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1

Moura, Hipassia M., and Miriam M. Unterlass. "Biogenic Metal Oxides." Biomimetics 5, no. 2 (June 23, 2020): 29. http://dx.doi.org/10.3390/biomimetics5020029.

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Biogenic metal oxides (MxOy) feature structures as highly functional and unique as the organisms generating them. They have caught the attention of scientists for the development of novel materials by biomimicry. In order to understand how biogenic MxOy could inspire novel technologies, we have reviewed examples of all biogenic MxOy, as well as the current state of understanding of the interactions between the inorganic MxOy and the biological matter they originate from and are connected to. In this review, we first summarize the origins of the precursors that living nature converts into MxOy. From the point-of-view of our materials chemists, we present an overview of the biogenesis of silica, iron and manganese oxides, as the only reported biogenic MxOy to date. These MxOy are found across all five kingdoms (bacteria, protoctista, fungi, plants and animals). We discuss the key molecules involved in the biosynthesis of MxOy, the functionality of the MxOy structures, and the techniques by which the biogenic MxOy can be studied. We close by outlining the biomimetic approaches inspired by biogenic MxOy materials and their challenges, and we point at promising directions for future organic-inorganic materials and their synthesis.
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Wang, Jun Wei, Jian Li Yang, and Zhen Yu Liu. "Hg0 Removal by Activated Coke Supported Metal Oxide Catalysts." Advanced Materials Research 347-353 (October 2011): 1847–51. http://dx.doi.org/10.4028/www.scientific.net/amr.347-353.1847.

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Gas-phase elemental mercury (Hg0) removal by activated coke (AC) supported metal oxide catalysts MxOy/AC (MxOy=MnO2, Fe2O3, CuO) were studied under N2+HCl atmosphere and compared with that by AC. The influences of MxOy loading, temperature and Hg0 concentration on Hg0 removal were investigated. The results indicate that the capabilities of MxOy/AC for Hg0 removal were much higher than that of AC, indicating the important role of MxOy. The capabilities were found to follow the trend MnO2/AC > Fe2O3/AC > CuO/AC, which was corresponding to the oxidation activities of MxOy. The Hg0 removal capability of MnO2/AC increased with an increase of the MnO2 loading (1-10 wt.%) and temperature (120-200 °C). Scanning electron microscope-energy dispersive X-ray analysis confirmed the correlation between MnO2 and Hg adsorbed over MnO2/AC.
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KOWADA, Yoshiyuki, Hirohiko ADACHI, and Tsutomu MINAMI. "Electronic States of SiO2-MxOy(MxOy=P2O5, TiO2, ZrO2) Glasses." Journal of the Ceramic Society of Japan 101, no. 1180 (1993): 1330–34. http://dx.doi.org/10.2109/jcersj.101.1330.

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4

Robert, Didier. "Photosensitization of TiO2 by MxOy and MxSy nanoparticles for heterogeneous photocatalysis applications." Catalysis Today 122, no. 1-2 (April 2007): 20–26. http://dx.doi.org/10.1016/j.cattod.2007.01.060.

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5

Zhao, Jing, Ming Qiao Zhu, Jia Jing Chen, Yang Yang Yang, Yue Tang, Zhen Yu Cai, Yang Yi Shen, and Chao Hong He. "Cyclohexane Oxidation Catalyzed by Au/MxOyAl2O3 Using Molecular Oxygen." Advanced Materials Research 233-235 (May 2011): 254–59. http://dx.doi.org/10.4028/www.scientific.net/amr.233-235.254.

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Alumina was modified by doping with metal oxide and then used as the support for depositing gold by an impregnation-ammonia washing method to obtain Au/MxOy/Al2O3(M=Co, Zr and Ce) catalysts. These samples were characterized by inductively coupled plasma-atomic emission spectrometry (ICP-AES), transmission electron microscope (TEM) and X-ray diffraction (XRD). The effects of Co3O4content, metal oxide and mixed metal oxides on the catalytic activity for the selective oxidation of cyclohexane to cyclohexanone and cyclohexanol using molecular oxygen as oxidant were studied. The results showed that better catalytic performance was obtained over Au/MxOy/Al2O3catalysts compared with over Au/Al2O3catalysts. 9.69% conversion of cyclohexane and 93.31% selectivity to cyclohexanone, cyclohexanol and cyclohexyl hydroperoxide, with 1.02 ratio of cyclohexanone to cyclohexanol were obtained over the Au/MxOy/Al2O3catalyst at 150 , 1.5 MPa for 3 h. Moreover, according to the recycling test, the catalyst could be reused four times without remarkable loss of activity.
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6

Tatsumisago, M. "Crystallization of α-AgI from AgI–Ag2O–MxOy (MxOy=B2O3, GeO2, WO3) melts and glasses." Solid State Ionics 121, no. 1-4 (June 1999): 193–200. http://dx.doi.org/10.1016/s0167-2738(98)00547-5.

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7

Foreman, M. R. St J., R. A. Howie, M. J. Plater, J. M. S. Skakle, and A. M. Z. Slawin. "Synthesis of MXOY and Related Rings." Phosphorus, Sulfur, and Silicon and the Related Elements 169, no. 1 (January 1, 2001): 297–300. http://dx.doi.org/10.1080/10426500108546647.

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8

Pakrieva, Ekaterina, Ekaterina Kolobova, Yulia Kotolevich, Laura Pascual, Sónia A. C. Carabineiro, Andrey N. Kharlanov, Daria Pichugina, et al. "Effect of Gold Electronic State on the Catalytic Performance of Nano Gold Catalysts in n-Octanol Oxidation." Nanomaterials 10, no. 5 (May 2, 2020): 880. http://dx.doi.org/10.3390/nano10050880.

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This study aims to identify the role of the various electronic states of gold in the catalytic behavior of Au/MxOy/TiO2 (where MxOy are Fe2O3 or MgO) for the liquid phase oxidation of n-octanol, under mild conditions. For this purpose, Au/MxOy/TiO2 catalysts were prepared by deposition-precipitation with urea, varying the gold content (0.5 or 4 wt.%) and pretreatment conditions (H2 or O2), and characterized by low temperature nitrogen adsorption-desorption, X-ray powder diffraction (XRD), energy dispersive spectroscopy (EDX), scanning transmission electron microscopy-high angle annular dark field (STEM HAADF), diffuse reflectance Fourier transform infrared (DRIFT) spectroscopy of CO adsorption, temperature-programmable desorption (TPD) of ammonia and carbon dioxide, and X-ray photoelectron spectroscopy (XPS). Three states of gold were identified on the surface of the catalysts, Au0, Au1+ and Au3+, and their ratio determined the catalysts performance. Based on a comparison of catalytic and spectroscopic results, it may be concluded that Au+ was the active site state, while Au0 had negative effect, due to a partial blocking of Au0 by solvent. Au3+ also inhibited the oxidation process, due to the strong adsorption of the solvent and/or water formed during the reaction. Density functional theory (DFT) simulations confirmed these suggestions. The dependence of selectivity on the ratio of Brønsted acid centers to Brønsted basic centers was revealed.
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9

Ahn, Ho-Geun, Byoung-Min Choi, and Do-Jin Lee. "Complete Oxidation of Ethylene over Supported Gold Nanoparticle Catalysts." Journal of Nanoscience and Nanotechnology 6, no. 11 (November 1, 2006): 3599–603. http://dx.doi.org/10.1166/jnn.2006.17990.

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Complete oxidation of ethylene was performed over supported noble metals or transition metals oxide catalysts and on monoliths under atmospheric pressure. Gold nanoparticles on Al2O3 or MxOy (M = Mo, Fe, Mn) were prepared by impregnation, coprecipitation, deposition, and dispersion methods. Nanoparticles prepared by impregnation method were irregular and very large above 25 nm, but those by coprecipitation and deposition method were uniformly nanosized at 4 ∼ 5 nm. The gold nanoparticle were outstandingly active in catalyzing oxidation of ethylene. The activity order of these catalysts with preparation methods was deposition > coprecipitation > impregnation, and Au/Co3O4 prepared by deposition method showed the best performance in ethylene oxidation. The addition of gold particles to MxOy/Al2O3 catalyst enhanced the ethylene oxidation activity significantly. The main role of the gold nanoparticles apparently was to promote dissociative adsorption of oxygen and to enhance the reoxidation of the catalyst.
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10

Sinel’nikov, Viktor V., Galina O. Bragina, Nataliya S. Telegina, Galina N. Baeva, and Aleksandr Yu Stakheev. "Dynamics of ethane transformation under redox conditions over Pt/MxOy/Al2O3: effect of an oxygen storage component (MxOy)." Mendeleev Communications 18, no. 5 (September 2008): 268–69. http://dx.doi.org/10.1016/j.mencom.2008.09.014.

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11

TATSUMISAGO, M., A. TANIGUCHI, and T. MINAMI. "ChemInform Abstract: Formation of Frozen α-AgI in Twin-Roller-Quenched AgI-Ag2O-MxOy ( MxOy: WO3, V2O5) Glasses at Ambient Temperature." ChemInform 24, no. 14 (August 20, 2010): no. http://dx.doi.org/10.1002/chin.199314306.

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12

Azzi, Hajer, I. Rekkab-Hammoumraoui, L. Chérif-Aouali, and A. Choukchou-Braham. "Mesoporous Co3O4 as a New Catalyst for Allylic Oxidation of Cyclohexene." Bulletin of Chemical Reaction Engineering & Catalysis 14, no. 1 (April 15, 2019): 112. http://dx.doi.org/10.9767/bcrec.14.1.2467.112-123.

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Mesoporous cobalt oxide was investigated for the liquid phase oxidation of cyclohexene using tertiobutylhydroperoxide (TBHP) as an oxidant. The results were compared with several series of supported cobalt catalysts to study the influence of the cobalt loading and solvents on the overall conversion and selectivity. Mesoporous cobalt was synthesized through the nanocasting route using siliceous SBA-15 mesoporous material as a hard template and cobalt nitrate as the cobalt oxide precursor. Supported cobalt oxide catalysts (Co/MxOy) were synthesized by the impregnation method using two loadings (1 and 5 wt.%) and Al2O3, TiO2, and ZrO2 as supports. Samples were characterised by means: elemental analysis, X-ray powder Diffraction (XRD), BET (surface area), UV-Vis DR Spectroscopy, and MET. The results obtained showed that the cobalt oxide retains the mesoporous structure of SBA-15, and in all Co/MxOy, crystalline Co3O4 and CoO phases are observed. The mesoporous cobalt oxide is more active than the supported cobalt catalysts in the allylic oxidation of cyclohexene, with a conversion of 78 % of cyclohexene and 43.3 % selectivity toward 2-cyclohexene-1-ol. The highest activity of mesoporous cobalt oxide could be ascribed to its largest surface area. Furthermore, Co3O4 has both Lewis and Brönsted acidic sites whereas Co/MxOy has only Lewis acidic sites, which could also explain its superior catalytic activity. Moreover, mesoporous cobalt oxide was more stable than supported cobalt catalysts. Therefore, this catalyst is promising for allylic oxidation of alkenes. Copyright © 2018 BCREC Group. All rights reservedReceived: 30th March 2018; Revised: 24th September 2018; Accepted: 8th Oktober 2018; Available online: 25th January 2019; Published regularly: April 2019How to Cite: Azzi, H., Rekkab-Hammoumraoui, I., Chérif-Aouali1, L., Choukchou-Braham, A. (2019). Mesoporous Co3O4 as a New Catalyst for Allylic Oxidation of Cyclohexene. Bulletin of Chemical Reaction Engineering & Catalysis, 14 (1): 112-123 (doi:10.9767/bcrec.14.1.2467.112-123)Permalink/DOI: https://doi.org/10.9767/bcrec.14.1.2467.112-123
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13

Coutures, J. P., R. Erre, D. Massiot, C. Landron, D. Billard, and G. Peraudeau. "Ar+ ion beam effects on MxOy-alumina silica glasses." Radiation Effects 98, no. 1-4 (September 1986): 83–91. http://dx.doi.org/10.1080/00337578608206100.

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14

ABE, Yoshimoto, Noriyasu SUGIMOTO, Yukinori NAGAO, and Takahisa MISONO. "A New Method for Preparing Monolithic Gels as Precursor for MxOy and SiO2-MxOy Glasses (M=Al, Ti, Zr) of an Arbitrary." Journal of the Ceramic Association, Japan 95, no. 1107 (1987): 1141–44. http://dx.doi.org/10.2109/jcersj1950.95.1107_1141.

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15

Brichkov, Anton, Viktoriya Brichkova, Lidia Egorova, Aleksandra Malchik, and Vladimir Kozik. "The Thermal Analysis Data of the Hydrolysates of the Film-Forming Solutions, Containing Tetraethoxysilane and Mn2+, Fe3+, Co2+, Ni2+." Key Engineering Materials 683 (February 2016): 106–12. http://dx.doi.org/10.4028/www.scientific.net/kem.683.106.

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The paper considers the formation of silicon oxides and d-metals using differential-scanning calorimetry data of the film-forming solutions hydrolysates containing tetraethoxysilane and d-metal salts. The major stages of double oxides SiO2-MxOy (where M – Mn, Fe, Co, Ni) formation, and behavior of the systems upon the application of heat are analyzed. Thermal treatment intervals which display the difference of the systems behavior depending on the metal nature were determined.
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16

Henry, Aurélien, Peter Hesemann, Johan G. Alauzun, and Bruno Boury. "Reductive mineralization of cellulose with vanadium, iron and tungsten chlorides and access to MxOy metal oxides and MxOy/C metal oxide/carbon composites." Carbohydrate Polymers 174 (October 2017): 697–705. http://dx.doi.org/10.1016/j.carbpol.2017.06.106.

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17

Pesl, J., and R. H. Eric. "High temperature carbothermic reduction of Fe2O3–TiO2–MxOy oxide mixtures." Minerals Engineering 15, no. 11 (November 2002): 971–84. http://dx.doi.org/10.1016/s0892-6875(02)00136-x.

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18

Bogatyrev, V., O. Khyzhun, B. Ilkiv, S. Petrovska, V. Gun’ko, and Y. Zaulychnyy. "Electronic structure of MxOy/SiO2 (M=Mg, Cu) inorganic nanocomposites." Inorganic and Nano-Metal Chemistry 49, no. 10 (September 11, 2019): 335–42. http://dx.doi.org/10.1080/24701556.2019.1661436.

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19

Grabowski, P., and J. L. Nowinski. "Alpha Silver Iodide Stabilization in Mechanosynthesized AgI-Ag2O-MxOy Systems." Procedia Engineering 98 (2014): 86–92. http://dx.doi.org/10.1016/j.proeng.2014.12.492.

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20

Chen, Feng Tao, San Chuan Yu, and Shi Shen Zhang. "Electrochemical Synthesis of Methoxy-Dimethylbenzene and its Application in Gasoline." Advanced Materials Research 441 (January 2012): 403–7. http://dx.doi.org/10.4028/www.scientific.net/amr.441.403.

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P, Mo metal-salt catalysts (MxOy-MoO3-P2O5,M = Cu, V, Ni, Cr) were prepared and investigated by means of Fourier transform infrared and X-ray photoelectron spectroscopy. All catalysts exhibited good catalytic activity for the electrochemical catalytic oxidation ofp-xylene in methanol solvent assisted with a pair of porous graphite plane electrodes at room temperature and atmospheric pressure. Higher than 88% chemical conversion of the main product (methoxy-dimethylbenzene) was observed, and the products used as booster to improve fuel combustion were also studied.
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21

Jonayat, A. S. M., Adri C. T. van Duin, and Michael J. Janik. "Ab Initio Thermodynamic Investigation of Monolayer Stability of Multicomponent Metal Oxides: MxOy/ZnO(0001) and MxOy/TiO2(110) (M = Pd, Ru, Ni, Pt, Au, Zn)." Journal of Physical Chemistry C 121, no. 39 (September 26, 2017): 21439–48. http://dx.doi.org/10.1021/acs.jpcc.7b06521.

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22

Reddy, Benjaram M., Gunugunuri K. Reddy, Ibram Ganesh, and Jose M. F. Ferreira. "Single step synthesis of nanosized CeO2–MxOy mixed oxides (MxOy = SiO2, TiO2, ZrO2, and Al2O3) by microwave induced solution combustion synthesis: characterization and CO oxidation." Journal of Materials Science 44, no. 11 (June 2009): 2743–51. http://dx.doi.org/10.1007/s10853-009-3358-2.

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23

Aniya, M. "Chemical scaling of the ionic conductivity in AgI-Ag2O-MxOy glasses." Solid State Ionics 79 (July 1995): 259–63. http://dx.doi.org/10.1016/0167-2738(95)00071-d.

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24

Gao, Yilong, Jianxiang Wu, Wei Zhang, Yueyue Tan, Jing Gao, Bohejin Tang, and Jiachang Zhao. "Electrochemical capacitor behavior of SO42-/MxOy (M-Fe, Ti, Zr, Sn)." Ceramics International 41, no. 3 (April 2015): 3791–99. http://dx.doi.org/10.1016/j.ceramint.2014.11.054.

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25

Garrido, Francisco M. S., Rafael Franklin Medeiros, Nathalia O. Borges de Nogueira, Rosa C. Dias Peres, Emerson Schwingel Ribeiro, and Marta Eloísa Medeiros. "Síntese de óxidos mistos SiO2 /Mn xOy para aplicação na reação de redução de O2." Matéria (Rio de Janeiro) 18, no. 2 (2013): 1294–305. http://dx.doi.org/10.1590/s1517-70762013000200005.

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Os óxidos mistos SiO2/MxOy obtidos pelo processo sol-gel, designados de compósitos, normalmente aliam as propriedades mecânicas e químicas da sílica gel com as propriedades químicas do óxido metálico (MxOy), apresentando propriedades tais como: elevado grau de dispersão e homogeneidade das partículas do óxido metálico na matriz de sílica, assim como elevada resistência mecânica e química. O objetivo deste trabalho foi o de preparar e caracterizar materiais do sistema SiO2/Mn xOy, obtidos pelo processo sol-gel, utilizando diferentes concentrações dos precursores de Mn (II), acetato ou nitrato. A técnica de fluorescência de raios X (FRX) mostrou que a concentração do óxido metálico nos materiais é dependente do precursor utilizado e da sua concentração no meio reacional, variando de 9,4% até 20,9% em massa. A maior concentração de óxido de manganês foi obtida quando se utilizou como precursor o (CH3CO2)2Mn.4H2O. Os espectros de infravermelho indicam que a rede de SiO2 é pouco perturbada pelo aumento da quantidade de óxido de manganês, sugerindo que o Mn xOy está disperso na superfície da matriz de sílica. Os difratogramas de raiosX (DRX) mostram que os materiais apresentam baixa cristalinidade. No entanto, observa-se uma mudança no DRX em 2θ = 35,7º quando o material é aquecido a 400 0C, provavelmente devido à formação de cristalitos de Mn3O4. O método de síntese proposto para os materiais SiO2/Mn xOy é reprodutível. A aplicação destes materiais como eletrodos para a redução de O2 foi avaliada e observou-se que a atividade eletrocatalítica desses materiais pode ser aumentada através do seu aquecimento a 400 0C.
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26

NAKATANI, Toshio, Takahiro WAKITA, Rikuo OTA, Takashi WAKASUGI, and Katsuhisa TANAKA. "Preparation of Mixed Oxide Powders in the Systems ZrO2-MxOy and [20CeO2-80ZrO2(mol%)]-MxOy from Zirconium Sulfated Slurry for the Purification Catalysts of Automotive Emission." Journal of the Society of Materials Science, Japan 53, no. 3Appendix (2004): 53–57. http://dx.doi.org/10.2472/jsms.53.3appendix_53.

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27

Chowdari, B. "Studies on Ag2O.MxOy.TeO2 (MxOy=WO3, MoO3, P2O5 and B2O3) ionic conducting glasses." Solid State Ionics 113-115, no. 1-2 (December 1, 1998): 665–75. http://dx.doi.org/10.1016/s0167-2738(98)00393-2.

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28

Sinel’nikov, V. V., N. N. Tolkachev, and A. Yu Stakheev. "Comparative Study of the Oxygen Storage Capacity of Pt/MxOy/Al2O3 Systems." Kinetics and Catalysis 46, no. 4 (July 2005): 550–54. http://dx.doi.org/10.1007/s10975-005-0108-6.

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29

Zhang, Ming-Zhu, and Yan Zhang. "The Principle of Vapor-Phase Technics and Application in Synthesis of MxOy Nanomaterials." Science of Advanced Materials 11, no. 8 (August 1, 2019): 1174–79. http://dx.doi.org/10.1166/sam.2019.3534.

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30

Hua, Weiming, Yongde Xia, Yinghong Yue, and Zi Gao. "Promoting Effect of Al on SO2−4/MxOy (M=Zr, Ti, Fe) Catalysts." Journal of Catalysis 196, no. 1 (November 2000): 104–14. http://dx.doi.org/10.1006/jcat.2000.3032.

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Huang, Zhen-Kun, and Dong-Sheng Yan. "Phase relationships in Si3N4-AIN-MxOy systems and their implications for sialon fabrication." Journal of Materials Science 27, no. 20 (January 1, 1992): 5640–44. http://dx.doi.org/10.1007/bf00541636.

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Ma, Zhen, Weiming Hua, Yi Tang, and Zi Gao. "Catalytic decomposition of CFC-12 over solid acids WO3/MxOy (M=Ti, Sn, Fe)." Journal of Molecular Catalysis A: Chemical 159, no. 2 (October 2000): 335–45. http://dx.doi.org/10.1016/s1381-1169(00)00191-6.

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Reddy, Gunugunuri K., Torin C. Peck, and Charles A. Roberts. "CeO2–MxOy (M = Fe, Co, Ni, and Cu)-Based Oxides for Direct NO Decomposition." Journal of Physical Chemistry C 123, no. 47 (November 2019): 28695–706. http://dx.doi.org/10.1021/acs.jpcc.9b07736.

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34

Wenelska, Karolina, and Ewa Mijowska. "Preparation, thermal conductivity, and thermal stability of flame retardant polyethylene with exfoliated MoS2/MxOy." New Journal of Chemistry 41, no. 22 (2017): 13287–92. http://dx.doi.org/10.1039/c7nj02566a.

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In this work, exfoliated molybdenum disulfide (MoS2) modified by a metal oxide (MoS2/MxOy) was prepared by a hydrothermal method and characterized by atomic force microscopy (AFM), Raman spectroscopy and transmission electron microscopy (TEM).
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35

Tao, Xiaojun, Yanbao Zhao, Zhiwei Li, and Shaomin Zhou. "A universal route for synthesizing nearly monodisperse MxOy (M=Zn, In, Co, Fe) nanocrystals." Materials Science in Semiconductor Processing 24 (August 2014): 132–37. http://dx.doi.org/10.1016/j.mssp.2014.03.017.

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36

Konakov, V. G., O. Yu Kurapova, N. V. Borisova, S. N. Golubev, V. M. Ushakov, E. V. Koroleva, and I. Yu Archakov. "Synthesis and phase formation in MxOy–ZrO2 nanosized precursors (M = Zn2+, Cd2+, Pb2+, Bi3+)." Journal of Sol-Gel Science and Technology 82, no. 1 (December 15, 2016): 214–23. http://dx.doi.org/10.1007/s10971-016-4278-7.

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37

Jiaxiu, Guo, Shi Zhonghua, Wu Dongdong, Yin Huaqiang, Gong Maochu, and Chen Yaoqiang. "Study of Pt–Rh/CeO2–ZrO2–MxOy (M=Y, La)/Al2O3 three-way catalysts." Applied Surface Science 273 (May 2013): 527–35. http://dx.doi.org/10.1016/j.apsusc.2013.02.074.

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38

Oros-Ruiz, Socorro, Rodolfo Zanella, Sebastián E. Collins, Agileo Hernández-Gordillo, and Ricardo Gómez. "Photocatalytic hydrogen production by Au–MxOy (M Ag, Cu, Ni) catalysts supported on TiO2." Catalysis Communications 47 (March 2014): 1–6. http://dx.doi.org/10.1016/j.catcom.2013.12.033.

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39

Ray, Manisha, Sarah E. Waller, and Caroline Chick Jarrold. "Effect of Alkyl Group on MxOy– + ROH (M = Mo, W; R = Me, Et) Reaction Rates." Journal of Physical Chemistry A 120, no. 9 (February 24, 2016): 1508–19. http://dx.doi.org/10.1021/acs.jpca.6b00102.

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40

Wang, Peng Cheng, Jie Zhu, Xiang Liu, Ting Ting Lu, and Ming Lu. "Regioselective Nitration of Aromatics with Nanomagnetic Solid Superacid SO42−/ZrO2-MxOy-Fe3O4and Its Theoretical Studies." ChemPlusChem 78, no. 4 (February 12, 2013): 310–17. http://dx.doi.org/10.1002/cplu.201300001.

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41

Erdemoğlu, M., F. Sayılkan, S. Erdemoğlu, Ş. Şener, M. Akarsu, and H. Sayılkan. "Natural Pyrophyllite and M(OR)x Based MxOy Powders as New Adsorbents for Heavy Metal Adsorption." Key Engineering Materials 264-268 (May 2004): 2239–42. http://dx.doi.org/10.4028/www.scientific.net/kem.264-268.2239.

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Zhen, Ma, Hua Wei-Ming, Tang Yi, and Gao Zi. "Catalytic decomposition of CFC-12 on solid acids SO42-/MxOy (MZr, Ti, Sn, Fe, Al)." Chinese Journal of Chemistry 18, no. 3 (August 27, 2010): 341–45. http://dx.doi.org/10.1002/cjoc.20000180315.

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Yun, Hyeonjun, Yeongho Lee, Jangho Cho, Minchul Chung, Sunghun Jung, Wonbong Kwak, and Ho-Geun Ahn. "A Study on H2SO4-Treated MxOy Catalysts for Styrenated Phenols by Alkylation of Phenol with Styrene." Journal of Nanoscience and Nanotechnology 18, no. 2 (February 1, 2018): 1457–60. http://dx.doi.org/10.1166/jnn.2018.14903.

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Wang, Guo, Dongsen Mao, Xiaoming Guo, and Jun Yu. "Methanol synthesis from CO2 hydrogenation over CuO-ZnO-ZrO2-MxOy catalysts (M=Cr, Mo and W)." International Journal of Hydrogen Energy 44, no. 8 (February 2019): 4197–207. http://dx.doi.org/10.1016/j.ijhydene.2018.12.131.

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Zhu, Zhaoqiang, Kefu Zhang, Ruizhi Zhang, Jiahao Lin, Chunhua Zhao, Guorong Chen, and Chongjun Zhao. "A general strategy to inner tuned hydrothermal preparation of MxOy@M electrodes and improved electrochemical performances." Electrochimica Acta 310 (July 2019): 162–72. http://dx.doi.org/10.1016/j.electacta.2019.04.114.

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Wei, Guijuan, Xixia Zhao, Kun Du, Zhaojie Wang, Ming Liu, Shuo Zhang, Shutao Wang, Jun Zhang, and Changhua An. "A general approach to 3D porous CQDs/MxOy (M = Co, Ni) for remarkable performance hybrid supercapacitors." Chemical Engineering Journal 326 (October 2017): 58–67. http://dx.doi.org/10.1016/j.cej.2017.05.127.

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He, Donglin, Changlei Qin, Zonghao Zhang, Shuai Pi, Jingyu Ran, and Ge Pu. "Investigation of Y2O3/MxOy-Incorporated Ca-Based Sorbents for Efficient and Stable CO2 Capture at High Temperature." Industrial & Engineering Chemistry Research 57, no. 34 (July 31, 2018): 11625–35. http://dx.doi.org/10.1021/acs.iecr.8b02064.

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Zheng, Shu, Hong-Xia Guo, and Feng-Chun Jia. "Catalytic Combustion of Methane over CuO/ZrO2-Al2O3 Catalysts Modified by MxOy (M = Y, Cr, Mg, Ce)." Asian Journal of Chemistry 25, no. 7 (2013): 4094–98. http://dx.doi.org/10.14233/ajchem.2013.14636.

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Hayashi, Akitoshi, Hiromasa Muramatsu, Takamasa Ohtomo, Sigenori Hama, and Masahiro Tatsumisago. "Improvement of chemical stability of Li3PS4 glass electrolytes by adding MxOy (M = Fe, Zn, and Bi) nanoparticles." Journal of Materials Chemistry A 1, no. 21 (2013): 6320. http://dx.doi.org/10.1039/c3ta10247e.

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Kumar, Sushant, Rohit Srivastava, and Jayeeta Chattopadhyay. "MxOy/M/graphene coated multi-shelled nano-sphere as Bi-functional electrocatalysts for hydrogen and oxygen evolution." International Journal of Hydrogen Energy 46, no. 1 (January 2021): 341–56. http://dx.doi.org/10.1016/j.ijhydene.2020.09.139.

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