Relevant bibliographies by topics / MOFSL

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  1. Journal articles
  2. Dissertations / Theses
  3. Books
  4. Book chapters
  5. Conference papers
  6. Reports

Academic literature on the topic 'MOFSL'

Author: Grafiati
Published: 4 June 2025
Last updated: 23 June 2025

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Journal articles on the topic "MOFSL"

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Sonia, Lobo, and Bhat S. Ganesh. "Financial Performance Analysis of Motilal Oswal Financial Services Ltd (MOFSL)." International Journal of Case Studies in Business, IT, and Education (IJCSBE) 5, no. 2 (2021): 50–61. https://doi.org/10.5281/zenodo.5171575.

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<strong>Purpose: </strong><em>Over the last two decades, globalization and technology advancements in financial markets have resulted in a surge of individual investors, granting them improved access to the financial markets. However, the large range of investment avenues available makes the investors&rsquo; decision-making process more complex. To make investors&rsquo; lives easier, a stockbroker functions as a liaison between the investor and the stock exchange, allowing them to make more precise investment decisions that are more advantageous for them. Motilal Oswal Financial Services Ltd (MOFSL) is the leading stockbroker firm that offers a wide range of financial services and is the popular choice among Indian investors. To attract new clients and retain the trust of existing customers, the firm needs to maintain a good financial track record. The investment advisor&rsquo;s financial performance helps to a large measure in determining the firm&rsquo;s overall financial health. This paper attempts to analyze the financial performance of Motilal Oswal Financial Services Ltd, for the past three fiscal years i.e., 2018-19, 2019-20, and 2020-21.</em> <strong>Design/Methodology/Approach:</strong> <em>The technique of ratio analysis has been adopted to assess the financial performance of MOFSL using secondary data. Also, the correlation between profitability and efficiency of MOFSL was examined using Pearson correlation. Moreover, SWOC analysis is performed to gain a better understanding of the company&rsquo;s strategic position.</em> <strong>Findings/Result: </strong><em>The interpretation of the ratios calculated, given a favorable impression of the financial status of the company and the tested hypothesis of correlation significance has discoursed that there is no significant correlation between profitability and efficiency of MOFSL. Further, the result of the SWOC investigation has offered new insights into the business. It can be concluded from the study that in the FY 2020-21, the company has outperformed in terms of profitability, liquidity, solvency, and efficiency ratios.</em> <strong>Originality/Value: </strong><em>To acknowledge MOFSL&rsquo;s growing popularity in the financial services industry, research was conducted in which the company&rsquo;s financial performance was evaluated using four key financial indicators: profitability, liquidity, solvency, and efficiency ratios.</em> <strong>Paper Type: </strong><em>A case study analysis based on empirical data.</em>
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L.RahulYadav, M.Pavan Kumar M.Chaitanya V.Madhu Latha. "A STUDY ON CUSTOMER UNDERSTANDING TOWARDS INVESTMENT IN MUTUAL FUNDS AT VIJAYAWADA." International Journal Of Research and Analytical Reviews. 10, no. 3 (2023): 452–58. https://doi.org/10.5281/zenodo.8132121.

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The mutual fund sector in India has seen rapid growth in recent years. This research aims to investigate client perceptions of Motilal Oswal Financial Services Ltd&#39;s Vijayawada-based mutual fund investments. The main justification of this paper is to adobe limits for customer or consumer who are investing their funds in the mutual funds. The major data used in this study was gathered via a structured questionnaire given to MOFSL customers. The findings of the study reveal that customers have a positive belief in MOFSL Company and perceive the company&#39;s mutual funds as having good returns and minimal risk. The study further emphasizes how essential it is for clients&#39; investment behavior regarding mutual funds to be impacted by elements such as prior performance, credibility, and financial advisor recommendations.
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Moksh, Parmar, Gupta Anita, Kumar Lucky, and Uday Kiran Cheripelly. "Analysis of Financial Investments." International Journal of Innovative Science and Research Technology (IJISRT) 9, no. 2 (2024): 9. https://doi.org/10.5281/zenodo.10731777.

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This research paper examines the financial performance and stock analysis of Motilal Oswal Financial Services Ltd. (MOFSL) and HDFC Asset &nbsp;Management Company Ltd. (HDFCAMC) over a five- year period from 2018 to 2023. The study utilizes ratio &nbsp;analysis, fundamental analysis, and technical analysis techniques to assess various aspects of the companies' profitability, liquidity, solvency, and efficiency. Findings indicate positive trends in profitability, liquidity, solvency, and efficiency ratios for both companies, reflecting their ability to generate income, manage costs, and utilize resources effectively. Additionally, the stock analysis reveals promising trends, suggesting favorable outcomes for investors. Overall, these findings highlight the companies' strong financial performance and potential as investment opportunities, subject to market conditions and individual investor considerations. Keywords:- Financial Performance, Stock Analysis, Ratio Analysis, Fundamental Analysis, Technical Analysis, Profitability, Liquidity, Solvency, Efficiency, Investment Opportunities, Market Conditions, Risk Assessment, And Investment Strategy.
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Li, Ruofan, Xiaoli Yan, and Long Chen. "2D Conductive Metal–Organic Frameworks for Electrochemical Energy Application." Organic Materials 06, no. 02 (2024): 45–65. http://dx.doi.org/10.1055/s-0044-1786500.

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Two-dimensional conductive metal–organic frameworks (2D c-MOFs) have attracted research attention, benefitting from their unique properties such as superior electronic conductivity, designable topologies, and well-defined catalytic/redox-active sites. These advantages enable 2D c-MOFs as promising candidates in electrochemical energy applications, including supercapacitors, batteries and electrocatalysts. This mini-review mainly highlights recent advancements of 2D c-MOFs in the utilization for electrochemical energy storage, as well as the forward-looking perspective on the future prospects of 2D c-MOFs in the field of electrochemical energy.Table of content:1 Introduction2 Design Principles of 2D c-MOFs3 Synthesis of 2D c-MOFs4 2D c-MOFs for Electrochemical Energy Storage4.1 Supercapacitors4.2 Metallic Batteries4.2.1 Lithium-Ion Batteries4.2.2 Sodium-Ion Batteries4.2.3 Zinc-Ion Batteries4.2.4 Sodium–Iodine Batteries4.2.5 Lithium–Sulfur Batteries4.2.6 Potassium-Ion Batteries5 2D c-MOFs for Electrochemical Energy Conversion6 Conclusions and Outlook
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Johannes, Bitzer, Otterbach Steffen, Kavipriya Thangavel, et al. "Experimental evidence for the incorporation of two metals at equivalent lattice positions in mixed-metal metal-organic frameworks." Chemistry - A European Journal 26, no. 25 (2019): 5667–75. https://doi.org/10.1002/chem.201905596.

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Experimental evidence for the incorporation of two metals at equivalent lattice positions in mixed-metal metal-organic frameworks. <strong>Publication History:</strong> Issue Online - Final published version: <strong>04 May 2020</strong> Version of Record online: <strong>11 March 2020</strong> Accepted manuscript online: <strong>20 December 2019</strong> Manuscript received: <strong>11 December 2019</strong> <strong>Two versions of the paper and of the supporting information are available in this Zenodo record:</strong> - accepted version of the paper: filename: &quot;Bitzer_et_al-2020-Chemistry_-_A_European_Journal&quot; - accepted version of the supporting information: filename: &quot;supp_info_to_Pub_Bitzer_et_al-2019-Chemistry_-_A_European_Journal&quot; - final published version of the paper: filename: &quot;chem.201905596&quot; - final published version of the supporting information: filename: &quot;chem201905596-sup-0001-misc_information&quot;. The final published version is the one to be cited. Please cite as follows:&nbsp; J. Bitzer, S. Otterbach, K. Thangavel, A. Kultaeva, R. Schmid, A. P&ouml;ppl, W. Kleist,&nbsp;<em>Chem. Eur. J.</em>&nbsp;<strong>2020</strong>,&nbsp;<em>26</em>, 5667.&nbsp;https://doi.org/10.1002/chem.201905596
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Pettinari, Claudio, Riccardo Pettinari, Corrado Di Nicola, Alessia Tombesi, Stefania Scuri, and Fabio Marchetti. "Antimicrobial MOFs." Coordination Chemistry Reviews 446 (November 2021): 214121. http://dx.doi.org/10.1016/j.ccr.2021.214121.

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Taroni, Andrea. "Cool MOFs." Nature Materials 12, no. 8 (2013): 688. http://dx.doi.org/10.1038/nmat3730.

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Faust, Thomas. "MOFs deliver." Nature Chemistry 7, no. 4 (2015): 270–71. http://dx.doi.org/10.1038/nchem.2229.

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Dusastre, Vincent. "Printed MOFs." Nature Materials 11, no. 4 (2012): 266. http://dx.doi.org/10.1038/nmat3296.

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Astria, Efwita, Martin Thonhofer, Raffaele Ricco, et al. "Carbohydrates@MOFs." Materials Horizons 6, no. 5 (2019): 969–77. http://dx.doi.org/10.1039/c8mh01611a.

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Dissertations / Theses on the topic "MOFSL"

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Heinke, Lars. "Diffusion in MOFs." Universitätsbibliothek Leipzig, 2016. http://nbn-resolving.de/urn:nbn:de:bsz:15-qucosa-198185.

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Klimakow, Maria. "Metallorganische Gerüstverbindungen (MOFs)." Doctoral thesis, Humboldt-Universität zu Berlin, Mathematisch-Naturwissenschaftliche Fakultät I, 2014. http://dx.doi.org/10.18452/17097.

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In dieser Arbeit werden das Potential der mechanochemischen Synthesemethode zur Herstellung von metallorganischen Gerüstverbindungen (MOFs) vorgestellt und mögliche Anwendungsgebiete aufgezeigt. Im Forschungsfokus bezüglich schnellerer und effizienterer Darstellungsmethoden ist die Mechanochemie eine aussichtsreiche Alternative. Die Feststoff-Reaktion ist ohne die Verwendung von Lösungsmitteln durchführbar, zeichnet sich durch verkürzte Reaktionszeiten und quantitativen Eduktumsatz aus und gilt somit als Green Chemistry-Methode, die stetig wachsende Bedeutung erlangt. Die Ergebnisse dieser Arbeit belegen, dass über die mechanochemische Synthese metallorganische Verbindungen in allen Dimensionalitäten herstellbar sind. Die Reaktionsparameter sind auf die Herstellung isostruktureller und strukturanaloger Verbindungen übertragbar. Es wurden Synthesebedingungen identifiziert, die die Produktbildung beeinflussen, so dass ihre Kontrolle zur gezielten Herstellung verschiedener Verbindungen diente. Des Weiteren wurden Reaktionsparameter ermittelt, die einen Einfluss auf die Eigenschaften des Produkts ausüben. Im Hinblick auf eine größtmögliche spezifische Oberfläche wurde die Synthese optimiert und eine postsynthetische Aktivierungsprozedur entwickelt, die gemeinsam in einer verbesserten Gasadsorptionskapazität resultieren und auf andere Verbindungen übertragbar sind. Die Ergebnisse zur Gasspeicherung zeigen ein erstes Anwendungspotential für mechanochemisch synthetisierte MOFs auf, die als feine Pulver mit vergrößerter Oberfläche erhalten werden. Weiterhin wurde die Einlagerung von Solvensmolekülen in die Poren eines MOFs untersucht. Dabei zeigte sich, dass das MOF seine Gitterparameter an die jeweiligen Gastmoleküle anpasst. Das Potential zur Interkalation von Feststoffen wird anhand der Einlagerung pharmazeutischer Wirkstoffmoleküle belegt. Katalytische Untersuchungen zeigen eine gute Aktivität des mechanochemisch synthetisierten Rohprodukts.<br>In this work the potential of mechanochemical synthesis to produce metal-organic frameworks (MOFs) is presented and possible applications for the materials are shown. In the focus of research regarding faster and more efficient methods of synthesis, mechanochemistry is an promising alternative. This solid-state reaction can be carried out without the use of solvent, exhibits shortened reaction times and a quantitative turnover of reactands. Therefore it is a method of green chemistry, and its importance is constantly increasing. The results show that mechanochemical synthesis is capable of producing metal-organic compounds in all dimensionalities. The reaction conditions can be transferred to synthesize isostructural and structural analogous compounds. Parameters influencing the formation of products were identified, and their control led to a well-aimed design of various compounds. In addition, conditions influencing the properties of the product were determined. In terms of a specific surface area as large as possible, the synthesis was optimized and a postsynthetic activation was developed, together resulting in an improved capacity for gas adsorption and transferrable to other compounds. The results concerning gas storage present one possible application of mechanochemically synthesized MOFs, that are produced as fine powders with enlarged surfaces. Furthermore, intercalation of solvent molecules in the pores of a MOF was investigated. It shows that the MOF adjustes its lattice paramters to the guest molecules. The potential to intercalate solid-state compounds is demonstrated using pharmaceutical drug molecules. Catalytic investigations show a good activity of the mechanochemically synthesized raw product.
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Espín, Martí Jordi. "The photothermal effect in MOFs." Doctoral thesis, Universitat Autònoma de Barcelona, 2018. http://hdl.handle.net/10803/665204.

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Aquesta Tesi està dedicada a l’estudi de la interacció de la llum amb Polímers de Coordinació (CPs) i Xarxes Metalorgàniques (MOFs). S’ha seguit dos camins per aconseguir aquest objectiu; en primer lloc estudiant l’efecte fototèrmic observat en diferents subfamilies de MOFs, els quals, un cop irradiats amb llum UV‐Vis, presenten un escalfament local. Aquest augment de temperatura ha resultat útil tant en processos d’activació de MOFs com en Modificacions Covalents Post‐Sintètiques (CPSM). Per altra banda, sintetitzant nous CPs seguint l’estratègia de disseny de lligands fent servir complexos de coordinació de Ru2+‐terpiridines amb propietats de captació de llum. El Capítol 1 inclou una introducció general als CPs i MOFs, amb una visió històrica del seu descobriment i evolució, així com algunes de les múltiples aplicacions en les que aquests materials es poden implicar. En aquest sentit, ens hem centrat en les aplicacions que aprofiten la llum com a estímul extern. En el Capítol 2, hem resumit l’objectiu principal d’aquesta Tesi i n’hem detallat els objectius parcials. El Capítol 3 presenta una introducció als fonaments de la conversió de llum a calor en diferents materials. Alguns exemples de composites de MOFs, on les nanopartícules demostren un comportament fototèrmic, es troben resumits. Per altra banda també s’hi expliquen alguns dels mètodes més emprats per evacuar molècules que obstrueixen els porus de MOFs (activació). En aquest capítol es demostra que els MOFs també presenten efecte fototèrmic i que aquest efecte es pot utilitzar per a activar‐los eliminant les molècules de dissolvent un cop irradiats amb una làmpada UV‐Vis per temps curts. En el Capítol 4, la Modificació Post‐Sintètica (PSM) de MOFs es resumeix basant‐se en les interaccions entre l’esquelet del material porós i els agents modificants. També s’hi inclouen algunes estratègies alternatives per realitzar aquestes transformacions. En aquest sentit, l’ús de la calor local generada a partir de irradiar MOFs és utilitzada per aconseguir reaccions de CPSM. MOFs amb funcionalitzacions amino que presenten un fort efecte fototèrmic i anhídrids o aldehids es van mesclar (sense dissolvent) i la posterior exposició a llum UV‐Vis per temps curts va afavorir la fusió dels reactius i la reacció covalent. En el Capítol 5, les propietats d’absorció de llum i fototèrmiques d’alguns complexos organometàl∙lics s’exemplifiquen. També s’hi descriu l’estratègia beneficiosa de confinar aquests grups com a unitats estructurals en CPs i MOFs per a millorar la seva activitat. La síntesi i caracterització de tres nous CPs construïts a partir de complexos de Ru2+‐terpiridina i ions catalítics és descrita en aquest apartat. La caracterització fototèrmica d’aquests nous CPs demostra que presenten temperatures màximes en el rang dels MOFs amb un efecte fototèrmic més elevat. També es proposa realitzar un estudi dels CPs en reaccions de fotocatàlisi aprofitant la disposició dels complexes de Ru i dels ions metàl∙lics en els nodes.<br>This Thesis is devoted to the study of the interaction of light with Coordination Polymers (CPs) and Metal‐Organic Frameworks (MOFs). Two strategies have been followed to accomplish this objective. The first approach consisted on the study of the photothermal effect observed in different subfamilies of reported MOFs, which exhibited local heating upon UV‐Vis irradiation. Such temperature increase was proved useful for MOF activation and Covalent Post‐Synthetic Modification (CPSM) purposes. The second strategy was based on the synthesis of CPs following a ligand design approach using light‐harvesting Ru2+‐terpyridine complexes. Chapter 1 encloses a general introduction to CPs and MOFs, containing a historical overview of their discoveries and evolution, as well as some of the multiple applications in which these materials are involved. In this sense, we have focused on the applications arisen from the use of light as external stimulus. In Chapter 2, we have summarized the main objective of this Thesis and detailed the specific sub goals. Chapter 3 introduces the fundamentals of the light‐to‐heat conversion in different materials. Some examples of MOFs composites, where the nanoparticles exhibit the photothermal properties are reviewed. Moreover, a summary of some of the most common methods for removing guests from MOF pores (activation) is included. In this chapter, we demonstrate that MOFs also show photothermal effect and that this effect can be used to activate them by removing the solvent molecules after their irradiation with a UV‐Vis lamp for short periods. In Chapter 4, Post‐Synthetic Modification (PSM) of MOFs is reviewed based on the interactions between the framework and the desired modifying agents. To this end, some alternative strategies to perform such reactions are included. Thereafter, the use of the local heat generated upon MOF irradiation in CPSM reactions is reported. Amino‐tagged MOFs with strong photothermal effects and anhydrides or aldehydes were mixed (sovent‐free), and subsequent UV‐Vis exposure for short times allowed the melting of the reagents and the covalent reaction. In Chapter 5, the light‐harvesting and photothermal properties of some organometallic complexes are exemplified. The beneficial strategy of confining these moieties as building units in CPs and MOFs for enhancing their performance is described. The synthesis and characterization of three new CPs build up from Ru2+‐terpyridine complexes is reported here. Their photothermal characterization is performed and the new CPs showed maximum temperatures in the range of the MOFs with the strongest photothermal effect. In addition, future assessment of the CPs in photocatalytic reactions might be carried out, taking advantage of the close disposition of the Ru complexes and the metal ions of the nodes.
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Dai, Shan. "Synthèse ambiante verte de solides hybrides poreux (MOFs) robustes et de composites nanoparticules métalliques@MOFs." Electronic Thesis or Diss., Université Paris sciences et lettres, 2021. http://www.theses.fr/2021UPSLE068.

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Les catalyseurs hétérogènes constituent une pierre angulaire de l'industrie chimique et sont l'une des technologies les plus cruciales pour un avenir durable. À cet égard, les matériaux hybrides représentent une direction très excitante pour le développement de catalyseurs innovants. L'incorporation de nanoparticules métalliques (MNPs) dans des réseaux hybrides poreux cristallisés appelés « Metal-Organic Frameworks » (MOFs) est une stratégie prometteuse pour préparer des catalyseurs hétérogènes très efficaces, combinant les propriétés à la fois du MOF hôte et des MNPs invitées. Les composites préparés présentent un grand potentiel pour plusieurs applications en dehors de la catalyse (par exemple, détection, bio-applications) car les matériaux invités encapsulés peuvent introduire de nouvelles propriétés souhaitées qui sont absentes/peu efficaces dans le matériau hôte. Dans cette thèse, les composites MNPs et MOFs ont été préparés grâce à une stratégie dite « bottle-around-ship », dans laquelle les MOFs sont assemblés dans une solution contenant des MNPs préformées pour fabriquer des structures cœur-coquille. Dans un premier temps, plusieurs approches ont été développées pour préparer à température ambiante des MOFs robustes à base de cations tétravalents, basées sur des approches séquentielles ou directes. Par la suite, ces approches de synthèse à température ambiante ont été adaptées pour incorporer des nanoparticules ultra-petites dans les MOFs afin de former de manière reproductible des composites cœur-coquille MNPs@MOF capables de relever plusieurs défis en catalyse hétérogène (réduction de CO2, hydrolyse de liaison peptidique…)<br>Heterogeneous catalysts frame a cornerstone of the chemical industry and are one of the most crucial technologies for a sustainable future. Hybrid materials represent a very exciting direction for developing innovative catalysts. Incorporating guest metal nanoparticles (MNPs) into Metal-Organic Frameworks (MOFs) is an effective route to prepare highly efficient heterogeneous catalysts, which combines the properties of both the host MOF and guest MNPs. The prepared composites present a great potential for several applications apart from catalysis (e.g. sensing, bio-applications), as the encapsulated guest materials can introduce new desired properties that are absent/ poor in the parent material. In this thesis, MNPs and MOFs composites were prepared through challenging bottle-around-ship strategy. As the first step, multiple approaches were developed to prepare robust tetravalent Metal-organic frameworks (MOFs) at room temperature, including conventional stepwise and more facile direct strategies. Subsequently, the new room temperature synthesis approaches were adapted to incorporate ultra-small MNPs into the MOF to reproducibly form core-shell MNPs@MOF composites, prior to addressing several heterogeneous catalysis challenges (e.g., CO2 reduction, peptide hydrolysis)
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Morris, Samuel Alexander. "X-ray studies of zeolites and MOFs." Thesis, University of St Andrews, 2016. http://hdl.handle.net/10023/9891.

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This thesis is largely a study of the ADOR process (assembly-disassembly-organisation-reassembly) when applied to zeolite UTL. The final chapter of this thesis deals with the adsorption of the medical gases NO and CO onto the metal organic framework NiNaSIP. Chapter 4 is devoted to the disassembly and organisation steps of the ADOR process. Calcined UTL was hydrolysed using 0.1 – 12 M HCl solutions from 75 – 95 °C run over 10 mins to 72 hrs. A three step mechanism is proposed, which is comprised of an initial rapid hydrolysis that removes the majority of the interlayer constituents of UTL, causing the silica-rich layers to largely collapse. This is followed by a slow, temperature and molarity dependent, deintercalation process that sees the remainder of the interlayer material removed resulting in the full collapse of the layers to form IPC-1P. The third step is a temperature and molarity dependent rebuilding process, whereby the interlayer region is slowly rebuilt, eventually forming a precursor which upon calcination becomes IPC-2 (OKO). Chapter 5 uses the pair distribution function (PDF) technique to structurally confirm the intermediate of the ADORable zeolite UTL. The intermediate, IPC-1P, is a disordered layered compound formed by the hydrolysis of UTL in 0.1 M HCl. Its structure is unsolvable by traditional X-ray diffraction techniques. The PDF technique was first benchmarked against high-quality synchrotron Rietveld refinements of IPC-2 (OKO) and IPC-4 (PCR) – two end products of IPC-1P condensation that share very similar structural features. An IPC-1P starting model derived from density functional theory was used for the PDF refinement, which yielded a final fit of Rw = 18% and a geometrically reasonable structure. This confirms that the layers do stay intact throughout the ADOR process, and shows that PDF is a viable technique for layered zeolite structure determination. Chapter 6 examines the reassembly stage by following the in-situ calcination of a variety of hydrolysed intermediates into their three-dimensional counterparts. Beamline I11 at Diamond Light Source provided high-quality PXRD patterns as a function of temperature, which were refined against using sequential Pawley refinements to track the unit cell changes. 0.1, 1.75, 2.5 and 12 M hydrolysed lamellar precursor phases were calcined. The largest unit cell changes were observed for 0.1 M, and the smallest for 12 M. This shows that increasing the molarity must prebuild most of the interlayer connections, such that upon calcination, only minimal condensation occurs to fully connect the layers. Chapter 7 probes the uptake of the medical gases CO and NO into the metal organic framework NiNaSIP. An in-situ single-crystal XRD study was undertaken using an environmental gas cell at beamline 11.3.1 at the Advanced Light Source. NiNaSIP was first dehydrated to reveal an open nickel site, which acted as the main site of adsorption for the inputted gases. NO was observed in a bent geometry at an occupancy of 40 % and a Ni – N bond length of 2.166(16) Å. The oxygen was modelled to be disordered over two sites. CO was not fully observed, as only the carbon was able to be modelled with an occupancy of 31.2 % and a Ni – C bond length of 2.27(3) Å.
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Chen, Yipei. "Synthesis of MOFs for carbon capture application." Thesis, University of Nottingham, 2018. http://eprints.nottingham.ac.uk/55542/.

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The work in this thesis focuses on the synthesis of metal organic frameworks (MOFs) both in batch and continuous work. Improvements are made in both, compared to the previous research. Furthermore, post-modification experiments are conducted to advance the characteristics of end product. Also, their application as solid sorbents in carbon capture is investigated. In Chapter 1, the background of greenhouse gas emissions is reviewed and discussed, followed by the development of carbon capture technologies and different adsorbents used in post-combustion carbon capture. An introduction to metal organic frameworks is then presented, including a literature review of the research to date, and various synthesis methods including batch and continuous routes. The last part of this chapter presents a literature review on how pre-synthetic design and post-synthetic modification synthesis of MOFs can be achieved. The theories and introductions of the characterization techniques used in this thesis are discussed in detail in Chapter 2. Chapter 3 discusses a new batch method for the efficient synthesis of micro-sized HKUST-1 with high yield (84%) under mild conditions. Different activation methods are conducted in the washing process. Both ethanol and methanol are tested to remove the impurities in pores of the samples. Finally, the optimal sample of HKUST-1 achieved is shown to produce a relatively high surface area (1615 m2/g) with a CO2 adsorption of 8.1% (measured by TGA at 1 atm and 27 oC). A step increase in the surface area is made by immersing the powders into a solution consisting of NaCl, water and methanol. Nano scale HKUST-1 is synthesized by adding trimethylamine (TEA) solution with the organic ligand precursor. The reaction rate is accelerated with this case because TEA solution is able to deprotonate the trimesic acid (the organic ligand). The method for nano scale HKUST-1 synthesis is the focus of Chapter 4. Chapter 5 reports the continuous synthesis process of HKUST-1 and ZIF-8. This work builds on previous work at Nottingham. A counter-current Nozzle reactor is used in this work. The products were compared with commercial equivalents. Post-synthetic modification of HKUST-1 was made to improve the hydrophobicity of HKUST-1 to extend its resilience to breakdown in the presence of moisture. In Chapter 6, a hybrid material TiO2@ZIF-8 is synthesized using the same reactor. Different reactor configurations were also used to generate a range of different products that are then compared. To conclude, a summary of the work conducted in this thesis is presented in Chapter 7, followed by a discussion on potential future work.
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Heinke, Lars. "Diffusion in MOFs: the surface barrier phenomenon." Diffusion fundamentals 24 (2015) 19, S. 1, 2015. https://ul.qucosa.de/id/qucosa%3A14533.

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Çamur, Ceren. "Advances on the synthesis of MOFs at scale." Doctoral thesis, Universitat Autònoma de Barcelona, 2019. http://hdl.handle.net/10803/667179.

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La presente tesis doctoral ha sido dedicada al desarrollo y optimización de metodologías para la síntesis de MOFs en medio acuoso, así como su conformación y el avance hacia la producción a gran escala de estos materiales. El primer capítulo presenta una breve introducción a los materiales porosos, empezando por los ejemplos presentes en la naturaleza, a los que luego sigue una breve historia sobre los MOFs y sus principales aplicaciones. Se prestará también especial atención a las metodologías usadas actualmente en la síntesis a gran escala de MOFs y su posterior procesado. El segundo capítulo presenta los objetivos, generales y específicos, de esta tesis. En el tercer capítulo se ilustra el uso de complejos metálicos de acetilacetonato como precursores alternativos en la síntesis acuosa a baja temperatura de varios MOFs, entre ellos MOFs basados en Zr, Fe y Al. Para cada material (UiO-66-NH2, Zr-fumarato, UiO-66-(OH)2, UiO-66-(COOH)2, MIL-88A y CAU-10), se definieron y optimizaron diversos parámetros experimentales con el fin de aumentar el rendimiento y la calidad del material final. Finalmente, se confirma la escalabilidad de esta metodología a través de una síntesis optimizada a gran escala de UiO-66-NH2 en agua a temperatura ambiente. El cuarto capítulo demuestra el uso de la técnica de secado por atomización, o ‘Spray Drying’, como un método “verde” y escalable para la producción de Zr-MOFs en forma de cuentas esféricas. Se definirá la importancia de diversos factores experimentales, y se demostrará su impacto en la síntesis de UiO-66-NH2 y Zr-fumarato. Finalmente, la escalabilidad del método será probada a través de una síntesis acuosa optimizada de UiO-66-NH2 a escala de gramos. Finalmente, el capítulo final se estudia el proceso de estructuración de varios MOF obtenidos con la técnica de ‘Spray Drying’ (HKUST-1 y UiO-66- NH2) y de lotes de síntesis (UiO-66 y UiO-67) y su influencia en sus propiedades de adsorción. Tras ser modelados en forma de pastilla a diferentes presiones, se estudiaron sus nuevas propiedades mecánicas y de superficie.<br>The present PhD Thesis has been dedicated to the development of basic knowledge on aqueous synthesis methodologies of MOFs and their shaping in order to make advances towards the large scale production of MOFs. The first chapter presents a brief introduction to the porous materials, starting with the examples from nature, which is then followed by a short history of MOFs and their main applications. Additionally, we pay special attention to the current methodologies that are performed for the synthesis of MOFs at scale and downstream processes. The second chapter consists of general and specific objectives of this Thesis. In the third chapter, the usage of metal acetylacetonate complexes as an alternative metal salt for the synthesis of MOFs is illustrated in water for several MOFs, including Zr-, Fe- and Al- based MOFs at low temperatures. For each MOF (UiO-66-NH2, Zr-fumarate, UiO-66-(OH)2, UiO-66-(COOH)2, UiO-66- COOH, MIL-88A and CAU-10), critical experimental parameters are defined and optimized to obtain high quality materials with high yields. Finally, the scalability of the methodology is shown with the gram scale synthesis of UiO- 66-NH2 by using optimized parameters in water at room temperature. The forth chapter demonstrates the continuous flow spray-drying technique that can be used as a green and scalable method to produce Zr-MOFs in the form of spherical beads. The influences of the important experimental factors are defined and the impact of those parameters on the synthesis of UiO- 66-NH2 and Zr-fumarate is shown. Finally, the scalability of the methodology is proven with the gram scale synthesis of UiO-66-NH2 by using optimized parameters in water. In the final chapter, the shaping process of the several MOFs that were synthesized by the spray-drying (HKUST-1 and UiO-66-NH2) and batch (UiO- 66 and UiO-67) synthesis methodologies is demonstrated. Mild pelletization technique is used to shape the MOFs into tablets to study textural and mechanical properties.
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Graham, Alexander John. "Effect of pressure on metal-organic frameworks (MOFs)." Thesis, University of Edinburgh, 2013. http://hdl.handle.net/1842/8900.

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A growing field of research has evolved around the design and synthesis of a variety of porous metal-organic framework (MOF) materials. Some of the most promising areas for which these materials are potentially useful candidates include gas-separation, heterogeneous catalysis, and gas-storage, and all of these applications involve placing the MOF under pressure. There is clearly a need to understand the structural response of MOFs to applied pressure. Nevertheless, hitherto there are very few published investigations dedicated to determining the behaviour of porous hybrid materials under pressure. Through the use of high-pressure single-crystal X-ray diffraction studies, a series of MOF materials have been studied. Here we present the effect of pressure on a series of MOFs. In chapter 2, the effect of pressure on the prototypical MOF called MOF-5 was studied experimentally from ambient pressure to 3.2 GPa. Here, application of pressure was driven by the hydrostatic medium being forced into the pores of the MOF, which altered the mechanical properties of MOF-5, in particular, medium inclusion delayed the onset of amorphization. Complementary computational analysis was also performed to elucidate further the effect of medium inclusion on compressive behaviour. Detailed structural data was also collected as a function of pressure on the MOF Cu-btc. Application of pressure caused solvent to be squeezed into the pores (like MOF-5) until a phase transition occurred, driven by the sudden compression and expansion of equatorial and axial Cu–O bonds. High-pressure post-synthetic modification of a MOF is reported for the first time. On application of pressure of 0.2 GPa to the Cu-based MOF called STAM-1, a ligand exchange reaction takes place resulting in a change in pore size, shape, and hydrophilicity of the resulting pores. Here, we also demonstrate the ability to force hydrophilic molecules into hydrophobic pores using pressure, counteracting the hydrophobic effect. A high-pressure combined experimental and computational study has been carried to probe the effect of pressure on ‘breathing’ mechanisms in a zeolitic imidazolate framework (or ZIF) called ZIF-8. The penetration of guest molecules and the accommodation of pressure are shown to be inextricably linked to the rotation of methylimidazolate groups in the structure. Finally, the application of pressure to the MOF Sc₂BDC₃ and the nitro functionalized derivative Sc₂(NO₂-BDC)₃ was also studied. Here, the effect of chemical modification of the organic ligand, whilst maintaining framework topology, has been investigated as it pertains to compressibility. Directionality of compression is observed and this is rationalized with respect to the framework topology and medium inclusion/exclusion.
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Silva, Patrícia Vanessa Palma da. "Síntese e caracterização de MOFs – Metal Organic Frameworks." Master's thesis, Faculdade de Ciências e Tecnologia, 2012. http://hdl.handle.net/10362/8544.

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Books on the topic "MOFSL"

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Kumar, Pawan, Naresh Kumar, and Deepak Kumar Aneja, eds. Metal Organic Framework (MOFs). Springer Nature Singapore, 2024. http://dx.doi.org/10.1007/978-981-97-5971-2.

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Gulati, Shikha, ed. Metal-Organic Frameworks (MOFs) as Catalysts. Springer Singapore, 2022. http://dx.doi.org/10.1007/978-981-16-7959-9.

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Blay, Vincent, Luis Francisco Bobadilla, and Alejandro Cabrera, eds. Zeolites and Metal-Organic Frameworks. Amsterdam University Press, 2018. http://dx.doi.org/10.5117/9789462985568.

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Zeolites are natural or synthetic materials with porous chemical structures that are valuable due to their absorptive and catalytic qualities. Metal-Organic Frameworks (MOFs) are manmade organometallic polymers with similar porous structures. This introductory book, with contributions from top-class researchers from all around the world, examines these materials and explains the different synthetic routes available to prepare zeolites and MOFs. The book also highlights how the substances are similar yet different and how they are used by science and industry in situations ranging from fueling cars to producing drugs.
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MOFs [Working Title]. IntechOpen, 2018. http://dx.doi.org/10.5772/intechopen.74642.

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MOFs for Advanced Applications. MDPI, 2022. http://dx.doi.org/10.3390/books978-3-0365-3542-5.

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Bedia, Jorge, and Carolina Belver. MOFs for Advanced Applications. Mdpi AG, 2022.

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Metal-Organic Frameworks (MOFs) As Catalysts. Springer, 2023.

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Gulati, Shikha. Metal-Organic Frameworks (MOFs) As Catalysts. Springer Singapore Pte. Limited, 2022.

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Metal-Organic Frameworks (MOFs) for Environmental Applications. Elsevier, 2019. http://dx.doi.org/10.1016/c2017-0-01721-4.

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Functional Supramolecular Materials: From Surfaces to MOFs. Royal Society of Chemistry, The, 2017.

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Book chapters on the topic "MOFSL"

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Hajizadeh, Zoleikha, and Mohammad Mehdi Salehi. "MOFs Bandstructure." In Physicochemical Aspects of Metal-Organic Frameworks. Springer International Publishing, 2023. http://dx.doi.org/10.1007/978-3-031-18675-2_6.

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Navalón, Sergio, and Hermenegildo García. "MOFs as Photocatalysts." In Metal-Organic Frameworks. Wiley-VCH Verlag GmbH & Co. KGaA, 2018. http://dx.doi.org/10.1002/9783527809097.ch15.

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Yu, Hao, and Yonghai Cao. "Carbon from MOFs." In Carbon Catalysis. CRC Press, 2024. http://dx.doi.org/10.1201/9781003545248-9.

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Salehi, Mohammad Mehdi, Farhad Esmailzadeh, and Fereshte Hassanzadeh-Afruzi. "Applications of MOFs." In Physicochemical Aspects of Metal-Organic Frameworks. Springer International Publishing, 2023. http://dx.doi.org/10.1007/978-3-031-18675-2_13.

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Rahimi, Jamal, and Fatemeh Ganjali. "Industrialization of MOFs." In Physicochemical Aspects of Metal-Organic Frameworks. Springer International Publishing, 2023. http://dx.doi.org/10.1007/978-3-031-18675-2_14.

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Kamalzare, Maryam. "MOFs Functionalization Approaches." In Physicochemical Aspects of Metal-Organic Frameworks. Springer International Publishing, 2023. http://dx.doi.org/10.1007/978-3-031-18675-2_4.

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Zarei-Shokat, Simindokht, Fatemeh Ansari, Mohadeseh Forouzandeh-Malati, and Ana Zamani. "MOFs Structural Morphologies." In Physicochemical Aspects of Metal-Organic Frameworks. Springer International Publishing, 2023. http://dx.doi.org/10.1007/978-3-031-18675-2_5.

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Cepeda, Javier, Antonio Rodríguez-Diéguez, and Alfonso Salinas-Castillo. "Biosensing Using MOFs." In Metal-Organic Frameworks in Biomedical and Environmental Field. Springer International Publishing, 2021. http://dx.doi.org/10.1007/978-3-030-63380-6_14.

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Aneja, Deepak Kumar, Monika Sihag, Rinku Soni, Neha Rani, and Sandeep Malik. "Fundamental Behind MOF Synthesis." In Metal Organic Framework (MOFs). Springer Nature Singapore, 2024. http://dx.doi.org/10.1007/978-981-97-5971-2_2.

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Sikka, Rajit, and Gaurav Awasthi. "MOFs for Nitroaromatic Compound Degradation." In Metal Organic Framework (MOFs). Springer Nature Singapore, 2024. http://dx.doi.org/10.1007/978-981-97-5971-2_7.

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Conference papers on the topic "MOFSL"

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Ostresh, Sarah, James Nyakuchena, Daniel Streater, et al. "Optical Pump THz Probe Spectroscopy on Metal-Organic Frameworks." In CLEO: Fundamental Science. Optica Publishing Group, 2024. http://dx.doi.org/10.1364/cleo_fs.2024.fw4i.3.

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Optical Pump THz Probe (OPTP) Spectroscopy is an outstanding technique to understand photoconductivity in emerging materials. We utilized OPTP to explore the photoconductivity in porous crystalline metal-organic frameworks (MOFs). MOFs are highly porous and their properties can be adjusted by synthesize and chemical composition, making them an tool box for advanced ultralight electro-optical applications. These applications are limited by the insight into the underlying photophysics in MOFs. Our OPTP results revealed ultrafast photoconductivity. We were able to understand the influence of different metal centers in two types of MOFs and OPTP results agreed with catalytical activity measurements and demonstrate that the catalysis in this material is more determined by photoconductivity than by “common” catalytic chemistry wisdom.
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Zhang, Xiao-Yu, Jing-Ge Liu, Hao-Chen Yan, Zi-Han Yu, and Gang Li. "Flexible Sweat Sensors based on MOFs: Preparation and Application." In 17th Textile Bioengineering and Informatics Symposium. Textile Bioengineering and Informatics Society Limited (TBIS), 2024. https://doi.org/10.52202/076989-0002.

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Mahato, Manmatha, and Il-Kwon Oh. "Developing MOFs for dual electrical and magnetic response in soft actuators." In Soft Mechatronics and Wearable Systems 2025, edited by Ilkwon Oh, Woon-Hong Yeo, and Wei Gao. SPIE, 2025. https://doi.org/10.1117/12.3050923.

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Xi, Meng. "Research on Heavy Metal Ion Adsorption Using Metal Organic Frameworks (MOFs) Materials." In International Conference on Modern Logistics and Supply Chain Management. SCITEPRESS - Science and Technology Publications, 2024. https://doi.org/10.5220/0013327000004558.

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Otay, Oumayma, Amir Mrayeh, Ge Shi, et al. "Plasma-Treated Polyimide Film Modified by Liquid Epitaxially Grown HKUST-1 MOFs for Sensing Application." In 2024 International Workshop on Impedance Spectroscopy (IWIS). IEEE, 2024. https://doi.org/10.1109/iwis63047.2024.10847257.

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Lu, Gang, Xiuyi Jiang, Qingyuan Yang, Zhengyang Zhao, Weiwei Gu, and Ruiqi Li. "Predicting methane adsorption ability of MOFs based on the crystal structural information by convolutional neural network." In 5th International Conference on Material Science and Technology (ICMST 2025), edited by Sin Yee Gan, Zhongwei Guan, and Paulo César De Morais. SPIE, 2025. https://doi.org/10.1117/12.3067331.

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Mrayeh, Amir, Oumayma Otay, Ge Shi, et al. "Chemically Treated Polyimide Film Modified by Liquid Phase Epitaxially Grown HKUST-1 MOFs for Electrochemical Sensing Applications." In 2024 International Workshop on Impedance Spectroscopy (IWIS). IEEE, 2024. https://doi.org/10.1109/iwis63047.2024.10847152.

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Kim, Dong Yun, Md Asaduzzaman, Ahmad A. Samad, and Jae Yeong Park. "MOFs-derived nanoporous carbon incorporated 3D porous graphenes-based patch sensor for wearable sweat Na+ and pH continuous monitoring." In Health Monitoring of Structural and Biological Systems XIX, edited by Zhongqing Su. SPIE, 2025. https://doi.org/10.1117/12.3052471.

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Al-Ansari, Dana E., Nura A. Mohamed, Isra Marei, Huseyin Yalcin, and Haissam Abou-Saleh. "Assessment of Metal Organic Framework as Potential Drug Carriers in Cardiovascular Diseases." In Qatar University Annual Research Forum & Exhibition. Qatar University Press, 2020. http://dx.doi.org/10.29117/quarfe.2020.0127.

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Background: Cardiovascular diseases (CVDs) are considered the major cause of death worldwide. Therapeutic delivery to the cardiovascular system may play an important role in the successful treatment of a variety of CVDs, including atherosclerosis, ischemic-reperfusion injury, and microvascular diseases. Despite their clinical benefits, current therapeutic drugs are hindered by their short half-life and systemic side effects. This limitation could be overcome using controlled drug release with the potential for targeted drug delivery using a nanomedicine approach. In the current study, we have assessed the use of a highly porous nano-sized preparation of iron-based Metal-organic Framework (MOF) commonly referred to as MIL-89 as potential drug carriers in the cardiovascular system. Aims: To assess the effect of MOFs on the viability and cytotoxicity of human vascular cells and the cellular uptake in vitro, and the organ-system toxicity of MOF in vivo using the Zebrafish model. Methods: Human pulmonary endothelial cells (HPAECs) and pulmonary smooth muscle cells (HPASMCs) were treated with variable concentrations of MOFs. The viability, cytotoxicity and anti-inflammatory effects were measured using AlamarBlue, LDH assay and ELISA. The cellular uptake of MOFs were assessed using light, confocal, and transmission electron microscopes and EDS analysis. Moreover, Zebrafish embryos were cultured and treated with MOFs-nanoparticles at 0 hours post fertilization (hpf) followed by different organ-specific assays at 24, 48, and 72 hpf. Results: Although MOFs affect the viability at high concentrations, it does not cause any significant cytotoxicity on HPAECs and HPASMCs. Interestingly, MOFs were shown to have an anti-inflammatory effect. Microscopic images showed an increased (concentration-dependent) cellular uptake of MOFs and transfer to daughter cells in both cell types. Moreover, the in vivo study showed that high concentrations of MOFs delay zebrafish embryos hatching and cause heart deformation, which is currently investigated using cardiotoxicity markers. Conclusion: MOFs is a promising nanoparticle prototypes for drug delivery in the cardiovascular system with high cellular uptake and anti-inflammatory effects. Further investigations of MOFs, including diseased models and drug- loaded formulation is required.
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Arayachukiat, Sunatda, Taradon Pironchart, and Kanokwan Kongpatpanich. "The Versatile and Tunable Metal-Organic Framework MOF for Condensate Decontamination." In Offshore Technology Conference Asia. OTC, 2022. http://dx.doi.org/10.4043/31664-ms.

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Abstract Contamination of heavy metals especially for Mercury (Hg) and Arsenic (As) in condensates becomes one of major concerns in Natural Gas production due to theirs high toxicity and carcinogenicity. The key challenge to develop adsorbents for Hg/As removal is to find suitable porous materials with high adsorption capacity, long-term stability and easy to handle the toxic wastes after the adsorption process. Metal-organic frameworks (MOFs) are one of promising porous materials constructed from metal clusters and organic linkers to create the 3D framework structures. MOFs are one of the promising adsorbents for removal of Hg/As from condensates owning to their versatile structures, tunable porosity, and tailorable chemical functionalities. In this work, Zr-based MOFs have been developed for dual removal of Hg and As species owning to their chemical stability in moisture conditions, which is highly desirable for industrial processes. Zr-based MOFs with different topology and pore size distribution have been synthesized for Hg/As adsorption to understand the contribution of porous structure on the removal of Hg/As species in condensates. The performance of Zr-based MOFs results showed Hg and As removal up to 99.5% in condensates from several petroleum sources. The removal efficiencies were found to be influenced by topology of MOF adsorbents and the speciation of Hg/As in different petroleum sources. In addition, Zr-based MOFs have proposed some future trends and challenges of porous material that can be used as an alternative to the conventional metal oxides and zeolites.
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Reports on the topic "MOFSL"

1

Ingram, Conrad, and Dinadayalane Tandabany. Engineering Accessible Adsorption Sites in MOFs for CO2 Capture. Office of Scientific and Technical Information (OSTI), 2019. http://dx.doi.org/10.2172/1582449.

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Ingram, Conrad, and Dinadayalane Tandabany. Engineering Accessible Adsorption Sites in MOFs for CO2 Capture. Office of Scientific and Technical Information (OSTI), 2019. http://dx.doi.org/10.2172/1571173.

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Fujimoto, Meghan S., Amy K. Welty, Mitchell Greenhalgh, and Troy G. Garn. Developing an Engineered Form of MOFs CaSDB and HKUST –1. Office of Scientific and Technical Information (OSTI), 2019. http://dx.doi.org/10.2172/1503605.

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Yaghi, Omar M. Metal-organic and zeolite imidazolate frameworks (MOFs and ZIFs) for highly selective separations. Office of Scientific and Technical Information (OSTI), 2012. http://dx.doi.org/10.2172/1050881.

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Mohamed, Eddaoudi, Michael Zaworotko, Brian Space, and Juergen Eckert. Design and Synthesis of Novel Porous Metal-Organic Frameworks (MOFs) Toward High Hydrogen Storage Capacity. Office of Scientific and Technical Information (OSTI), 2013. http://dx.doi.org/10.2172/1150238.

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Thallapally, Praveen K., and Denis M. Strachan. Initial proof-of-principle for near room temperature Xe and Kr separation from air with MOFs. Office of Scientific and Technical Information (OSTI), 2012. http://dx.doi.org/10.2172/1122332.

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