Academic literature on the topic 'Monosulfide solid solution, metal sulfides'

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Journal articles on the topic "Monosulfide solid solution, metal sulfides"

1

Sinyakova, Elena, Victor Kosyakov, Galina Palyanova, and Nikolay Karmanov. "Experimental Modeling of Noble and Chalcophile Elements Fractionation during Solidification of Cu-Fe-Ni-S Melt." Minerals 9, no. 9 (2019): 531. http://dx.doi.org/10.3390/min9090531.

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We carried out a directed crystallization of a melt of the following composition (in mol. %): Fe 31.79, Cu 15.94, Ni 1.70, S 50.20, Sn 0.05, As 0.04, Pt, Pd, Rh, Ru, Ag, Au, Se, Te, Bi, and Sb by 0.03. The obtained cylindrical sample consisted of monosulfide solid solution (mss), nonstoichometric isocubanite (icb*), and three modifications of intermediate solid solution (iss1, iss2, iss3) crystallized from the melt. The simultaneous formation of two types of liquids separated during cooling of the parent sulfide melt was revealed. In the first, concentrations of noble metals associated with Bi
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2

Georgatou, Ariadni A., and Massimo Chiaradia. "Magmatic sulfides in high-potassium calc-alkaline to shoshonitic and alkaline rocks." Solid Earth 11, no. 1 (2020): 1–21. http://dx.doi.org/10.5194/se-11-1-2020.

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Abstract. We investigate the occurrence and chemistry of magmatic sulfides and their chalcophile metal cargo behaviour during the evolution of compositionally different magmas from diverse geodynamic settings both in mineralised and barren systems. The investigated areas are the following: (a) the Miocene Konya magmatic province (hosting the Doğanbey Cu–Mo porphyry and Inlice Au epithermal deposits, representing post-subduction) and (b) the Miocene Usak basin (Elmadag, Itecektepe, and Beydagi volcanoes, the latter associated with the Kişladağ Au porphyry in western Turkey, representing post-su
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3

Akizawa, Norikatsu, Tetsu Kogiso, Akira Miyake, Akira Tsuchiyama, Yohei Igami, and Masayuki Uesugi. "Formation process of sub-micrometer-sized metasomatic platinum-group element-bearing sulfides in a Tahitian harzburgite xenolith." Canadian Mineralogist 58, no. 1 (2020): 99–114. http://dx.doi.org/10.3749/canmin.1800082.

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ABSTRACT Base-metal sulfides (BMSs) are minerals that host platinum-group elements (PGE) in mantle peridotites and significantly control the bulk PGE content. They have been investigated in detail down to the sub-micrometer scale to elucidate PGE behavior in the Earth's interior. Base-metal sulfides are supposedly subjected to supergene and seawater weathering, leading to the redistribution of PGEs at low temperatures. Careful and thorough measurements of BMSs are thus required to elucidate PGE behavior in the Earth's interior. In the present study, a sub-micrometer-sized PGE-bearing sulfide i
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4

Andreev, O. V., V. V. Ivanov, A. V. Gorshkov, P. V. Miodushevskiy, and P. O. Andreev. "Chemistry and Technology of Samarium Monosulfide." Eurasian Chemico-Technological Journal 18, no. 1 (2016): 55. http://dx.doi.org/10.18321/ectj396.

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<p class="Pa10">Samarium monosulfide SmS (Fm3m, а = 5.967 Å, ΔЕ = 0.23 V, n = 10<sup>20</sup> cm<sup>–1</sup>, <em>σ</em><em> </em>= 500 Ω<sup>–1</sup> cm<sup>–1</sup>, <em>α</em><em> </em>= 350 μВ/K) is a thermoelectric material (Z>1) and, at the same time, a pressure-sensitive material (K≥40–50). Samarium monosulfide is a daltonide phase with a solid solution whose extent is mostly in the range of cationic vacancies: Sm<sub>1+x </sub>S<sub>1-x</sub>□<sub>
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5

Barnes, Sarah-Jane, E. Makovicky, M. Makovicky, J. Rose-Hansen, and S. Karup-Moller. "Partition coefficients for Ni, Cu, Pd, Pt, Rh, and Ir between monosulfide solid solution and sulfide liquid and the formation of compositionally zoned Ni – Cu sulfide bodies by fractional crystallization of sulfide liquid." Canadian Journal of Earth Sciences 34, no. 4 (1997): 366–74. http://dx.doi.org/10.1139/e17-032.

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Many nickel–copper sulfide orebodies contain Cu- and Fe-rich portions. The Fe-rich ore is generally richer in Os, Ir, Ru, and Rh and poorer in Pt, Pd, and Au than the Cu-rich ore. In komatiite-hosted ores Ni tends to be concentrated in the Cu-rich ore, whereas in tholeiitic ores it tends to be concentrated in the Fe-rich ore. The origin of this zonation could be due to crystal fractionation of Fe-rich monosulfide solid solution from a sulfide liquid. The crystal fractionation would produce an Fe-rich cumulate enriched in Os, Ir, Ru, and Rh and a fractionated liquid enriched in Cu, Pt, Pd, and
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6

Helmy, Hassan M., and Roman Botcharnikov. "Experimental determination of the phase relations of Pt and Pd antimonides and bismuthinides in the Fe-Ni-Cu sulfide systems between 1100 and 700 °C." American Mineralogist 105, no. 3 (2020): 344–52. http://dx.doi.org/10.2138/am-2020-7154.

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Abstract The stability relations of Pt and Pd antimonides and bismuthinides in the Sb- and Bi-bearing Fe-Ni-Cu sulfide systems have been experimentally determined at temperatures between 1100 and 700 °C in evacuated silica tubes. Both PtSb and PdSb are stable as immiscible liquids at temperatures above 1100 and 1000 °C, respectively. The Fe-Ni-Cu-sulfide melt that coexists with the immiscible antimonide melt can dissolve up to 3.8 wt% Sb at 1100 °C, whereas monosulfide solid solution (mss) dissolves very low amounts of Sb over the entire 1100–700 °C temperature range. The liquidus of Pt-antimo
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7

Shapovalova, Maria, Nadezhda Tolstykh, Roman Shelepaev, and Valery Kalugin. "PGE-Cu-Ni Mineralization of Mafic-Ultramafic Massifs of the Khangai Upland, Western Mongolia." Minerals 10, no. 11 (2020): 942. http://dx.doi.org/10.3390/min10110942.

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The mafic-ultramafic massifs with the PGE-Cu-Ni mineralization located in North-Central Mongolia: Oortsog, Dulaan, Mankhan, Yamat, and Nomgon were investigated. For the first time we consider these massifs as a single magmatic association and as fragments of Khangai batholith caused by the action of the plume responsible for the formation Permian Khangai LIP. The massifs fractionated from peridotite to gabbro have a similar typomorphic ore mineralogical and geochemical features, which change depending on the degrees of fractionation of magma and evolution of the sulfide melt. The least fractio
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8

Nishio, M., N. Kuwata, H. Hinode, M. Wakihara, and M. Taniguchi. "Partial molar enthalphy of formation of solid solution in transition metal sulfides by a combustion calorimetry." Thermochimica Acta 88, no. 1 (1985): 101–8. http://dx.doi.org/10.1016/0040-6031(85)85417-4.

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9

Brovchenko, Valeriya D., Sergey F. Sluzhenikin, Elena V. Kovalchuk, Sofia V. Kovrigina, Vera D. Abramova, and Marina A. Yudovskaya. "Platinum Group Element Enrichment of Natural Quenched Sulfide Solid Solutions, the Norilsk 1 Deposit, Russia." Economic Geology 115, no. 6 (2020): 1343–61. http://dx.doi.org/10.5382/econgeo.4741.

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Abstract The deepest terminations of the Mount Rudnaya subvertical massive sulfide offshoots of the Norilsk 1 orebody are composed of exceptionally fine grained sulfides that are believed to be natural quenched sulfide solid solutions. Copper-rich intermediate solid solution (ISS) and Fe-rich monosulfide solid solution (MSS) form an equigranular and lamellar matrix hosting MSS- and ISS-dominant globules. The nonstoichiometric chemical compositions of the solid solutions plot within their high-temperature fields known from experiments. MSS contains 19 to 35 wt % Ni, 0.09 to 0.45 wt % Co, and up
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10

Long, Yaqiong, Jing Yang, Xin Gao, et al. "Solid-Solution Anion-Enhanced Electrochemical Performances of Metal Sulfides/Selenides for Sodium-Ion Capacitors: The Case of FeS2–xSex." ACS Applied Materials & Interfaces 10, no. 13 (2018): 10945–54. http://dx.doi.org/10.1021/acsami.8b00931.

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