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1

Sonia, Lobo, and Bhat S. Ganesh. "Financial Performance Analysis of Motilal Oswal Financial Services Ltd (MOFSL)." International Journal of Case Studies in Business, IT, and Education (IJCSBE) 5, no. 2 (2021): 50–61. https://doi.org/10.5281/zenodo.5171575.

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<strong>Purpose: </strong><em>Over the last two decades, globalization and technology advancements in financial markets have resulted in a surge of individual investors, granting them improved access to the financial markets. However, the large range of investment avenues available makes the investors&rsquo; decision-making process more complex. To make investors&rsquo; lives easier, a stockbroker functions as a liaison between the investor and the stock exchange, allowing them to make more precise investment decisions that are more advantageous for them. Motilal Oswal Financial Services Ltd (MOFSL) is the leading stockbroker firm that offers a wide range of financial services and is the popular choice among Indian investors. To attract new clients and retain the trust of existing customers, the firm needs to maintain a good financial track record. The investment advisor&rsquo;s financial performance helps to a large measure in determining the firm&rsquo;s overall financial health. This paper attempts to analyze the financial performance of Motilal Oswal Financial Services Ltd, for the past three fiscal years i.e., 2018-19, 2019-20, and 2020-21.</em> <strong>Design/Methodology/Approach:</strong> <em>The technique of ratio analysis has been adopted to assess the financial performance of MOFSL using secondary data. Also, the correlation between profitability and efficiency of MOFSL was examined using Pearson correlation. Moreover, SWOC analysis is performed to gain a better understanding of the company&rsquo;s strategic position.</em> <strong>Findings/Result: </strong><em>The interpretation of the ratios calculated, given a favorable impression of the financial status of the company and the tested hypothesis of correlation significance has discoursed that there is no significant correlation between profitability and efficiency of MOFSL. Further, the result of the SWOC investigation has offered new insights into the business. It can be concluded from the study that in the FY 2020-21, the company has outperformed in terms of profitability, liquidity, solvency, and efficiency ratios.</em> <strong>Originality/Value: </strong><em>To acknowledge MOFSL&rsquo;s growing popularity in the financial services industry, research was conducted in which the company&rsquo;s financial performance was evaluated using four key financial indicators: profitability, liquidity, solvency, and efficiency ratios.</em> <strong>Paper Type: </strong><em>A case study analysis based on empirical data.</em>
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2

L.RahulYadav, M.Pavan Kumar M.Chaitanya V.Madhu Latha. "A STUDY ON CUSTOMER UNDERSTANDING TOWARDS INVESTMENT IN MUTUAL FUNDS AT VIJAYAWADA." International Journal Of Research and Analytical Reviews. 10, no. 3 (2023): 452–58. https://doi.org/10.5281/zenodo.8132121.

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The mutual fund sector in India has seen rapid growth in recent years. This research aims to investigate client perceptions of Motilal Oswal Financial Services Ltd&#39;s Vijayawada-based mutual fund investments. The main justification of this paper is to adobe limits for customer or consumer who are investing their funds in the mutual funds. The major data used in this study was gathered via a structured questionnaire given to MOFSL customers. The findings of the study reveal that customers have a positive belief in MOFSL Company and perceive the company&#39;s mutual funds as having good returns and minimal risk. The study further emphasizes how essential it is for clients&#39; investment behavior regarding mutual funds to be impacted by elements such as prior performance, credibility, and financial advisor recommendations.
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3

Moksh, Parmar, Gupta Anita, Kumar Lucky, and Uday Kiran Cheripelly. "Analysis of Financial Investments." International Journal of Innovative Science and Research Technology (IJISRT) 9, no. 2 (2024): 9. https://doi.org/10.5281/zenodo.10731777.

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This research paper examines the financial performance and stock analysis of Motilal Oswal Financial Services Ltd. (MOFSL) and HDFC Asset &nbsp;Management Company Ltd. (HDFCAMC) over a five- year period from 2018 to 2023. The study utilizes ratio &nbsp;analysis, fundamental analysis, and technical analysis techniques to assess various aspects of the companies' profitability, liquidity, solvency, and efficiency. Findings indicate positive trends in profitability, liquidity, solvency, and efficiency ratios for both companies, reflecting their ability to generate income, manage costs, and utilize resources effectively. Additionally, the stock analysis reveals promising trends, suggesting favorable outcomes for investors. Overall, these findings highlight the companies' strong financial performance and potential as investment opportunities, subject to market conditions and individual investor considerations. Keywords:- Financial Performance, Stock Analysis, Ratio Analysis, Fundamental Analysis, Technical Analysis, Profitability, Liquidity, Solvency, Efficiency, Investment Opportunities, Market Conditions, Risk Assessment, And Investment Strategy.
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4

Li, Ruofan, Xiaoli Yan, and Long Chen. "2D Conductive Metal–Organic Frameworks for Electrochemical Energy Application." Organic Materials 06, no. 02 (2024): 45–65. http://dx.doi.org/10.1055/s-0044-1786500.

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Two-dimensional conductive metal–organic frameworks (2D c-MOFs) have attracted research attention, benefitting from their unique properties such as superior electronic conductivity, designable topologies, and well-defined catalytic/redox-active sites. These advantages enable 2D c-MOFs as promising candidates in electrochemical energy applications, including supercapacitors, batteries and electrocatalysts. This mini-review mainly highlights recent advancements of 2D c-MOFs in the utilization for electrochemical energy storage, as well as the forward-looking perspective on the future prospects of 2D c-MOFs in the field of electrochemical energy.Table of content:1 Introduction2 Design Principles of 2D c-MOFs3 Synthesis of 2D c-MOFs4 2D c-MOFs for Electrochemical Energy Storage4.1 Supercapacitors4.2 Metallic Batteries4.2.1 Lithium-Ion Batteries4.2.2 Sodium-Ion Batteries4.2.3 Zinc-Ion Batteries4.2.4 Sodium–Iodine Batteries4.2.5 Lithium–Sulfur Batteries4.2.6 Potassium-Ion Batteries5 2D c-MOFs for Electrochemical Energy Conversion6 Conclusions and Outlook
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5

Johannes, Bitzer, Otterbach Steffen, Kavipriya Thangavel, et al. "Experimental evidence for the incorporation of two metals at equivalent lattice positions in mixed-metal metal-organic frameworks." Chemistry - A European Journal 26, no. 25 (2019): 5667–75. https://doi.org/10.1002/chem.201905596.

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Experimental evidence for the incorporation of two metals at equivalent lattice positions in mixed-metal metal-organic frameworks. <strong>Publication History:</strong> Issue Online - Final published version: <strong>04 May 2020</strong> Version of Record online: <strong>11 March 2020</strong> Accepted manuscript online: <strong>20 December 2019</strong> Manuscript received: <strong>11 December 2019</strong> <strong>Two versions of the paper and of the supporting information are available in this Zenodo record:</strong> - accepted version of the paper: filename: &quot;Bitzer_et_al-2020-Chemistry_-_A_European_Journal&quot; - accepted version of the supporting information: filename: &quot;supp_info_to_Pub_Bitzer_et_al-2019-Chemistry_-_A_European_Journal&quot; - final published version of the paper: filename: &quot;chem.201905596&quot; - final published version of the supporting information: filename: &quot;chem201905596-sup-0001-misc_information&quot;. The final published version is the one to be cited. Please cite as follows:&nbsp; J. Bitzer, S. Otterbach, K. Thangavel, A. Kultaeva, R. Schmid, A. P&ouml;ppl, W. Kleist,&nbsp;<em>Chem. Eur. J.</em>&nbsp;<strong>2020</strong>,&nbsp;<em>26</em>, 5667.&nbsp;https://doi.org/10.1002/chem.201905596
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6

Pettinari, Claudio, Riccardo Pettinari, Corrado Di Nicola, Alessia Tombesi, Stefania Scuri, and Fabio Marchetti. "Antimicrobial MOFs." Coordination Chemistry Reviews 446 (November 2021): 214121. http://dx.doi.org/10.1016/j.ccr.2021.214121.

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7

Taroni, Andrea. "Cool MOFs." Nature Materials 12, no. 8 (2013): 688. http://dx.doi.org/10.1038/nmat3730.

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8

Faust, Thomas. "MOFs deliver." Nature Chemistry 7, no. 4 (2015): 270–71. http://dx.doi.org/10.1038/nchem.2229.

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9

Dusastre, Vincent. "Printed MOFs." Nature Materials 11, no. 4 (2012): 266. http://dx.doi.org/10.1038/nmat3296.

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10

Astria, Efwita, Martin Thonhofer, Raffaele Ricco, et al. "Carbohydrates@MOFs." Materials Horizons 6, no. 5 (2019): 969–77. http://dx.doi.org/10.1039/c8mh01611a.

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11

Li, Wen-Hua, Wei-Hua Deng, Guan-E. Wang, and Gang Xu. "Conductive MOFs." EnergyChem 2, no. 2 (2020): 100029. http://dx.doi.org/10.1016/j.enchem.2020.100029.

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12

Shi, Zhennan, Ling Li, Yuxiang Xiao, et al. "Synthesis of mixed-ligand Cu–MOFs and their adsorption of malachite green." RSC Advances 7, no. 49 (2017): 30904–10. http://dx.doi.org/10.1039/c7ra04820c.

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13

Pankaj, Patil*1 Ganesh Basarkar2 Sakshi Patil3. "Advancing Drug Delivery with Metal-Organic Frameworks: Challenges, Synthesis and Application." International Journal of Pharmaceutical Sciences 3, no. 2 (2025): 1100–1122. https://doi.org/10.5281/zenodo.14871790.

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Metal-Organic Frameworks (MOFs), a novel class of crystalline hybrid materials composed of metal ions or clusters bridged by organic linkers, have emerged as promising candidates in drug delivery due to their high porosity, exceptional surface area, and customizable structural features. This review provides a comprehensive analysis of the design, functionalization, and application of MOFs in advanced drug delivery systems. The synthesis methods, including solvothermal, microwave-assisted, are discussed in relation to tailoring MOF properties for specific therapeutic purposes. Particular focus is placed on the capacity of MOFs to encapsulate a wide variety of therapeutic agents, ranging from small-molecule drugs to macromolecules such as peptides, proteins, and nucleic acids, with high efficiency. Key mechanisms of drug release, including pH-sensitive, enzyme-responsive, and photo-thermal triggered systems, are explored, showcasing the potential of MOFs to enable targeted and controlled release profiles. The role of functionalized MOFs in enhancing biocompatibility, reducing systemic toxicity, and improving pharmacokinetics is examined in depth, along with the incorporation of MOFs in multi-modal therapeutic strategies such as combined chemotherapy and photodynamic therapy. Furthermore, the review highlights recent breakthroughs in leveraging MOFs for challenging therapeutic applications, including cancer treatment, antimicrobial resistance, and precision medicine. This review emphasizes ongoing efforts to address these challenges through innovative material design, offering a roadmap for future research. By synthesizing the current knowledge and identifying gaps in the field, this article underscores the transformative role of MOFs in advancing drug delivery technologies and their promise to revolutionize therapeutic interventions in the near future.
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14

Liu, Junfeng. "Application of MOFs in Lithium-Ion Batteries." Highlights in Science, Engineering and Technology 73 (November 29, 2023): 73–77. http://dx.doi.org/10.54097/hset.v73i.12842.

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In recent ten years, environmental pressure has been increasing, and the demand for batteries has been increasing, requiring high cycling capacity and large capacity clean batteries. This article introduces the research and application of metal–organic frameworks (MOFs) in lithium-ion batteries. This article also introduces the types and characteristics of MOFs, and explains the mechanism by which MOFs-based functional materials improve battery performance, such as enhancing electrode conductivity through the good conductivity of MOFs nanomaterials. The stable spatial structure of MOF materials brings more ion adsorption sites and changes in buffer electrode materials. Then, through the application of Co-MOFs materials in batteries, a brief introduction was given on the application of MOFs for negative electrode materials in lithium-ion batteries, demonstrating the superiority of MOFs as electrode materials. Finally, by introducing the characteristics of MOFs materials, the application of MOFs in batteries was prospected, and more design possibilities for MOFs materials were proposed.
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15

Meena, Khushbu, Shalini Dixit, and Balram Tripathi. "Metal-Organic Frameworks (MOFs) as Solid State Hydrogen Storage System: A Critical Review." Energy and Environment Focus 7, no. 1 (2023): 1–16. http://dx.doi.org/10.1166/eef.2023.1271.

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Metal organic frameworks (MOFs) are a class of hybrid porous materials which consists inorganic and organic linkers bounded to metal ions. The important properties of MOFs such as greater surface area, synthetic versatility, variable pore size, long range order and inherent structure makes MOFs very interesting in the field of hydrogen storage. In this manuscript we are reporting a detailed review on metal organic frameworks with the help of available previous reported literature. This review summarizes MOFs structure aspect, synthesis, nomenclature, progress of MOFs, gas storage applications, energy consumption, hydrogen storage targets, tabulation of MOFs for hydrogen storage and limitations of synthesized MOFs system related technologies, present challenges and importance of MOFs as hydrogen storage system.
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16

Wang, Panxue, Yan Sun, Xiang Li, Li Wang, Ying Xu, and Guoliang Li. "Recent Advances in Metal Organic Frameworks Based Surface Enhanced Raman Scattering Substrates: Synthesis and Applications." Molecules 26, no. 1 (2021): 209. http://dx.doi.org/10.3390/molecules26010209.

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Metal-organic frameworks (MOFs) are supramolecular nanomaterials, in which metal ions or clusters are connected by organic ligands to form crystalline lattices with highly ordered periodic porous network structure. MOFs have been widely applied in various fields, such as catalyst, sample preparation, and sensing. In recent years, MOFs based surface enhanced Raman scattering (SERS) substrates have attracted much attention since MOFs can largely improve the performance of metallic SERS substrates toward target enrichment and signal enhancement. MOFs have been exploited in SERS analysis to tackle some challenges that bare metal substrates cannot achieve. Combination of MOFs and SERS improved the sensitivity of traditional SERS analysis and extended the application scope of SERS. With the increasing exploration of MOFs based SERS substrates, there is a great demand to review the advances in these researches. Herein, this review concentrated on summarizing the preparation and applications of MOFs based SERS substrates. Representative researches were discussed to better understand the property of MOFs based SERS substrates. The advantages of MOFs based SERS substrates were highlighted, as well as their limitations. In addition, the challenges, opportunities, and future trends in MOFs based SERS analysis were tentatively discussed.
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17

Yin, Hang. "Stimuli-response of MOFs in Drug Delivery Systems." MATEC Web of Conferences 404 (2024): 03003. http://dx.doi.org/10.1051/matecconf/202440403003.

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Metal-organic frameworks (MOFs) attracted much attention of researchers in biomedicine because of its diverse functions, tuneable pore sizes, and large surface area. MOFs act as a possible drug delivery system and have numerous advantages. It exhibits high loading of drug, biocompatibility, target delivery of drugs, cytotoxicity, and biodegradability. The sizes of MOFs can also be changed without changing its topology. It makes MOFs a appropriate drug delivery carrier in various situations. In recent years, MOFs have become a multifunctional drug carrier, and researchers have designed a variety of MOFs based drug delivery strategies. The significant efficacy of these strategies is also verified. Therefore, exploring MOFs in drug delivery systems is of vital importance. This work mainly discusses about the formulation of drug-delivery MOFs and different kinds of stimuli-response of MOFs. Along with them, the efficacy of the MOFs drug delivery system are also demonstrated experimentally. It is acknowledged that using MOFs to delivery drug is a new method of curing and have a better treatment than current. This work can do help to the further research on the stimuli-response of MOF drug delivery systems.
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18

Wang, Weifu. "Matel Organic Frameworks in Drug Delivery: Synthesis and Drug Loading Strategies." MATEC Web of Conferences 404 (2024): 03013. http://dx.doi.org/10.1051/matecconf/202440403013.

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Metal-organic frameworks (MOFs), are widely used in the field of biomedicine. This material display the capacity to change the structures. It can achieve the appropriate size of the apertures by changing the preparation conditions. MOFs have numerous benefits due to their inherent qualities. It can serve as a medication carrier and has several advantages. Among them, an important advantage of MOFs as drug delivery systems is their ability to load large amounts of drugs. Moreover, it is biocompatible to use MOFs as drug delivery carriers. Besides, it is also biodegradable so that the use of MOFs is environmental-friendly. Therefore, studying the application of MOFs in drug delivery systems is of great value. The synthesis method has a significant impact on the structure of MOFs. In this work, the synthesis of MOFs for drug delivery applications is the main topic of this article. The synthesis procedures are discussed in detail. In addition, the drug loading strategy of MOFs is also worth studying. This work also summarizes the drug delivery strategies of MOFs. The research of this work will contribute to the further development of MOFs as drug delivery systems.
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19

Elrasheedy, Asmaa, Norhan Nady, Mohamed Bassyouni, and Ahmed El-Shazly. "Metal Organic Framework Based Polymer Mixed Matrix Membranes: Review on Applications in Water Purification." Membranes 9, no. 7 (2019): 88. http://dx.doi.org/10.3390/membranes9070088.

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Polymeric membranes have been widely employed for water purification applications. However, the trade-off issue between the selectivity and permeability has limited its use in various applications. Mixed matrix membranes (MMMs) were introduced to overcome this limitation and to enhance the properties and performance of polymeric membranes by incorporation of fillers such as silica and zeolites. Metal-organic frameworks (MOFs) are a new class of hybrid inorganic–organic materials that are introduced as novel fillers for incorporation in polymeric matrix to form composite membranes for different applications especially water desalination. A major advantage of MOFs over other inorganic fillers is the possibility of preparing different structures with different pore sizes and functionalities, which are designed especially for a targeted application. Different MMMs fabrication techniques have also been investigated to fabricate MMMs with pronounced properties for a specific application. Synthesis techniques include blending, layer-by-layer (LBL), gelatin-assisted seed growth and in situ growth that proved to give the most homogenous dispersion of MOFs within the organic matrix. It was found that the ideal filler loading of MOFs in different polymeric matrices is 10%, increasing the filler loading beyond this value led to formation of aggregates that significantly decreased the MOFs-MMMs performance. Despite the many merits of MOFs-MMMs, the main challenge facing the upscaling and wide commercial application of MOFs-MMMs is the difficult synthesis conditions of the MOFs itself and the stability and sustainability of MOFs-MMMs performance. Investigation of new MOFs and MOFs-MMMs synthesis techniques should be carried out for further industrial applications. Among these new synthesis methods, green MOFs synthesis has been highlighted as low cost, renewable, environmentally friendly and recyclable starting materials for MOFs-MMMs. This paper will focus on the investigation of the effect of different recently introduced MOFs on the performance of MOFs-MMMs in water purification applications.
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20

Khan, Mohammad Mansoob, Ashmalina Rahman, and Shaidatul Najihah Matussin. "Recent Progress of Metal-Organic Frameworks and Metal-Organic Frameworks-Based Heterostructures as Photocatalysts." Nanomaterials 12, no. 16 (2022): 2820. http://dx.doi.org/10.3390/nano12162820.

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In the field of photocatalysis, metal-organic frameworks (MOFs) have drawn a lot of attention. MOFs have a number of advantages over conventional semiconductors, including high specific surface area, large number of active sites, and an easily tunable porous structure. In this perspective review, different synthesis methods used to prepare MOFs and MOFs-based heterostructures have been discussed. Apart from this, the application of MOFs and MOFs-based heterostructures as photocatalysts for photocatalytic degradation of different types of pollutants have been compiled. This paper also highlights the different strategies that have been developed to modify and regulate pristine MOFs for improved photocatalytic performance. The MOFs modifications may result in better visible light absorption, effective photo-generated charge carriers (e−/h+), separation and transfer as well as improved recyclability. Despite that, there are still many obstacles and challenges that need to be addressed. In order to meet the requirements of using MOFs and MOFs-based heterostructures in photocatalysis for low-cost practical applications, future development and prospects have also been discussed.
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21

Wu, Ming-Xue, Yan Wang, Guohui Zhou, and Xiaomin Liu. "Core–Shell MOFs@MOFs: Diverse Designability and Enhanced Selectivity." ACS Applied Materials & Interfaces 12, no. 49 (2020): 54285–305. http://dx.doi.org/10.1021/acsami.0c16428.

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Wang, Fengqin, Fengxiao Zhang, Zhongrui Zhao, et al. "Multifunctional MOF-based probes for efficient detection and discrimination of Pb2+, Fe3+ and Cr2O72−/CrO42−." Dalton Transactions 50, no. 35 (2021): 12197–207. http://dx.doi.org/10.1039/d1dt01446c.

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As sensors, both MOFs and Ln3+@MOFs exhibit multi-target detection performances. And also, the combination of Eu3+@MOFs and the original MOFs can effectively distinguish analytes due to different quenching effects.
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23

Tan, Xiaohong, Xiaoqing Yao, and Zhishun Chen. "Synthesis and Application of Lead Halide Perovskite Nanocrystals@Metal-Organic Frameworks Composites." Journal of Physics: Conference Series 2393, no. 1 (2022): 012010. http://dx.doi.org/10.1088/1742-6596/2393/1/012010.

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Abstract LHP@MOFs composites, combined lead halide perovskite (LHP) nanocrystals (NCs) with metal-organic frameworks (MOFs), show great potential in the field of optoelectronic applications. Meanwhile, the stability of LHP NCs is improved by encapsulating them in MOFs. The recent progress of LHP@MOFs composites in terms of synthesis and applications is first summarized in this paper. Thereafter, a brief outlook is given for the possible future prospects of LHP@MOFs composites, which may provide the further development of stable LHP@MOFs.
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Wang, Zhengyun, Yanyu Zhong, Chenhuinan Wei, Lipei Jiang, and Hongfang Liu. "Review—Metal-Organic Framework-Based Supercapacitors." Journal of The Electrochemical Society 169, no. 1 (2022): 010516. http://dx.doi.org/10.1149/1945-7111/ac4841.

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Supercapacitors as a class of energy storage devices possess high power density, outstanding reversibility and long cycle life. The development of innovative electrode materials and unconventional configurations determine the successful operation of supercapacitors. Owing to controllable porous structure and unique electrochemical behavior, great efforts have been devoted to designing and fabricating innovative metal-organic frameworks (MOFs) based supercapacitors. In this review, recent developments in MOFs related supercapacitors electrodes are summarized. Furthermore, the advances in MOFs composites for supercapactiors application including pristine MOFs, MOFs composites and MOFs-derived composites are systematically discussed by integrating charge storing principle. Finally, future prospects and opportunities in the design of MOFs related electrodes are also delineated.
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Wang, Kuai-Bing, Rong Bi, Zi-Kai Wang, Yang Chu, and Hua Wu. "Metal–organic frameworks with different spatial dimensions for supercapacitors." New Journal of Chemistry 44, no. 8 (2020): 3147–67. http://dx.doi.org/10.1039/c9nj05198h.

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Recent progress in MOF materials for SCs with different spatial dimensions, such as 2D MOFs, including conductive MOFs and nanosheets, and 3D MOFs, categorized as single metallic and multiple metallic MOFs, are reviewed.
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Fang, Ruiqi, Amarajothi Dhakshinamoorthy, Yingwei Li, and Hermenegildo Garcia. "Metal organic frameworks for biomass conversion." Chemical Society Reviews 49, no. 11 (2020): 3638–87. http://dx.doi.org/10.1039/d0cs00070a.

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This review narrates the recent developments on the catalytic applications of pristine metal–organic frameworks (MOFs), functionalized MOFs, guests embedded over MOFs and MOFs derived carbon composites for biomass conversion into platform chemicals.
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Feng, Linxuan, and Chenxi Song. "Coated Metal-Organic Framework Composites for Anti-Cancer Drug Delivery: Preparation and Applications." Highlights in Science, Engineering and Technology 6 (July 27, 2022): 155–64. http://dx.doi.org/10.54097/hset.v6i.957.

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Metal-organic frameworks (MOFs) are made from metal ions and various organic ligands, which have been demonstrated to be an essential material used as drug delivery vehicles because of their large surface area, simple functionalization, high porosity and excellent biocompatibility. Recently, coated MOFs are promising approaches to overcome the limitations of pure MOFs in drug delivery systems with improved targeting, better biodistribution and lower cytotoxicity. In this review, the preparation and applications of polymer-coated MOFs, magnetic core-shell MOFs and membrane-coated MOFs are mainly introduced. The polymer-coated MOFs with high structural and functional flexibility achieve greater drug loadings via covalent grafting and polymerization. Magnetic core-shell MOFs can effectively detect the location of tumors by applying a magnetic field. Their enhanced biodegradability is realized due to the presence of these magnetic agents. Membrane-coated MOFs, especially for cancer cell membranes and red blood cell membranes, are capable of making drug substances more durable in the immune system and preventing them from being digested with improvement in tumor-targeting and biointerfacing effects. These coated MOFs and corresponding MOFs with detailed modifications result in better therapeutic efficacy in anticancer activities, providing new insights into the development of chemical synthesis and biomedical applications.
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Vodyashkin, Andrey A., Antonina V. Sergorodceva, Parfait Kezimana, and Yaroslav M. Stanishevskiy. "Metal-Organic Framework (MOF)—A Universal Material for Biomedicine." International Journal of Molecular Sciences 24, no. 9 (2023): 7819. http://dx.doi.org/10.3390/ijms24097819.

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Metal-organic frameworks (MOFs) are a very promising platform for applications in various industries. In recent years, a variety of methods have been developed for the preparation and modification of MOFs, providing a wide range of materials for different applications in life science. Despite the wide range of different MOFs in terms of properties/sizes/chemical nature, they have not found wide application in biomedical practices at present. In this review, we look at the main methods for the preparation of MOFs that can ensure biomedical applications. In addition, we also review the available options for tuning the key parameters, such as size, morphology, and porosity, which are crucial for the use of MOFs in biomedical systems. This review also analyses possible applications for MOFs of different natures. Their high porosity allows the use of MOFs as universal carriers for different therapeutic molecules in the human body. The wide range of chemical species involved in the synthesis of MOFs makes it possible to enhance targeting and prolongation, as well as to create delivery systems that are sensitive to various factors. In addition, we also highlight how injectable, oral, and even ocular delivery systems based on MOFs can be used. The possibility of using MOFs as therapeutic agents and sensitizers in photodynamic, photothermal, and sonodynamic therapy was also reviewed. MOFs have demonstrated high selectivity in various diagnostic systems, making them promising for future applications. The present review aims to systematize the main ways of modifying MOFs, as well as the biomedical applications of various systems based on MOFs.
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29

Du, Zhehua. "Research progress on degradation of organic pollutants based on metal–organic frameworks materials." E3S Web of Conferences 385 (2023): 04035. http://dx.doi.org/10.1051/e3sconf/202338504035.

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As an advanced oxidation process, Fenton oxidation has attracted much attention because its reactants and products are green and pollution - free. The traditional Fenton oxidation method has some problems, such as high PH requirement and low utilization rate of hydrogen peroxide. Over the past few years, the advancements in application research of Metal-Organic Frameworks (MOFs) have presented innovative and effective ideas for addressing the aforementioned issues. This paper presents the recent advancements in Fenton oxidation technique utilizing Fenton-based materials. Based on literature analysis, it can be seen that Fe-based MOFs were initially used for catalytic reaction and the research shows that the catalytic activity of Fe-based MOFs can be increased by increasing the number of unsaturated Fe metal sites. And the doping of other metals into Fe-based MOF or dual ligand Fe-based MOFs can play a role in changing the structure and increasing the unsaturated metal sites which can further expand the direct application of MOFs in the Fenton oxidation method. However, due to the limited types of iron-based MOFs, non-iron-based MOFs materials and indirect use of MOFs have been reported in the indirect use of MOFs, catalytic active substances can be compounded into MOFs materials through in-situ growth, forming a synergistic effect to improve the efficiency of degradation by means of carbonization or pyrolysis of MOFs, MOFs derived materials can be obtained.
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30

Sun, Ao. "Applications of MOFs in Drug Delivery." Highlights in Science, Engineering and Technology 58 (July 12, 2023): 351–57. http://dx.doi.org/10.54097/hset.v58i.10122.

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The main research focus of this article is the application of Metal-Organic Frameworks (MOFs) in drug delivery applications. The review primarily concentrates on the methods used for loading drugs into MOFs, their response to stimuli, potential applications, and limitations. The article begins with discussing the limitations of traditional drug delivery systems and introduces MOFs as a potential solution to these limitations. The drug loading strategy section describes the three main methods for loading drugs into MOFs, including their respective benefits and drawbacks. The stimulus response release program section explores various stimuli that can trigger drug release from MOFs, including physical, chemical, and biological factors, and provides examples of how MOFs can respond to these stimuli. The section on application and challenges provides an overview of current studies exploring the potential of MOFs in biomedical applications, including cancer therapy, antibacterial therapy, and anti-inflammatory therapy, while also highlighting the key challenges facing MOFs research, such as biocompatibility and toxicity. Finally, the article concludes by offering prospects for future developments in MOFs research. This review article provides a significant resource for drug delivery researchers and practitioners who wish to investigating the possibility of utilizing MOFs as novel drug delivery vehicles.
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Cai, Mengru, Gongsen Chen, Liuying Qin, et al. "Metal Organic Frameworks as Drug Targeting Delivery Vehicles in the Treatment of Cancer." Pharmaceutics 12, no. 3 (2020): 232. http://dx.doi.org/10.3390/pharmaceutics12030232.

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In recent years, metal organic frameworks (MOFs) have been widely developed as vehicles for the effective delivery of drugs to tumor tissues. Due to the high loading capacity and excellent biocompatibility of MOFs, they provide an unprecedented opportunity for the treatment of cancer. However, drugs which are commonly used to treat cancer often cause side effects in normal tissue accumulation. Therefore, the strategy of drug targeting delivery based on MOFs has excellent research significance. Here, we introduce several intelligent targeted drug delivery systems based on MOFs and their characteristics as drug-loading systems, and the challenges of MOFs are discussed. This article covers the following types of MOFs: Isoreticular Metal Organic Frameworks (IRMOFs), Materials of Institute Lavoisier (MILs), Zeolitic Imidazolate Frameworks (ZIFs), University of Oslo (UiOs), and MOFs-based core-shell structures. Generally, MOFs can be reasonably controlled at the nanometer size to effectively achieve passive targeting. In addition, different ligands can be modified on MOFs for active or physicochemical targeting. On the one hand, the targeting strategy can improve the concentration of the drugs at the tumor site to improve the efficacy, on the other hand, it can avoid the release of the drugs in normal tissues to improve safety. Despite the challenges of clinical application of MOFs, MOFs have a number of advantages as a kind of smart delivery vehicle, which offer possibilities for clinical applications.
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Han, Yaoyao, Weicong Liu, Jianjing Huang, et al. "Cyclodextrin-Based Metal-Organic Frameworks (CD-MOFs) in Pharmaceutics and Biomedicine." Pharmaceutics 10, no. 4 (2018): 271. http://dx.doi.org/10.3390/pharmaceutics10040271.

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Metal-organic frameworks (MOFs) show promising application in biomedicine and pharmaceutics owing to their extraordinarily high surface area, tunable pore size, and adjustable internal surface properties. However, MOFs are prepared from non-renewable or toxic materials, which limit their real-world applications. Cyclodextrins (CDs) are a typical natural and biodegradable cyclic oligosaccharide and are primarily used to enhance the aqueous solubility, safety, and bioavailability of drugs by virtue of its low toxicity and highly flexible structure, offering a peculiar ability to form CD/drug inclusions. A sophisticated strategy where CD is deployed as a ligand to form an assembly of cyclodextrin-based MOFs (CD-MOFs) may overcome real-world application drawbacks of MOFs. CD-MOFs incorporate the porous features of MOFs and the encapsulation capability of CD for drug molecules, leading to outstanding properties when compared with traditional hybrid materials. This review focuses on the inclusion technology and drug delivery properties associated with CD-MOFs. In addition, synthetic strategies and currently developed uses of CD-MOFs are highlighted as well. Also, perspectives and future challenges in this rapidly developing research area are discussed.
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Zhang, Hao, Cha Li, Yang Li, Jiandong Pang, and Xianhe Bu. "The Advanced Synthesis of MOFs-Based Materials in Photocatalytic HER in Recent Three Years." Catalysts 12, no. 11 (2022): 1350. http://dx.doi.org/10.3390/catal12111350.

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Since the advent of metal–organic frameworks (MOFs), researchers have paid extensive attention to MOFs due to their determined structural composition, controllable pore size, and diverse physical and chemical properties. Photocatalysis, as a significant application of MOFs catalysts, has developed rapidly in recent years and become a research hotspot continuously. Various methods and approaches to construct and modify MOFs and their derivatives can not only affect the structure and morphology, but also largely determine their properties. Herein, we summarize the advanced synthesis of MOFs-based materials in the field of the photocatalytic decomposition of water to produce hydrogen in the recent three years. The main contents include the overview of the novel synthesis strategies in four aspects: internal modification and structure optimization of MOFs materials, MOFs/semiconductor composites, MOFs/COFs-based hybrids, and MOFs-derived materials. In addition, the problems and challenges faced in this direction and the future development goals were also discussed. We hope this review will help deepen the reader’s understanding and promote continued high-quality development in this field.
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34

Zhu, Rongyue, Mengru Cai, Tingting Fu, et al. "Fe-Based Metal Organic Frameworks (Fe-MOFs) for Bio-Related Applications." Pharmaceutics 15, no. 6 (2023): 1599. http://dx.doi.org/10.3390/pharmaceutics15061599.

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Metal–organic frameworks (MOFs) are porous materials composed of metal ions and organic ligands. Due to their large surface area, easy modification, and good biocompatibility, MOFs are often used in bio-related fields. Fe-based metal–organic frameworks (Fe-MOFs), as important types of MOF, are favored by biomedical researchers for their advantages, such as low toxicity, good stability, high drug-loading capacity, and flexible structure. Fe-MOFs are diverse and widely used. Many new Fe-MOFs have appeared in recent years, with new modification methods and innovative design ideas, leading to the transformation of Fe-MOFs from single-mode therapy to multi-mode therapy. In this paper, the therapeutic principles, classification, characteristics, preparation methods, surface modification, and applications of Fe-MOFs in recent years are reviewed to understand the development trends and existing problems in Fe-MOFs, with the view to provide new ideas and directions for future research.
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35

Cong, Zihan. "Application of Zn-MOFs in Treating Cancer." Highlights in Science, Engineering and Technology 36 (March 21, 2023): 139–44. http://dx.doi.org/10.54097/hset.v36i.5653.

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Metal-organic frameworks (MOFs) are extremely porous crystals belonging to metallic complexes, made up of metal ions or clusters and organic ligands via coordinative bonding. The construction of tailored MOFs has attracted increasing interest over the past few decades. Particularly, a variety of applications for the delivery of drugs using MOFs are being investigated. MOFs were initially employed to deliver small-molecule medications. In this article, the construction of electrochemical (EC) biosensors based on MOFs that are directed toward certain analytes are mainly introduced. The classification of MOFs for drug-delivery systems (DDSs) based on the types of constitutes is presented in this article as an overview and point of view of MOF-based DDSs, among which, Zn-based MOFs are one of the best choices to be used in cancer treatment. This article demonstrates the advantages of Zn-based MOFs in cancer treatment compared to their counterparts.
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36

宋, 青岳. "Application of MOFs in Water Purification." Advances in Environmental Protection 12, no. 02 (2022): 309–13. http://dx.doi.org/10.12677/aep.2022.122042.

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37

Qian, Yanda, Hao Zhan, Xiaoxue Wang, Shengjiao Xu, and Zhengchuan Wu. "Preparation of Magnetic Chitosan-Based MOFs (FCM) for Antimony Removal." International Journal of Oceanography & Aquaculture 8, no. 3 (2024): 1–10. http://dx.doi.org/10.23880/ijoac-16000328.

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The rapid development of industry has led to heavy metal pollution becoming a significant environmental concern, with particular attention being focused on antimony pollution. China, as one of the world’s largest producers of antimony, faces potential threats to ecosystems and human health from this type of pollution. To address this issue, an innovative method for preparing new green functional materials was proposed in this study. An efficient and economical composite material (FCM) was developed, based on non-toxic chitosan loaded with the metal-organic framework (MOFs) and magnetic nano ferrosolferric oxide. This material was then used to adsorb Sb (III) in water environments. The effects of the mass ratio of chitosan to metal-organic frameworks (MOFs) denoted as MIL-100(Fe), ferrosolferric oxide nanoparticles (Nano-Fe3 O4 ) to chitosan, reaction temperature, reaction time, and initiator concentration on the removal rate of Sb (III) were investigated. The results indicated that a mass ratio of 1:2:2 for Fe3 O4 , chitosan, and MOFs, an initiator concentration of 1.25 mmoL·L-1, a reaction time of 90min, and a water bath temperature of 60℃ resulted in a removal rate of Sb (III) from FCM reaching 96.8%. Characterization analysis revealed the rough and uneven surface of FCM, with numerous aggregated irregular particles and porous crystalline structures. In conclusion, FCM demonstrates effective removal of heavy metal antimony from water while exhibiting high environmental compatibility and sustainability.
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38

孙, 亮. "Application Research Progress of MOFs Materials." Open Journal of Natural Science 08, no. 06 (2020): 547–51. http://dx.doi.org/10.12677/ojns.2020.86064.

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39

Yoon, Geon-Gon, Joon-Yeob Lee, and Jeong-Hak Choi. "Aqueous Adsorption of Lead Ions Using Copper-Based MOFs Immobilized Nanofibers." Journal of Environmental Science International 34, no. 6 (2025): 359–73. https://doi.org/10.5322/jesi.2025.34.6.359.

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40

Zheng, Anqi, Kuibo Yin, Rui Pan, Mingyun Zhu, Yuwei Xiong, and Litao Sun. "Research Progress on Metal–Organic Frameworks by Advanced Transmission Electron Microscopy." Nanomaterials 13, no. 11 (2023): 1742. http://dx.doi.org/10.3390/nano13111742.

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Metal–organic frameworks (MOFs), composed of metal nodes and inorganic linkers, are promising for a wide range of applications due to their unique periodic frameworks. Understanding structure–activity relationships can facilitate the development of new MOFs. Transmission electron microscopy (TEM) is a powerful technique to characterize the microstructures of MOFs at the atomic scale. In addition, it is possible to directly visualize the microstructural evolution of MOFs in real time under working conditions via in situ TEM setups. Although MOFs are sensitive to high-energy electron beams, much progress has been made due to the development of advanced TEM. In this review, we first introduce the main damage mechanisms for MOFs under electron-beam irradiation and two strategies to minimize these damages: low-dose TEM and cryo-TEM. Then we discuss three typical techniques to analyze the microstructure of MOFs, including three-dimensional electron diffraction, imaging using direct-detection electron-counting cameras, and iDPC-STEM. Groundbreaking milestones and research advances of MOFs structures obtained with these techniques are highlighted. In situ TEM studies are reviewed to provide insights into the dynamics of MOFs induced by various stimuli. Additionally, perspectives are analyzed for promising TEM techniques in the research of MOFs’ structures.
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41

Bull, Okpara Sergeant, Ibiso Bull, Gloria Kelechi Amadi, Chikwem Obaalologhi Odu, and Eyu Okpa Okpa. "A Review on Metal- Organic Frameworks (MOFS), Synthesis, Activation, Characterisation, and Application." Oriental Journal Of Chemistry 38, no. 3 (2022): 490–516. http://dx.doi.org/10.13005/ojc/380301.

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A myriad of MOFs reported in the literature are made up of transition metal ions (nodes), single or in clusters, braced by organic supports or ligands. But there are other MOFs in which the central metal are non-transition elements. MOFs are prepared by the combination of inorganic and organic building units to give materials with high porosity, and other unique properties. Due to MOFs unique structural topographies, they find applications in diverse areas such as gas adsorption, gas purification and separation, catalysis, and in drug delivery. In this review article, the design and methods for MOFs synthesis, MOFs- activation, characterization, as well as organic linkers used for the making of MOFs are discussed. Furthermore the shortage of MOFs research based on silicon-containing aryl building units as well as boron-containing building units in comparison to carbon-containing building units are highlighted. We hope that this review will help researchers, industrialists and academics.
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Zha, Xiaoqian, Xianhui Zhao, Erin Webb, Shifa Ullah Khan, and Yang Wang. "Beyond Pristine Metal–Organic Frameworks: Preparation of Hollow MOFs and Their Composites for Catalysis, Sensing, and Adsorption Removal Applications." Molecules 28, no. 1 (2022): 144. http://dx.doi.org/10.3390/molecules28010144.

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Metal–organic frameworks (MOFs) have been broadly applied to numerous domains with a substantial surface area, tunable pore size, and multiple unsaturated metal sites. Recently, hollow MOFs have greatly attracted the scientific community due to their internal cavities and gradient pore structures. Hollow MOFs have a higher tunability, faster mass-transfer rates, and more accessible active sites when compared to traditional, solid MOFs. Hollow MOFs are also considered to be candidates for some functional material carriers. For example, composite materials such as hollow MOFs and metal nanoparticles, metal oxides, and enzymes have been prepared. These composite materials integrate the characteristics of hollow MOFs with functional materials and are broadly used in many aspects. This review describes the preparation strategies of hollow MOFs and their composites as well as their applications in organic catalysis, electrochemical sensing, and adsorption separation. Finally, we hope that this review provides meaningful knowledge about hollow-MOF composites and their derivatives and offers many valuable references to develop hollow-MOF-based applied materials.
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Chen, Yan, Chao Lei, Yong-Gang Zhao, Ming-Li Ye, and Kun Yang. "Orientation Growth of N-Doped and Iron-Based Metal–Organic Framework and Its Application for Removal of Cr(VI) in Wastewater." Molecules 29, no. 5 (2024): 1007. http://dx.doi.org/10.3390/molecules29051007.

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A series of NH2-functionalized nano-sized magnetic metal–organic frameworks (MOFs) were prepared in this study for Cr(VI) removal from wastewater. It was observed that not only the morphological, i.e., orientation growth of N-doped and iron-based metal–organic frameworks, but also the adsorption of magnetic MOFs is largely related to the used amount of ammonium hydroxide in preparation. For example, with increasing amounts of ammonium hydroxide used in preparation, the morphology of magnetic MOFs changed from spherical to cube and triangular cone. Moreover, the maximum adsorption capacity of spherical-magnetic MOFs, cubic-magnetic MOFs and triangular cone-magnetic MOFs could be up to 204.08 mg/g, 232.56 mg/g and 270.27 mg/g, respectively. Under optimal conditions, the adsorption process of magnetic MOFs for Cr(VI) was consistent with the pseudo-second-order rate equation (R2 = 1) and Langmuir isotherm model (R2 &gt; 0.99). Therefore, magnetic MOFs developed in this work offered a viable option for the removal of Cr(VI) from wastewater.
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Yang, Ning, Zongyan He, and Tianqun Lang. "Drug Delivery Systems Based on Metal–Organic Frameworks for Tumor Immunotherapy." Pharmaceutics 17, no. 2 (2025): 225. https://doi.org/10.3390/pharmaceutics17020225.

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Metal–organic frameworks (MOFs) are a class of inorganic-organic hybrid nanoparticles formed by the coordination of metal ions/clusters and organic ligands. Due to their high porosities, large surface areas, adjustable structures, and responsiveness to light/sound, etc., MOFs have shown great clinical potential in the field of tumor therapy. Tumor immunotherapy exerts antitumor effects through reshaping tumor immune microenvironment, showing significant preclinical and clinical advantages. Based on the mechanisms of immunity activation, the tumor immunotherapy agents can be divided into chemotherapeutic agents, immunomodulators, enzymes, tumor vaccines and oligonucleotide drugs, etc. Herein, we review the MOFs-based drug delivery systems for tumor immunotherapy. The classification of MOFs, followed by their antitumor immunity activation mechanisms, are first introduced. Drug delivery systems based on MOFs with different immunotherapy agents are also summarized, especially the synergetic immunity activation mechanisms triggered by MOFs and their loadings. Furthermore, the merits and drawbacks of MOFs and the potential strategies for MOFs to promote their clinical applications are discussed.
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45

Levin, Ilya, and Osnat Keren. "A Generalized If-Then-Else Operator for the Representation of Multi-Output Functions." Mathematical Problems in Engineering 2013 (2013): 1–13. http://dx.doi.org/10.1155/2013/401616.

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The paper deals with fundamentals of systems of Boolean functions called multi-output functions (MOFs). A new approach to representing MOFs is introduced based on a Generalized If-Then-Else (GITE) function. It is shown that known operations on MOFs may be expressed by a GITE function. The GITE forms the algebra of MOFs. We use the properties of this algebra to solve an MOF-decomposition problem. The solution provides a compact representation of MOFs.
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46

Jiang, Di, Chuanying Wei, Ziyang Zhu, Xiaohui Xu, Min Lu, and Guangsheng Wang. "Preparation of Flower-like Nickel-Based Bimetallic Organic Framework Electrodes for High-Efficiency Hybrid Supercapacitors." Crystals 11, no. 11 (2021): 1425. http://dx.doi.org/10.3390/cryst11111425.

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Metal organic frameworks (MOFs) have been rapidly developed in the application of electrode materials due to their controllable morphology and ultra-high porosity. In this research, flower-like layered nickel-based bimetallic MOFs microspheres with different metal central ions were synthesized by solvothermal method. Compared with Ni-MOFs, the optimization of the specific capacitance of NiCo-MOFs and NiMn-MOFs was been confirmed. For example, the specific capacitance of NiCo-MOFs can reach 882 F·g−1 at 0.5 A·g−1 while maintaining satisfactory cycle life (the specific capacity remains 90.1% of the initial value after 3000 charge-discharge cycles at 5 A·g−1). In addition, the NiCo-MOFs//AC HSCs, which are composed of NiCo-MOFs and activated carbon (AC), achieved a maximum energy density of 18.33 Wh·kg−1 at a power density of 400 W·kg−1, and showed satisfactory cycle life (82.4% after 3000 cycles). These outstanding electrochemical properties can be ascribed to the synergistic effect between metal ions, the optimized conductivity, and the unique layered stacked flower structure, which provides a smooth transmission channel for electrons/ions. In addition, this research gives a general method for the application of MOFs in the field of supercapacitors.
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Zhang, Nan, Pengfei Cui, Jinrong Zhang, and Yang Qiao. "MOF-Derived Electrocatalysts for High-Efficiency Hydrogen Production via Water Electrolysis." Catalysts 15, no. 6 (2025): 579. https://doi.org/10.3390/catal15060579.

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Water electrolysis for hydrogen production has garnered significant attention in the context of increasing global energy demands and the “dual-carbon” strategy. However, practical implementation is hindered by challenges such as high overpotentials, high catalysts costs, and insufficient catalytic activity. In this study, three mono and bimetallic metal−organic framework (MOFs)-derived electrocatalysts, Fe-MOFs, Fe/Co-MOFs, and Fe/Mn-MOFs, were synthesized via a one-step hydrothermal method, using nitro-terephthalic acid (NO2-BDC) as the ligand and N,N-dimethylacetamide (DMA) as the solvent. Electrochemical tests demonstrated that the Fe/Mn-MOFs catalyst exhibited superior performance, achieving an overpotential of 232.8 mV and a Tafel slope of 59.6 mV·dec−1, alongside the largest electrochemical active surface area (ECSA). In contrast, Fe/Co-MOFs displayed moderate catalytic activity, while Fe-MOFs exhibited the lowest efficiency. Stability tests revealed that Fe/Mn-MOFs retained 92.3% of its initial current density after 50 h of continuous operation, highlighting its excellent durability for the oxygen evolution reaction (OER). These findings emphasize the enhanced catalytic performance of bimetallic MOFs compared to monometallic counterparts and provide valuable insights for the development of high-efficiency MOF-based electrocatalysts for sustainable hydrogen production.
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Biswas, Sulagna, Debabrata Singha, and Nilasish Pal. "Luminescent metal-organic frameworks." International Journal of Experimental Research and Review 26 (December 30, 2021): 99–113. http://dx.doi.org/10.52756/ijerr.2021.v26.008.

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Metal-organic frameworks (MOFs) show a wide range of luminescent behaviours. In this review, there is a brief discussion on the origins of MOF luminosity due to various type of linkers and their special arrangement in MOFs, the structure and synthesis of the multiple kinds of linker-based luminescent MOFs. Finally, luminescent MOFs as the chemical sensor has been discussed. This article will be helpful for researchers and synthetic chemists attempting for designing luminescent MOFs and their application as a chemical sensor.
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Peng, Yaguang, Qiang Tan, Hongliang Huang, et al. "Customization of functional MOFs by a modular design strategy for target applications." Chemical Synthesis 2, no. 3 (2022): 15. http://dx.doi.org/10.20517/cs.2022.15.

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Herein, we propose a versatile “functional modular assembly” strategy for customizing MOFs that allows installing the desired functional unit into a host material. The functional unit could be switched according to different applications. MOF-808, a highly stable Zr-MOF containing dangling formate groups, was selected as a host material for demonstration. Functional molecules with carboxyl connectors can be directly inserted into MOF-808 to form functional modular MOFs (FM-MOFs) through single substitution, while for those without carboxyl connectors, a pre-designed convertor was grafted firstly followed by the functional molecules in a stepwise manner. A series of tailor-made FM-MOFs were generated and show excellent performance toward different applications, such as adsorption, catalysis, fluorescent sensing, electrochemistry, and the control of surface wettability. On the other hand, the functional units on the FM-MOFs can switch freely and completely via full interconversion, as well as partly to construct multivariate MOFs (MTV-MOFs). Therefore, this strategy provides a benchmark for rapid customization of functional MOFs for diverse applications that can realize the rapid modular design of materials.
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Jeong, WooSeok, Dae-Woon Lim, Sungjune Kim, et al. "Modeling adsorption properties of structurally deformed metal–organic frameworks using structure–property map." Proceedings of the National Academy of Sciences 114, no. 30 (2017): 7923–28. http://dx.doi.org/10.1073/pnas.1706330114.

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Structural deformation and collapse in metal-organic frameworks (MOFs) can lead to loss of long-range order, making it a challenge to model these amorphous materials using conventional computational methods. In this work, we show that a structure–property map consisting of simulated data for crystalline MOFs can be used to indirectly obtain adsorption properties of structurally deformed MOFs. The structure–property map (with dimensions such as Henry coefficient, heat of adsorption, and pore volume) was constructed using a large data set of over 12000 crystalline MOFs from molecular simulations. By mapping the experimental data points of deformed SNU-200, MOF-5, and Ni-MOF-74 onto this structure–property map, we show that the experimentally deformed MOFs share similar adsorption properties with their nearest neighbor crystalline structures. Once the nearest neighbor crystalline MOFs for a deformed MOF are selected from a structure–property map at a specific condition, then the adsorption properties of these MOFs can be successfully transformed onto the degraded MOFs, leading to a new way to obtain properties of materials whose structural information is lost.
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