Academic literature on the topic 'Multivalent-Ion'

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Journal articles on the topic "Multivalent-Ion"

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Proffit, Danielle L., Albert L. Lipson, Baofei Pan, et al. "Reducing Side Reactions Using PF6-based Electrolytes in Multivalent Hybrid Cells." MRS Proceedings 1773 (2015): 27–32. http://dx.doi.org/10.1557/opl.2015.590.

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ABSTRACTThe need for higher energy density batteries has spawned recent renewed interest in alternatives to lithium ion batteries, including multivalent chemistries that theoretically can provide twice the volumetric capacity if two electrons can be transferred per intercalating ion. Initial investigations of these chemistries have been limited to date by the lack of understanding of the compatibility between intercalation electrode materials, electrolytes, and current collectors. This work describes the utilization of hybrid cells to evaluate multivalent cathodes, consisting of high surface a
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Greene, Samuel M., and Donald J. Siegel. "Computational Investigations of Features for Predicting Ionic Conductivity in Multivalent Solid Electrolytes." ECS Meeting Abstracts MA2024-02, no. 9 (2024): 1428. https://doi.org/10.1149/ma2024-0291428mtgabs.

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A significant challenge hindering the development of batteries based on the redox of multivalent ions is the sluggish mobility of such ions in most solids. Computational methods for efficiently predicting conductivity can accelerate the discovery of faster ion conductors. Direct first-principles calculations of conductivity are expensive and difficult to automate, which has prompted a search for other properties related to conductivity that are easier to calculate or measure. Previous studies have identified features related to the electronic charge density and phonon spectrum that are correla
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Rutt, Ann, and Kristin A. Persson. "Expanding the Materials Search Space for Multivalent Cathodes." ECS Meeting Abstracts MA2022-02, no. 4 (2022): 446. http://dx.doi.org/10.1149/ma2022-024446mtgabs.

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Multivalent batteries are an energy storage technology with the potential to surpass lithium-ion batteries, however their performance has been limited by the low voltages and poor solid-state ionic mobility of available cathodes. A computational screening approach to identify high-performance multivalent intercalation cathodes among materials that do not contain the working ion of interest has been developed which greatly expands the search space that can be considered for materials discovery. This approach has been applied to magnesium cathodes as a proof of concept and resulting candidate ma
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Iton, Zachery W. B., and Kimberly A. See. "Multivalent Ion Conduction in Inorganic Solids." Chemistry of Materials 34, no. 3 (2022): 881–98. http://dx.doi.org/10.1021/acs.chemmater.1c04178.

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Palacin, M. Rosa, Patrik Johansson, Robert Dominko, et al. "Roadmap on Multivalent Batteries." JPhys Energy 6, no. 3 (2024): 031501. https://doi.org/10.1088/2515-7655/ad34fc.

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Battery technologies based in multivalent charge carriers with ideally two or three electrons transferred per ion exchanged between the electrodes have large promises in raw performance numbers, most often expressed as high energy density, and are also ideally based on raw materials that are widely abundant and less expensive. Yet, these are still globally in their infancy, with some concepts (e.g., Mg metal) being more technologically mature. The challenges to address are derived on one side from the highly polarizing nature of multivalent ions when compared to single valent concepts such as
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Dong, Liubing, Wang Yang, Wu Yang, Yang Li, Wenjian Wu, and Guoxiu Wang. "Multivalent metal ion hybrid capacitors: a review with a focus on zinc-ion hybrid capacitors." Journal of Materials Chemistry A 7, no. 23 (2019): 13810–32. http://dx.doi.org/10.1039/c9ta02678a.

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Gates, Leslie, and Niya Sa. "Investigation of Suitability of Electrolytes in a Trivalent System." ECS Meeting Abstracts MA2023-01, no. 1 (2023): 425. http://dx.doi.org/10.1149/ma2023-011425mtgabs.

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As lithium-ion batteries (LIB) start to approach their theoretical limit, researchers are focusing on alternatives such as nonaqueous multivalent systems. There are many advantages of multivalent systems such as higher natural abundance, low cost and possible high volumetric capacity. Suitable electrolytes are vital for the development of such multivalent battery systems which offer compatibility of utilizing metal anode. To create a better understanding of the opportunities and challenges of the trivalent electrolytes in aluminum batteries, this work investigates the reaction mechanisms and S
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Li, Zhong-Qiu, Yang Wang, Zeng-Qiang Wu, Ming-Yang Wu, and Xing-Hua Xia. "Bioinspired Multivalent Ion Responsive Nanopore with Ultrahigh Ion Current Rectification." Journal of Physical Chemistry C 123, no. 22 (2019): 13687–92. http://dx.doi.org/10.1021/acs.jpcc.9b02279.

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Hasnat, Abul, and Vinay A. Juvekar. "Dynamics of ion-exchange involving multivalent cations." Chemical Engineering Science 52, no. 14 (1997): 2439–42. http://dx.doi.org/10.1016/s0009-2509(97)00047-x.

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KC, Bilash, Jinglong Guo, Robert Klie, et al. "TEM Analysis of Multivalent Ion Battery Cathode." Microscopy and Microanalysis 26, S2 (2020): 3170–72. http://dx.doi.org/10.1017/s1431927620024058.

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Dissertations / Theses on the topic "Multivalent-Ion"

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Keyzer, Evan. "Development of electrolyte salts for multivalent ion batteries." Thesis, University of Cambridge, 2019. https://www.repository.cam.ac.uk/handle/1810/288431.

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This dissertation focuses on the synthesis and electrochemical testing of new electrolyte salts for rechargeable multivalent ion batteries. In chapters 2 and 3 the synthesis of Mg and Ca hexafluoropnictogenate salts as well as the electrochemical behaviour of Mg(PF6)2 is presented. Pure samples of Mg(EF6)2 (E = P, As, and Sb) can be synthesized using Mg metal and NOPF6/NOSbF6 in CH3CN or via a ammonium salt deprotonation route using Me3NHAsF6 and Bu2Mg. The NOPF6 method was extended to the Ca variant, but isolation of a pure Ca(PF6)2 material required the presence of a crown ether. Electrochem
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Li, Na. "Aluminum intercalation behaviours of Molecular Materials." Electronic Thesis or Diss., Sorbonne université, 2024. https://accesdistant.sorbonne-universite.fr/login?url=https://theses-intra.sorbonne-universite.fr/2024SORUS222.pdf.

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Le premier chapitre introduit le concept et les caractéristiques fondamentales des matériaux moléculaires. Il met en évidence leurs vastes applications et les avantages qu'ils offrent dans les dispositifs électrochimiques, ainsi qu'un aperçu de leur développement dans ce domaine. Ensuite, les matériaux moléculaires sont classés de trois manières distinctes selon différents critères. Les sous-catégories de chaque classification sont systématiquement expliquées, mettant en lumière différents aspects des matériaux moléculaires selon la méthode de classification.À partir des batteries à ions multi
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Wu-Tiu-Yen, Jenny. "Valorisation de la vinasse de canne à sucre : étude d'un procédé d'extraction d'un acide organique multivalent." Thesis, Université Paris-Saclay (ComUE), 2017. http://www.theses.fr/2017SACLA008.

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La vinasse de distillerie, co-produit de l’industrie canne-sucre-alcool-énergie, contient de 5 à 7 g/L d’un acide d’intérêt, l’acide aconitique, au sein d’un milieu complexe comportant d’autres acides organiques, des acides aminés, mais surtout des sels minéraux (chlorures et sulfates) et des colorants, rendant sa purification complexe. Afin d’améliorer les performances du procédé d’échange d’ions, au coeur de cette purification, la résine anionique faible Lewatit S4528 a été caractérisée. Le dosage de la résine et des mesures d’isothermes d’échange d’ions ont permis de définir : la capacité t
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Book chapters on the topic "Multivalent-Ion"

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Elia, Giuseppe Antonio, Muhammad E. Abdelhamid, Jun Ming, and Piotr Jankowski. "Application of nanotechnology in multivalent ion-based batteries." In Frontiers of Nanoscience. Elsevier, 2021. http://dx.doi.org/10.1016/b978-0-12-821434-3.00011-9.

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Das, Himadri Sekhar, Sudipta Banerjee, Heranmoy Maity, and Gourisankar Roymahapatra. "Battery Chemistry Li-ion Solid-State and Beyond." In Sustainable Chemistry and Pioneering Green Engineering Solutions. IGI Global, 2025. https://doi.org/10.4018/979-8-3373-1409-9.ch003.

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Battery chemistry has undergone a transformative journey, propelling advancements in energy storage technologies that are pivotal to modern applications. This chapter delves into the evolution and comparative analysis of lithium-ion (Li-ion) batteries, solid-state batteries, and emerging alternatives. Li-ion batteries, known for their high energy density and longevity, have dominated the energy storage market, yet face challenges such as safety concerns and resource dependency. Solid-state batteries, featuring non-flammable solid electrolytes, promise enhanced safety, higher energy densities,
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Abe, Mitsuo. "Oxides And Hydrous Oxides Of Multivalent Metals As Inorganic Ion Exchangers." In Inorganic Ion Exchange Materials. CRC Press, 2018. http://dx.doi.org/10.1201/9781351073561-6.

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Alkhayer, Ghaidaa. "Alginate Metal Complexes and Their Application." In Properties and Applications of Alginates [Working Title]. IntechOpen, 2021. http://dx.doi.org/10.5772/intechopen.98885.

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Alginate is a natural polymer that can form complexes in the presence of multivalent metal. In this chapter, we summarized the newest alginate metal complexes application in many fields; organic synthesis, environmental and medical application. The main idea was about alginate complexes’ role in the drug delivery system as a chiral excipient to reach the enantioselective release in the case of chiral drugs. We also present a case study about the ketoprofen enantioselective release investigation from alginate mixed beads with two ion metal types.
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Hossain, Mohammad. "Inorganic Mesoporous Materials for Sorption of Heavy Metal Ions." In Materials Research Foundations. Materials Research Forum LLC, 2025. https://doi.org/10.21741/9781644903452-1.

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In this chapter, we consider typical inorganic mesoporous materials, which are widely used for sorption of heavy metal ions: hydrophosphates, hydrous oxides and double hydroxides of multivalent metals, and also zeolites. Oxidized graphene and its composites with these inorganic substances are also in a focus of attention. Composites based on ion exchange resins modified with mentioned inorganic compounds are discussed, since this type of polymers is also related to mesoporous materials, when they are in a swollen state. Embedded inorganic particles (non-aggregated nanoparticles, aggregates or
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Schmickler, Wolfgang. "Metal deposition and dissolution." In Interfacial Electrochemistry. Oxford University Press, 1996. http://dx.doi.org/10.1093/oso/9780195089325.003.0015.

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On a liquid metal electrode all surface sites are equivalent, and the deposition of a metal ion from the solution is conceptually simple: The ion loses a part of its solvation sheath, is transferred to the metal surface, and is discharged simultaneously; after a slight rearrangement of the surface atoms it is incorporated into the electrode. The details of the process are little understood, but it seems that the discharge step is generally rate determining, and the Butler-Volmer equation is obeyed if the concentration of the supporting electrolyte is sufficiently high. For example, the formati
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Płocharski, Janusz. "Multivalent Cation Systems: Electrolytes for Magnesium Batteries." In Designing Electrolytes for Lithium-Ion and Post-Lithium Batteries. Jenny Stanford Publishing, 2021. http://dx.doi.org/10.1201/9781003050933-7.

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Piszcz, Michał, and Maciej Siekierski. "Multivalent Cation Systems: Toward Aluminum, Zinc, and Calcium Batteries." In Designing Electrolytes for Lithium-Ion and Post-Lithium Batteries. Jenny Stanford Publishing, 2021. http://dx.doi.org/10.1201/9781003050933-8.

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Conference papers on the topic "Multivalent-Ion"

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Porter, R. L., and B. J. Saldanha. "Effect of Fe(III) Levels on the Corrosion Resistance of Titanium Alloys in HCl Solutions." In CORROSION 2003. NACE International, 2003. https://doi.org/10.5006/c2003-03453.

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Abstract Corrosion tests were run concurrently at Location A and Location B to determine the effects of ferric ion [Fe(III)] content on inhibiting general corrosion of titanium Grades 2 (UNS R50400), 7 (UNS R52400), 12 (UNS R53400), 16 (UNS R52402), 27 (UNS R52254), and 28 (UNS R56323) in hydrochloric acid (HCl) solutions at 66-282°C. Tests were conducted at Location A with 1,000 and 10,000 ppm Fe(III) additions to boiling HCl solutions to establish 5 mpy isocorrosion diagrams as an extension of previous work(1). Location A tests also assessed the effects of higher temperatures (282°C) on the
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Wei, Zhenqiang, Paul Duby, and Ponisseril Somasundaran. "Surfactants as Green Inhibitors for Pitting Corrosion of Stainless Steels." In CORROSION 2004. NACE International, 2004. https://doi.org/10.5006/c2004-04539.

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Abstract Recently sodium dodecylsulfate (SDS) and some other surfactants have been shown to be promising inhibitors for the pitting corrosion of stainless steels and aluminum alloys in chloride media. In the present research, the effect of other compounds such as multivalent metal cations and other surfactants on the pitting inhibition of 304 stainless steel by SDS was investigated to determine its inhibition behavior in relevant mixed systems. It was shown that calcium ion increased the pitting inhibition efficiency of SDS. The efficiency increase was attributed to the increased SDS adsorptio
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Tan, Qiyan, Weichuan Guo, Gutian Zhao, Yajing Kan, Yinghua Qiu, and Yunfei Chen. "Charge Inversion of Mica Surface in Multivalent Electrolytes." In ASME 2013 International Mechanical Engineering Congress and Exposition. American Society of Mechanical Engineers, 2013. http://dx.doi.org/10.1115/imece2013-62356.

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Interaction between solid surfaces in aqueous electrolyte solutions is of great importance to many diverse domains, such as bioMEMS, nanofluidics, colloid science, polymer physics, and molecular biophysics. Several counterintuitive phenomena occur at high concentrations of multivalent ions. In this article, charge reversion, the sign reversal of the effective surface charge in the presence of multivalent counterions, is directly observed through the force between two mica surfaces in aqueous solutions of trivalent cations by surface forces measurements. The effective surface potential function
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Oh, K., U. C. Paek, and T. F. Morse. "Photosensitivity in multi-valent rare earth ion doped aluminosilicate glass optical fiber." In Bragg Gratings, Photosensitivity, and Poling in Glass Fibers and Waveguides. Optica Publishing Group, 1997. http://dx.doi.org/10.1364/bgppf.1997.jsue.18.

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Multivalent rare earth ion, Sm+2/Sm+3 was incorporated into aluminosilicate glass fiber using an aerosol delivery technique. Co-doping of trivalent and divalent states of the ions has been spectroscopically confirmed. Irradiated by multi-line CW Ar ion laser of 1 Watt, the fiber showed photoinduced refractive change of 7.6 × 10−5. Bleaching of Sm+2 absorption band was also observed. Photoionization of Sm+2 is believed to be a main cause of the photosensitivity.
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Lapitsky, Yakov, Sabrina Alam, Udaka de Silva, Jennifer Brown, Carolina Mather, and Youngwoo Seo. "Surfactant-loaded Polyelectrolyte/multivalent Ion Coacervates for the Multi-month Release of Antibacterial and Therapeutic Payloads." In Virtual 2021 AOCS Annual Meeting & Expo. American Oil Chemists' Society (AOCS), 2021. http://dx.doi.org/10.21748/am21.267.

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Feldmann, Felix, Emad W. Al-Shalabi, and Waleed AlAmeri. "Carbonate Mineral Effect on Surface Charge Change During Low-Salinity Imbibition." In SPE Annual Technical Conference and Exhibition. SPE, 2021. http://dx.doi.org/10.2118/206013-ms.

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Abstract Low-salinity waterflooding is a relatively simple and cheap improved oil recovery technique in which the reservoir salinity is optimized to increase oil recovery. Multivalent ion enriched as well as diluted brines have shown promising potential to increase oil production over conventional waterflooding. While the literature generally acknowledges that low-salinity improves oil recovery, the physical mechanisms behind low-salinity effects are still controversial. Surface charge change refers to a low-salinity mechanism in which modified brine is believed to cause a re-equilibrium of th
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