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Journal articles on the topic 'Multinuclear complexes'

Author: Grafiati

Published: 5 June 2025

Last updated: 1 August 2025

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1

Schreiber, A., H. Rauter, M. Krumm, S. Menzer, E. C. Hillgeris, and B. Lippert. "Multinuclear Metal Nucleobase Complexes." Metal-Based Drugs 1, no. 2-3 (1994): 241–46. http://dx.doi.org/10.1155/mbd.1994.241.

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Of all properties of metal nucleobase complexes, formation of multinuclear species appears to be an outstanding feature. After a brief introduction into well known polymeric metal nucleobase complexes, three aspects recently Studied in our laboratory will be dealt with in more detail: (i) Heteronuclear complexes derived from trans-[(amine)2Pt(1-MeC)2]2+ (1-MeC=1-methylcytosine). They form, e. g. with Pd(II) or Hg(II), upon single deprotonation of the exocyclic amino group of each 1-MeC ligand, compounds of type trans-[(amine)2Pt(1-MeC-)2MY]n+, displaying Pt-M bond formation. (ii) Cyclic nucleo

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2

B., Chakravarty. "Substitution reactions of ligand bridged multinuclear complexes of platinum group metal ions." Journal of Indian Chemical Society Vol. 80, Apr 2003 (2003): 227–31. https://doi.org/10.5281/zenodo.5839342.

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Department of Chemistry, University of Kalyani, Kalyani-741 235, India <em>E-mail:</em> bnc@klyuniv.ernet.in <em>Manuscript received 11 September 2002</em> This review discusses the kinetic aspects of the substitutions in various ligand bridge multinuclear complexes of platinum group metal ions. The reactions have been categorized with various bridging bonds and metal ions acting as nuclei. Polymerization of complex compounds involves formation of multinuclear complexes. Kinetics and mechanistic features associated with all such reactions have been highlighted and discussed critically.

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3

Kostova, Irena. "Homo- and Hetero-Multinuclear Iridium(III) Complexes with Cytotoxic Activity." Inorganics 13, no. 5 (2025): 156. https://doi.org/10.3390/inorganics13050156.

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Towards the efforts to expand the bioactivity and to reduce toxic and adverse properties of known metal-based drugs, various multinuclear complexes have recently been studied. They have shown enhancement of target specificity and selectivity. Different from small organic compounds and traditional metal-based complexes with anticancer activity, iridium(III) multinuclear or heteronuclear metallodrugs have confirmed potential advantages due to their unique biological and chemical diversities, better activity and different anticancer mechanisms. Ir(III) coordination compounds, similar to most Pt g

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4

Yamazaki, Yasuomi, Tatsuki Morimoto, and Osamu Ishitani. "Synthesis of novel photofunctional multinuclear complexes using a coupling reaction." Dalton Transactions 44, no. 25 (2015): 11626–35. http://dx.doi.org/10.1039/c5dt01717c.

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5

Willcocks, Alexander M., Thomas P. Robinson, Christopher Roche, et al. "Multinuclear Copper(I) Guanidinate Complexes." Inorganic Chemistry 51, no. 1 (2011): 246–57. http://dx.doi.org/10.1021/ic201602m.

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6

Yuan, Guozan, Qi Zhang, Zhiping Wang, et al. "Assembly of four 8-quinolinate-based multinuclear complexes: the effect of substituents on core structures and photoluminescence properties." Inorganic Chemistry Frontiers 4, no. 5 (2017): 764–72. http://dx.doi.org/10.1039/c7qi00082k.

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Four multinuclear complexes with different core structures are synthesized. The core structures and photoluminescence properties of M(ii)–quinolinate complexes are controlled by the different substituent groups of ligands.

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7

Nath, Bikash Dev, Kazuto Takaishi, and Tadashi Ema. "Macrocyclic multinuclear metal complexes acting as catalysts for organic synthesis." Catalysis Science & Technology 10, no. 1 (2020): 12–34. http://dx.doi.org/10.1039/c9cy01894h.

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8

Pal Chaudhuri, Urmila, Laura R. Whiteaker, Lei Yang, and Robert P. Houser. "Multinuclear copper complexes of pyridylmethylamide ligands." Dalton Transactions, no. 15 (2006): 1902. http://dx.doi.org/10.1039/b513763b.

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9

Fedorov, Yu V., N. E. Shepel, O. Yu Kolosova, et al. "Multinuclear complexes of crown-containing monostyrylphenantrolines." Russian Chemical Bulletin 63, no. 10 (2014): 2271–80. http://dx.doi.org/10.1007/s11172-014-0734-0.

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10

Lange, Peter, Annette Schier, and Hubert Schmidbaur. "Dendrimer-Based Multinuclear Gold(I) Complexes." Inorganic Chemistry 35, no. 3 (1996): 637–42. http://dx.doi.org/10.1021/ic950644l.

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11

SCHREIBER, A., H. RAUTER, M. KRUMM, S. MENZER, E. C. HILLGERIS, and B. LIPPET. "ChemInform Abstract: Multinuclear Metal Nucleobase Complexes." ChemInform 26, no. 15 (2010): no. http://dx.doi.org/10.1002/chin.199515322.

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12

Yam, Vivian W. W., and Eddie C. C. Cheng. "Molecular Gold—Multinuclear Gold(I) Complexes." Angewandte Chemie 39, no. 23 (2000): 4240–42. http://dx.doi.org/10.1002/1521-3773(20001201)39:23<4240::aid-anie4240>3.0.co;2-d.

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13

Rohacova, Jana, and Osamu Ishitani. "Photofunctional multinuclear rhenium(i) diimine carbonyl complexes." Dalton Transactions 46, no. 28 (2017): 8899–919. http://dx.doi.org/10.1039/c7dt00577f.

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14

Patricio-Rangel, Emmanuel B., Verónica Salazar-Pereda, Omar Cortezano-Arellano, and Daniel Mendoza-Espinosa. "Multinuclear mesoionic 1,2,3-triazolylidene complexes: design, synthesis, and applications." Dalton Transactions 51, no. 7 (2022): 2641–51. http://dx.doi.org/10.1039/d1dt04221a.

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15

Zhang, Sihan, Rong Shang, Masaaki Nakamoto, Yohsuke Yamamoto, Yohei Adachi, and Joji Ohshita. "Bis(diphenylphosphinyl)-functionalized dipyrido-annulated NHC towards copper(i) and silver(i)." Dalton Transactions 48, no. 32 (2019): 12250–56. http://dx.doi.org/10.1039/c9dt02435b.

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16

Maity, Ramananda, Margarethe van der Meer, and Biprajit Sarkar. "Redox-active multinuclear Pd(ii) complexes with bis- and tris-mesoionic carbenes." Dalton Transactions 44, no. 1 (2015): 46–49. http://dx.doi.org/10.1039/c4dt03239j.

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17

Nierzwicki, L., M. Wieczor, V. Censi, et al. "Interaction of cisplatin and two potential antitumoral platinum(ii) complexes with a model lipid membrane: a combined NMR and MD study." Physical Chemistry Chemical Physics 17, no. 2 (2015): 1458–68. http://dx.doi.org/10.1039/c4cp04360j.

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18

Kennedy, Zachary C., Allan Jay P. Cardenas, Jordan F. Corbey, and Marvin G. Warner. "2,6-Diiminopiperidin-1-ol: an overlooked motif relevant to uranyl and transition metal binding on poly(amidoxime) adsorbents." Chemical Communications 52, no. 57 (2016): 8802–5. http://dx.doi.org/10.1039/c6cc02488b.

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19

Tabrizi, Leila, and Hossein Chiniforoshan. "The cytotoxicity and mechanism of action of new multinuclear Scaffold AuIII, PdIIpincer complexes containing a bis(diphenylphosphino) ferrocene/non-ferrocene ligand." Dalton Trans. 46, no. 41 (2017): 14164–73. http://dx.doi.org/10.1039/c7dt02887c.

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20

Das, Bishnu, and Parna Gupta. "Luminescent terpyridine appended geminal bisazide and bistriazoles: multinuclear Pt(ii) complexes and AIPE-based DNA detection with the naked eye." Dalton Transactions 50, no. 29 (2021): 10225–36. http://dx.doi.org/10.1039/d1dt01108a.

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Terpyridine appended stable gem-bistriazoles afford multinuclear platinum(ii) complexes upon reaction with Pt(dmso)<sub>2</sub>Cl<sub>2</sub>. Pt-complexes show excellent AIPE when interacts with ct-DNA. Naked eye DNA-detection is possible when exposed to 366 nm light.

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21

Matela, Garima, and Robina Aman. "Organotin(IV) complexes of carboxylic acid derivatives." Open Chemistry 10, no. 1 (2012): 1–15. http://dx.doi.org/10.2478/s11532-011-0107-6.

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AbstractA comprehensive review, >100 references, on organotin(IV) complexes of the carboxylic acid derivatives are presented with special reference to their methods of synthesis, spectroscopic and structural studies and their biological activities. The structures of these complexes are discussed on the basis of IR, multinuclear (1H-, 13C- and 119Sn-) NMR.

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22

Suter, Riccardo, Mona Wagner, Lorenzo Querci, Riccardo Conti, Zoltán Benkő, and Hansjörg Grützmacher. "1,3,4-Azadiphospholides as building blocks for scorpionate and bidentate ligands in multinuclear complexes." Dalton Transactions 49, no. 24 (2020): 8201–8. http://dx.doi.org/10.1039/d0dt01864c.

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23

Gorle, Anil K., Alaina J. Ammit, Lynne Wallace, F. Richard Keene, and J. Grant Collins. "Multinuclear ruthenium(ii) complexes as anticancer agents." New J. Chem. 38, no. 9 (2014): 4049–59. http://dx.doi.org/10.1039/c4nj00545g.

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The dinuclear ruthenium complex with X = H is four-times more cytotoxic than cisplatin against breast cancer cell lines; however, when X = NO<sub>2</sub> the ruthenium complex is less active than cisplatin.

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24

Merz, Kenneth M., and Roald Hoffmann. "d10-d10 Interactions: multinuclear copper(I) complexes." Inorganic Chemistry 27, no. 12 (1988): 2120–27. http://dx.doi.org/10.1021/ic00285a022.

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25

Izu, Hitoshi, Mio Kondo, Yutaka Saga, Hikaru Iwami, and Shigeyuki Masaoka. "Rational Synthetic Strategy for Heterometallic Multinuclear Complexes." Chemistry Letters 49, no. 2 (2020): 125–28. http://dx.doi.org/10.1246/cl.190815.

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26

Li, Lijuan, and Linlin Li. "Recent advances in multinuclear metal nitrosyl complexes." Coordination Chemistry Reviews 306 (January 2016): 678–700. http://dx.doi.org/10.1016/j.ccr.2015.03.026.

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27

Puttock, Emma V., Melissa T. Walden, and J. A. Gareth Williams. "The luminescence properties of multinuclear platinum complexes." Coordination Chemistry Reviews 367 (July 2018): 127–62. http://dx.doi.org/10.1016/j.ccr.2018.04.003.

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28

Oshio, Hiroki, and Masayuki Nihei. "Rational Syntheses of Multinuclear High-Spin Complexes." Bulletin of the Chemical Society of Japan 80, no. 4 (2007): 608–20. http://dx.doi.org/10.1246/bcsj.80.608.

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29

Frei, Angelo, Pennie P. Mokolokolo, Robin Bolliger, et al. "Self-Assembled Multinuclear Complexes Incorporating 99m Tc." Chemistry - A European Journal 24, no. 41 (2018): 10397–402. http://dx.doi.org/10.1002/chem.201800600.

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30

Wagner, Matthias. "A New Dimension in Multinuclear Metallocene Complexes." Angewandte Chemie International Edition 45, no. 36 (2006): 5916–18. http://dx.doi.org/10.1002/anie.200601787.

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31

Omorodion, Harrison, Miguel Palenzuela, Manuel Ruether, Brendan Twamley, James A. Platts, and Robert J. Baker. "A rationally designed perfluorinated host for the extraction of PFOA from water utilising non-covalent interactions." New Journal of Chemistry 42, no. 10 (2018): 7956–68. http://dx.doi.org/10.1039/c7nj03026f.

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32

Shi, Jian Yun, Peng Yun Chen, Ming Ze Wu, Li Tian, and Zhong Yi Liu. "Synthesis of a series of hetero-multi-spin Ln2Cu3 complexes based on a methyl-pyrazole nitronyl nitroxide radical with slow magnetic relaxation behaviors." Dalton Transactions 48, no. 25 (2019): 9187–93. http://dx.doi.org/10.1039/c9dt00981g.

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33

García, Cristina Murcia, Gregor Schnakenburg, and Rainer Streubel. "Study on the Acid-Induced Ring-Expansion of an Oxaphosphirane Complex with an Electron-Withdrawing C-Substituent." Australian Journal of Chemistry 70, no. 4 (2017): 442. http://dx.doi.org/10.1071/ch16609.

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A study on the acid-induced ring-expansion reaction of the first oxaphosphirane complexes bearing an electron-withdrawing C-substituent is described. The stereoselectively obtained 1,3,4-dioxaphospholane complexes 4a–c, representing the first examples of such fluorinated ligands, were unambiguously characterized by multinuclear NMR, elemental analysis, mass spectrometry, and single-crystal X-ray diffraction studies.

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34

Zhang, Ling-Juan, Yan-Hong Wang, Jie Liu, Mei-Chen Xu, and Xian-Ming Zhang. "Efficient and environmentally friendly Glaser coupling of terminal alkynes catalyzed by multinuclear copper complexes under base-free conditions." RSC Advances 6, no. 34 (2016): 28653–57. http://dx.doi.org/10.1039/c6ra01262k.

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An efficient catalytic system with multinuclear copper complexes as catalysts has been developed for the aerobic Glaser coupling reaction, which adopts environmentally friendly water as the solvent at room temperature under base-free condition.

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35

Vlahopoulou, G., S. Möller, J. Haak, et al. "Synthesis of Rh(iii) thiophosphinito pincer hydrido complexes by base-free C–H bond activation at room temperature." Chemical Communications 54, no. 49 (2018): 6292–95. http://dx.doi.org/10.1039/c8cc03913e.

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Rhodium(iii) thiophosphinito pincer hydrido complexes were synthesised by C–H activation under exceptionally mild conditions at room temperature without additional base or irradiation and fully characterised by multinuclear NMR spectroscopy and X-ray crystallography.

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36

Zhao, Jin'an, Kun Peng, Yan Guo, Jin Zhang, Shufang Chen, and Jiyong Hu. "Photoluminescent and cytotoxic properties of multinuclear complexes and multinuclear-based polymers with group 12 metals and a tripodal ligand." New Journal of Chemistry 39, no. 8 (2015): 6016–24. http://dx.doi.org/10.1039/c5nj00222b.

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37

Bickley, Jamie, Simon J. Higgins, and Annemarie A. La Pensée. "Homoleptic Rh(III)-Diphosphine and Rh(III)-Diarsine Complexes." Collection of Czechoslovak Chemical Communications 68, no. 8 (2003): 1461–66. http://dx.doi.org/10.1135/cccc20031461.

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The first examples of homoleptic diarsine and diphosphine coordination to Rh(III), viz. [Rh(1,2-C6H4{AsMe2}2)3]3+ and [Rh(Me2PCH2PMe2)3]3+, are reported, together with details of their characterisation by multinuclear NMR spectroscopy and mass spectrometry.

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38

Carravetta, Marina, Maria Concistre, William Levason, Gillian Reid, and Wenjian Zhang. "Unique Group 1 cations stabilised by homoleptic neutral phosphine coordination." Chemical Communications 51, no. 46 (2015): 9555–58. http://dx.doi.org/10.1039/c5cc03184b.

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A unique series of distorted octahedral Li<sup>+</sup> and Na<sup>+</sup> complexes with homoleptic coordination via three chelating neutral diphosphines is described, together with their crystallographic characterisation and solid state and solution multinuclear NMR properties.

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39

Yamazaki, Yasuomi, and Osamu Ishitani. "Selectivity control between Mizoroki–Heck and homo-coupling reactions for synthesising multinuclear metal complexes: unique addition effects of tertiary phosphines and O2." Dalton Transactions 46, no. 14 (2017): 4816–23. http://dx.doi.org/10.1039/c7dt00922d.

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Selectivity control between the Mizoroki–Heck and the homo-coupling reactions for synthesising multinuclear metal complexes could be achieved by using tertiary phosphines and air, which affected the particle size of Pd species as catalysts for the reactions.

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40

Haak, Robert M., Ana M. Castilla, Marta Martínez Belmonte, Eduardo C. Escudero-Adán, Jordi Benet-Buchholz, and Arjan W. Kleij. "Access to multinuclear salen complexes using olefin metathesis." Dalton Transactions 40, no. 13 (2011): 3352. http://dx.doi.org/10.1039/c0dt01411g.

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41

Wu, Xiao, Benjamin J. Peters, Christopher D. Rithner, and Debbie C. Crans. "Multinuclear NMR studies of aqueous vanadium–HEDTA complexes." Polyhedron 114 (August 2016): 325–32. http://dx.doi.org/10.1016/j.poly.2016.01.001.

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42

McMorran, David A., and Peter J. Steel. "New multinuclear zinc complexes with N4O2 coordination spheres." Inorganic Chemistry Communications 6, no. 1 (2003): 43–47. http://dx.doi.org/10.1016/s1387-7003(02)00677-9.

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43

McWilliams, Sean F., and Patrick L. Holland. "Dinitrogen Binding and Cleavage by Multinuclear Iron Complexes." Accounts of Chemical Research 48, no. 7 (2015): 2059–65. http://dx.doi.org/10.1021/acs.accounts.5b00213.

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44

Wong, Wai-Kwok, Xiaoping Yang, Richard A. Jones, et al. "Multinuclear Luminescent Schiff-Base Zn−Nd Sandwich Complexes." Inorganic Chemistry 45, no. 11 (2006): 4340–45. http://dx.doi.org/10.1021/ic051866e.

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45

Gupta, Gajendra, Abhishek Das, Junseong Lee, Nripendranath Mandal, and Chang Yeon Lee. "Multinuclear Ir-BODIPY complexes: Synthesis and binding studies." Inorganic Chemistry Communications 113 (March 2020): 107759. http://dx.doi.org/10.1016/j.inoche.2019.107759.

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46

Zheng, Tu Cai, William R. Cullen, and Steven J. Rettig. "Multinuclear Complexes Derived from Ferrocenylphosphines and Triruthenium Dodecacarbonyl." Organometallics 13, no. 9 (1994): 3594–604. http://dx.doi.org/10.1021/om00021a036.

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47

Gudat, Dietrich, Uwe Fischbeck, Frank Tabellion, Martin Billen, and Fritz Preuss. "Multinuclear magnetic resonance study of some imidovanadium complexes." Magnetic Resonance in Chemistry 40, no. 2 (2002): 139–46. http://dx.doi.org/10.1002/mrc.978.

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48

Nakajima, Takayuki, Kanako Nakamae, Yasuyuki Ura, and Tomoaki Tanase. "Multinuclear Copper Hydride Complexes Supported by Polyphosphine Ligands." European Journal of Inorganic Chemistry 2020, no. 23 (2020): 2211–26. http://dx.doi.org/10.1002/ejic.202000328.

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49

Yam, Vivian W. W., and Eddie C. C. Cheng. "ChemInform Abstract: Molecular Gold-Multinuclear Gold(I) Complexes." ChemInform 32, no. 6 (2001): no. http://dx.doi.org/10.1002/chin.200106221.

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50

Nabanita, Sadhukhan, Saha Sayantani, and K. Bera Jitendra. "Multinuclear complexes derived from bi-1,8-naphthyridine ligands." Journal of Indian Chemical Society Vol. 92, Dec 2015 (2015): 1957–64. https://doi.org/10.5281/zenodo.5602409.

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Department of Chemistry, Indian Institute of Technology Kanpur, Kanpur-208 016, Uttar Pradesh, India <em>E-mail</em> : jbera@iitk.ac.in 2,2´–Bis(1,8-naphthyridine) (NP<sub>2</sub> ) and 2´-methyl-2,3´-bi(1,8-naphthyridine) (MeNP<sub>2</sub> ) ligands have been synthesized via Friedlander condensation. NP<sub>2</sub> ligand displays chelate, bridge as well as bridge-chelate binding modes with metal ions. Mononuclear [Co(NP<sub>2</sub> )Cl<sub>2</sub> ] (1) was isolated in the reaction of CoCl<sub>2</sub> with NP<sub>2</sub> . Use of diruthenium(II) [Ru<sub>2</sub> (CH<su

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