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Journal articles on the topic 'MoF6'

Author: Grafiati

Published: 4 June 2021

Last updated: 1 February 2022

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1

Dinman, J. D., and R. B. Wickner. "Translational maintenance of frame: mutants of Saccharomyces cerevisiae with altered -1 ribosomal frameshifting efficiencies." Genetics 136, no. 1 (1994): 75–86. http://dx.doi.org/10.1093/genetics/136.1.75.

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Abstract A special site on the (+) strand of the L-A dsRNA virus induces about 2% of ribosomes translating the gag open reading frame to execute a -1 frameshift and thus produce the viral gag-pol fusion protein. Using constructs in which a -1 ribosomal frameshift at this site was necessary for expression of lacZ we isolated chromosomal mutants in which the efficiency of frameshifting was increased. These mutants comprise eight genes, named mof (maintenance of frame). The mof1-1, mof2-1, mof4-1, mof5-1 and mof6-1 strains cannot maintain M1 dsRNA at 30 degrees, but, paradoxically, do not lose L-A. The mof2-1, mof5-1 and mof6-1 strains are temperature sensitive for growth at 37 degrees, and all three show striking cell cycle phenotypes. The mof2-1 strains arrest with mother and daughter cells almost equal in size, mof5-1 arrests with multiple buds and mof6-1 arrests as single large unbudded cells. mof2-1 and mof5-1 strains are also Pet-. The mof mutations show differential effects on various frameshifting signals.

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2

Ameen, Mubarak, Adelaja Akinlolu, Mukadam Abdulhamid, et al. "Effects of MOF6 Fraction from Ethanolic Extract of the Leaves of Moringa oleifera against Sodium Arsenite-Induced Hepatotoxicity in Rats." Ethiopian Pharmaceutical Journal 36, no. 2 (2021): 73–80. http://dx.doi.org/10.4314/epj.v36i2.1.

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Moringa oleifera (MO) is a plant of significant medicinal importance. The dried leaves of MO were pulverized, extracted with ethanol and fractionated using column chromatography to provide seven fractions (MOF1-7) with MOF6 having the best preliminary antioxidant potential. Therefore, this study evaluated the hepatoprotective potentials of MOF6 in sodium arsenite (SA)-induced hepatotoxicity in rats. Thirty-five adult male Wistar rats were randomly divided into seven groups of five rats each. Control Group I received normal saline. Groups II and III received 20 mg/kg body weight (bw) of SA for 3 and 6 weeks, respectively. Groups IV and V received 20 mg/kg bw of SA for 3 weeks followed by treatment with 5.0 and 7.5 mg/kg bw of fraction MOF6, respectively, for 6 weeks. Groups VI and VII received only 5.0 and 7.5 mg/kg bw of fraction MOF6, respectively, for 6 weeks. Antioxidant (lipid peroxidation) and biochemical analyses of liver enzymes of all rats were carried out after the completion of experimental procedures. Results showed statistically significant lower mean values (p ≤ 0.05) of malondialdehyde (MDA), acid phosphatase (ACP) and γ-glutamyl transferase (GGT) in rats of Groups IV and V compared with Group III. However, there were statistically significant higher mean values (p ≤ 0.05) of alkaline phosphatase (ALP) in Groups IV and V compared with Groups I and III. In conclusion, these results implied that fraction MOF6 has antioxidant and hepatoprotective potentials. However, results of ALP analyses implied that MOF6 possibly augmented SA-induced hepatotoxicity in rats.

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3

Friedman, Jeffrey F., Amy E. Stevens, Thomas M. Miller, and A. A. Viggiano. "Electron attachment to MoF6, ReF6, and WF6; reaction of MoF6− with ReF6 and reaction of Ar+ with MoF6." Journal of Chemical Physics 124, no. 22 (2006): 224306. http://dx.doi.org/10.1063/1.2202851.

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4

Oyama, Toshiyuki, Sakae Satooka, Shuji Kato, Katsumi Midorikawa, Hideo Tashiro, and Kazuo Takeuchi. "Isotopically Selective Infrared Multiple-Photon Dissociation of MoF6 by a H2-Raman Laser." Laser Chemistry 8, no. 2-4 (1988): 235–42. http://dx.doi.org/10.1155/lc.8.235.

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Infrared multiple-photon dissociation (IRMPD) of MoF6 has been investigated with a parallel beam of a para-H2 Raman laser newly developed by our group. MoF6 gas (2 Torr, natural abundance) was put into in a static cell cooled to −58℃ and was irradiated with the laser line at 728 cm−1. The critical fluence of 0.11 Jcm−2 for complete dissociation was determined by analysis with a Gaussian beam model. Irradiation at the lower frequency side (728 cm−1) of the MoF6 ν3 band enriched the lighter isotopes in the residue. A maximum value for selectivity of 1.1 was obtained.

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5

Quiñones, Gustavo Santiso, Gerhard Hägele, and Konrad Seppelt. "MoF6 and WF6: Nonrigid Molecules?" Chemistry - A European Journal 10, no. 19 (2004): 4755–62. http://dx.doi.org/10.1002/chem.200400095.

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6

Akinlolu, Adelaja, Mubarak Ameen, Tobilola Quadri, et al. "Extraction, isolation and evaluation of anti-toxic principles from Moringa oleifera (MOF6) and Myristica fragrans (Trimyristin) upregulated Acetylcholinesterase concentrations in Sodium arsenite-induced neurotoxicity in rats." Journal of Phytomedicine and Therapeutics 19, no. 2 (2021): 466–82. http://dx.doi.org/10.4314/jopat.v19i2.1.

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This study evaluated the neuroprotective effects of MOF6 (isolated from Moringa oleifera leaves) and Trimyristin (isolated from Myristica fragrans seeds) on Acetylcholinesterase concentrations in cerebral cortices of rats with Sodium arsenite-induced neurotoxicity. Sixty-five adult male rats (150 g-250 g) were randomly divided into thirteen groups comprising of five rats per group. Groups 1 and 3 received physiological saline and 1 ml/200 g bodyweight of Olive oil respectively for 9 weeks. Group 2 received 20 mg/kg bodyweight of Sodium arsenite (SA) for 6 weeks and left untreated for another 3 weeks. Groups 4-5 received 20 mg/kg bodyweight of SA for 3 weeks followed by treatments with 5.0 and 7.5 mg/kg bodyweight of MOF6 respectively for 6 weeks. Groups 6-7 received 20 mg/kg bodyweight of SA for 3 weeks followed by treatments with 15 and 30 mg/kg bodyweight of Trimyristin respectively for 6 weeks. Groups 8-11 received 5.0 and 7.5 mg/kg bodyweight of MOF6; 15 and 30 mg/kg bodyweight of Trimyristin respectively for 9 weeks. Groups 12-13 received 7.5 mg/kg bodyweight of MOF6 and 30 mg/kg bodyweight of Trimyristin respectively for 6 weeks followed by co-administration of each extract dose with 20 mg/kg bodyweight of SA for another 3 weeks. Histological examination of cerebral cortices and biochemical analyses of Acetylcholinesterase concentrations were carried out in all rats. Computed data were analyzed using Microsoft Excel 2016 with statistical significance at p≤0.05. Histo-pathological evaluations revealed normal histo-architecture of cerebral cortices of all rats. Results showed statistically significant (p≤0.05) increases in Acetylcholinesterase concentrations in rats of Groups 1-10 and 12 compared with Group 2 (2.78±1.76 𝜇mole/min/g). 7.5 mg/kg bodyweight of MOF6 showed the best therapeutic and neuro-regenerative potential against SA-induced neurotoxicity.Conclusions: Our findings implied that MOF6 and Trimyristin reversed downregulation of Acetylcholinesterase concentrations in SA-induced neurotoxicity in rats; and possess neuro-protective and neuro-regenerative potentials.

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7

Lee, Woo Y., Theodore M. Besmann, and Michael W. Stott. "Preparation of MoS2 thin films by chemical vapor deposition." Journal of Materials Research 9, no. 6 (1994): 1474–83. http://dx.doi.org/10.1557/jmr.1994.1474.

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The chemical vapor deposition (CVD) of MoS2 by reaction of H2S with molybdenum halides was determined to be thermodynamically favored over a wide range of temperature, pressure, and precursor concentration conditions as long as excess H2S was available. The thermochemical stability of H2S, MoF6, and MoCI5 was also assessed to address their suitability as precursors for the CVD of MoS2. The results from the thermodynamic analysis were used as guidance in the deposition of MoS2 thin films from MoF6 and H2S. The (002) basal planes of MoS2 films deposited above 700 K were preferentially oriented perpendicular to the substrate surface.

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8

Ehrhorn, Henrike, Janin Schlösser, Dirk Bockfeld, and Matthias Tamm. "Efficient catalytic alkyne metathesis with a fluoroalkoxy-supported ditungsten(III) complex." Beilstein Journal of Organic Chemistry 14 (September 18, 2018): 2425–34. http://dx.doi.org/10.3762/bjoc.14.220.

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The molybdenum and tungsten complexes M2(OR)6 (Mo2F6, M = Mo, R = C(CF3)2Me; W2F3, M = W, R = OC(CF3)Me2) were synthesized as bimetallic congeners of the highly active alkyne metathesis catalysts [MesC≡M{OC(CF3) n Me3− n }] (MoF6, M = Mo, n = 2; WF3, M = W, n = 1; Mes = 2,4,6-trimethylphenyl). The corresponding benzylidyne complex [PhC≡W{OC(CF3)Me2}] (W Ph F3) was prepared by cleaving the W≡W bond in W2F3 with 1-phenyl-1-propyne. The catalytic alkyne metathesis activity of these metal complexes was determined in the self-metathesis, ring-closing alkyne metathesis and cross-metathesis of internal and terminal alkynes, revealing an almost equally high metathesis activity for the bimetallic tungsten complex W2F3 and the alkylidyne complex W Ph F3. In contrast, Mo2F6 displayed no significant activity in alkyne metathesis.

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9

Wang, G., P. K. Ummat, W. R. Datars, and Zhibing Hu. "The de Haas van Alphen effect of MoF6− intercalated graphite." Canadian Journal of Physics 73, no. 7-8 (1995): 489–92. http://dx.doi.org/10.1139/p95-070.

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The de Haas van Alphen (dHvA) effect of the stage-1 MoF6− graphite intercalation compound was investigated in magnetic fields up to 5.5 T. The dHvA-frequency spectrum of the stage-1 compound consists of a high frequency, a midfrequency, and a set of low frequencies. The dominant oscillation is the high frequency at 1530 T. It is associated with the single graphite energy band of the stage-1 compound. The cyclotron mass of the carrier with the dominant frequency is 0.31 m0 where m0 is the free-electron mass. The electron charge transfer per intercalated MoF6− molecule is 0.3 for the C8.4MoF6 compound. The low frequencies and midfrequencies are compared with those in other stage-1 chloride graphite intercalation compounds.

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10

Ursu, I., M. Bogdan, P. Fitori, A. Darabont, and D. E. Demco. "19F spin-lattice relaxation in WF6, MoF6, and UF6gases." Molecular Physics 56, no. 2 (1985): 297–302. http://dx.doi.org/10.1080/00268978500102321.

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11

Zhang, Zenghui, Cheng-An Tao, Jie Zhao, Fang Wang, Jian Huang, and Jianfang Wang. "Microwave-Assisted Solvothermal Synthesis of UiO-66-NH2 and Its Catalytic Performance toward the Hydrolysis of a Nerve Agent Simulant." Catalysts 10, no. 9 (2020): 1086. http://dx.doi.org/10.3390/catal10091086.

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Zr-containing metal-organic frameworks (MOFs) exhibit a good performance of catalyzing the hydrolysis of chemical warfare agents, which is closely related to the size of MOF particles and its defects, but these two factors are often intertwined. In this article, we synthesized UiO-66-NH2 nanoparticles using a microwave-assisted hydrothermal method. By using a new modulator 4-Fluoro-3-Formyl-Benzoic Acid (FFBA) in different proportions, MOF particles with the same defect degree but different scales and those with similar sizes but different defect degrees can be obtained. The performance of the obtained MOF particles to catalyze the hydrolysis of the nerve agent simulant, dimethyl 4-nitrophenyl phosphate (DMNP), was investigated, and the effects of single factors of size or defect were compared for the first time. As the size of the obtained MOF particles increased from 81 nm to 159 nm, the catalytic degradation efficiency toward DMNP gradually decreased, and the half-life increased from 3.9 min to 11.1 min. For MOFs that have similar crystal sizes, the catalytic degradation half-life of MOF3 is only 5 min, which is much smaller than that of MOF5 due to the defects increase from 1.2 to 1.8 per Zr6 cluster.

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12

Takami, Michio, та Yoshiyasu Matsumoto. "Free jet infrared absorption spectroscopy of the ν3band of MoF6". Molecular Physics 64, № 4 (1988): 645–58. http://dx.doi.org/10.1080/00268978800100463.

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13

Miyoshi, Eisaku, Yoshiko Sakai, Akinori Murakami, et al. "On the electron affinities of hexafluorides CrF6, MoF6, and WF6." Journal of Chemical Physics 89, no. 7 (1988): 4193–98. http://dx.doi.org/10.1063/1.455690.

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14

Meskauskas, Arturas, Jennifer L. Baxter, Edward A. Carr, et al. "Delayed rRNA Processing Results in Significant Ribosome Biogenesis and Functional Defects." Molecular and Cellular Biology 23, no. 5 (2003): 1602–13. http://dx.doi.org/10.1128/mcb.23.5.1602-1613.2003.

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ABSTRACT mof6-1 was originally isolated as a recessive mutation in Saccharomyces cerevisiae which promoted increased efficiencies of programmed −1 ribosomal frameshifting and rendered cells unable to maintain the killer virus. Here, we demonstrate that mof6-1 is a unique allele of the histone deacetylase RPD3, that the deacetylase function of Rpd3p is required for controlling wild-type levels of frameshifting and virus maintenance, and that the closest human homolog can fully complement these defects. Loss of the Rpd3p-associated histone deacetylase function, either by mutants of rpd3 or loss of the associated gene product Sin3p or Sap30p, results in a delay in rRNA processing rather than in an rRNA transcriptional defect. This results in production of ribosomes having lower affinities for aminoacyl-tRNA and diminished peptidyltransferase activities. We hypothesize that decreased rates of peptidyl transfer allow ribosomes with both A and P sites occupied by tRNAs to pause for longer periods of time at −1 frameshift signals, promoting increased programmed −1 ribosomal frameshifting efficiencies and subsequent loss of the killer virus. The frameshifting defect is accentuated when the demand for ribosomes is highest, suggesting that rRNA posttranscriptional modification is the bottleneck in ribosome biogenesis.

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15

Mane, Anil U., Steven Letourneau, David J. Mandia, et al. "Atomic layer deposition of molybdenum disulfide films using MoF6 and H2S." Journal of Vacuum Science & Technology A: Vacuum, Surfaces, and Films 36, no. 1 (2018): 01A125. http://dx.doi.org/10.1116/1.5003423.

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16

Kjems, J. K., D. Vaknin, D. Davidov, H. Selig, and Y. Yeshurun. "Incommensurate structures OsF6 and MoF6 graphite intercalates studied by neutron scattering." Synthetic Metals 23, no. 1-4 (1988): 113–19. http://dx.doi.org/10.1016/0379-6779(88)90470-5.

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17

Kirschner, A., A. Kreter, P. Wienhold, et al. "Modelling of deposition and erosion of injected WF6 and MoF6 in TEXTOR." Nuclear Materials and Energy 12 (August 2017): 564–68. http://dx.doi.org/10.1016/j.nme.2016.10.022.

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18

Stene, Riane E., Benjamin Scheibe, Winfried Petry, and Florian Kraus. "Synthesis and Characterization of the Hexafluoridomolybdates(V) A [MoF6 ] (A = Li - Cs)." European Journal of Inorganic Chemistry 2020, no. 19 (2020): 1834–43. http://dx.doi.org/10.1002/ejic.202000141.

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19

Stene, Riane E., Benjamin Scheibe, Winfried Petry, and Florian Kraus. "Synthesis and Characterization of the Hexafluoridomolybdates(V) A [MoF6 ] (A = Li - Cs)." European Journal of Inorganic Chemistry 2020, no. 19 (2020): 1820. http://dx.doi.org/10.1002/ejic.202000420.

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20

McGhee, L., and J. M. Winfield. "Oxidation of I2, Br2 and Cl2 by MoF6 and UF6 in acetonitrile." Journal of Fluorine Chemistry 35, no. 1 (1987): 105. http://dx.doi.org/10.1016/0022-1139(87)95082-2.

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21

Morita, Hiroshi, Hiromi Nakai, Pasquale Tomasello, and Hiroshi Nakatsuji. "Theoretical Study of the Ionized Electronic Structure of the Octahedral Complex MoF6." Bulletin of the Chemical Society of Japan 69, no. 7 (1996): 1893–99. http://dx.doi.org/10.1246/bcsj.69.1893.

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22

Dhankhar, Sandeep Singh, Nayuesh Sharma, and C. M. Nagaraja. "Construction of bifunctional 2-fold interpenetrated Zn(ii) MOFs exhibiting selective CO2 adsorption and aqueous-phase sensing of 2,4,6-trinitrophenol." Inorganic Chemistry Frontiers 6, no. 4 (2019): 1058–67. http://dx.doi.org/10.1039/c9qi00044e.

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Design of Zn(ii) MOFs, [{Zn(BINDI)<sub>0.5</sub>(bpa)<sub>0.5</sub>(H<sub>2</sub>O)}·4H<sub>2</sub>O]<sub>n</sub> (MOF1) and [{Zn(BINDI)<sub>0.5</sub>(bpe)}·3H<sub>2</sub>O]<sub>n</sub> (MOF2) for selective CO<sub>2</sub> storage and aqueous-phase detection of TNP is demonstrated.

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23

HUNT, R. D., L. ANDREWS, and L. M. TOTH. "ChemInform Abstract: Matrix IR Spectra of HCl Complexes with UF6, WF6, and MoF6." ChemInform 23, no. 1 (2010): no. http://dx.doi.org/10.1002/chin.199201003.

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24

Cui, Rongrong, Zhiqiang Cheng, Qiang Dou, and Qingnuan Li. "Study on the adsorption behavior of UF6 and MoF6 on the NaF adsorbents." Journal of Radioanalytical and Nuclear Chemistry 326, no. 1 (2020): 603–10. http://dx.doi.org/10.1007/s10967-020-07360-w.

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25

Poh, Hwee Ling, Zdeněk Sofer, Kateřina Klímová, and Martin Pumera. "Fluorographenes via thermal exfoliation of graphite oxide in SF6, SF4 and MoF6 atmospheres." J. Mater. Chem. C 2, no. 26 (2014): 5198–207. http://dx.doi.org/10.1039/c4tc00395k.

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26

Vaknin, D., D. Davidov, H. Selig, and Y. Yeshurun. "Magnetic and electronic properties of HOPG/MoF6 graphite intercalation compounds: An ESR study." Journal of Chemical Physics 83, no. 8 (1985): 3859–62. http://dx.doi.org/10.1063/1.449096.

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27

Brunet, F., H. le Bail, and J. Virlet. "Effets quadrupulaires en R.M.N. de 95Mo et 97Mo dans MoF6 en phase condensée." Journal of Fluorine Chemistry 35, no. 1 (1987): 241–42. http://dx.doi.org/10.1016/0022-1139(87)95187-6.

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28

Kim, Youngjun, Daeguen Choi, Whang Je Woo, et al. "Synthesis of two-dimensional MoS2/graphene heterostructure by atomic layer deposition using MoF6 precursor." Applied Surface Science 494 (November 2019): 591–99. http://dx.doi.org/10.1016/j.apsusc.2019.07.168.

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29

Artyukhov, A. A., Ya M. Kravets, M. B. Seregin, D. Yu Chuvilin, A. V. Shatrov, and N. G. Shchepetov. "Transfer by metallic service lines and sorption extraction of MoF6 from the gas flow." Journal of Engineering Physics and Thermophysics 83, no. 2 (2010): 235–42. http://dx.doi.org/10.1007/s10891-010-0338-y.

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30

Lee, Woo Y., and Karren L. More. "Crystal orientation and near-interface structure of chemically vapor deposited MoS2 films." Journal of Materials Research 10, no. 1 (1995): 49–53. http://dx.doi.org/10.1557/jmr.1995.0049.

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Crystalline MoS2 films were deposited on Si and graphite substrates using MoF6 and H2S as precursors. The crystal orientation and near-interface structure of the MoS2 films were studied using transmission electron microscopy. In general, the preferred orientation of the (002) basal planes of the MoS2 films with respect to the substrate surface changed from parallel to perpendicular with increased deposition temperature from 320 to 430 °C. At 430 °C, the basal planes were primarily oriented perpendicular to the Si substrate, except for the presence of a ∼5 nm interface region in which the basal planes were oriented in the parallel direction. The formation of this transitional region was also observed on the graphite substrate.

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31

Bittner, Celine, Dirk Bockfeld, and Matthias Tamm. "Formation of alkyne-bridged ferrocenophanes using ring-closing alkyne metathesis on 1,1’-diacetylenic ferrocenes." Beilstein Journal of Organic Chemistry 15 (October 24, 2019): 2534–43. http://dx.doi.org/10.3762/bjoc.15.246.

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Novel alkyne-bridged ferrocenophanes [fc{CO2(CH2) n C≡}2] (2a: n = 2; 2b: n = 3) were synthesized from the corresponding terminal diacetylenic ferrocenes [fc{CO2(CH2) n C≡CH}2] (1a: n = 2; 1b: n = 3) through ring-closing alkyne metathesis (RCAM) utilizing the highly effective molybdenum catalyst [MesC≡Mo{OC(CF3)2CH3}3] (MoF6; Mes = 2,4,6-trimethylphenyl). The metathesis reaction occurs in short time with high yields whilst giving full conversion of the terminal alkynes. Furthermore, the solvent-dependant reactivity of 2a towards Ag(SbF6) is investigated, leading to oxidation and formation of the ferrocenium hexafluoroantimonate 4 in dichloromethane, whereas the silver(I) coordination polymer 5 was isolated from THF solution.

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32

Parsons, Ian W., and Stephen J. Till. "Quasi-relativistic MSX? calculations of a 1g potential-energy curves for MoF6, WF6 and UF6." Journal of the Chemical Society, Faraday Transactions 89, no. 1 (1993): 25. http://dx.doi.org/10.1039/ft9938900025.

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33

HUNT, R. D., L. ANDREWS, and L. M. TOTH. "ChemInform Abstract: IR Spectra of UF6, WF6, MoF6, and SF6 Complexes with Hydrogen Fluoride in Solid Argon." ChemInform 22, no. 17 (2010): no. http://dx.doi.org/10.1002/chin.199117004.

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34

Brisdon, Alan K., John H. Holloway, Eric G. Hope, William Levason, J. Steven Ogden, and Ahmed K. Saad. "Metal K-edge extended X-ray absorption fine structure studies of MoF6, RuF6, RhF6 and related fluoroanions." Journal of the Chemical Society, Dalton Transactions, no. 3 (1992): 447. http://dx.doi.org/10.1039/dt9920000447.

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35

Fonseca, Javier, Tenghua Gong, Li Jiao, and Hai-Long Jiang. "Metal–organic frameworks (MOFs) beyond crystallinity: amorphous MOFs, MOF liquids and MOF glasses." Journal of Materials Chemistry A 9, no. 17 (2021): 10562–611. http://dx.doi.org/10.1039/d1ta01043c.

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The field of MOFs has been incorrectly believed to be purely crystalline. Herein, non-crystalline MOFs (amorphous MOFs, MOF liquids, and MOF glasses) are reviewed. Future research directions are also discussed.

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36

Falaleyev, A. G., V. A. Andreyev, and V. I. Vovna. "Ab initioMO calculations on the stability of the CF4+, PF5+, SF6+, and MoF6+ ions with the F1s core hole." International Journal of Quantum Chemistry 43, no. 4 (1992): 573–78. http://dx.doi.org/10.1002/qua.560430409.

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37

BRISDON, A. K., J. H. HOLLOWAY, E. G. HOPE, W. LEVASON, J. S. OGDEN, and A. K. SAAD. "ChemInform Abstract: Metal K-Edge Extended X-Ray Absorption Fine Structure Studies of MoF6, RuF6, RhF6 and Related Fluoroanions." ChemInform 23, no. 15 (2010): no. http://dx.doi.org/10.1002/chin.199215002.

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38

Prouff, N., R. M. Siddique, and J. M. Winfield. "Oxidation of 3d transition metals by MoF6 and WF6 in acetonitrile and some reactions of the solvated cation producrs." Journal of Fluorine Chemistry 35, no. 1 (1987): 129. http://dx.doi.org/10.1016/0022-1139(87)95104-9.

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39

Guillot, Florence, Christine Dézarnaud-Dandine, Michel Tronc, Adriana Lisini, Piero Decleva, and Giovanna Fronzoni. "Experimental and ab initio study of the molybdenum K and L edge excitation in Mo(CO)6 and MoF6." Chemical Physics 191, no. 1-3 (1995): 289–302. http://dx.doi.org/10.1016/0301-0104(94)00338-b.

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40

Zhang, Liangliang, Zixi Kang, Xuelian Xin, and Daofeng Sun. "Metal–organic frameworks based luminescent materials for nitroaromatics sensing." CrystEngComm 18, no. 2 (2016): 193–206. http://dx.doi.org/10.1039/c5ce01917f.

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During the various applications of MOFs, the photoluminescence properties of MOFs have received growing attention, especially for nitroaromatics (NACs) sensing. In this highlight, we summarize the progress in recent research in NACs sensing based on MOFs and sensing applications for nano-MOF type materials and MOF film.

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41

Seth, Soana, Govardhan Savitha, and Jarugu Narasimha Moorthy. "Diverse isostructural MOFs by postsynthetic metal node metathesis: anionic-to-cationic framework conversion, luminescence and separation of dyes." Journal of Materials Chemistry A 3, no. 45 (2015): 22915–22. http://dx.doi.org/10.1039/c5ta04551g.

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Postsynthetic metal-node metathesis of a flexible, yet robust porous anionic Cd–MOF with different metal ions of varying ionic radii, charges and chemical nature leads to diverse isostructural MOFs. The Eu@MOF and Tb@MOF – accessed by PSME – are brilliantly luminescent. The modified MOFs permit organic dye separation.

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42

Heo, Do Yeon, Ha Huu Do, Sang Hyun Ahn, and Soo Young Kim. "Metal-Organic Framework Materials for Perovskite Solar Cells." Polymers 12, no. 9 (2020): 2061. http://dx.doi.org/10.3390/polym12092061.

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Metal-organic frameworks (MOFs) and MOF-derived materials have been used for several applications, such as hydrogen storage and separation, catalysis, and drug delivery, owing to them having a significantly large surface area and open pore structure. In recent years, MOFs have also been applied to thin-film solar cells, and attractive results have been obtained. In perovskite solar cells (PSCs), the MOF materials are used in the form of an additive for electron and hole transport layers, interlayer, and hybrid perovskite/MOF. MOFs have the potential to be used as a material for obtaining PSCs with high efficiency and stability. In this study, we briefly explain the synthesis of MOFs and the performance of organic and dye-sensitized solar cells with MOFs. Furthermore, we provide a detailed overview on the performance of the most recently reported PSCs using MOFs.

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Feng, Liang, Kun-Yu Wang, Xiu-Liang Lv, Tian-Hao Yan, and Hong-Cai Zhou. "Hierarchically porous metal–organic frameworks: synthetic strategies and applications." National Science Review 7, no. 11 (2019): 1743–58. http://dx.doi.org/10.1093/nsr/nwz170.

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Abstract Despite numerous advantages, applications of conventional microporous metal–organic frameworks (MOFs) are hampered by their limited pore sizes, such as in heterogeneous catalysis and guest delivery, which usually involve large molecules. Construction of hierarchically porous MOFs (HP-MOFs) is vital to achieve the controllable augmentation of MOF pore size to mesopores or even macropores, which can enhance the diffusion kinetics of guests and improve the storage capacity. This review article focuses on recent advances in the methodology of HP-MOF synthesis, covering preparation of HP-MOFs with intrinsic hierarchical pores, and modulated, templated and template-free synthetic strategies for HP-MOFs. The key factors which affect the formation of HP-MOF architectures are summarized and discussed, followed by a brief review of their applications in heterogeneous catalysis and guest encapsulation. Overall, this review presents a roadmap that will guide the future design and development of HP-MOF materials with molecular precision and mesoscopic complexity.

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Stene, Riane E., Benjamin Scheibe, Winfried Petry, and Florian Kraus. "Front Cover: Synthesis and Characterization of the Hexafluoridomolybdates(V) A [MoF6 ] (A = Li - Cs) (Eur. J. Inorg. Chem. 19/2020)." European Journal of Inorganic Chemistry 2020, no. 19 (2020): 1819. http://dx.doi.org/10.1002/ejic.202000419.

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Jeong, WooSeok, Dae-Woon Lim, Sungjune Kim, et al. "Modeling adsorption properties of structurally deformed metal–organic frameworks using structure–property map." Proceedings of the National Academy of Sciences 114, no. 30 (2017): 7923–28. http://dx.doi.org/10.1073/pnas.1706330114.

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Structural deformation and collapse in metal-organic frameworks (MOFs) can lead to loss of long-range order, making it a challenge to model these amorphous materials using conventional computational methods. In this work, we show that a structure–property map consisting of simulated data for crystalline MOFs can be used to indirectly obtain adsorption properties of structurally deformed MOFs. The structure–property map (with dimensions such as Henry coefficient, heat of adsorption, and pore volume) was constructed using a large data set of over 12000 crystalline MOFs from molecular simulations. By mapping the experimental data points of deformed SNU-200, MOF-5, and Ni-MOF-74 onto this structure–property map, we show that the experimentally deformed MOFs share similar adsorption properties with their nearest neighbor crystalline structures. Once the nearest neighbor crystalline MOFs for a deformed MOF are selected from a structure–property map at a specific condition, then the adsorption properties of these MOFs can be successfully transformed onto the degraded MOFs, leading to a new way to obtain properties of materials whose structural information is lost.

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Rowe, Jennifer M., Erin M. Soderstrom, Jie Zhu, Pavel M. Usov, and Amanda J. Morris. "Synthesis, characterization, and luminescent properties of two new Zr(IV) metal–organic frameworks based on anthracene derivatives." Canadian Journal of Chemistry 96, no. 9 (2018): 875–80. http://dx.doi.org/10.1139/cjc-2017-0445.

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Metal–organic frameworks (MOFs) are crystalline materials constructed from metal ions or clusters, connected by multidentate organic ligands. Herein, we describe the synthesis and photophysical properties of two Zr-based, anthracene-containing MOFs, assembled from 2,6-anthracenedicarboxylic acid (2,6-ADCA and 2,6-MOF) and 1,4-anthracenedicarboxylic acid (1,4-ADCA and 1,4-MOF). The 2,6-ADCA analogue formed a highly crystalline octahedral structure that is isostructural with the well-known UiO-67 frameworks. Incorporation of the 1,4-ADCA ligand, on the other hand, resulted in large rod-shaped crystals. Both MOFs exhibit linker-based luminescence. The excited-state properties of the 2,6-MOF and 1,4-MOF were examined using stead-state diffuse reflectance and emission spectroscopies and time-correlated single photon counting (TCSPC) spectroscopy. The photophysical properties of the MOFs are compared with those of the corresponding ligand in solution.

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Rasheed, Tahir, Komal Rizwan, Muhammad Bilal, and Hafiz M. N. Iqbal. "Metal-Organic Framework-Based Engineered Materials—Fundamentals and Applications." Molecules 25, no. 7 (2020): 1598. http://dx.doi.org/10.3390/molecules25071598.

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Metal-organic frameworks (MOFs) are a fascinating class of porous crystalline materials constructed by organic ligands and inorganic connectors. Owing to their noteworthy catalytic chemistry, and matching or compatible coordination with numerous materials, MOFs offer potential applications in diverse fields such as catalysis, proton conduction, gas storage, drug delivery, sensing, separation and other related biotechnological and biomedical applications. Moreover, their designable structural topologies, high surface area, ultrahigh porosity, and tunable functionalities all make them excellent materials of interests for nanoscale applications. Herein, an effort has been to summarize the current advancement of MOF-based materials (i.e., pristine MOFs, MOF derivatives, or MOF composites) for electrocatalysis, photocatalysis, and biocatalysis. In the first part, we discussed the electrocatalytic behavior of various MOFs, such as oxidation and reduction candidates for different types of chemical reactions. The second section emphasizes on the photocatalytic performance of various MOFs as potential candidates for light-driven reactions, including photocatalytic degradation of various contaminants, CO2 reduction, and water splitting. Applications of MOFs-based porous materials in the biomedical sector, such as drug delivery, sensing and biosensing, antibacterial agents, and biomimetic systems for various biological species is discussed in the third part. Finally, the concluding points, challenges, and future prospects regarding MOFs or MOF-based materials for catalytic applications are also highlighted.

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Giliopoulos, Dimitrios, Alexandra Zamboulis, Dimitrios Giannakoudakis, Dimitrios Bikiaris, and Konstantinos Triantafyllidis. "Polymer/Metal Organic Framework (MOF) Nanocomposites for Biomedical Applications." Molecules 25, no. 1 (2020): 185. http://dx.doi.org/10.3390/molecules25010185.

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The utilization of polymer/metal organic framework (MOF) nanocomposites in various biomedical applications has been widely studied due to their unique properties that arise from MOFs or hybrid composite systems. This review focuses on the types of polymer/MOF nanocomposites used in drug delivery and imaging applications. Initially, a comprehensive introduction to the synthesis and structure of MOFs and bio-MOFs is presented. Subsequently, the properties and the performance of polymer/MOF nanocomposites used in these applications are examined, in relation to the approach applied for their synthesis: (i) non-covalent attachment, (ii) covalent attachment, (iii) polymer coordination to metal ions, (iv) MOF encapsulation in polymers, and (v) other strategies. A critical comparison and discussion of the effectiveness of polymer/MOF nanocomposites regarding their synthesis methods and their structural characteristics is presented.

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Sosa, Joshua, Timothy Bennett, Katherine Nelms, Brandon Liu, Roberto Tovar, and Yangyang Liu. "Metal–Organic Framework Hybrid Materials and Their Applications." Crystals 8, no. 8 (2018): 325. http://dx.doi.org/10.3390/cryst8080325.

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The inherent porous nature and facile tunability of metal–organic frameworks (MOFs) make them ideal candidates for use in multiple fields. MOF hybrid materials are derived from existing MOFs hybridized with other materials or small molecules using a variety of techniques. This led to superior performance of the new materials by combining the advantages of MOF components and others. In this review, we discuss several hybridization methods for the preparation of various MOF hybrids with representative examples from the literature. These methods include covalent modifications, noncovalent modifications, and using MOFs as templates or precursors. We also review the applications of the MOF hybrids in the fields of catalysis, drug delivery, gas storage and separation, energy storage, sensing, and others.

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Wang, Kuai-Bing, Rong Bi, Zi-Kai Wang, Yang Chu, and Hua Wu. "Metal–organic frameworks with different spatial dimensions for supercapacitors." New Journal of Chemistry 44, no. 8 (2020): 3147–67. http://dx.doi.org/10.1039/c9nj05198h.

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Recent progress in MOF materials for SCs with different spatial dimensions, such as 2D MOFs, including conductive MOFs and nanosheets, and 3D MOFs, categorized as single metallic and multiple metallic MOFs, are reviewed.

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