446. http://dx.doi.org/10.1016/j.sbsr.2021.100446.

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50

Yang, Z., H. Fischer, and R. Polder. "Modified hydrotalcites as a new emerging class of smart additive of reinforced concrete for anticorrosion applications: A literature review." Materials and Corrosion 64, no. 12 (2013): 1066–74. http://dx.doi.org/10.1002/maco.201206915.

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