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Journal articles on the topic 'Mutarotation of Glucose'

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Published: 5 June 2025
Last updated: 1 August 2025

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1

Dujardin, N., E. Dudognon, J. F. Willart, et al. "Solid State Mutarotation of Glucose." Journal of Physical Chemistry B 115, no. 7 (2011): 1698–705. http://dx.doi.org/10.1021/jp109382j.

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2

Yamabe, Shinichi, and Taikei Ishikawa. "Theoretical Study of Mutarotation of Glucose." Journal of Organic Chemistry 64, no. 12 (1999): 4519–24. http://dx.doi.org/10.1021/jo9815453.

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3

Vala, Daniel, Martin Mičica, Daniel Cvejn, and Kamil Postava. "Broadband Mueller ellipsometer as an all-in-one tool for spectral and temporal analysis of mutarotation kinetics." RSC Advances 13, no. 10 (2023): 6582–92. http://dx.doi.org/10.1039/d3ra00101f.

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4

Shipunov, Boris Pavlovich, and Andrey Valerievich Ryabykh. "EFFECT OF HIGH-FREQUENCY ELECTROMAGNETIC FIELD ON THE MUTAROTATION OF AQUEOUS SOLU-TIONS OF GLUCOSE AND FRUCTOSE." chemistry of plant raw material, no. 3 (May 15, 2019): 235–40. http://dx.doi.org/10.14258/jcprm.2019034456.

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The indirect influence of the high-frequency electromagnetic field of the 30–200 MHz low power range on the reaction rate of the mutation of D-glucose solutions and on the equilibrium in D-fructose and D-glucose solutions was studied. Solutions were prepared using both deionized water and water exposed to a high-frequency electromagnetic field. Control of the process of mutarotation was carried out polarimetrically. To assess the effectiveness of field exposure, the effective constants of the reaction rate of mutarotation were calculated. It has been established that the rate of mutarotation o
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5

Hossain, Mohammad, Noortaz Chowdhury, Amiya Atahar, and Md Abu Bin Hasan Susan. "Water structure modification by d-(+)-glucose at different concentrations and temperatures-effect of mutarotation." RSC Advances 13, no. 28 (2023): 19195–206. http://dx.doi.org/10.1039/d3ra03081d.

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6

Panov, M. Yu, and O. B. Sokolova. "Kinetics of glucose mutarotation in aqueous isopropanol." Russian Journal of General Chemistry 74, no. 9 (2004): 1451–53. http://dx.doi.org/10.1007/s11176-005-0030-7.

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7

Ramesh, Pranav, Athanasios Kritikos, and George Tsilomelekis. "Effect of metal chlorides on glucose mutarotation and possible implications on humin formation." Reaction Chemistry & Engineering 4, no. 2 (2019): 273–77. http://dx.doi.org/10.1039/c8re00233a.

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An in situ Raman spectroscopic kinetic study of the glucose mutarotation reaction in the presence of Lewis acids is presented herein. The effect of Lewis acids on humin formation reactions is also discussed.
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8

Ozawa, Sentaro, Jiro Nakatani, Masanori Sato та Yoshisada Ogino. "Mutarotation of α-D-Glucose over Several Al2O3Catalysts". Bulletin of the Chemical Society of Japan 60, № 12 (1987): 4273–78. http://dx.doi.org/10.1246/bcsj.60.4273.

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9

Panov, M. Yu, and O. B. Sokolova. "Kinetics of Glucose Mutarotation in Aqueous Urea Solutions." Russian Journal of General Chemistry 73, no. 12 (2003): 1914–18. http://dx.doi.org/10.1023/b:rugc.0000025153.17060.6f.

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10

Vogel, J., G. Westphal, and C. Pippig. "Mutarotation von D-Glucose in Abhängigkeit vom Reaktionsmilieu." Food / Nahrung 32, no. 7 (1988): 709–14. http://dx.doi.org/10.1002/food.19880320716.

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11

Silva, Alexander M., Edilson C. da Silva, and Clarissa O. da Silva. "A theoretical study of glucose mutarotation in aqueous solution." Carbohydrate Research 341, no. 8 (2006): 1029–40. http://dx.doi.org/10.1016/j.carres.2006.02.035.

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12

Syroeshkin, A. V., T. V. Pleteneva, E. V. Uspenskaya, et al. "POLARIMETRIC RESEARCH OF PHARMACEUTICAL SUBSTANCES IN AQUEOUS SOLUTIONS WITH DIFFERENT WATER ISOTOPOLOGUES RATIO." International Journal of Applied Pharmaceutics 10, no. 5 (2018): 243. http://dx.doi.org/10.22159/ijap.2018v10i5.28151.

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Objective: Methodology development for quality control of optically active pharmaceutical substances based on water isotopologues.Methods: Solutions of L-ascorbic acid, glucose, galactose and valine stereoisomers were prepared using deuterium depleted water (DDW-«light» water, D/H=4 ppm), natural deionized high-ohmic water (BD, D/H=140 ppm), heavy water (99.9% D2O). The optical rotation was observed using an automatic polarimeter Atago POL-1/2. The size distribution of giant heterogeneous clusters (GHC) of water was recorded by low angle laser light scattering (LALLS) method.Results: The infri
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13

ARAI, Kenichiro. "Mutarotation of .ALPHA.-D-Glucose in Aqueous Solution of Boric Acid." NIPPON KAGAKU KAISHI, no. 8 (1992): 830–33. http://dx.doi.org/10.1246/nikkashi.1992.830.

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14

OKUDA, JUN, TADAO TAGUCHI, and AIKO TOMIMURA. "Mutarotation of D-glucose in body fluids and perfused rat liver." CHEMICAL & PHARMACEUTICAL BULLETIN 35, no. 10 (1987): 4332–37. http://dx.doi.org/10.1248/cpb.35.4332.

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15

Massoui, M., D. Beaupere, G. Goethals, and R. Uzan. "Oxydation de glucides: mutarotation catalytique du D-glucose en milieu aprotique." Journal of Molecular Catalysis 29, no. 1 (1985): 7–12. http://dx.doi.org/10.1016/0304-5102(85)85125-7.

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16

Los, J. M., and L. B. Simpson. "The mutarotation and ionization of D-glucose in alkaline solution II." Recueil des Travaux Chimiques des Pays-Bas 76, no. 4 (2010): 267–85. http://dx.doi.org/10.1002/recl.19570760404.

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17

Stults, C. L. M., A. P. Wade, and S. R. Crouch. "Immobilized enzyme kinetic study of D-glucose mutarotation by flow injection analysis." Analytical Chemistry 59, no. 18 (1987): 2245–47. http://dx.doi.org/10.1021/ac00145a007.

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18

Wlodarczyk, P., M. Paluch, A. Wlodarczyk, and M. Hyra. "A mutarotation mechanism based on dual proton exchange in the amorphous d-glucose." Physical Chemistry Chemical Physics 16, no. 10 (2014): 4694. http://dx.doi.org/10.1039/c3cp54833c.

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19

Lin, Chu-En, Chih-Jen Yu, Chuan-Lin Chen, Li-Dek Chou, and Chien Chou. "Kinetics of Glucose Mutarotation Assessed by an Equal-Amplitude Paired Polarized Heterodyne Polarimeter." Journal of Physical Chemistry A 114, no. 4 (2010): 1665–69. http://dx.doi.org/10.1021/jp906523s.

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20

Perles, Carlos E., and Pedro L. O. Volpe. "A Simple Laboratory Experiment To Determine the Kinetics of Mutarotation of D-Glucose Using a Blood Glucose Meter." Journal of Chemical Education 85, no. 5 (2008): 686. http://dx.doi.org/10.1021/ed085p686.

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21

Achs, M. J., and D. Garfinkel. "Pancreatic islet discrimination of hexose anomers. II. Transient computer simulation." American Journal of Physiology-Endocrinology and Metabolism 255, no. 2 (1988): E201—E205. http://dx.doi.org/10.1152/ajpendo.1988.255.2.e201.

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We have previously modeled pancreatic islet glycolysis under idealized steady-state conditions where the input is a pure hexose anomer and there is no mutarotation and reproduced the known preference for the alpha-anomers of glucose and mannose as substrates. This model is here extended to simulate real experiments, where the hexoses mutarotate and measurements may be taken over time. The behavior of our model system agrees with available experimental data. The hexose diphosphate activators of phosphofructokinase, whose effect was seen as not important in the preceding steady-state analysis, a
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22

Lamelas, F. J. "Compressed-tube pressure cell for optical studies at ocean pressures: Application to glucose mutarotation kinetics." Review of Scientific Instruments 87, no. 12 (2016): 124101. http://dx.doi.org/10.1063/1.4971417.

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23

Hardee, John R., Bryan Delgado, and Wray Jones. "Kinetic Parameters for the Noncatalyzed and Enzyme-Catalyzed Mutarotation of Glucose Using a Blood Glucometer." Journal of Chemical Education 88, no. 6 (2011): 798–800. http://dx.doi.org/10.1021/ed101079k.

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24

Pagnotta, M., C. L. F. Pooley, B. Gurland, and M. Choi. "Microwave activation of the mutarotation of ?-D-glucose: An example of an interinsic microwave effect." Journal of Physical Organic Chemistry 6, no. 7 (1993): 407–11. http://dx.doi.org/10.1002/poc.610060705.

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25

Dona, Anthony C., Guilhem Pages, and Philip W. Kuchel. "Kinetics of starch hydrolysis and glucose mutarotation studied by NMR chemical exchange saturation transfer (CEST)." Carbohydrate Polymers 86, no. 4 (2011): 1525–32. http://dx.doi.org/10.1016/j.carbpol.2011.06.056.

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26

SATO, Masanori, Jiro NAKATANI, Sentaro OZAWA, and Yoshisada OGINO. "Pressure effects upon heterogeneous liquid phase catalysis - Mutarotation of .ALPHA.-D-glucose over an alumina catalyst." NIPPON KAGAKU KAISHI, no. 11 (1988): 1794–99. http://dx.doi.org/10.1246/nikkashi.1988.1794.

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27

Le Barc'H, N., J. M. Grossel, P. Looten, and M. Mathlouthi. "Kinetic study of the mutarotation of D-glucose in concentrated aqueous solution by gas-liquid chromatography." Food Chemistry 74, no. 1 (2001): 119–24. http://dx.doi.org/10.1016/s0308-8146(01)00139-x.

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28

Murdock, Margaret, R. W. Holman, Tyler Slade, Shelley L. D. Clark, and Kenneth J. Rodnick. "An Introductory Organic Chemistry Review Homework Exercise: Deriving Potential Mechanisms for Glucose Ring Opening in Mutarotation." Journal of Chemical Education 91, no. 12 (2014): 2146–47. http://dx.doi.org/10.1021/ed500307d.

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29

Imamura, Akira, Toshiya Okajima, and Katsuya Kanda. "A Molecular Orbital Approach to the Effect of Acid and Base on Mutarotation of D-Glucose." Bulletin of the Chemical Society of Japan 59, no. 3 (1986): 943–45. http://dx.doi.org/10.1246/bcsj.59.943.

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30

Awichi, Aminiel, Eric M. Tee, Giri Srikanthan, and Wei Zhao. "Identification of Overlapped Near-Infrared Bands of Glucose Anomers Using Two-Dimensional Near-Infrared and Middle-Infrared Correlation Spectroscopy." Applied Spectroscopy 56, no. 7 (2002): 897–901. http://dx.doi.org/10.1366/000370202760171572.

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Near-infrared (NIR) spectroscopy is a useful tool in determining glucose in biological matrices. Because α-anomers and β-anomers of glucose are in equilibrium in the solution, the observed NIR bands may come from the overlapping of vibrational modes of the anomers. We have conducted NIR and mid-infrared (MIR) absorption spectra measurements to determine the nature of the observed NIR features by using two-dimensional (2D) NIR and MIR correlation spectroscopy. The 2D NIR correlation spectra and 2D synchronous NIR and MIR correlation heterospectra are constructed based on the spectral changes of
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31

Bethell, Donald, Peter J. Galsworthy, and Keith Jones. "Mutarotation of glucose derivatives in solutions of surfactants in organic solvents: co-operativity and bimodal catalytic behaviour." Journal of the Chemical Society, Perkin Transactions 2, no. 12 (1988): 2035. http://dx.doi.org/10.1039/p29880002035.

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32

Abayakoon, Palika, James P. Lingford, Yi Jin, et al. "Discovery and characterization of a sulfoquinovose mutarotase using kinetic analysis at equilibrium by exchange spectroscopy." Biochemical Journal 475, no. 7 (2018): 1371–83. http://dx.doi.org/10.1042/bcj20170947.

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Bacterial sulfoglycolytic pathways catabolize sulfoquinovose (SQ), or glycosides thereof, to generate a three-carbon metabolite for primary cellular metabolism and a three-carbon sulfonate that is expelled from the cell. Sulfoglycolytic operons encoding an Embden–Meyerhof–Parnas-like or Entner–Doudoroff (ED)-like pathway harbor an uncharacterized gene (yihR in Escherichia coli; PpSQ1_00415 in Pseudomonas putida) that is up-regulated in the presence of SQ, has been annotated as an aldose-1-epimerase and which may encode an SQ mutarotase. Our sequence analyses and structural modeling confirmed t
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33

Libnau, Fred O., Alfred A. Christy, and Olav M. Kvalheim. "Resolution of infrared spectra and kinetic analysis of mutarotation of d-glucose in water by sequential rank analysis." Vibrational Spectroscopy 7, no. 2 (1994): 139–48. http://dx.doi.org/10.1016/0924-2031(94)85024-0.

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34

Arai, Kenichiro. "Preparation of poly(4-vinyl-2-hydroxypyridine) and its catalytic activity on mutarotation of 2,3,4,6-tetramethyl-α-D-glucose". Journal of Polymer Science Part A: Polymer Chemistry 31, № 1 (1993): 193–97. http://dx.doi.org/10.1002/pola.1993.080310123.

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35

Xu, Yuanpeng, Yunhuan Zhang, Jinyin Zhu, et al. "Phytophthora sojae apoplastic effector AEP1 mediates sugar uptake by mutarotation of extracellular aldose and is recognized as a MAMP." Plant Physiology 187, no. 1 (2021): 321–35. http://dx.doi.org/10.1093/plphys/kiab239.

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Abstract Diseases caused by Phytophthora pathogens devastate many crops worldwide. During infection, Phytophthora pathogens secrete effectors, which are central molecules for understanding the complex plant–Phytophthora interactions. In this study, we profiled the effector repertoire secreted by Phytophthora sojae into the soybean (Glycine max) apoplast during infection using liquid chromatography–mass spectrometry. A secreted aldose 1-epimerase (AEP1) was shown to induce cell death in Nicotiana benthamiana, as did the other two AEP1s from different Phytophthora species. AEP1 could also trigge
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36

Mitzner, Rolf, Ekkehard Behrenwald, Karl-Friedrich Lüssow та Hans Rieche. "Die Bestimmung der Geschwindigkeitskonstanten für die Hin- und Rückreaktion bei der Mutarotation von α-D-Glucose in 70%igem Dioxan". Zeitschrift für Chemie 15, № 6 (2010): 230–31. http://dx.doi.org/10.1002/zfch.19750150616.

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37

Noda, Isao. "Two-dimensional correlation and codistribution spectroscopy (2DCOS and 2DCDS) analyses of time-dependent ATR IR spectra of d-glucose anomers undergoing mutarotation process in water." Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy 197 (May 2018): 4–9. http://dx.doi.org/10.1016/j.saa.2017.09.052.

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38

Rivlin, Michal, and Gil Navon. "3-O-Methyl-d-glucose mutarotation and proton exchange rates assessed by 13C, 1H NMR and by chemical exchange saturation transfer and spin lock measurements." Journal of Biomolecular NMR 72, no. 1-2 (2018): 93–103. http://dx.doi.org/10.1007/s10858-018-0209-y.

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39

Bailly, Christian, Xavier Thuru та Bruno Quesnel. "Modulation of the Gal-9/TIM-3 Immune Checkpoint with α-Lactose. Does Anomery of Lactose Matter?" Cancers 13, № 24 (2021): 6365. http://dx.doi.org/10.3390/cancers13246365.

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The disaccharide lactose is an excipient commonly used in pharmaceutical products. The two anomers, α- and β-lactose (α-L/β-L), differ by the orientation of the C-1 hydroxyl group on the glucose unit. In aqueous solution, a mutarotation process leads to an equilibrium of about 40% α-L and 60% β-L at room temperature. Beyond a pharmaceutical excipient in solid products, α-L has immuno-modulatory effects and functions as a major regulator of TIM-3/Gal-9 immune checkpoint, through direct binding to the β-galactoside-binding lectin galectin-9. The blockade of the co-inhibitory checkpoint TIM-3 exp
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40

Dunstan, T. Don John, and Richard E. Pincock. "Heterogeneous catalysis of glucose mutarotation by alumina in dimethyl sulfoxide. 2. Catalytic activity of various aluminas, effects of inhibitors, and the acid/base properties of the active sites." Journal of Organic Chemistry 50, no. 6 (1985): 863–66. http://dx.doi.org/10.1021/jo00206a028.

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41

Penkov, Nikita V. "Application of Terahertz Time-Domain Spectroscopy to Study the Microheterogeneities of Solutions: A Case Study of Aqueous Sugar Solutions." Photonics 10, no. 8 (2023): 887. http://dx.doi.org/10.3390/photonics10080887.

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The phenomenon of the formation of microheterogeneities (MHs) in solutions, which, according to chemical handbooks, are considered true solutions, has been known for a long time. MHs have been found in more than 100 binary solutions, many of which are used both in various scientific studies and in life. However, the nature of this phenomenon is largely unclear. It is only well-known that MHs are stable areas of increased concentration of one of the components of the solution. The main reason for the poor knowledge of MHs is the use of very few experimental methods, mainly light scattering meth
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42

Parra-Santamaria, Maider, Aran Insausti, Elena R. Alonso, Francisco J. Basterretxea, and Emilio J. Cocinero. "Structural effects of oxidation on sugars: glucose as a precursor of gluconolactone and glucuronolactone." Chemical Communications, 2024. http://dx.doi.org/10.1039/d4cc00735b.

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This atomic-resolution study reveals glucose changes due to oxidation, exploring key carbohydrate aspects like hydrogen bonding, ring-puckering, anomeric effect, and tautomeric selection. Results confirm mutarotation suppression in the gas phase.
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43

LEVITSKAYA, OLGA V., TATIANA V. PLETENEVA, DARIA A. GALKINA, NADEZDA A. KHODOROVICH, ELENA V. USPENSKAYA, and ANTON V. SYROESHKIN. "CHIRAL SWITCHING CONTROL OF PHARMACEUTICAL SUBSTANCES." International Journal of Applied Pharmaceutics, May 7, 2024, 206–10. http://dx.doi.org/10.22159/ijap.2024v16i3.50481.

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Objective: The aim of this study was to demonstrate that chiral switching should be recognized as a widespread phenomenon that extends beyond the production of pure enantiomeric drugs. Methods: To investigate the optical activity of substances from various chemical classes, enantiomers of chiral compounds (Sigma-Aldrich, USA) were chosen: valine and its racemic form (D-valine, L-valine, and racemic valine with optical purity ≥ 99%), L-ascorbic acid (content ≥ 99%), carbohydrates (D-glucose, D-galactose, L-galactose, contents ≥ 99.5%). Solutions were prepared using deuterium-depleted water (DDW
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44

BETHELL, D., P. J. GALSWORTHY, and K. JONES. "ChemInform Abstract: Mutarotation of Glucose Derivatives (I)-(III) in Solutions of Surfactants in Organic Solvents: Cooperativity and Bimodal Catalytic Behavior." ChemInform 20, no. 14 (1989). http://dx.doi.org/10.1002/chin.198914074.

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45

Parra Cordova, Alejandro. "A Lab Tool for Sugar: The Optical Rotatory Dispersion of d-Glucose from Its Mutarotation Kinetics with a Home-Made Polarimeter." Journal of Chemical Education, December 26, 2024. https://doi.org/10.1021/acs.jchemed.4c00372.

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46

Dabrowska, Alicja, Andreas Schwaighofer, and Bernhard Lendl. "EXPRESS: Mid-Infrared Dispersion Spectroscopy as a Tool for Monitoring Time-Resolved Chemical Reactions on the Examples of Enzyme Kinetics and Mutarotation of Sugars." Applied Spectroscopy, June 16, 2024. http://dx.doi.org/10.1177/00037028241258109.

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Ongoing technological advancements in the field of mid-infrared (MIR) spectroscopy continuously yield novel sensing modalities, offering capabilities beyond traditional techniques like Fourier transform infrared spectroscopy (FT-IR). One such advancement is MIR dispersion spectroscopy, utilizing a tunable quantum cascade laser and Mach–Zehnder interferometer for liquid-phase analysis. Our study assesses the performance of a custom MIR dispersion spectrometer at its current development stage, benchmarks its performance against FT-IR, and validates its potential for time-resolved chemical reacti
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47

DUNSTAN, T. D. J., and R. E. PINCOCK. "ChemInform Abstract: HETEROGENEOUS CATALYSIS OF GLUCOSE MUTAROTATION BY ALUMINA IN DIMETHYL SULFOXIDE. 2. CATALYTIC ACTIVITY OF VARIOUS ALUMINAS, EFFECTS OF INHIBITORS, AND THE ACID/BASE PROPERTIES OF THE ACTIVE SITES." Chemischer Informationsdienst 16, no. 33 (1985). http://dx.doi.org/10.1002/chin.198533343.

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48

Chostenko, A., S. Truszkowski, A. Buchalski та A. Churkin. "Mutarotation of γ-Irradiated D-Glucoses". ChemInform 36, № 45 (2005). http://dx.doi.org/10.1002/chin.200545276.

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49

Tran, Dang-Bao-An, Evan G. P. Edwards, David P. Tew, Robert Peverall, and Grant A. D. Ritchie. "Continuous-wave cavity ringdown for high-sensitivity polarimetry and magnetometry measurements." Journal of Chemical Physics 160, no. 5 (2024). http://dx.doi.org/10.1063/5.0187832.

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We report the development of a novel variant of cavity ringdown polarimetry using a continuous-wave laser operating at 532 nm for highly precise chiroptical activity and magnetometry measurements. The key methodology of the apparatus relies upon the external modulation of the laser frequency at the frequency splitting between non-degenerate left- and right-circularly polarized cavity modes. The method is demonstrated by the evaluation of the Verdet constants of crystalline CeF3 and fused silica, in addition to the observation of gas- and solution-phase optical rotations of selected chiral mole
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