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Dissertations / Theses on the topic 'Molecular sieves and catalysts'

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1

Axon, Sean Alexander. "MFI-type zeolites synthesized in non-alkaline media." Thesis, University of Cambridge, 1991. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.240100.

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2

Yiu, Humphrey Hak Ping. "The application of MCM-41 type mesoporous molecular sieves as heterogeneous acid catalysts and catalyst supports." Thesis, University of Huddersfield, 1998. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.285629.

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Two types of mesoporous molecular sieves, MCM-41 and MMS, were prepared, fully characterised and tested as solid acid catalysts and catalyst support materials. Three different methods for characterising the surface acidity of these solid acids were examined and compared. These methods were 1. Fourier Transform infrared (FTIR) spectroscopy of adsorbed pyridine, 2. Pulsed ammonia adsorption using a combination of thermogravimetry and differential scanning calorimetry (TG/DSC), and 3. Temperature-programmed desorption of amines. The acidity results of these molecular sieves were compared with zeo
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3

O'Connor, James Francis. "The removal of lead pollutants from effluents using zeolites." Thesis, City University London, 1989. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.304673.

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4

Öhrman, Olov. "Molecular sieve film catalysts." Licentiate thesis, Luleå, 2003. http://urn.kb.se/resolve?urn=urn:nbn:se:ltu:diva-26344.

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In this study, well defined ZSM-5 films were prepared on monoliths, ceramic foams, alumina beads, glass beads and crushed quartz glass by further refinement of a method originally developed at the division of Chemical Technology, Luleå University of Technology. The supports were seeded with silicalite-1 seeds and hydrothermally treated, either at 75 °C or at 150 °C in a single or several steps. By adding sodium to the solution the aluminum concentration increased in the zeolite, which is beneficial for catalytic activity. Consequently, films with different Si/Al ratios could be prepared. The f
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5

SILVA, JAQUELINE FARIAS DA. "CATALYSTS SUPPORTED IN MICRO AND MESOPOROUS MOLECULAR SIEVES FOR THE FISCHER- TROPSCH SYNTHESIS." PONTIFÍCIA UNIVERSIDADE CATÓLICA DO RIO DE JANEIRO, 2004. http://www.maxwell.vrac.puc-rio.br/Busca_etds.php?strSecao=resultado&nrSeq=6221@1.

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CONSELHO NACIONAL DE DESENVOLVIMENTO CIENTÍFICO E TECNOLÓGICO<br>A síntese de Fischer-Tropsch converte o gás de síntese (H2 + CO), em uma variedade complexa de hidrocarbonetos na presença de um catalisador (principalmente Co/Al2O3). Neste trabalho foram estudados catalisadores de Co e o Fe (1 e 5% em massa), incorporados aos suportes: zeólitas KL, HL 0,1M e HL 1,0 M, além da peneira molecular mesoporosa MCM- 41, pelo método de impregnação úmida incipiente, para a reação de Fischer- Tropsch. As amostras preparadas foram analisadas pelas técnicas de: Espectometria de Emissão Atômica de Pla
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6

Bruce, David Alan. "Synthesis and characterization of heterogeneous metal oxide catalysts on amorphous and molecular sieve supports." Diss., Georgia Institute of Technology, 1994. http://hdl.handle.net/1853/30409.

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7

Sun, Jian. "Mesoporous molecular sieves, from catalysis to solid phase synthesis." Thesis, National Library of Canada = Bibliothèque nationale du Canada, 2000. http://www.collectionscanada.ca/obj/s4/f2/dsk1/tape3/PQDD_0024/MQ62158.pdf.

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8

Wight, Andrea P. Davis Mark E. "I. Synthesis, characterization, and base catalysis of organic-functionalized molecular sieves. : II. Selective oxidation of ethane via heteropolyanion-containing solid catalysts /." Diss., Pasadena, Calif. : California Institute of Technology, 2004. http://resolver.caltech.edu/CaltechETD:etd-05252004-102344.

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9

鄭嘉慧 and Kar-wai Anita Cheng. "Preparation, reactivities and oxidative catalytic activities of ruthenium(II) polypyridines, rhenium(I) carbonyl complexes andruthenium-encapsulated meso- and micro-porous molecular sieves." Thesis, The University of Hong Kong (Pokfulam, Hong Kong), 1998. http://hub.hku.hk/bib/B31236662.

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10

Cheng, Kar-wai Anita. "Preparation, reactivities and oxidative catalytic activities of ruthenium(II) polypyridines, rhenium(I) carbonyl complexes and ruthenium-encapsulated meso- and micro-porous molecular sieves /." Hong Kong : University of Hong Kong, 1998. http://sunzi.lib.hku.hk/hkuto/record.jsp?B1973816X.

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11

Pearce, Gordon Michael. "Synthesis, adsorption and catalysis of large pore metal phosphonates /." St Andrews, 2009. http://hdl.handle.net/10023/823.

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12

Kirton, Eirene. "Inorganic-organic hybrids : Novel molecular sieves with potential application in asymmetric catalysis." Thesis, University of St Andrews, 2002. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.503204.

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13

Pillinger, Martyn. "EXAFS studies of polyoxometalates and polyoxometalate-pillared layered double hydroxides." Thesis, University of Southampton, 1994. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.240624.

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14

Fabiano, Demian Patrick. "Síntese e avaliação de sílica tipo M41S contendo cátions CTA em transesterificação catalítica." Universidade Federal de São Carlos, 2010. https://repositorio.ufscar.br/handle/ufscar/3887.

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Made available in DSpace on 2016-06-02T19:55:27Z (GMT). No. of bitstreams: 1 3154.pdf: 5552497 bytes, checksum: 0a1853852321cef9c6280241685ff21d (MD5) Previous issue date: 2010-08-13<br>Universidade Federal de Sao Carlos<br>The investments in the biofuel production have increased a lot in the last years mainly because of smaller damages they cause to the environment in comparison with the derived conventional petroleum fuels. The reaction of biodiesel formation is denominated transesterification and, nowadays that reaction happens in the presence of homogeneous catalyst as the sodium methoxi
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15

Michel, Typhène [Verfasser], Fritz Elmar [Akademischer Betreuer] Kühn, and Volker [Akademischer Betreuer] Sieber. "Epoxidation of Terpenes with Molecular Catalysts in Homogeneous Phase / Typhène Michel. Gutachter: Volker Sieber ; Fritz Elmar Kühn. Betreuer: Fritz Elmar Kühn." München : Universitätsbibliothek der TU München, 2012. http://d-nb.info/1031513361/34.

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16

Nguyen, Khanh Dieu Hong. "Framework redox sites in nanoporous molecular sieve catalyst." Thesis, University College London (University of London), 2008. http://discovery.ucl.ac.uk/17226/.

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The work described in this thesis is concerned with the characterisation of metal ions substituted nanoporous materials. The first chapter deals with the introduction to nanoporous materials, with historical background, structural chemistry, synthetic methods and catalytic applications. The second chapter describe the experimental techniques used in this work. Chapter 3 deals with the study of cobalt ions substituted nanoporous aluminophosphate material. Here the main aim is to understand the effect of synthesis condition used in preparing CoA1PO-34, CoSAPO-34 materials on the particle size, m
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17

Yoshikawa, Masahito. "Studies on Syntheses of Molecular Sieves Aimed at Extra-Large-Pore Molecular Sieves." Kyoto University, 1999. http://hdl.handle.net/2433/181340.

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18

La, Salvia Nathália 1985. "Síntese e caracterização de MCM-41 impregnada com magnésio e cromo e suas propriedades catalíticas para reações de conversão de etanol." [s.n.], 2014. http://repositorio.unicamp.br/jspui/handle/REPOSIP/266085.

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Orientador: Gustavo Paim Valença<br>Tese (doutorado) - Universidade Estadual de Campinas, Faculdade de Engenharia Química<br>Made available in DSpace on 2018-08-24T23:01:25Z (GMT). No. of bitstreams: 1 LaSalvia_Nathalia_D.pdf: 7860896 bytes, checksum: 356f0e957d83d2daaba9cb36b26a4056 (MD5) Previous issue date: 2014<br>Resumo: Peneiras moleculares do tipo MCM-41 foram sintetizadas com e sem alumínio estrutural e impregnadas com 5% de magnésio e 5 e 10% de cromo. As amostras foram então calcinadas e caracterizadas, e utilizadas na conversão catalítica de etanol. Esses materiais foram caracteri
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19

Nair, Vinayan. "Characterization of ferrisilicate molecular sieves." Diss., Georgia Institute of Technology, 1987. http://hdl.handle.net/1853/32765.

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20

Tearle, Kathryn Mary. "Modification of aluminophosphate molecular sieves." Thesis, University of Southampton, 1995. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.295923.

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21

Hampson, Brian. "Characterisation of new molecular sieves." Thesis, University of Edinburgh, 1991. http://hdl.handle.net/1842/14976.

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A general introduction to zeolites and aluminophosphate based molecular sieves is followed by a more detailed review of EU-1 and AlPOj-S, the two molecular sieves studied in this work. The synthesis and characterisation of these molecular sieves is described. The characterisation techniques gave details of the framework structure and composition, surface area, and morphology. A time study of the crystallisation of AlPO4-5 from an aluminophosphate gel containing two organic templates showed the formation of a hydrate phase before the AlPO4-5 phase, the change in pH during hydrothermal crystalli
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22

EDUARDO, Raphael da Silva. "Avaliação dos catalisadores Fe/Cu/K/SBA-15TEOS e Fe/Cu/K/SBA-15CCA na síntese de Fischer-Tropsch." Universidade Federal de Campina Grande, 2014. http://dspace.sti.ufcg.edu.br:8080/jspui/handle/riufcg/528.

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Submitted by Johnny Rodrigues (johnnyrodrigues@ufcg.edu.br) on 2018-04-30T16:52:44Z No. of bitstreams: 1 RAPHAEL DA SILVA EDUARDO - DISSERTAÇÃO PPGEQ 2014..pdf: 2452018 bytes, checksum: 88b5f90f5371eb8c9bb004e2e69c6bd8 (MD5)<br>Made available in DSpace on 2018-04-30T16:52:44Z (GMT). No. of bitstreams: 1 RAPHAEL DA SILVA EDUARDO - DISSERTAÇÃO PPGEQ 2014..pdf: 2452018 bytes, checksum: 88b5f90f5371eb8c9bb004e2e69c6bd8 (MD5) Previous issue date: 2014<br>Capes<br>A síntese de Fischer-Tropsch, reação de polimerização de gás de síntese na presença de um catalisador, se apresenta como uma oport
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23

Brinen, Jeffrey Lawrence. "Characterization of modified aluminophosphate molecular sieves." Diss., Georgia Institute of Technology, 1989. http://hdl.handle.net/1853/11813.

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24

Möller, Andreas, Joachim Guderian, Marcus Lange, and Jens Möllmer. "Carbon Molecular Sieves – a kinetic study." Universitätsbibliothek Leipzig, 2015. http://nbn-resolving.de/urn:nbn:de:bsz:15-qucosa-183868.

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25

Chagger, Harnit Kaur. "Carbon molecular sieves for air separation." Thesis, University of Newcastle Upon Tyne, 1994. http://hdl.handle.net/10443/851.

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Carbon is one of the naturally occurring elements and has an atomic weight 12.01 atomic mass units (amu) and atomic number 6. It has six electrons and has an electronic configuration of: ls2 2S2 1p2 in the ground state. This element exists in different crystalline forms-diamond, graphite, buckminsterfullerene1 and carbyne2. Carbon also has the ability of catenation via formation of σ and π bonds.
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26

Heslop, Mark J. "Binary gas adsorption in molecular sieves." Thesis, Loughborough University, 1993. https://dspace.lboro.ac.uk/2134/6861.

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This thesis is concerned with the development of sorption-effect chromatography as a rapid method for the determination of binary gas-mixture adsorption isotherms.There are many alternative non-chromatographic methods but these have inherent disadvantages the direct experimental methods require excessive equilibration times and the predictive methods require the respective pure-component isotherms and an ideal adsorbed phase. A computer simulation has shown that for an alternative chromatographic method, good results will only be obtained if both binary isotherms are close to linear. Sorption-
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27

Sinclair, D. M. "Crystallization of high silica molecular sieves." Thesis, University of Edinburgh, 1986. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.384262.

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28

He, Heyong. "Structural studies of novel molecular sieves." Thesis, University of Cambridge, 1993. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.309870.

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29

Möller, Andreas, Joachim Guderian, Marcus Lange, and Jens Möllmer. "Carbon Molecular Sieves – a kinetic study." Diffusion fundamentals 20 (2013) 97, S. 1, 2013. https://ul.qucosa.de/id/qucosa%3A12634.

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30

Torres, Melissa Christine. "Copper adsorption on functionalized molecular sieves." Thesis, University of Iowa, 2011. https://ir.uiowa.edu/etd/1096.

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31

Simmons, Donald Karl. "Acid catalytic properties of metallosilicate molecular sieves." Thesis, Georgia Institute of Technology, 1986. http://hdl.handle.net/1853/10151.

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32

Biz, Sophie. "Synthesis and characterization of mesostructured molecular sieves." Diss., Georgia Institute of Technology, 1998. http://hdl.handle.net/1853/17920.

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33

Naydenov, Valeri. "Structured molecular sieves : synthesis, modification and characterization /." Luleå, 2003. http://epubl.luth.se/1402-1544/2003/39.

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34

Klimczyk, Malgorzata. "Separation of hexane isomers using molecular sieves." Thesis, De Montfort University, 1994. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.697435.

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35

Vaughan, James Stuart. "Synthesis, characterization and high pressure propene oligomerization over heteropoly acids, SAPO-11 molecular sieves and MeAPSO-11 molecular sieves." Doctoral thesis, University of Cape Town, 1993. http://hdl.handle.net/11427/21991.

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Bibliography: pages 219-232.<br>Heteropoly acids, HPAs, and SAPO-11 and MeAPSO-11 molecular sieves have been proposed to be active for the oligomerization of propene to high quality distillate fuels. In this study these catalysts have been synthesized, characterized, modified and screened for the oligomerization of propene to distillate fuels. Heteropoly acids consist of high molecular weight poly-oxoanions, counter cations and water of hydration and are strongly acidic. The following salts of 12-tungstophosphoric acid, a 12-type HPA with the Keggin anion structure, were synthesized: AI, Fe, C
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36

Khan, Tasneem Anwar. "Syntheses of molecular sieves and inorganic porphyrinic solids." Thesis, University of Birmingham, 2001. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.369393.

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37

Sinclair, Phillip Edward. "Computational studies of organic transformations in molecular sieves." Thesis, University College London (University of London), 1998. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.301298.

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38

Cheng, Chi-Feng. "Solid-state NMR studies of mesoporous molecular sieves." Thesis, University of Cambridge, 1995. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.243004.

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39

Barrie, Patrick J. "Synthesis and characterization of aluminophosphate-based molecular sieves." Thesis, University of Cambridge, 1991. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.335103.

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40

Fletcher-Wood, Rowena. "Zeolites and other molecular sieves for chromate remediation." Thesis, University of Birmingham, 2015. http://etheses.bham.ac.uk//id/eprint/5789/.

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Porous solids loaded with redox-active ions were examined for the selective uptake and simultaneous reduction of Cr(VI) from aqueous solution. XRF spectroscopy was used to determine the extent of chromium uptake by molecular sieves: 29.1 mg\(_C\)\(_r\)/g\(_s\)\(_i\)\(_e\)\(_v\)\(_e\) for Mn-loaded AIPO-5. Some systems were templated: TEM confirmed the introduction of mesopores. Mössbauer and EPR spectroscopies characterised oxidation states and site symmetries of metal ions. Fe(II)-loaded molecular sieves were found to be appreciably oxidised (~ 80 %). To increase the fraction of redox-active
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41

Triebe, Robert W. "Separation and purification of gases with molecular sieves." Thesis, University of Ottawa (Canada), 1994. http://hdl.handle.net/10393/9657.

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Equilibrium adsorption constants were determined for CO, CO$\sb2$, NO, N$\sb2$, CH$\sb4$, C$\sb2$H$\sb4$, and C$\sb2$H$\sb6$ on various molecular sieves between 233 and 523 K. The molecular sieves tested for adsorption of these gases were 4A and 5A zeolite, 13X and a CaX zeolite, H-mordenite, a natural clinoptilolite and a carbon molecular sieve. The gas chromatographic method was used for all equilibrium measurements. Upon choosing the promising CO/N$\sb2$/clinoptilolite system for further studies, kinetic (diffusion) characteristics of each of these pure gases in the clinoptilolite ports was
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42

Franklin, Keith Campbell. "The synthesis of aluminophosphate and silica molecular sieves." Thesis, University of Edinburgh, 1993. http://hdl.handle.net/1842/13845.

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The work described in this thesis is concerned with the synthesis of aluminophosphate and silica molecular sieves, in particular, the search for novel large pore materials. Reactions were studied systematically under a range of conditions and, to assist in this, a new type of reaction vessel was designed and fabricated. In the aluminophosphate system, a novel synthetic method using a water soluble aluminium phosphate hydrochloride ethanolate precursor is described. This provides a new synthesis route to the ultra-wide pore aluminophosphate molecular sieve VPI-5, without the use of quaternary a
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43

Annen, Michael J. "Synthesis and characterization of novel molecular sieves containing three-membered rings." Diss., This resource online, 1992. http://scholar.lib.vt.edu/theses/available/etd-07282008-134605/.

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44

Patel, Urmila. "Ti-containing mesoporous molecular sieves and selective oxidation reactions." Thesis, University of Liverpool, 2003. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.288130.

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45

Browning, Jonathan Darren. "Synthesis of discrete models for aluminophosphate-type molecular sieves." Thesis, University of Southampton, 1997. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.241907.

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46

Khouw, Charles B. Davis Mark E. Davis Mark E. "Partial oxidation of hydrocarbons using titanium containing molecular sieves /." Diss., Pasadena, Calif. : California Institute of Technology, 1995. http://resolver.caltech.edu/CaltechETD:etd-10122007-103304.

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47

Rose, Jamey. "Hydroxylation of 2-methylnaphthalene to 2-methylnaphthoquinone over TI-substituted catalysis." Thesis, Stellenbosch : University of Stellenbosch, 2010. http://hdl.handle.net/10019.1/5192.

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Thesis (MScEng (Process Engineering))--University of Stellenbosch, 2010.<br>ENGLISH ABSTRACT: Partially oxygenated aromatic compounds, e.g. quinones, hydroquinones and cresols, play a vital role in the fine chemical industry and were initially prepared by stoichiometric oxidation processes that produce toxic products that are hazardous towards the environment. As a result, it was important to investigate environmentally friendly processes for the hydroxylation of aromatic compounds. This resulted in newer methods using Ti-substituted microporous zeolites as catalysts with hydrogen peroxid
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48

Thomas, Susan Murphree. "The synthesis and characterization of novel, inorganically pillared molecular sieves." Diss., Georgia Institute of Technology, 1997. http://hdl.handle.net/1853/30891.

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49

Ylihautala, Mika. "NMR of small solutes in liquid crystals and molecular sieves /." Oulu : Oulun Yliopisto, 1999. http://www.gbv.de/dms/goettingen/304055468.pdf.

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50

Fegan, S. G. "Hydrophilic and organophilic properties of zeolites and silica molecular sieves." Thesis, University of Edinburgh, 1985. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.354124.

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