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Journal articles on the topic 'Multilayer nitride coatings'

Author: Grafiati

Published: 28 May 2022

Last updated: 31 July 2025

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1

Chang, Yin-Yu, and Kai-Chun Huang. "Improvement of Tribological Performance of TiAlNbN Hard Coatings by Adding AlCrN." Materials 15, no. 21 (2022): 7750. http://dx.doi.org/10.3390/ma15217750.

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In tribological applications, the degradation of alloy nitride coatings is an issue of increasing concern. The drawbacks of monolayer hard coatings can be overcome using a multilayer coating system. In this study, single-layer TiAlNbN and multilayer TiAlNbN/AlCrN coatings with AlCrN layer addition into TiAlNbN were prepared by cathodic arc evaporation (CAE). The multilayer TiAlNbN/AlCrN showed B1 NaCl structure, and the columnar structure continued from the bottom interlayer of CrN to the top multilayers without interruption. After AlCrN addition, the TiAlNbN/AlCrN coating consisted of TiAlNbN

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Virk, Ranjot Singh, Muhammad Atiq Ur Rehman, Muhammad Azeem Munawar, et al. "Curcumin-Containing Orthopedic Implant Coatings Deposited on Poly-Ether-Ether-Ketone/Bioactive Glass/Hexagonal Boron Nitride Layers by Electrophoretic Deposition." Coatings 9, no. 9 (2019): 572. http://dx.doi.org/10.3390/coatings9090572.

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Electrophoretic deposition (EPD) was used to produce a multilayer coatings system based on chitosan/curcumin coatings on poly-ether-ether-ketone (PEEK)/bioactive glass (BG)/hexagonal boron nitride (h-BN) layers (previously deposited by EPD on 316L stainless steel) to yield bioactive and antibacterial coatings intended for orthopedic implants. Initially, PEEK/BG/h-BN coatings developed on 316L stainless steel (SS) substrates were analyzed for wear studies. Then, the EPD of chitosan/curcumin was optimized on 316L SS for suspension stability, thickness, and homogeneity of the coatings. Subsequent

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3

Xu, Jiaming, Ping Zhang, Jianjian Yu, et al. "Tribological Properties of MoN/TiN Multilayer Coatings Prepared via High-Power Impulse Magnetron Sputtering." Lubricants 13, no. 8 (2025): 319. https://doi.org/10.3390/lubricants13080319.

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To address the limitations of single-layer nitride coatings, such as poor load adaptability and low long-term durability, MoN/TiN multilayer coatings were prepared via high-power impulse magnetron sputtering (HiPIMS). HiPIMS produces highly ionized plasmas that enable intense ion bombardment, yielding nitride films with enhanced mechanical strength, durability, and thermal stability versus conventional methods. The multilayer coating demonstrated a low coefficient of friction (COF, ~0.4) and wear rate (1.31 × 10−7 mm3/[N·m]). In contrast, both TiN and MoN coatings failed at 5 N and 10 N loads,

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Giagkas, N., J. Nasr, D. Matei, S. Vizireanu, D. L. Cursaru, and S. Mihai. "Preparation and tribologic properties of Ti and Zr nitride multilayer coatings." Digest Journal of Nanomaterials and Biostructures 19, no. 2 (2024): 743–49. http://dx.doi.org/10.15251/djnb.2024.192.743.

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This paper focuses on synthesis and characterization of Zr/Ti and Ti/Zr nitride multilayer coatings by magnetron plasma sputtering to enhance the tribologic properties. The synthesis of nitrides was achieved by non-reactive deposition using Ti or Zr nitride targets or by reactive deposition using Ti or Zr targets in the presence of nitrogen. The formation of nitride layers was highlighted by XRD, EDX and XPS investigations, while the tribologic properties were made with HFRR equipment. The tribological study showed that the coefficient of friction and wear scar diameter decrease in multilayer

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Grebenshchikova, Marina M., and Mikhail M. Mironov. "Peculiar properties of hafnium nitride in coatings for medical materials." Vestnik Тomskogo gosudarstvennogo universiteta. Khimiya, no. 35 (2024): 55–67. https://doi.org/10.17223/24135542/35/4.

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A titanium and hafnium nitride coating obtained by the CIB method is promising for use in medical products. Multilayer nanocomposite coatings of titanium and hafnium nitrides formed at a nitrogen pressure in a vacuum chamber of up to 0.5 Pa and an arc evaporator current of 70-90 A have antimicrobial properties without toxicity. Features of the condensation of hafnium nitride coatings include the presence of a visually noticeable amount of the droplet phase falling out of the plasma flow and the weak ability to etch substrates due to the low energy of hafnium ions. The thickness of the coating

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6

Liu, Yanfei, Shengtao Yu, Qiuyu Shi, Xiangyu Ge, and Wenzhong Wang. "Multilayer Coatings for Tribology: A Mini Review." Nanomaterials 12, no. 9 (2022): 1388. http://dx.doi.org/10.3390/nano12091388.

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Friction and wear usually lead to huge energy loss and failure of machine pairs, which usually causes great economic losses. Researchers have made great efforts to reduce energy dissipation and enhance durability through advanced lubrication technologies. Single-layer coatings have been applied in many sectors of engineering, but the performance of single-layer coatings still has many limitations. One solution to overcome these limitations is to use a multilayer coating that combines different components with varied physical and chemical properties. In addition, multilayer coating with alterna

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7

Smolik, Jerzy, Adam Mazurkiewicz, Zbigniew Słomka, et al. "Nanomultilayer Coatings Based on Vanadium Nitride." Solid State Phenomena 237 (August 2015): 15–20. http://dx.doi.org/10.4028/www.scientific.net/ssp.237.15.

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Based on the analysis of the research directions in the field of coatings and layers with special operating properties, the production technologies of composite coatings, including the gradient, multi-layer, and multi-component coatings, should be distinct. The paper presents the results of material properties tests of a multi-layer coating Ti / TiN / TiAlNgradient / (TiAlN/VN)multinano obtained on hot working steel EN X32CrMoV3.3. The preparation of the multilayer coating was specially designed to increase the durability of forging dies in the brass forging process. The authors discuss the re

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8

bin Abdullah, Mohd Zakuan, Ahmad Nizam bin Abdullah, Mohamad Hazri bin Othman, Amin bin Morat, and Mohamad Azmiruddin bin Ahmad. "Mechanical Properties of Cr/CrN/CrCN/ZrN Multilayer Coatings by Physical Vapour Deposition (PVD)." Advanced Materials Research 1133 (January 2016): 99–102. http://dx.doi.org/10.4028/www.scientific.net/amr.1133.99.

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Multilayer coating onto orthopedic implants has been studied extensively due to their excellence mechanical and biological properties. A multilayer coating was coated onto metal implants to prevent the leaching of metallic ions into human body. This paper aims to study the hardness of multilayer coatings of Chromium (Cr), Chromium Nitride (CrN), Chromium Carbonitride (CrCN) and Zirconium Nitride (ZrN) by Physical Vapour Deposition (PVD). The deposited multilayer coating was characterised by Scanning Electron Microscope (SEM), X-ray Diffraction (XRD) and Energy Dispersive X-ray (EDX). Cr, CrN,

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9

Yu, WX, YH Tian, SS Chen, LY Lin, and N. Hu. "Corrosion resistance behavior of Ti/TiN multilayer coatings deposited on Ti6Al4V substrates." Journal of Physics: Conference Series 2301, no. 1 (2022): 012019. http://dx.doi.org/10.1088/1742-6596/2301/1/012019.

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Abstract DC magnetron sputtering was used to deposit titanium (Ti), titanium nitride (TiN), and Ti/TiN multilayer coatings on Ti6Al4V alloy substrates. The multilayer coatings have 1, 4, 10, 16, 32 modulation periods respectively. SEM were used to analyze the surface and cross-sectional micro-features of the coatings. Electrochemical tests were carried out 3.5 wt% NaCl solution at room temperature. The resistance of the coating reaches the maximum value, which is 6 times that of the substrate, 2.4 times that of a single layer of titanium, and 5 times that of titanium nitride. With the increase

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10

Vorontsov, Andrey, Andrey Filippov, Nikolay Shamarin, et al. "In situ crystal lattice analysis of nitride single-component and multilayer ZrN/CrN coatings in the process of thermal cycling." Metal Working and Material Science 25, no. 4 (2023): 202–15. http://dx.doi.org/10.17212/1994-6309-2023-25.4-202-215.

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Introduction. Thermal expansion is an important thermal and physical characteristic of materials, showing its expansion when heated. Knowing this property is important both from a scientific point of view and for practical applications. Materials with low thermal expansion are widely used in electronics, thermal barrier coatings and other applications. Mismatch in thermal expansion between different materials can lead to thermal stress on contact surfaces. The in-situ synchrotron X-ray diffraction method can detect this mismatch. Thermal stress requires an analysis of the coefficient of therma

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11

Sagalovich, Alex, and Vlad Sagalovych. "EXPERIMENTAL RESEARCH OF MULTICOMPONENT MULTILAYER ION-PLASMA AVINIT COATINGS." Фізична інженерія поверхні 11, no. 1 (2013): 4–17. https://doi.org/10.5281/zenodo.4457315.

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Metallographic examination of improved structures of Avinit С multilayer nitride-based coatings, particularly coatings of Ti-Al-N system and Mo-N system-based coating have been carried out. Use of effective methods of surface cleaning and three-level arc control system in the techniques under development for prevention of surface damaging, caused by micro arcs, allows to apply coatings of precision and high finish class surfaces up to 12 – 13 grade of finish without deterioration of surface finish class. The experimental findings confirm a possibility of low-temperature deposition of ver

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12

Kolesnikov, D. A., U. S. Nyemchenko, V. M. Beresnev, et al. "Multilayer Nitride Coatings (TiZrNbHf)N/MoN." Journal of Nano- and Electronic Physics 8, no. 3 (2016): 03045–1. http://dx.doi.org/10.21272/jnep.8(3).03045.

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13

Sun, Yong, Cheng Lu, Hai Liang Yu, et al. "Deformation Behavior and Wear Resistance of Hard TiCN and TiCN/Ti Coatings on Ti6Al4V Alloy." Advanced Materials Research 939 (May 2014): 451–58. http://dx.doi.org/10.4028/www.scientific.net/amr.939.451.

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Monolayer titanium carbide nitride (TiCN) and multilayer TiCN reinforced titanium (Ti) are coated on the surface of Ti6Al4V alloy by Filtered Arc Deposition System (FADS). Surface chemical composition has been characterized by an X-ray diffraction (XRD). Wear resistance of TiCN coating and TiCN/Ti coating have been detected by hommel tester T1000. Hardness and deformation mechanisms of the multilayer coatings are investigated using depth-sensing indentation comparison with the monolayer TiCN coatings. Focused Ion Beam (FIB) and Transmission Electron Microscopy (TEM) are used to identify the fr

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14

Vorontsov, Andrey, Andrey Filippov, Nickolay Shamarin, et al. "High-Temperature Oxidation of CrN/ZrN Multilayer Coatings." Metals 12, no. 10 (2022): 1746. http://dx.doi.org/10.3390/met12101746.

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Multilayer nitride coatings provide some of the best performance when in their use for the production of metalworking tools. In this work, vacuum-arc plasma-assisted deposited multilayer ZrN/CrN coatings with different numbers of constituent layers were characterized for high-temperature oxidization in air using weighing, confocal and scanning electron microscopy and synchrotron XRD. Oxidizing at 300 °C did not deteriorate the coating surfaces, while higher temperatures caused surface deterioration and oxidation accompanied by cracking, delamination and considerable mass gains. The coating wit

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15

Sakharova, Nataliya A., José Valdemar Fernandes, Marta C. Oliveira, and Jorge M. Antunes. "A Numerical Study on the Mechanical Behaviour of Hard Coatings with Ductile Interlayers under Depth-Sensing Indentation." Materials Science Forum 636-637 (January 2010): 1194–98. http://dx.doi.org/10.4028/www.scientific.net/msf.636-637.1194.

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In the present study, numerical simulations of nanohardness tests of titanium aluminium nitride (TiAlN) hard coatings with titanium and aluminium ductile interlayers were performed in order to determine the influence of interlayers of ductile metals on the overall mechanical properties of multilayer coatings. The investigation was designed to determine the role of ductile interlayers in altering the hardness value and the Young´s modulus of the multilayer coating as a whole, in comparison with a monolayer TiAlN hard coating, for the cases of composites with different numbers and thicknesses of

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16

Kovalev, Anatoly I., Vladimir O. Vakhrushev, Ben D. Beake, et al. "Damage Accumulation Phenomena in Multilayer (TiAlCrSiY)N/(TiAlCr)N, Monolayer (TiAlCrSiY)N Coatings and Silicon upon Deformation by Cyclic Nanoindentation." Nanomaterials 12, no. 8 (2022): 1312. http://dx.doi.org/10.3390/nano12081312.

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The micromechanism of the low-cycle fatigue of mono- and multilayer PVD coatings on cutting tools was investigated. Multilayer nanolaminate (TiAlCrSiY)N/(TiAlCr)N and monolayer (TiAlCrSiY)N PVD coatings were deposited on the cemented carbide ball nose end mills. Low-cycle fatigue resistance was studied using the cyclic nanoindentation technique. The obtained results were compared with the behaviour of the polycrystalline silicon reference sample. The fractal analysis of time-resolved curves for indenter penetration depth demonstrated regularities of damage accumulation in the coatings at the e

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17

Serdiuk, Iryna, Viacheslav Oleksandrovich Stolbovyi, Anatolij Andreev, Viktor Fedorovich Gorban, and Ruslan Vasilievich Kryvoshapka. "Structural state and physical-mechanical properties of multilayer vacuum arc Ti/TiN coating." Bulletin of Kharkov National Automobile and Highway University, no. 106 (September 19, 2024): 37. http://dx.doi.org/10.30977/bul.2219-5548.2024.106.0.37.

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Abstract. Problem. Increasing the resource of the cutting tools in conditions of variable load is of great importance, as it affects not only the cost of production but also the competitiveness of the enterprise. A wide range of properties of vacuum arc multilayer coatings allows them to be used in mechanical engineering to increase the performance of the tools in the variable conditions of cutting. Goal. The goal is to study the structural state and physical and mechanical properties of vacuum arc multilayer Ti/TiN coatings. To achieve the goal, it is necessary to analyze the effect of the th

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18

Tkachuk, Mykola M., Nataliya Pinchuk, Andrii Meilekhov, et al. "THEORY OF TECHNOLOGY AND METHODS OF ENGINEERING ANALYSIS OF HIGH-STRENGTH NANOSTRUCTURED COATINGS FOR ENHANCED SERVICE CHARACTERISTICS OF MILITARY AND CIVIL EQUIPMENT OBJECTS." Bulletin of the National Technical University «KhPI» Series: Engineering and CAD, no. 1 (December 28, 2024): 132–38. https://doi.org/10.20998/2079-0775.2024.1.13.

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Modern military and civil equipment objects need to improve the service properties of the most critical and loaded contacting elements, which determine their tactical and technical characteristics. So far, traditional and new materials have exhausted such possibilities in many aspects. These capabilities can be dramatically increased by means of strengthening, in particular, application of nanostructured high-strength and multilayer nitride coatings based on titanium nitrides, zirconium, etc., as well as modified vacuum condensates. At the same time, for structural elements with closeshaped co

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19

Dobrzański, Leszek Adam, and Daniel Pakuła. "Structure and Properties of the Wear Resistant Coatings Obtained in the PVD and CVD Processes on Tool Ceramics." Materials Science Forum 513 (May 2006): 119–34. http://dx.doi.org/10.4028/www.scientific.net/msf.513.119.

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The paper presents investigation results of structure and functional properties of the hard wear resistant coatings obtained in the PVD and CVD processes on the Si3N4 nitride tool ceramics. Examinations of coatings structures were made using the transmission (TEM) and scanning (SEM) electron microscopes, microhardness tests, coating adhesion to the substrate with the „scratch test”, and the coatings abrasive resistance „pin-on-disc” test. Machining tests results and roughness tests results for the machined grey cast iron surface are also presented. The research carried out proved that depositi

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20

Šnajdar, Mateja, Danko Ćorić, and Matija Sakoman. "Comparative Study of Multilayer Hard Coatings Deposited on WC-Co Hardmetals." Coatings 14, no. 6 (2024): 674. http://dx.doi.org/10.3390/coatings14060674.

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This paper examines the impact of a multilayered gradient coating, applied via plasma-activated chemical vapor deposition (PACVD), on the structural and mechanical attributes of nanostructured WC-Co cemented carbides. WC-Co samples containing 5 and 15 wt.% Co were synthesized through a hot isostatic pressing (HIP) process using nanoparticle powders and coated with two distinct multilayer coatings: titanium nitride (TiN) and titanium carbonitride (TiCN). Nanosized grain formation without microstructural defects of the substrates, prior to coating, was confirmed by magnetic saturation and coerci

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21

Ivanov, Yu F., Yu H. Akhmadeev, N. N. Koval, et al. "Multi-element nitride coatings of quasi-equiatomic composition synthetized by the ion-plasma method." Izvestiya vysshikh uchebnykh zavedenii. Fizika, no. 11 (2022): 59–64. http://dx.doi.org/10.17223/00213411/65/11/59.

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Multi-element nitride coatings of quasi-equiatomic composition (NbMoCrTiAl)N and (NbZrCu-TiAl)N are synthesized by deposition on a substrate in vacuum from a multicomponent gas-metal plasma. This plasma was generated by simultaneous independent vacuum-arc evaporation of the cathodes of the selected elements in the regime with plasma assistance in a nitrogen atmosphere. It has been established that the synthesized coatings are single-phase materials with a face-centered cubic crystal lattice. For the coating composition (NbZrCuTiAl)N, the crystal lattice parameter was a = 0.44288 nm, and for (N

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Filippov, Andrey, Nikolay Shamarin, Evgenij Moskvichev, et al. "Investigation of the structural-phase state and mechanical properties of ZrCrN coatings obtained by plasma-assisted vacuum arc evaporation." Metal Working and Material Science 24, no. 1 (2022): 87–102. http://dx.doi.org/10.17212/1994-6309-2022-24.1-87-102.

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Introduction. Modern technologies allow the synthesis of nanostructured coatings from multiple chemical elements to combine different physical, mechanical, and chemical properties in one coating. Promising in this respect are coatings formed via layer-by-layer deposition of zirconium and chromium nitrides. The deposition of various chemical elements on various substrates requires separate studies in order to produce high-strength and wear-resistant coatings. The purpose of this work is to study the structural-phase state and mechanical properties of ZrCrN coatings formed by plasma-assisted vac

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23

González-Hernández, Andrés, Ana Beatriz Morales-Cepeda, Martín Flores, Julio C. Caicedo, William Aperador, and César Amaya. "Electrochemical Properties of TiWN/TiWC Multilayer Coatings Deposited by RF-Magnetron Sputtering on AISI 1060." Coatings 11, no. 7 (2021): 797. http://dx.doi.org/10.3390/coatings11070797.

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Nitride and carbide ternary coatings improve the wear and corrosion resistance of carbon steel substrates. In this work, Ti-W-N and Ti-W-C coatings were deposited on AISI 1060 steel substrates using reactive radio frequency (RF) magnetron sputtering. The coatings were designed as monolayers, bilayers, and multilayers of 40 periods. The coatings were obtained with simultaneous sputtering of Ti and W targets. The microstructure, composition, and electrochemical properties were investigated by techniques such as X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), scanning electron mi

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24

GREBENSHCHIKOVA, M. M. "THE OBTAINMENT OF NANOSTRUCTURED BIOLOGICALLY ACTIVE COATINGS BASED ON HAFNIUM NITRIDE FOR MEDICAL IMPLANTS AND MEDICAL INSTRUMENTS BY ACTIVATING THE SURFACE WITH A FLOW OF LOW-ENERGY IONS." IZVESTIA VOLGOGRAD STATE TECHNICAL UNIVERSITY, no. 2(285) (February 2024): 36–41. http://dx.doi.org/10.35211/1990-5297-2024-2-285-36-41.

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The possibility of obtaining biologically active materials with antimicrobial properties has been studied. The materials are made on the basis of multilayer nanostructured coatings, which were obtained by condensation with ion bombardment of nitride layers on medical instruments in a nitrogen atmosphere. The surface was treated in a flow of low-energy ions with energies ranging from 70 to 100 eV. We received a medical instrument with a high-strength coating that has an antimicrobial effect. IT has no negative effect on animal cells, with a proliferation index of 1.07-2.0. The research results

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25

Liu, Jie, Yongchao Wang, Guiqian Liu, Junfang Hua, and Xin Deng. "Properties and Performance of TiAlSiN and AlCrN Monolayer and Multilayer Coatings for Turning Ti-6Al-4V." Coatings 13, no. 7 (2023): 1229. http://dx.doi.org/10.3390/coatings13071229.

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The high chemical activity, low thermal conductivity, and high strength of titanium alloys lead to severe tool wear during cutting. The coating applied to the tool surface insulates the effect of heat and chemical reactions. TiAlSiN coating and AlCrN coating are two representative coatings with excellent properties in TiN-based and CrN-based applications, respectively. Three types of nanocoatings—TiAlSiN monolayer, AlCrN monolayer, and TiAlSiN/AlCrN multilayer—were prepared, and the microstructure, mechanical properties, oxidation resistance, diffusion properties with titanium alloy, and cutti

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26

Song, Dong Hwan, Jong Kook Lee, Dong Seok Seo, and Gon Seung Yang. "Corrosion Resistance of TiAlN/ZrN and TiCrN/ZrN Multilayers during Heat Treatment." Materials Science Forum 569 (January 2008): 85–88. http://dx.doi.org/10.4028/www.scientific.net/msf.569.85.

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Titanium-based nitride coatings on cutting tools, press molds and dies can prolong their life cycle because of superior corrosion and oxidation resistance of coatings. In this study, TiAlN/ZrN and TiCrN/ZrN multilayer coatings were prepared by R.F magnetron sputtering, and microstructural evolution and corrosion resistance of the coatings were investigated during heat treatment. The TiAlN/ZrN and TiCrN/ZrN multilayer coatings were degraded by heating up to 600 oC with formation of oxides particles on the surface. During the heat treatment, the TiCrN/ZrN and TiAlN/ZrN multilayer coatings showed

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27

Puppa, Jan, and Bernd Arno Behrens. "Optimization of Cooling and Lubrication for Nitrided and Ceramic-Coated Hot Forging Dies." Applied Mechanics and Materials 794 (October 2015): 97–104. http://dx.doi.org/10.4028/www.scientific.net/amm.794.97.

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In order to enhance the tool life of hot forging dies, increasing the wear resistance of the forming tool surface is of great importance. In addition to thermal and thermo-chemical surface treatments, methods applying thin wear-resistant coatings gain more importance. Therefore, ceramic-based mono- or multilayer hard coatings are used in combination with a supporting nitride layer. Due to their low material-specific thermal conductivity, ceramic coatings have an increased sensitivity to abrupt temperature changes. To avoid such thermal shocks, an adjustment of the cooling behaviour is required

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Chayeuski, Vadzim, Valery Zhylinski, Victor Kazachenko, Aleksandr Tarasevich, and Abdelhafed Taleb. "Structural and Mechanical Properties of DLC/TiN Coatings on Carbide for Wood-Cutting Applications." Coatings 13, no. 7 (2023): 1192. http://dx.doi.org/10.3390/coatings13071192.

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In this work, the diamond-like carbon and titanium nitride (DLC/TiN) multilayer coatings were prepared on a cemented tungsten carbide substrate (WC—3 wt.% Co) using the cathodic vacuum arc physical vapor deposition (Arc-PVD) method and pulsed Arc-PVD method with a graphite cathode for the deposition of TiN and carbon layers, respectively. The structural and mechanical properties of the prepared coatings were studied, and different techniques, such as scanning electron microscope (SEM), energy-dispersive X-ray spectroscopy (EDX), X-ray diffraction (XRD), Raman spectroscopy, and microindentation

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Harvinder, Singh, Singh Rajdeep, Kumar Satish, and Goyal Aneesh. "A comprehensive review of tribological performance of coatings on automotive piston rings." i-manager's Journal on Mechanical Engineering 14, no. 4 (2024): 48. https://doi.org/10.26634/jme.14.4.21585.

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Friction and wear significantly influence automotive engine performance and efficiency, leading to substantial fuel power loss across various engine components. Among these, the frictional losses between the piston ring and cylinder liner assembly contribute notably to overall inefficiencies. To address this issue, thin-film coating techniques have emerged as a promising solution for enhancing the mechanical and tribological properties of engine components. This paper reviews various wear-resistant, corrosion-resistant, and antifriction coatings, including carbon-based coatings, nitride coatin

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Major, Ł., M. Janusz, J. M. Lackner, and B. Major. "Contribution of Titanium, Chromium and Carbon Buffer Interlayers to Bio-Tribological Properties of Multilayer Composites." Archives of Metallurgy and Materials 61, no. 3 (2016): 1391–98. http://dx.doi.org/10.1515/amm-2016-0228.

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Abstract Research studies on bio-tribological protective coatings of titanium, chromium and carbon based have been performed. Thin films were fabricated by hybrid PLD technique (PLD supported by magnetron sputtering). Coatings consisted of two parts; the inner part (first from the substrate) in each case was formed by titanium or chromium/titanium nitride or chromium nitride (Ti/TiN or Cr/Cr2N). The outer part was formed by pure DLC or multilayer DLC/Ti or Cr. No delamination was found at the interface. Titanium or chromium metallic layer was deposited as a first layer directly on the metallic

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Pogrebnjak, Alexander, Kateryna Smyrnova, and Oleksandr Bondar. "Nanocomposite Multilayer Binary Nitride Coatings Based on Transition and Refractory Metals: Structure and Properties." Coatings 9, no. 3 (2019): 155. http://dx.doi.org/10.3390/coatings9030155.

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One area of constant interest in many fields of industry is development of functional multilayer coatings that possess excellent performance characteristics. That is why in our brief review the results of studies of structure and properties of multilayer structures based on binary nitrides of transition or refractory metals obtained by various physical-vapor deposition (PVD) techniques are presented. The influence of substrate temperature, substrate bias voltage, bilayer thickness and interface boundaries on the structure of coatings and their properties, such as hardness, plasticity, wear and

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Warcholinski, Bogdan, Adam Gilewicz, and Maria Tarnowska. "The Surface Assessment and the Properties of Selected Multilayer Coatings." Lubricants 11, no. 9 (2023): 371. http://dx.doi.org/10.3390/lubricants11090371.

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The paper presents an evaluation of the surface quality and properties of multilayer coatings, obtained using cathodic arc evaporation, of the same structure, in which the top layer is a CrN chromium nitride layer. The second components of a double-layer module with a thickness of 400 nm and a thickness of each layer about 200 nm are two component TiN, Mo2N systems and three component TiAlN and CrCN systems. In studies using scanning electron microscopy and optical microscopy, the surface density of the macroparticles of the coating and their dimensions were estimated. The largest amount of ma

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Yu-Jie, Zhu, Ma Jing-Ling, Wang Guang-Xin, Song Ke-Xing, and Heinz Rolf Stock. "Corrosion behaviour of multilayer CrN coatings deposited by hybrid HIPIMS after oxidation treatment." Nanotechnology Reviews 9, no. 1 (2020): 596–609. http://dx.doi.org/10.1515/ntrev-2020-0048.

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AbstractChromium nitride coatings prepared by physical vapour deposition (PVD) show high hardness, high strength and good thermal conductivity, which makes them useful for cutting and forming tools. In this article, the microstructure and corrosion resistance of multilayer Cr/CrN coatings deposited by arc evaporation and hybrid high power impulse magnetron sputtering (hybrid HIPIMS) after oxidation between 500 and 800°C were examined. The average thickness of the coatings was about 3.5 µm. By means of the surface morphology analysis, elemental energy spectrometry and potentiodynamic polarizati

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Lloyd, S. J., J. E. Pitchford, J. M. Molina-Aldareguia, Z. H. Barber, M. G. Blamire, and W. J. Clegg. "Nanoindentation in Tin/Nbn Multilayers and Thin Films Examined Using Transmission Electron Microscopy." Microscopy and Microanalysis 5, S2 (1999): 776–77. http://dx.doi.org/10.1017/s1431927600017207.

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Nanoindentation allows the hardness of thin coatings and synthetic multilayer structures to be measured, since indentation depths can be as little as a few 10s of nm. In combination with the cross-sectional transmission electron microscopy (TEM) analysis described here it is possible to observe the deformation structure under an indent, and potentially to understand deformation mechanisms on a nm scale in a wide variety of materials. Synthetic multilayers are a particularly interesting system to investigate. Variations in hardness with the multilayer compositional repeat distance (A) have been

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Kasymbaev, A., S. V. Plotnikov, A. Turlybekuly, and A. Pogrebnyak. "RESEARCH OF THE PHYSICAL PROPERTIES OF MULTI-COMPONENT, MULTILAYER, SOLID NANOCOMPOSITE COATINGS." Bulletin of Shakarim University. Technical Sciences, no. 1(13) (March 29, 2024): 312–19. http://dx.doi.org/10.53360/2788-7995-2024-1(13)-38.

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The results of studies of the physical and mechanical properties of nitride and carbide multilayer systems based on ((TiZrNbTa)N, depending on the methods of deposition and heat treatment are analyzed and summarized. The coatings were deposited by magnetron sputtering. Studies of the original and processed alloy samples were carried out in a regional engineering laboratory. When extremely high doses of N+ ions (1018 cm-2) are introduced into nanostructured coatings (TiZrNbTa)N, a multilayer structure is formed, consisting of amorphous, nanocrystalline (dispersed) and nanostructured layers.The

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Rzepiejewska-Malyska, K. A., W. M. Mook, M. Parlinska-Wojtan, J. Hejduk, and J. Michler. "In situ scanning electron microscopy indentation studies on multilayer nitride films: Methodology and deformation mechanisms." Journal of Materials Research 24, no. 3 (2009): 1208–21. http://dx.doi.org/10.1557/jmr.2009.0139.

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Systematic studies of the deformation mechanisms of multilayer transition metal nitride coatings TiN/CrN, TiN/NbN, and NbN/CrN, and corresponding reference coatings of TiN, NbN, and CrN deposited by a direct current (dc) magnetron sputtering process onto silicon 〈100〉 have been performed. Mechanical characterization was conducted using a combination of microindentation and nanoindentation in the load range 30 to 150 mN and 0.5 to 3.5 mN, respectively. For both load ranges, scanning electron microscopy (SEM) in situ indentation was used to observe the indentation process including any pileup, s

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Gorban’, V. F., A. O. Andreev, V. A. Stolbovoi, A. M. Myslyvchenko, and A. D. Kostenko. "Properties of Metal–Metal Nitride Vacuum-Arc Multilayer Coatings." Journal of Superhard Materials 42, no. 1 (2020): 25–29. http://dx.doi.org/10.3103/s1063457620010050.

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Kumar, D. Dinesh, N. Kumar, S. Kalaiselvam, S. Dash, and R. Jayavel. "Wear resistant super-hard multilayer transition metal-nitride coatings." Surfaces and Interfaces 7 (June 2017): 74–82. http://dx.doi.org/10.1016/j.surfin.2017.03.001.

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Ivashchenko, L. A., O. K. Porada, V. I. Ivashchenko, I. M. Zakiev, S. M. Dub, and I. I. Timofeeva. "Characteristics of monolayer and multilayer titanium nitride plasmochemical coatings." Powder Metallurgy and Metal Ceramics 45, no. 11-12 (2006): 547–52. http://dx.doi.org/10.1007/s11106-006-0118-6.

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Maksakova, O. V., V. M. Beresnev, S. V. Lytovchenko, et al. "Multilayer WNbN/WNbC, WN/WC and NbN/NbC Coatings: Vacuum-Arc Deposition Strategy and Microstructure Assessment." East European Journal of Physics, no. 1 (March 3, 2025): 396–402. https://doi.org/10.26565/2312-4334-2025-1-49.

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Reactive gases such as nitrogen, oxygen, and carbon-based gases (e.g., acetylene) are introduced into the generated plasma flow to create coatings with chemical compounds including nitrides, oxides, and carbides. By managing the rate of gas addition, the stoichiometric composition of the material, which influences its crystal structure and range of properties, can be controlled. In light of this, the vacuum-arc PVD technique was utilised to deposit carbide/nitride multilayer coatings based on W and Nb in a dynamically changing atmosphere of nitrogen and acetylene gases. The two-channel control

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Kovalev, Anatoly Ivanovich, Vladimir Olegovich Vakhrushev, Egor Pavlovich Konovalov, et al. "Features of the Oxidation of Multilayer (TiAlCrSiY)N/(TiAlCr)N Nanolaminated PVD Coating during Temperature Annealing." Coatings 13, no. 2 (2023): 287. http://dx.doi.org/10.3390/coatings13020287.

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A nano-multilayer Ti0.2Al0.55Cr0.2Si0.03Y0.02N/Ti0.25Al0.65Cr0.1N PVD coating was deposited on Kennametal carbide K 313 inserts. These coatings are widely used to protect cutting tools under severe exploitation conditions. Under equilibrium conditions, it was found that the Al2O3 oxide possessed better adhesive properties than the TiO2. The addition of chromium further enhanced the oxidation resistance of the coatings. Silicon significantly increased the oxidation resistance of this type of coating. The properties of the diffusion process in this coating have not been sufficiently investigated

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Loskutova, Tetiana, Michal Hatala, Inna Pogrebova, et al. "Composition, Structure, and Properties of Ti, Al, Cr, N, C Multilayer Coatings on AISI W1-7 Alloyed Tool Steel." Coatings 12, no. 5 (2022): 616. http://dx.doi.org/10.3390/coatings12050616.

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New methods of diffusion metallization of AISI W1-7 steel have been developed. The paper proposes a comparative analysis of the properties and characteristics of AISI W1-7 steel after three methods of chemical heat treatment: diffusion nitriding, nitrogen titration by physical deposition from the gas phase, and diffusion chromium plating with subsequent titanium alloys. The results are presented as a comprehensive analysis of coatings: metallographic, micro-X-ray spectral, X-ray phase, durometric, heat resistance, and wear resistance. It is established that multilayer protective coatings are f

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Margono, Muhammad Kozin, David Setiadhi, Hassan Khamis Hassan, and Rajeshkumar Lakshminarasimhan. "Development of Titanium Nitride-Based Coatings for Wear Resistant Materials: A Review." Mechanics Exploration and Material Innovation 1, no. 3 (2024): 102–19. https://doi.org/10.21776/ub.memi.2024.001.03.5.

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Friction and wear are significant contributors to energy consumption, requiring the development of wear-resistant materials. Titanium nitride (TiN) coatings provide a potential solution for protecting metal parts from wear when they are applied over forming and cutting tools as TiN is characterized by low coefficient of friction and high hardness. However, local heat generation and brittle properties can cause cracks, affecting tool life and finished product accuracy. This article explores the wear behavior of TiN-based coatings over the substrates. In most cases, the TiN coatings are applied

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Pavlenko, Ivan, Jozef Zajac, Nadiia Kharchenko, Ján Duplák, Vitalii Ivanov, and Kateryna Kostyk. "Estimation of Wear Resistance for Multilayer Coatings Obtained by Nitrogenchroming." Metals 11, no. 8 (2021): 1153. http://dx.doi.org/10.3390/met11081153.

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This article deals with improving the wear resistance of multilayer coatings as a fundamental problem in metal surface treatment, strengthening elements of cutting tools, and ensuring the reliability of machine parts. It aims to evaluate the wear depth for multilayer coatings by the mass loss distribution in layers. The article’s primary purpose is to develop a mathematical method for assessing the value of wear for multilayer steel-based coatings. The study material is a multilayer coating applied to steel DIN C80W1. The research was performed using up-to-date laboratory equipment. Nitrogench

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Devarajan, Dinesh Kumar, Baskaran Rangasamy, and Kamalan Kirubaharan Amirtharaj Mosas. "State-of-the-Art Developments in Advanced Hard Ceramic Coatings Using PVD Techniques for High-Temperature Tribological Applications." Ceramics 6, no. 1 (2023): 301–29. http://dx.doi.org/10.3390/ceramics6010019.

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Hard and wear-resistant coatings created utilizing physical vapor deposition (PVD) techniques are extensively used in extreme tribological applications. The friction and wear behavior of coatings vary significantly with temperature, indicating that advanced coating concepts are essential for prolonged load-bearing applications. Many coating concepts have recently been explored in this area, including multicomponent, multilayer, gradient coatings; high entropy alloy (HEA) nitride; and functionally modified coatings. In this review, we highlighted the most significant findings from ongoing resea

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Zaoui, Mehdi, Alexandre Bourceret, Yves Gaillard, et al. "RELATION BETWEEN HARDNESS OF (Ti, Al)N BASED MULTILAYERED COATINGS AND PERIODS OF THEIR STACKING." Acta Polytechnica CTU Proceedings 27 (June 11, 2020): 79–83. http://dx.doi.org/10.14311/app.2020.27.0079.

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This study aims to model, by using a finite element method, the relationship between the hardness and the period Λ of metal/nitride multilayer coatings (Ti0.54Al0.46/Ti0.54Al0.46N)n in order to understand the increase of the hardness at the low periods [1] and then optimise the multilayer coating architecture to obtain the best mechanical properties. A 2D axisymmetric finite element model of the Berkovich nanoindentation test was developed. The coating was designed as a stacking of Ti0.54Al0.46 and Ti0.54Al0.46N nanolayers with, in the first hypothesis, equal thickness and perfect interface. T

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Kumar, Sumit, and M. S. Charoo. "Evaluation of Tribological Properties of Different Coatings on Automotive Piston Rings: A Review." Journal of Materials and Engineering 2, no. 4 (2024): 288–302. http://dx.doi.org/10.61552/jme.2024.04.007.

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Friction and wear play crucial roles in automotive engine performances and their efficiency. Overall, 40% of fuel power loss occurs in friction of various components of the engine. Frictional loss between piston rings and cylinder liner assembly contributes major loss of fuel power in the automotive engine and it is about 15% of total fuel power loss occurs due to friction. In the present scenario, thin film coating techniques are in trend to enhance the mechanical and tribological properties of machine components. In this paper, different types of wear-resistant, corrosion-resistant, and anti

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Kupczyk, Maciej Jan, and Jerzy Józwik. "Effect of Laser Heating on the Life of Cutting Tools Coated with Single- and Multilayer Coatings Containing a TiN Layer." Materials 15, no. 11 (2022): 4022. http://dx.doi.org/10.3390/ma15114022.

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This study proposes a novel use of laser heating to increase the adhesion between coatings fabricated by low-temperature PVD and replaceable cemented carbide cutting inserts, thus extending the life of these cutting tools in the machining of difficult-to-machine materials. Our previous studies conducted on CVD coatings showed that these coatings had higher adhesion due to a much higher process temperature. However, taking into account the fact that PVD coatings have better technological properties (e.g., lower structure porosity, higher hardness, and better tribological properties) than CVD co

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Janusz, M., L. Major, J. M. Lackner, B. Grysakowski, and H. Krawiec. "Microstructure characterization of localized corrosion wear of Cr/Cr2N+ a-C:H/a-C:H:Cr multilayer coatings on carbon fiber composites." Bulletin of the Polish Academy of Sciences Technical Sciences 65, no. 2 (2017): 171–77. http://dx.doi.org/10.1515/bpasts-2017-0021.

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Abstract The use of carbon fiber composites (CFC) for different applications is widespread. Carbon-based materials show, however, significant oxidative degradation in air. Modern materials are subjected to aggressive, corrosive environment. This type of environment may strongly reduce their mechanical properties. For the protection of CFC, it was necessary to apply coatings to the composite surface. In the presented paper, a chromium/chromium nitride (Cr/Cr2N) multilayer structure has been selected as the inner part. The outer part of the coating was a hydrogenated amorphous carbon (a-C:H), gr

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Bejarano, Gilberto, Julio Caicedo, and Juan Muñoz Saldaña. "Mechanical and tribological properties enhancement of heat treated AISI 4340 steel by using a TiN/TiAlN multilayer coating system." Revista Facultad de Ingeniería Universidad de Antioquia, no. 44 (February 12, 2014): 36–42. http://dx.doi.org/10.17533/udea.redin.18467.

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TiN/TiAlN (titanium nitride/titanium aluminum nitride) multilayer were deposited by d.c. reactive magnetron sputtering using titanium and aluminum targets with 10 cm in diameter and 99.9% purity in an argon/nitrogen (Ar/ N) atmosphere, applying a substrate temperature of 300°C and a pressure of 7x10-3 mbar. Silicon (100) and heat treated AISI 4340 steel samples with a hardness of 54 Rockwell C (HRC, approximately 5.4 GPa) were utilized as substrate. TiN/TiAlN coatings with 70% aluminum and 4 ìm total thicknesswere investigated as function of multilayer number and their mechanical and tribologi

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