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Journal articles on the topic 'Molecular cages'

Author: Grafiati

Published: 4 June 2021

Last updated: 26 July 2025

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1

Montà-González, Giovanni, Eduardo Ortiz-Gómez, Rocío López-Lima, Guillermo Fiorini, Ramón Martínez-Máñez, and Vicente Martí-Centelles. "Water-Soluble Molecular Cages for Biological Applications." Molecules 29, no. 7 (2024): 1621. http://dx.doi.org/10.3390/molecules29071621.

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The field of molecular cages has attracted increasing interest in relation to the development of biological applications, as evidenced by the remarkable examples published in recent years. Two key factors have contributed to this achievement: First, the remarkable and adjustable host–guest chemical properties of molecular cages make them highly suitable for biological applications. This allows encapsulating therapeutic molecules to improve their properties. Second, significant advances have been made in synthetic methods to create water-soluble molecular cages. Achieving the necessary water so

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2

Berthelsen, H., and L. T. Hansen. "The Effect of Hay on the Behaviour of Caged Rabbits (Oryctolagus Cuniculus)." Animal Welfare 8, no. 2 (1999): 149–57. http://dx.doi.org/10.1017/s0962728600021485.

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AbstractTo examine the effect of hay on behaviour of caged rabbits, Oryctolagus cuniculus, a study was carried out on 86 rabbits, kept in wire cages with no access to hay in one period and with access to hay in a second period. As the study was part of a larger experiment analysing the rabbits’ behaviour in two different cage systems, the rabbits were equally distributed across two systems: a system with conventional barren wire cages, and an enriched system with boxes and raised height at the back of the wire cages. The rabbits’ behaviour was recorded using direct scan sampling during the day

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3

Martrenchar, A., E. Boilletot, J.-P. Cotte, and J.-P. Morisse. "Wire-Floor Pens as an Alternative to Metallic Cages in Fattening Rabbits: Influence on Some Welfare Traits." Animal Welfare 10, no. 2 (2001): 153–61. http://dx.doi.org/10.1017/s0962728600023824.

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AbstractThe possibility of improving the welfare of fattening rabbits by rearing them in pens instead of cages was investigated. Time budgets, locomotion, ear lesions, breaking strength of the femur and productivity were compared in fattening rabbits kept at the same stocking density (15 rabbits m−2) either in standard cages of 0.4m2 (6 animals) or in pens of 1.6m2 (24 animals). Behavioural observations, performed by video recording at 6 and 9 weeks of age, indicated that the frequency of rabbits walking over one another was higher in cages than in pens at 9 weeks of age. Although the time spe

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4

Tönnemann, Justus, Rosario Scopelliti, and Kay Severin. "Molecular Borophosphate Cages." European Journal of Inorganic Chemistry 2013, no. 29 (2013): 5071–74. http://dx.doi.org/10.1002/ejic.201300841.

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5

Tapia, Lucía, Ignacio Alfonso, and Jordi Solà. "Molecular cages for biological applications." Organic & Biomolecular Chemistry 19, no. 44 (2021): 9527–40. http://dx.doi.org/10.1039/d1ob01737c.

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6

Katin, Konstantin P., Valeriy B. Merinov, Alexey I. Kochaev, Savas Kaya, and Mikhail M. Maslov. "All-Nitrogen Cages and Molecular Crystals: Topological Rules, Stability, and Pyrolysis Paths." Computation 8, no. 4 (2020): 91. http://dx.doi.org/10.3390/computation8040091.

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We combined ab initio molecular dynamics with the intrinsic reaction coordinate in order to investigate the mechanisms of stability and pyrolysis of N4 ÷ N120 fullerene-like nitrogen cages. The stability of the cages was evaluated in terms of the activation barriers and the activation Gibbs energies of their thermal-induced breaking. We found that binding energies, bond lengths, and quantum-mechanical descriptors failed to predict the stability of the cages. However, we derived a simple topological rule that adjacent hexagons on the cage surface resulted in its instability. For this reason, th

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7

Russina, Margarita, Evout Kemner, and Ferenc Mezei. "Impact of the Confinement on the Intra-Cage Dynamics of Molecular Hydrogen in Clathrate Hydrates." Materials Science Forum 879 (November 2016): 1294–99. http://dx.doi.org/10.4028/www.scientific.net/msf.879.1294.

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We have studied the diffusive mobility of hydrogen molecules confined in different size cages in clathrate hydrates. In clathrate hydrate H2 molecules are effectively stored by confinement in two different size cages of the nanoporous host structure with accessible volumes of about 0.50 and 0.67 nm diameters, respectively. For the processes of sorption and desorption of the stored hydrogen the diffusive mobility of the molecules plays a fundamental role. In the present study we have focused on the dynamics of the H2 molecules inside the cages as one aspect of global guest molecule mobility acr

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8

Trauner, Dirk. "Molecular switches and cages." Beilstein Journal of Organic Chemistry 8 (June 13, 2012): 870–71. http://dx.doi.org/10.3762/bjoc.8.97.

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9

Huang, Xin, Zhenchao Li, Le Zhang, Jiayuan He, and Hailong Lu. "Molecular Insights into the Effect of Nitrogen Bubbles on the Formation of Tetrahydrofuran Hydrates." Molecules 27, no. 15 (2022): 4945. http://dx.doi.org/10.3390/molecules27154945.

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In this work, a molecular dynamics simulation was conducted to study the microscopic mechanism of how nitrogen bubbles affect the formation of THF hydrates at the molecular level. The results obtained reveal that the nitrogen bubble can promote the formation of THF hydrates. In the system with a nitrogen bubble, more THF-filled cages were generated, and the crystal structure was more orderly. The promotion of nitrogen bubbles on hydrate crystallization comes from the dissolution of nitrogen molecules. Some of dissolved nitrogen molecules can be enclosed in small hydrate cages near the nitrogen

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10

Service, Robert F. "Molecular ‘sponges’ could be hydrogen fuel tanks." Science 381, no. 6665 (2023): 1383. http://dx.doi.org/10.1126/science.adl0643.

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11

Avram, Liat, and Yoram Cohen. "Diffusion NMR of molecular cages and capsules." Chemical Society Reviews 44, no. 2 (2015): 586–602. http://dx.doi.org/10.1039/c4cs00197d.

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12

Mitra, Tamoghna, Kim E. Jelfs, Marc Schmidtmann, et al. "Molecular shape sorting using molecular organic cages." Nature Chemistry 5, no. 4 (2013): 276–81. http://dx.doi.org/10.1038/nchem.1550.

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13

COLEMAN, JULIAN, DAVID EVANS, CHRIS HAWES, DAVID HORSLEY, and LOUISE COLE. "Structure and molecular organization of higher plant coated vesicles." Journal of Cell Science 88, no. 1 (1987): 35–45. http://dx.doi.org/10.1242/jcs.88.1.35.

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Suspension-cultured cells of carrot contain three populations of coated vesicles, associated with the plasma membrane (84–91 nm diameter), Golgi dictyosomes and the partially coated reticulum (61–73 nm diameter). These were observed by thin sectioning, dry-cleaving and rapid-freeze deep-etching of cells. Dissociation of clathrin coats with Tris, released triskelions that were morphologically identical with those from mammalian tissue. The triskelion arm length of carrot clathrin was greater (61nm versus 44–50 nm), but packaging results in clathrin cages of pentagons and hexagons of similar siz

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14

Li, C., A. D. Manick, J. P. Dutasta, X. Bugaut, B. Chatelet, and A. Martinez. "Frustrated behavior of Lewis/Brønsted pairs inside molecular cages." Organic Chemistry Frontiers 9, no. 7 (2022): 1826–36. http://dx.doi.org/10.1039/d2qo00011c.

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15

Wang, Yu, Hongxun Fang, Wei Zhang, Yongbin Zhuang, Zhongqun Tian, and Xiaoyu Cao. "Interconversion of molecular face-rotating polyhedra through turning inside out." Chemical Communications 53, no. 64 (2017): 8956–59. http://dx.doi.org/10.1039/c7cc04159d.

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16

Edwardson, Thomas G. W., Mikail D. Levasseur, and Donald Hilvert. "The OP Protein Cage: A Versatile Molecular Delivery Platform." CHIMIA International Journal for Chemistry 75, no. 4 (2021): 323–28. http://dx.doi.org/10.2533/chimia.2021.323.

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Well-defined containers constructed from multiple protein subunits are a unique class of nanomaterial useful in supramolecular chemistry and biology. These protein cages are widespread in nature, where they are responsible for a diversity of important tasks. As such, producing our own designer protein cages, complete with bespoke functionalities, is a promising avenue to new nanodevices, biotechnology and therapies. Herein, we describe how an artificial, computationally designed protein cage can be rationally engineered using supramolecular intuition to produce new functional capsules. Positiv

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17

Huang, Hsin-Hua, and Tomáš Šolomek. "Photochemistry Meets Porous Organic Cages." CHIMIA International Journal for Chemistry 75, no. 4 (2021): 285–90. http://dx.doi.org/10.2533/chimia.2021.285.

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Chemistry of porous organic cages has developed in the past decade as an alternative to the wellknown nanoporous materials based on extended networks, such as metal organic frameworks (MOFs) or covalent organic frameworks (COFs). Unlike these extended polymeric materials, the molecular nature of organic cages offers important advantages, such as solubility of the material in common organic solvents. However, a simultaneous combination of porosity and additional optoelectronic properties, common in MOFs and COFs, is still quite rare. Therefore, porous organic cages are relatively underdeveloped

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18

Kumar, Mohit, Vijay Kumar Meena, and Suman Singh. "Static and Fatigue Load Bearing Investigation on Porous Structure Titanium Additively Manufactured Anterior Cervical Cages." BioMed Research International 2022 (March 21, 2022): 1–14. http://dx.doi.org/10.1155/2022/6534749.

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This study investigates the static and fatigue behavior of porous and conventional anterior cervical cages. Porous structure titanium anterior cervical cages were manufactured using direct selective laser sintering technique. Four different types of cervical cages were designed and manufactured, among which three designs consist of porous structure (type 1, type 2, and type 3) and manufactured using metal 3D printing. Remaining one design (type 4) was manufactured using conventional machining and did not consist any porous structure. All types of manufactured cages were tested in compression u

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19

Jiang, S., L. Chen, M. E. Briggs, T. Hasell, and A. I. Cooper. "Functional porous composites by blending with solution-processable molecular pores." Chemical Communications 52, no. 42 (2016): 6895–98. http://dx.doi.org/10.1039/c6cc01034b.

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20

Bulut, Aysun, Maria Maares, Kaan Atak, et al. "Mimicking cellular phospholipid bilayer packing creates predictable crystalline molecular metal–organophosphonate macrocycles and cages." CrystEngComm 20, no. 15 (2018): 2152–58. http://dx.doi.org/10.1039/c8ce00072g.

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21

Chen, Shangjun, and Li-Jun Chen. "Metal–Organic Cages: Applications in Organic Reactions." Chemistry 4, no. 2 (2022): 494–519. http://dx.doi.org/10.3390/chemistry4020036.

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Supramolecular metal–organic cages, a class of molecular containers formed via coordination-driven self-assembly, have attracted sustained attention for their applications in catalysis, due to their structural aesthetics and unique properties. Their inherent confined cavity is considered to be analogous to the binding pocket of enzymes, and the facile tunability of building blocks offers a diverse platform for enzyme mimics to promote organic reactions. This minireview covers the recent progress of supramolecular metal–organic coordination cages for boosting organic reactions as reaction vesse

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22

Decker, Gerald E., Gregory R. Lorzing, Meaghan M. Deegan, and Eric D. Bloch. "MOF-mimetic molecules: carboxylate-based supramolecular complexes as molecular metal–organic framework analogues." Journal of Materials Chemistry A 8, no. 8 (2020): 4217–29. http://dx.doi.org/10.1039/c9ta12497g.

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23

Long, Augustin, Sara Lefevre, Laure Guy, et al. "Recognition of the persistent organic pollutant chlordecone by a hemicryptophane cage." New Journal of Chemistry 43, no. 26 (2019): 10222–26. http://dx.doi.org/10.1039/c9nj01674k.

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24

Horii, Yoji, Hal Suzuki, Yuji Miyazaki, et al. "Dynamics and magnetic properties of NO molecules encapsulated in open-cage fullerene derivatives evidenced by low temperature heat capacity." Physical Chemistry Chemical Physics 23, no. 17 (2021): 10251–56. http://dx.doi.org/10.1039/d1cp00482d.

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25

Zhang, Dawei, Tanya K. Ronson, You-Quan Zou, and Jonathan R. Nitschke. "Metal–organic cages for molecular separations." Nature Reviews Chemistry 5, no. 3 (2021): 168–82. http://dx.doi.org/10.1038/s41570-020-00246-1.

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26

Pineda, Eufemio Moreno, Floriana Tuna, Yan-Zhen Zheng, Richard E. P. Winpenny, and Eric J. L. McInnes. "Wells–Dawson Cages as Molecular Refrigerants." Inorganic Chemistry 52, no. 23 (2013): 13702–7. http://dx.doi.org/10.1021/ic402296t.

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27

Hasell, Tom, Marc Schmidtmann, and Andrew I. Cooper. "Molecular Doping of Porous Organic Cages." Journal of the American Chemical Society 133, no. 38 (2011): 14920–23. http://dx.doi.org/10.1021/ja205969q.

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28

Moure, Alejandra, Santiago V. Luis, and Ignacio Alfonso. "Efficient Synthesis of Pseudopeptidic Molecular Cages." Chemistry - A European Journal 18, no. 18 (2012): 5496–500. http://dx.doi.org/10.1002/chem.201104045.

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29

Liu, Chanjuan, Xuebing Zhou, and Deqing Liang. "Molecular insight into carbon dioxide hydrate formation from saline solution." RSC Advances 11, no. 50 (2021): 31583–89. http://dx.doi.org/10.1039/d1ra04015d.

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30

Lee, Haeri, Dongwon Kim, Hyejin Oh, and Ok-Sang Jung. "Molecular balloon, Pd6L8 cages: recognition of alkyl sulfate surfactants." Chemical Communications 56, no. 19 (2020): 2841–44. http://dx.doi.org/10.1039/c9cc09742b.

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Significant structural contraction and expansion of flexible Pd<sub>6</sub>L<sub>8</sub> cages by encapsulation of alkyl sulfate were demonstrated. The contact angles on the fine-ground microcrystal layers shift according to the chain length of the alkyl sulfate.

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31

Wang, Meiling, Yong Zhang, Tianyuan Zhang, et al. "Confinement of single polyoxometalate clusters in molecular-scale cages for improved flexible solid-state supercapacitors." Nanoscale 12, no. 22 (2020): 11887–98. http://dx.doi.org/10.1039/d0nr01070g.

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32

Moeck, Henry A., and Clarence S. Simmons. "PRIMARY ATTRACTION OF MOUNTAIN PINE BEETLE, DENDROCTONUS PONDEROSAE HOPK. (COLEOPTERA: SCOLYTIDAE), TO BOLTS OF LODGEPOLE PINE." Canadian Entomologist 123, no. 2 (1991): 299–304. http://dx.doi.org/10.4039/ent123299-2.

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AbstractThree field tests were conducted in which fresh lodgepole pine (Pinus contorta Douglas var. latifolia Engl.) material, namely bolts with and without bark, bark only, and freshly tapped resin, were placed in beetle-excluding “greenhouse” cages; empty cages served as controls. Two “window” flight traps per cage, at right angles to each other, caught mountain pine beetles (Dendroctonus ponderosae Hopkins) arriving at the cages. Significantly more mountain pine beetles were trapped at cages baited with bolts and wood only than at empty control cages. Primary attraction in the mountain pine

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33

Craig, Gavin A., Patrick Larpent, Hinano Urabe, et al. "Hysteresis in the gas sorption isotherms of metal–organic cages accompanied by subtle changes in molecular packing." Chemical Communications 56, no. 25 (2020): 3689–92. http://dx.doi.org/10.1039/d0cc00932f.

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34

Lynden-Bell, R. M., D. J. C. Hutchinson, and M. J. Doyle. "Translational molecular motion and cages in computer molecular liquids." Molecular Physics 58, no. 2 (1986): 307–15. http://dx.doi.org/10.1080/00268978600101171.

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35

Hu, Yiyang, Haisheng Zhao, Wei Shi, Chunwei Bi, and Xin Li. "Numerical Study on Internal and External Flow Fields of the UHMWPE Cage." Journal of Marine Science and Engineering 11, no. 10 (2023): 1881. http://dx.doi.org/10.3390/jmse11101881.

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Ultra-high molecular weight polyethylene (UHMWPE) is a new kind of fishing gear material applied in deep-sea fishing cages, which is becoming a trend. Studies on the internal and external flow fields of cages made of UHMWPE have been scarce previously. Therefore, a three-dimensional numerical model for the UHMWPE cage is established herein, where the cage is modeled by a porous media model. The Darcy–Forchheimer coefficients of the porous media are obtained by physical model experiments and numerical simulations. Then, the cylindrical cage is divided into 16 planar nets circumferentially, alon

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36

Ng, Chee Koon, Ren Wei Toh, Ting Ting Lin, He-Kuan Luo, T. S. Andy Hor, and Jie Wu. "Metal–salen molecular cages as efficient and recyclable heterogeneous catalysts for cycloaddition of CO2 with epoxides under ambient conditions." Chemical Science 10, no. 5 (2019): 1549–54. http://dx.doi.org/10.1039/c8sc05019h.

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37

Domoto, Yuya, Masahiro Abe, Kidai Yamamoto, Takashi Kikuchi, and Makoto Fujita. "“Eggs in egg cartons”: co-crystallization to embed molecular cages into crystalline lattices." Chemical Science 11, no. 38 (2020): 10457–60. http://dx.doi.org/10.1039/d0sc03191g.

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38

de Souza Suguiura, Igor Massahiro, Rafaela Macagnan, Aline Myuki Omori, et al. "First report of Paracoccidioides brasiliensis infection in fish." Medical Mycology 58, no. 6 (2019): 737–43. http://dx.doi.org/10.1093/mmy/myz120.

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Abstract The thermodimorphic fungus Paracoccidioides brasiliensis is the etiological agent of paracoccidioidomycosis (PCM), a deep mycosis endemic in Latin American countries that affects mainly male rural workers. Infection by P. brasiliensis has also been reported in several species of terrestrial animals; however, the capacity of the fungus to infect aquatic organisms is poorly known. The aim of this study was to detect P. brasiliensis in a fish species, Nile tilapia (Oreochromis niloticus), the most farmed and widely distributed fish in endemic areas for human PCM in Brazil. As a first ste

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39

Itoh, H., B. Chazallon, H. Schober, K. Kawamura, and W. F. Kuhs. "Inelastic neutron scattering and molecular dynamics studies on low-frequency modes of clathrate hydrates." Canadian Journal of Physics 81, no. 1-2 (2003): 493–501. http://dx.doi.org/10.1139/p03-034.

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Low-frequency modes of gas hydrates with Xe, Ar, O2, and N2 atoms/molecules have been studied by inelastic neutron-scattering and molecular dynamics simulations. Type I and type II clathrate hydrates show some small but significant differences of the low-frequency host contribution to the density of states. Both differ markedly from that of ice Ih and depend only weakly on the guest. The vibrational modes associated with Xe atoms were observed at 2.2, 2.9, and 4.0 meV (T = 100 K). They are in good agreement with predictions from molecular dynamics simulations. In the case of N2 hydrate we foun

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40

Baek, Seung Bin, Dohyun Moon, Robert Graf, et al. "High-temperature in situ crystallographic observation of reversible gas sorption in impermeable organic cages." Proceedings of the National Academy of Sciences 112, no. 46 (2015): 14156–61. http://dx.doi.org/10.1073/pnas.1504586112.

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Crystallographic observation of adsorbed gas molecules is a highly difficult task due to their rapid motion. Here, we report the in situ single-crystal and synchrotron powder X-ray observations of reversible CO2 sorption processes in an apparently nonporous organic crystal under varying pressures at high temperatures. The host material is formed by hydrogen bond network between 1,3,5-tris-(4-carboxyphenyl)benzene (H3BTB) and N,N-dimethylformamide (DMF) and by π–π stacking between the H3BTB moieties. The material can be viewed as a well-ordered array of cages, which are tight packed with each o

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41

Poole, David A., Eduard O. Bobylev, Simon Mathew, and Joost N. H. Reek. "Topological prediction of palladium coordination cages." Chemical Science 11, no. 45 (2020): 12350–57. http://dx.doi.org/10.1039/d0sc03992f.

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A molecular mechanics approach enables the accurate prediction of polyhedral topology for homoleptic and heteroleptic palladium M<sub>x</sub>L<sub>2x</sub> coordination cages, allowing for new insight and design when considering endo- and exo-hedral functionalization.

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42

Yeon, Minjeong, Nayeon Kwon, Jaewhoon Jeoung, and Dooil Jeoung. "HDAC9 and miR-512 Regulate CAGE-Promoted Anti-Cancer Drug Resistance and Cellular Proliferation." Current Issues in Molecular Biology 46, no. 6 (2024): 5178–93. http://dx.doi.org/10.3390/cimb46060311.

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Histone deacetylase 9 (HDAC9) is known to be upregulated in various cancers. Cancer-associated antigens (CAGEs) are cancer/testis antigens that play an important role in anti-cancer drug resistance. This study aimed to investigate the relationship between CAGEs and HDAC9 in relation to anti-cancer drug resistance. AGSR cells with an anti-cancer drug-resistant phenotype showed higher levels of CAGEs and HDAC9 than normal AGS cells. CAGEs regulated the expression of HDAC9 in AGS and AGSR cells. CAGEs directly regulated the expression of HDAC9. Rapamycin, an inducer of autophagy, increased HDAC9

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43

Samanta, Dipak, Julius Gemen, Zonglin Chu, Yael Diskin-Posner, Linda J. W. Shimon, and Rafal Klajn. "Reversible photoswitching of encapsulated azobenzenes in water." Proceedings of the National Academy of Sciences 115, no. 38 (2018): 9379–84. http://dx.doi.org/10.1073/pnas.1712787115.

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Efficient molecular switching in confined spaces is critical for the successful development of artificial molecular machines. However, molecular switching events often entail large structural changes and therefore require conformational freedom, which is typically limited under confinement conditions. Here, we investigated the behavior of azobenzene—the key building block of light-controlled molecular machines—in a confined environment that is flexible and can adapt its shape to that of the bound guest. To this end, we encapsulated several structurally diverse azobenzenes within the cavity of

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44

Bai, Hui, Jia Li, Heng Zhang, and Shuya Liu. "Simulative Analysis of a Family of DNA Tetrahedrons Produced by Changing the Twisting Number of Each Double Helix." Journal of Computational Biophysics and Chemistry 20, no. 05 (2021): 529–37. http://dx.doi.org/10.1142/s2737416521500319.

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In this paper, three tetrahedral nanocages, composed of six DNA double helix edges with all having the twist number 1, 2 or 3, have been characterized using classical molecular dynamics simulation to measure the specific structural and conformational features produced by only changing the twisting number of each double helix. The simulation result indicates that three tetrahedral cages are relatively stable and are maintained along the entire trajectory. Each double helix is more inclined to behave as a whole in the 2TD and 3TD cages than in the 1TD cage according to the cross-correlation maps

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45

Reinhardt, V., C. Liss, and C. Stevens. "Space Requirement Stipulations for Caged Non-Human Primates in the United States: A Critical Review." Animal Welfare 5, no. 4 (1996): 361–72. http://dx.doi.org/10.1017/s0962728600019126.

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AbstractCage space requirements for non-human primates in the United States of America are less than those in European countries. Studies in support of the assumption that the US legal minimum cage size provides adequate space have limited value because they only tested cages without structural enhancement. It is not surprising that non-human primates cannot be animated to be more active or to behave in more species-typical manners by only providing them with extra barren space. Explicitly stipulating that all cages have to be equipped with properly installed, elevated structures appropriate t

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46

Yuan, Qi, Filip T. Szczypiński, and Kim E. Jelfs. "Explainable graph neural networks for organic cages." Digital Discovery 1, no. 2 (2022): 127–38. http://dx.doi.org/10.1039/d1dd00039j.

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We report the development of explainable Graph Neural Networks to predict shape persistence of organic cages. Integrated gradient analysis identifies collapse-inducing molecular fragments and helps chemists design more shape persistent structures.

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47

Sherwin, CM, and IAS Olsson. "Housing conditions affect self-administration of anxiolytic by laboratory mice." Animal Welfare 13, no. 1 (2004): 33–38. http://dx.doi.org/10.1017/s0962728600026634.

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AbstractTests of emotionality conducted outside the home-cage show that rodents from standard laboratory housing are more anxious than animals from enriched housing; however, it is not known if this also indicates increased anxiety within the home-cage. We used a novel method, recording the self-administration of a psychoactive anxiolytic, to examine home-cage anxiety levels of laboratory mice (three per cage) in Standard (n = 10 cages), Unpredictable (n = 10 cages) and Enriched (n = 6 cages) housing. The mice were given a choice of drinking either non-drugged water or a solution of the benzod

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48

Omoto, Kenichiro, Nobuhiko Hosono, Mika Gochomori, and Susumu Kitagawa. "Paraffinic metal–organic polyhedrons: solution-processable porous modules exhibiting three-dimensional molecular order." Chemical Communications 54, no. 53 (2018): 7290–93. http://dx.doi.org/10.1039/c8cc03705a.

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Metal–organic polyhedral cages with paraffinic side chains are designed as “porous modules” that self-organize into three-dimensional ordered structures and form into a self-supporting film, affording solution processable porous materials.

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49

Rodenburg, TB, FAM Tuyttens, K. de Reu, L. Herman, J. Zoons, and B. Sonck. "Welfare assessment of laying hens in furnished cages and non-cage systems: an on-farm comparison." Animal Welfare 17, no. 4 (2008): 363–73. http://dx.doi.org/10.1017/s096272860002786x.

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AbstractFrom 2012 onwards, all laying hens in Europe will need to be housed either in furnished cages or non-cage systems (aviaries or floor-housing systems). In terms of animal welfare, furnished cages and non-cage systems both have advantages and disadvantages. Data on direct comparisons between the two, however, are limited. The aim of this study was to carry out an on-farm comparison of laying hens’ welfare in furnished cages and non-cage systems. To meet this aim, six flocks of laying hens in furnished cages and seven flocks in non-cage systems (all without an outdoor run) were visited wh

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Wang, Zhen, Qing-Pu Zhang, Fei Guo, et al. "Self-similar chiral organic molecular cages." Nature Communications 15, no. 1 (2024). http://dx.doi.org/10.1038/s41467-024-44922-y.

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AbstractThe endeavor to enhance utility of organic molecular cages involves the evolution of them into higher-level chiral superstructures with self-similar, presenting a meaningful yet challenging. In this work, 2D tri-bladed propeller-shaped triphenylbenzene serves as building blocks to synthesize a racemic 3D tri-bladed propeller-shaped helical molecular cage. This cage, in turn, acts as a building block for a pair of higher-level 3D tri-bladed chiral helical molecular cages, featuring multilayer sandwich structures and displaying elegant characteristics with self-similarity in discrete sup

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