Academic literature on the topic 'Multi-functional Metal Organic Frameworks'

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Dissertations / Theses on the topic "Multi-functional Metal Organic Frameworks"

1

Cadman, Laura. "Multi-component metal-organic frameworks." Thesis, University of Bath, 2017. https://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.723319.

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The synthesis of metal-organic frameworks (MOFs) with new structures and multi-functional pore environments is an area of growing research interest. One route to forming materials of this kind is through the synthesis of multi-component MOFs, which may include multiple organic ligand types or metals in the framework. This thesis presents new examples of multi-component MOFs which aim to demonstrate how this approach affects the properties of the resulting frameworks. Chapter 1 details the terminology surrounding metal-organic frameworks and includes a review of the literature. The overall aims
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Kearns, Eleanor Rose. "Multi-stimuli Metal-organic frameworks and their composites." Thesis, The University of Sydney, 2022. https://hdl.handle.net/2123/29561.

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Metal-Organic Frameworks (MOFs) are a versatile class of materials. Their high surface area combined with the functionality of their constituent organic ligands make them suitable for a wide range of applications. In their scale-up to industry level uses, MOFs face several roadblocks. The largest of these obstacles are large-scale green syntheses of MOFs and processing the polycrystalline powders into useable forms. This thesis examines structure-activity relationships in a family of TTF-based MOFs, and presents a green synthesis for UiO-66-NH2. Finally, 3D-printing will be examined as a metho
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Carson, Fabian. "Development of Metal–Organic Frameworks for Catalysis : Designing Functional and Porous Crystals." Doctoral thesis, Stockholms universitet, Institutionen för material- och miljökemi (MMK), 2015. http://urn.kb.se/resolve?urn=urn:nbn:se:su:diva-115819.

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Metal–organic frameworks, or MOFs, have emerged as a new class of porous materials made by linking metal and organic units. The easy preparation, structural and functional tunability, ultrahigh porosity, and enormous surface areas of MOFs have led to them becoming one of the fastest growing fields in chemistry. MOFs have potential applications in numerous areas such as clean energy, adsorption and separation processes, biomedicine, and sensing. One of the most promising areas of research with MOFs is heterogeneous catalysis. This thesis describes the design and synthesis of new, carboxylate-ba
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Ryder, Matthew. "Physical phenomena in metal-organic frameworks : mechanical, vibrational, and dielectric response." Thesis, University of Oxford, 2017. https://ora.ox.ac.uk/objects/uuid:c7a51278-19d7-45ae-825a-bac8040775a7.

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This thesis entails the utilisation of ab initio density functional theory (DFT) in conjunction with neutron and synchrotron spectroscopy to study the mechanical, vibrational, and dielectric response of metal-organic framework (MOF) materials at the molecular level. MOFs are crystalline materials with nanoscale porosity, which have garnered immense scientific and technological interest for a wide variety of innovative engineering applications. One part of the thesis involves using low-frequency lattice vibrations to characterise the various physical motions that are possible for framework mate
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Nouar, Farid. "Design, Synthesis and Post-Synthetic Modifications of Functional Metal-Organic Materials." Scholar Commons, 2010. https://scholarcommons.usf.edu/etd/1725.

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Porous solids are a class of materials of high scientific and technological significance. Indeed, they have the ability to interact with atoms, ions or molecules not only at their surface but also throughout the bulk of the solid. This ability places these materials as a major class involved in many applications such as gas storage and separation, catalysis, drug delivery and sensor technology. Metal-Organic Materials (MOMs) or coordination polymers (CPs) are crystalline compounds constructed from metal ions or clusters and organic components that are linked via coordination bonds to form zero
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Lifshits, Liubov Mikhaylovna. "A supramolecular approach for engineering functional solid-state chromophore arrays within metal-organic materials." Bowling Green State University / OhioLINK, 2016. http://rave.ohiolink.edu/etdc/view?acc_num=bgsu1460155929.

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Das, Anita. "Metal- Organic Frameworks as a Platform for Elucidating the Effects of Functional Sites on CO2 Interaction." Thesis, The University of Sydney, 2015. http://hdl.handle.net/2123/13813.

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This thesis reports an investigation into metal-organic frameworks (MOFs) as candidate solid-state carbon dioxide capture materials. The modulation of CO2 uptake and heat of adsorption (|Qst|) were explored in response to the systematic variation of pore size, surface area and/or functionalisation in a range of targeted MOFs. Chapter 3 exploits ligand design and targeted MOF synthesis. Functionalised ligands based on the 4,4′-biphenyldicarboxylate core were generated through facile synthetic routes and incorporated into known MOF topologies, including the cubic UiO topology, the pillared paddl
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Epp, Konstantin [Verfasser], Roland A. [Akademischer Betreuer] Fischer, Vos Dirk [Gutachter] De, and Roland A. [Gutachter] Fischer. "Metalloporphyrin-based Metal-Organic Frameworks as Multi-Functional Heterogeneous Catalysts / Konstantin Epp ; Gutachter: Dirk De Vos, Roland A. Fischer ; Betreuer: Roland A. Fischer." München : Universitätsbibliothek der TU München, 2019. http://d-nb.info/1188408879/34.

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Penley, Drace Robert. "Multi-Layer Connectivity-Based Atom Contribution Method for Charge Assignments in Metal-Organic Frameworks (MOFs)." The Ohio State University, 2019. http://rave.ohiolink.edu/etdc/view?acc_num=osu1555599813789541.

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10

Elsaidi, Sameh Khamis. "Crystal Engineering of Functional Metal-Organic Material Platforms for Gas Storage and Separation Applications." Scholar Commons, 2014. https://scholarcommons.usf.edu/etd/5417.

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Metal-organic materials (MOMs) represent a unique class of porous materials that captured a great scientific interest in various fields such as chemical engineering, physics and materials science. They are typically assembled from metal ions or metal clusters connected by multifunctional organic ligands. They represent a wide range of families of materials that varied from 0D to 3D networks: the discrete (0D) structures exemplified by metal-organic polyhedra (MOPs), cubes and nanoballs while the polymeric 1D, 2D and 3D structures exemplified by coordination polymers (CPs). Indeed, the porous 3
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