Academic literature on the topic 'Molecular iodine'

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Journal articles on the topic "Molecular iodine"

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Markova, Ekaterina О., Dmitry A. Nekrasov, Michael Yu Dyakov, and Arkady A. Danilov. "Determination of the content of iodine, iodides and iodates in food products." Izvestiya of Saratov University. Chemistry. Biology. Ecology 22, no. 4 (2022): 373–81. http://dx.doi.org/10.18500/1816-9775-2022-22-4-373-381.

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Currently iodine deficiency diseases are one of the most important medical and social problems. In this regard, the purpose of the study is to determine the content of iodine, iodides, iodates in iodized salt, drinking and mineral water, seaweed, to determine the stability of the iodine content in salt. For the qualitative determination of iodides and iodates ions in salts and molecular iodine in seaweed, an iodine starch reaction has been carried out. The presence of iodide ions in iodized water has been determined by reaction with silver nitrate and chlorine water, the iodine released has be
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Moulay, Saad. "Molecular iodine/polymer complexes." Journal of Polymer Engineering 33, no. 5 (2013): 389–443. http://dx.doi.org/10.1515/polyeng-2012-0122.

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Abstract A unique feature of molecular iodine by far, is its ability to bind to polymeric materials. A plethora of natural and synthetic polymers develop complexes when treated with molecular iodine, or with a mixture of molecular iodine and potassium iodide. Many unexpected findings have been encountered upon complexation of iodine and the polymer skeleton, including the color formation, the polymer morphology changes, the complexation sites or regions, the biological activity, and the electrical conductivity enhancement of the complexes, with polyiodides (In¯), mainly I3¯ and I5¯, as the act
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Chikwana, Edward, Bradley Davis, Moshood K. Morakinyo, and Reuben H. Simoyi. "Oxyhalogen–sulfur chemistry — Kinetics and mechanism of oxidation of methionine by aqueous iodine and acidified iodate." Canadian Journal of Chemistry 87, no. 6 (2009): 689–97. http://dx.doi.org/10.1139/v09-038.

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The oxidation of methionine (Met) by acidic iodate and aqueous iodine was studied. Though the reaction is a simple two-electron oxidation to give methionine sulfoxide (Met–S=O), the dynamics of the reaction are, however, very complex, characterized by clock reaction characteristics and transient formation of iodine. In excess methionine conditions, the stoichiometry of the reaction was deduced to be IO3– + 3Met → I– + 3Met–S=O. In excess iodate, the iodide product reacts with iodate to give a final product of molecular iodine and a 2:5 stoichiometry: 2IO3– + 5Met + 2H+ → I2 + 5Met–S=O + H2O. T
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Yu, Huan, Lili Ren, Xiangpeng Huang, Mingjie Xie, Jun He, and Hang Xiao. "Iodine speciation and size distribution in ambient aerosols at a coastal new particle formation hotspot in China." Atmospheric Chemistry and Physics 19, no. 6 (2019): 4025–39. http://dx.doi.org/10.5194/acp-19-4025-2019.

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Abstract. Intense new particle formation (NPF) events were observed in the coastal atmosphere during algae growth and farming season at Xiangshan gulf of the east China coast. High nucleation-mode iodine concentrations measured by ultra-performance liquid chromatography coupled with quadrupole time-of-flight mass spectrometry (UPLC/Q-TOF-MS) confirmed that the NPF events were induced by iodine species. Our study provides important information on iodine speciation, size distributions, and its role in NPF in the context of heavy air pollution in China's coastal areas. For the first time, we iden
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Glowa, G. A., and J. C. Wren. "Aqueous-gas phase partitioning and hydrolysis of organic iodides." Canadian Journal of Chemistry 81, no. 3 (2003): 230–43. http://dx.doi.org/10.1139/v03-024.

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The volatility and decomposition of organic iodides in a reactor containment building are important parameters to consider when assessing the potential consequences of a nuclear reactor accident. However, there are few experimental data available for the volatilities (often reported as partition coefficients) or few rate constants regarding the decomposition (via hydrolysis) of organic iodides. The partition coefficients and hydrolysis rate constants of eight organic iodides, having a range of molecular structures, have been measured in the current studies. This data, and data accumulated in t
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Gardas, A., and H. Domek. "Iodine induced alteration in immunological and biochemical properties of thyroglobulin." Acta Biochimica Polonica 40, no. 2 (1993): 237–40. http://dx.doi.org/10.18388/abp.1993_4824.

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The influence of iodine-iodide solution on the biochemical and immunological properties of human thyroglobulin (hTg) were studied. Human Tg preincubated with the iodine-iodide solution is split to small molecular mass fragments after disulphide bridge reduction with dithiothreitol. The peptide bond cleavage by iodine pretreatment and reduction is possibly linked with the coupling reaction of diiodotyrosyl residues. Pretreatment of hTg with iodine-iodide solution at 1-10 microM decreased the binding of autoantibodies to hTg. The iodine-iodide induced inactivation of hTg autoepitopes is pH depen
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Ibragim, Umbarov, Khaid Turayev, Nuriddin Uralov, et al. "Investigating the processes and rate of iodide ion and compound oxidation in subterranean hydrothermal waters." BIO Web of Conferences 105 (2024): 05019. http://dx.doi.org/10.1051/bioconf/202410505019.

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Studies using physico-chemical methods have been conducted to evaluate the oxidative characteristics of various reagents for the technological extraction of iodine from groundwater and sufficient data have been obtained. According to the research results, iodine is predominantly present in the form of molecular iodine (85.6%), iodide ions (3.2%), iodate (9.1%) and iodine chloride (2.1%) were detected. Preserving all forms of iodine in solution at the same time is possible only in an alkaline environment, where the oxidizing properties of iodates are sharply reduced. This information is importa
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Lin, Lin, Senlin Tian, Jie Zhao, Dong Wang, Kai Li, and Ping Ning. "Optimized Iodine Recovery from Zinc Suboxide Derived from Steel Dust Using Alkaline Washing and Air Blowing-Out: A Sustainable Industrial Approach." Sustainability 16, no. 24 (2024): 10925. https://doi.org/10.3390/su162410925.

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The present paper proposes an advanced process to effectively recover and fully use iodine from steel dust-derived zinc suboxide, with considerations of effectiveness in the process and industrial viability. It includes, for example, alkali wash for the dissolution of iodine into an alkaline solution from steel dust and uses mechanical vapor recompression (MVR) to concentrate the dissolved iodine by preparing the solution for the air-blowing-out process. The hydrogen iodide is also oxidized under acidic conditions with the addition of hydrogen peroxide to form crude iodine, estimated at about
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Soriano, Ofelia, Guadalupe Delgado, Brenda Anguiano, et al. "Antineoplastic effect of iodine and iodide in dimethylbenz[a]anthracene-induced mammary tumors: association between lactoperoxidase and estrogen-adduct production." Endocrine-Related Cancer 18, no. 4 (2011): 529–39. http://dx.doi.org/10.1530/erc-11-0065.

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Several groups, including ours, have reported that iodine exhibited antiproliferative and apoptotic effects in various cancer cells only if this element is supplemented as molecular iodine, or as iodide, to cells that are able to oxidize it with the enzyme thyroperoxidase. In this study, we analyzed the effect of various concentrations of iodine and/or iodide in the dimethylbenz[a]anthracene (DMBA) mammary cancer model in rats. The results show that 0.1% iodine or iodide increases the expression of peroxisome proliferator-activated receptor type γ (PPARγ), triggering caspase-mediated apoptosis
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Raso, Angela R. W., Kyle D. Custard, Nathaniel W. May, et al. "Active molecular iodine photochemistry in the Arctic." Proceedings of the National Academy of Sciences 114, no. 38 (2017): 10053–58. http://dx.doi.org/10.1073/pnas.1702803114.

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During springtime, the Arctic atmospheric boundary layer undergoes frequent rapid depletions in ozone and gaseous elemental mercury due to reactions with halogen atoms, influencing atmospheric composition and pollutant fate. Although bromine chemistry has been shown to initiate ozone depletion events, and it has long been hypothesized that iodine chemistry may contribute, no previous measurements of molecular iodine (I2) have been reported in the Arctic. Iodine chemistry also contributes to atmospheric new particle formation and therefore cloud properties and radiative forcing. Here we present
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Dissertations / Theses on the topic "Molecular iodine"

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Booth, James L. "On the ortho - para enhancement of molecular iodine by selective laser excitation." Thesis, University of British Columbia, 1985. http://hdl.handle.net/2429/24484.

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Based upon the results reported by Balykin, V. S.r Letokhov, V. S., Mishen, V. I., and Semchishen, V. A., Chem. Phys., 17, 111 (1976), an attempt was made to shift the ortho-iodine to para-iodine ratio by (1) selectively predissociating the ortho-iodine molecules with the 5145 A argon ion laser line and (2) by reacting the selectively excited ortho molecules with the scavengers, 2-hexene, acetylene, nitric oxide, nitrosyl chloride, and ethyl iodide. In both cases the ortho to para ratio was monitored via the fluorescence induced by a scanning dye laser beam. Neither tactic prooved effective, i
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Zhou, Xiang. "Electric field induced predissociation of molecular iodine." Thesis, University of British Columbia, 1991. http://hdl.handle.net/2429/29903.

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Electric field induced predissociation of the B ³∏₀[formula omitted] electronic state of molecular iodine has been investigated. The flourescence spectra of I₂ , corresponding to the upper vibrational quantum mumber v'= 4 to v'= 10 have been recorded with and without a high electric field applied. Because these levels have a large natural predissociation, a specially designed high voltage cell has been built and electric fields up to 140kV/cm have been applied in order to observe the induced predissociation. By combining our results with the previous work by Dalby et al.[10] (from v'= 10 to v
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Döringshoff, Klaus. "Optical frequency references based on hyperfine transitions in molecular iodine." Doctoral thesis, Humboldt-Universität zu Berlin, 2018. http://dx.doi.org/10.18452/19156.

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Diese Arbeit beschäftigt sich mit der Entwicklung und Untersuchung von optischen Absolutfrequenzreferenzen basierend auf rovibronischen Übergängen in molekularen Jod. Dabei werden Methoden der Doppler-freien Sättigungsspektroskopie angewendet, um einzelne Übergänge der Hyperfeinstruktur mit Linienbreiten unterhalb von 1 MHz im B-X System von molekularem Iod bei 532 nm, der zweiten harmonischen des Nd:YAG-Laser, aufzulösen. Elektronische Regelungstechniken ermöglichen eine präzise Stabilisierung der optischen Frequenz auf die Linienmitte der Übergänge mit einer Auflösung von Teilen in 10^5.
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Jewsbury, P. J. "The electronic structure of the ion pair states of molecular iodine." Thesis, University of Edinburgh, 1992. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.653008.

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The electronic configurations of molecular states of iodine are studied through the Optical-Optical Double Resonance excitation of the ion pair states in low vibrational levels. The two photon OODR excitation of <i>ungerade</i> IP states from the <i>gerade</i> ground state is rationalised and the strength of <i>u</i>/<i>g</i> coupling at the intermediate step interpreted in terms of a hyperfine interaction first described by Broyer <i>et al</i>. The potential function of the cl<SUB>g</SUB>(<i>ab</i>) <i>gerade</i> coupling partner in the hyperfine Hamiltonian is derived, along with the lowest
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Lee, Hung Fai. "Molecular iodine chains formed in channels of an AEL zeolite single crystal /." View abstract or full-text, 2007. http://library.ust.hk/cgi/db/thesis.pl?PHYS%202007%20LEEH.

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Kerr, Elinor A. "Kinetic and spectroscopic studies of ion-pair states of iodine monochloride." Thesis, University of Edinburgh, 1989. http://hdl.handle.net/1842/12354.

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Adil-Smith, Iran. "Structural analysis of thyroid hormones by EXAFS and molecular simulation : biological effects of '1'2'5I." Thesis, Brunel University, 1997. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.362488.

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O'Shaughnessy, Simone Mary. "Line-tunable molecular iodine vapour lasers in the spectral range 526-1348 nm." Thesis, Keele University, 1993. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.359864.

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Deir, Christopher Alan. "A study of the interactions of gas phase molecular iodine with stainless steel tubing." Thesis, National Library of Canada = Bibliothèque nationale du Canada, 1995. http://www.collectionscanada.ca/obj/s4/f2/dsk3/ftp04/MQ45441.pdf.

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Kulkarni, Gajanan C. "NEW DESIGN CONCEPTS TOWARDS MOLECULAR BOWLS, HYPERVALENT IODINE BASED MATERIALS, AND ENERGY STORAGE MATERIALS." OpenSIUC, 2019. https://opensiuc.lib.siu.edu/dissertations/1755.

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In this dissertation, new cyclopenta-fused polycyclic aromatic hydrocarbons (CP-PAHs) based on a tetracene core have been developed and shown to be a bridge between the previously reported anthracene and pentacene cores. These tetracene derivatives were prepared by palladium-catalyzed cyclopentannulation between 5,11-dibromotetracene and two diaryl-ethynylene derivatives. The new compounds relatively small band gaps and have low-energy Lowest Unoccupied Molecular Orbitals (LUMOs) and because of their ability to form cyclopentadienyl anion-like structures that are stabilized by Hückel aromatics
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Books on the topic "Molecular iodine"

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Katō, Hajime. Doppler-free high resolution spectral atlas of iodine molecule 15 000 to 19 000 cm⁻¹. Japan Society for the Promotion of Science, 2000.

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Fletcher, D. G. Collisional shift and broadening of iodine spectral lines in air near 543 nm. National Aeronautics and Space Administration, 1995.

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Deir, Christopher Alan. A study of the interactions of gas phase molecular iodine with stainless steel tubing. National Library of Canada, 1995.

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Lukashov, Sergey, Alexander Petrov, and Anatoly Pravilov. The Iodine Molecule. Springer International Publishing, 2018. http://dx.doi.org/10.1007/978-3-319-70072-4.

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1947-, Scherbaum W. A., ed. Autoimmune thyroiditis: Approaches towards its etiological differentiation. Springer-Verlag, 1991.

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United States. National Aeronautics and Space Administration., ed. Design and chemical synthesis of iodine-containing molecules for application to solar-pumped I*: Semiannual progress report. National Aeronautics and Space Administration, 1987.

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International Symposium on Thyroperoxidase and Thyroid Autoimmunity (1990 Marseille, France). Thyroperoxidase and thyroid autoimmunity: Proceedings of the International Symposium on Thyroperoxidase and Thyroid Autoimmunity, held in Marseille (France), June 28-30, 1990 = Thyroperoxydase et autoimmunité thyroïdienne / sponsored by the Institut national de la santé et de la recherche médicale (INSERM). Editions INSERM, 1990.

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Pastalan, John Zachary. Dispersed fluorescence of photodissociated iodine complexes in the supersonic jet. 1988.

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Freysoldt, Tonia, Richard Göttlich, Monica Härtinger, and Stefan Härtinger. Science of Synthesis : Houben-Weyl Methods of Molecular Transformations Vol. 35: Chlorine, Bromine, and Iodine. Thieme Medical Publishers, Incorporated, 2006.

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Lukashov, Sergey, Alexander Petrov, and Anatoly Pravilov. The Iodine Molecule: Insights into Intra- and Intermolecular Perturbation in Diatomic Molecules. Springer, 2019.

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Book chapters on the topic "Molecular iodine"

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Zhao, Shengnan, Yinhui Ren, and Cunxu Wei. "Staining Starch with Iodine Solution." In Methods in Molecular Biology. Springer US, 2022. http://dx.doi.org/10.1007/978-1-0716-2675-7_23.

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Gartler, Stanley M., R. Scott Hansen, Vinzenz Oji, et al. "Iodine Deficiency and Excess." In Encyclopedia of Molecular Mechanisms of Disease. Springer Berlin Heidelberg, 2009. http://dx.doi.org/10.1007/978-3-540-29676-8_971.

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Gartler, Stanley M., R. Scott Hansen, Vinzenz Oji, et al. "Iodine-related Disease States." In Encyclopedia of Molecular Mechanisms of Disease. Springer Berlin Heidelberg, 2009. http://dx.doi.org/10.1007/978-3-540-29676-8_972.

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Chan, Wendy W. L., and Dora L. W. Kwong. "Radioactive Iodine for Papillary Thyroid Carcinoma." In Methods in Molecular Biology. Springer US, 2022. http://dx.doi.org/10.1007/978-1-0716-2505-7_16.

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Vallabhajosula, Shankar. "Radiohalogens for Molecular Imaging (Fluorine and Iodine)." In Molecular Imaging and Targeted Therapy. Springer International Publishing, 2023. http://dx.doi.org/10.1007/978-3-031-23205-3_10.

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Christen, Dines. "Molecular constants of IO X 2Πi iodine oxide." In Landolt-Börnstein - Group II Molecules and Radicals. Springer Berlin Heidelberg, 2021. http://dx.doi.org/10.1007/978-3-662-62327-5_129.

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Yuldasheva, Gulnara A., Georgii M. Zhidomirov, Jerzy Leszczynski, and Aleksandr I. Ilin. "Iodine Containing Drugs: Complexes of Molecular Iodine and Tri-iodide with Bioorganic Ligands and Lithium Halogenides in Aqueous Solutions." In Practical Aspects of Computational Chemistry IV. Springer US, 2016. http://dx.doi.org/10.1007/978-1-4899-7699-4_10.

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Zadoyan, R., M. Sterling, and V. A. Apkarian. "Femtosecond Dynamics of Molecular Iodine in Rare Gas Solids." In Ultrafast Processes in Spectroscopy. Springer US, 1996. http://dx.doi.org/10.1007/978-1-4615-5897-2_30.

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Albano, Domenico, Francesco Dondi, Pietro Bellini, and Francesco Bertagna. "Biomarkers and Molecular Imaging in Postoperative DTC Management." In Integrated Diagnostics and Theranostics of Thyroid Diseases. Springer International Publishing, 2023. http://dx.doi.org/10.1007/978-3-031-35213-3_8.

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AbstractThe standard of care for differentiated thyroid carcinoma (DTC) includes surgery, risk-adapted postoperative radioiodine [iodine-131 (131I)] therapy, individualized thyroid hormone therapy, and follow-up for detection of patients with recurrent or persistent disease.Recently, several international associations like ATA, EANM, and SNMMI developed specific guidelines for the management of these patients. They shared that an individualized risk-adapted approach should be suggested considering the main clinical, epidemiological, and histopathological features. The postoperative management
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Constant, E., H. Stapelfeldt, and P. B. Corkum. "Enhanced Ionization of Molecular Ions in Intense Laser Fields: Experiments on the Iodine Melecule." In Springer Series in Chemical Physics. Springer Berlin Heidelberg, 1996. http://dx.doi.org/10.1007/978-3-642-80314-7_43.

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Conference papers on the topic "Molecular iodine"

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Roslund, J., A. Cingoz, A. Kowligy, et al. "Molecular Iodine Optical Atomic Clocks." In CLEO: Applications and Technology. Optica Publishing Group, 2024. http://dx.doi.org/10.1364/cleo_at.2024.jw3l.8.

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Vector Atomic has developed optical clocks using iodine vapor cells. These clocks provide excellent short-term instability, require neither laser cooling nor cavity pre-stabilization, are insensitive to motion, and maintain holdovers of &lt;1ns for several days.
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Zhang, Zhenqi, Wen You, Xingyue Liu, et al. "High-Performance Molecular Iodine-Stabilized Laser." In 2024 European Frequency and Time Forum (EFTF). IEEE, 2024. http://dx.doi.org/10.1109/eftf61992.2024.10722285.

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Farina, S. B., G. S. Duffo, and J. R. Galvele. "Stress Corrosion Cracking of Zirconium and Zircaloy-4 in Iodine Containing Solutions." In CORROSION 2002. NACE International, 2002. https://doi.org/10.5006/c2002-02436.

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Abstract The stress corrosion cracking (SCC) susceptibility of zirconium (UNS R60702) and one of its alloys, Zircaloy-4 (UNS R60804), was studied in 10 g/L iodine dissolved in various alcohols: methanol, ethanol, 1-propanol, 1-butanol, 1-pentanol and 1-octanol. SCC was observed in all the systems studied and the crack propagation rate was found to vary depending on the size of the solvent molecule. As the solvent molecular weight increased, the crack propagation rate decreased. Preceding crack propagation, intergranular attack was found in all the solutions tested. The intergranular corrosion
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Nomura, Junia, Daisuke Akamatsu, and Feng-Lei Hong. "Hybrid frequency locking of a coin-sized laser module using both linewidth narrowing and Doppler-free spectroscopy." In CLEO: Science and Innovations. Optica Publishing Group, 2024. http://dx.doi.org/10.1364/cleo_si.2024.sm2g.6.

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We demonstrate a hybrid frequency locking method for a broad-linewidth coin-sized laser module based on linewidth reduction using a short-path imbalance fiber interferometer and Doppler-free spectroscopy of molecular iodine.
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Wang, Sheng, Zaiyang Yu, Guohua Li, et al. "Study on iodine molecular isotope identification based on absorption spectrum and laser-induced fluorescence spectroscopy." In Sixth International Symposium on Laser Interaction with Matter (LIMIS 2022), edited by Jin Guo, Pengling Yang, Yihua Hu, and Cangtao Zhou. SPIE, 2025. https://doi.org/10.1117/12.3059244.

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Ceolato, Romain, Manuela Hoyos, and Yoshitaka Jin. "Short-Range High-Spectral-Resolution Lidar Using a Low Energy Diode-Based Laser." In Applications of Lasers for Sensing and Free Space Communications. Optica Publishing Group, 2024. https://doi.org/10.1364/lsc.2024.lsm1c.4.

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A novel Short-Range High Spectral Resolution Lidar (SR-HSRL) instrument is presented using a non-injection seeded diode-based laser emitting low energy pulses at a high repetition rate and an iodine cell for spectral filtering. This instrument is used as a proof-of-concept to measure separately the aerosol Mie and molecular Rayleigh backscatter signals in the low Planetary Boundary Layer (PBL) using a bi-static bi-axial configuration. Full-text article not available; see video presentation
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Maia, Thalita Vaneska Moreira, Denilma Maurício Cardoso da Silva, Andréa Claudia Oliveira Silva, and Régis Casimiro Leal. "Theoretical study of the reaction mechanism of triiodide ion (I3–) from iodine (I2) and iodide anion (I–)." In VIII Simpósio de Estrutura Eletrônica e Dinâmica Molecular. Universidade de Brasília, 2020. http://dx.doi.org/10.21826/viiiseedmol2020155.

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This work studies the reaction mechanism of triiodide ion (I3–) from iodine (I2) and iodide anion (I–), furthermore it investigates the thermodynamic preference of formation of I3– in three different solvents. Through DFT calculations and using the continuous polarizable model (PCM) it was possible to determine the reaction mechanism, as well as to show that the formation of the triiodide ion, from iodine and iodide, is favored in solvents of less polarity.
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Arie, Ady, and Robert L. Byer. "Doppler-Free Spectroscopy of Molecular Iodine Near 532 nm." In High Resolution Spectroscopy. Optica Publishing Group, 1993. http://dx.doi.org/10.1364/hrs.1993.tub2.

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Molecular Iodine exhibits a very rich absorption spectrum1 near 532 nm. Frequency-doubled monolithic diode laser pumped Nd:YAG lasers, having narrow linewidths and relatively wide tuning range, provide an excellent tool to investigate these transitions. Furthermore, we have recently shown that the Nd:YAG laser frequency can be absolutely stabilized to the Doppler-free lines of Iodine2. In this paper we utilize the ability to lock two lasers to Iodine hyperfine transitions in order to measure precisely the hyperfine frequency splitting by heterodyne spectroscopy. These results are then used to
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Masuda, Taizo, Tomonari Nakamura, and Masamori Endo. "An all gas-phase iodine laser using molecular iodine as atomic iodine donor." In 18th International Symposium on Gas Flow & Chemical Lasers & High Power Lasers, edited by Tanja Dreischuh, Petar A. Atanasov, and Nikola V. Sabotinov. SPIE, 2010. http://dx.doi.org/10.1117/12.880233.

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Privalov, Vadim E., and Sergey K. Savelyev. "Atlas of molecular iodine absorption lines." In International Workshop on Nondestructive Testing and Computer Simulations in Science and Engineering, edited by Alexander I. Melker. SPIE, 1999. http://dx.doi.org/10.1117/12.347392.

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Reports on the topic "Molecular iodine"

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Sansonetti, C. J. Molecular iodine absolute frequencies. Final report. Office of Scientific and Technical Information (OSTI), 1990. http://dx.doi.org/10.2172/371207.

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Sansonetti, C. J. Precise measurements of hyperfine components in the spectrum of molecular iodine. Office of Scientific and Technical Information (OSTI), 1996. http://dx.doi.org/10.2172/464573.

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