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1

Klymyshyna, К., К. Тerebilenko, N. Strutynska, and M. Slobodyanik. "THE ROLE OF COMBINED MOLTEN SALTS IN SODIUM-CERIUM (III) ORTHOPHOSPHATE CRYSTALLIZATION." Bulletin of Taras Shevchenko National University of Kyiv. Chemistry, no. 1 (57) (2020): 9–12. http://dx.doi.org/10.17721/1728-2209.2020.1(57).2.

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The efficient crystallization conditions for high temperature synthesis of sodium-cerium(III) orthophosphate from binary molten salts have been investigated in a light of influence of the inert reaction media addition. Taking into consideration NaF and Na2MoO4 as an addictives to a convention phosphate melt the crystallization regions of CePO4 and Na3Ce(PO4)2 have been identified by means of IR spectroscopy and powder X-Ray diffraction methods. The initial Na/P ratio in the melt has been shown to play the key role in pure Na3Ce(PO4)2 phase formation. The concentration of NaF has been chosen as
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2

Xu, Yaohua, Shouhua Feng та Wenqin Pang. "Hydrothermal synthesis and characterization of β-Na3Ce(PO4)2". Materials Letters 28, № 4-6 (1996): 313–15. http://dx.doi.org/10.1016/0167-577x(96)00080-8.

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3

Zozulia, Valeria, Mykola Slobodyanik, Tetiana Ushchapivska, and Kateryna Terebilenko. "COEXISTENCE OF CERIUM(III)/(IV) IN PHOSPHATE AND MOLYBDATE MELTS." Ukrainian Chemistry Journal 90, no. 12 (2025): 57–66. https://doi.org/10.33609/2708-129x.90.12.2024.57-66.

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For the first time, the possibilities of controlled in fluence on the valence states of ceriumin phosphate and molybdate melts have been systematically analyzed. A series of molybdates with a scheelite structure, MICe(MoO4)2 (MI – Li, Na, K, Cs), were obtained by crystallization from melt solutions, and the crystallization regions of Na3Ce(PO4)2 were established. The role of the acidity of molybdate, phosphate-molybdate, and fluoride-phosphate melts in the stability of cerium compounds in different oxidation states was determined for the first time. The role of acidity in molybdate, phosphate-
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4

Godlewska, P., A. Matraszek, L. Macalik, et al. "Structural, optical and EPR studies of Cr3+ doped Na3Ce(PO4)2 orthophosphate." Journal of Alloys and Compounds 606 (September 2014): 124–31. http://dx.doi.org/10.1016/j.jallcom.2014.03.163.

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5

Yang, Bingwen, Yefeng Feng, Qinghu Zhao, Miao He, and Yang Lv. "Novel Tunable Green-Red Luminescence in Mn2+ Doped Ca9Tb(PO4)7 Phosphors Based on the Mn2+ Regulation and Energy Transfer." Coatings 10, no. 10 (2020): 952. http://dx.doi.org/10.3390/coatings10100952.

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β-Ca3(PO4)2 type phosphors Ca9Tb(PO4)7:Mn2+ were fabricated by high temperature solid state reaction. Under 377 nm light excitation, the Ca9Tb(PO4)7 host displays the green emission attributable to the characteristic emission of Tb3+ ions peaking at 488, 542, 586, and 620 nm, respectively. The red broadband emission is observed when Ca9Tb(PO4)7 is doped with Mn2+ ions. The emission is attributed to the energy transfer from Tb3+ to Mn2+ ions; this facilitates the realization of the tunable green–red emission. The energy transfer mechanism from Tb3+ to Mn2+ is defined as quadrupole–quadrupole in
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6

Matraszek, Aleksandra, and Irena Szczygieł. "Modified Pechini synthesis of Na3Ce(PO4)2 and thermochemistry of its phase transition." Journal of Thermal Analysis and Calorimetry 93, no. 3 (2008): 689–92. http://dx.doi.org/10.1007/s10973-008-9129-5.

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7

Nguyen, Thi Phuong Loan, and Doan Quoc Anh Nguyen. "Na3Ce(PO4)2:Tb3+ and Na(Mg2–xMnX)LiSi4O10F2:Mn phosphors: a suitable selection for enhancing color quality and luminous flux of remote white light-emitting diodes." TELKOMNIKA Telecommunication, Computing, Electronics and Control 18, no. 4 (2020): 2095–100. https://doi.org/10.12928/TELKOMNIKA.v18i4.13723.

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This study proposed the TRP, a remote phosphor structure that has 3 phosphor layers, to ehance the chromatic quality and lumen output for white light-emitting diodes devices (WLEDs). The arrangment of phosphor layers is yellow YAG:Ce<sup>3+</sup> phosphor, green Na<sub>3</sub>Ce(PO<sub>4</sub>)<sub>2</sub>:Tb<sup>3+</sup> phosphor, and red Na(Mg<sub>2&ndash;x</sub>Mn<sub>x</sub>)LiSi<sub>4</sub>O<sub>10</sub>F<sub>2</sub>:Mn phosphor from bottom to top. Red Na(Mg<sub>2&ndash;x</sub>Mn<sub>x</sub>)LiSi<sub>4</sub>O<sub>10</sub>F<sub>2</sub>:Mn phosphor is used for the red light component to boo
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8

Zhang, Shi-Rui, Dan Zhao, Rui-Juan Zhang, Lin-Ying Shi, Shao-Jie Dai, and Yun-Chang Fan. "A novel stibium phosphate, LiBa(SbO)2(PO4)3: synthesis, crystal structure and RE3+-activated (RE = Tb3+ and Eu3+) fluorescence performance." Acta Crystallographica Section C Structural Chemistry 75, no. 9 (2019): 1234–42. http://dx.doi.org/10.1107/s2053229619010155.

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A new stibium phosphate, lithium barium bis(antimony oxide) tris(phosphate), LiBa(SbO)2(PO4)3, was prepared by the molten salt method with LiF as the flux. The crystal structure consists of an original three-dimensional anionic framework of [(SbO)2(PO4)3]∞ built from PO4 tetrahedra sharing their corners with SbO6 octahedra. This framework delimits one-dimensional tunnels where the lithium(I) and barium(II) ions are located. The UV–Vis spectrum shows that LiBa(SbO)2(PO4)3 was transparent from 350 to 800 nm, and is thus suitable as a luminescent host matrix. We then used Tb3+ and Eu3+ activators
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9

Loan, Nguyen Thi Phuong, and Nguyen Doan Quoc Anh. "Na3Ce(PO4)2:Tb3+ and Na(Mg2–xMnX)LiSi4O10F2:Mn phosphors: a suitable selection for enhancing color quality and luminous flux of remote white light-emitting diodes." TELKOMNIKA (Telecommunication Computing Electronics and Control) 18, no. 4 (2020): 2095. http://dx.doi.org/10.12928/telkomnika.v18i4.13723.

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10

Ju, Guifang, Yihua Hu, Li Chen, Xiaojuan Wang, and Lihua Hung. "Persistent luminescence properties of SrMg2(PO4)2:Eu2+,Tb3+." Applied Physics A 114, no. 3 (2013): 867–74. http://dx.doi.org/10.1007/s00339-013-7716-1.

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11

Boyko, Volodymyr, Vitalii Chornii, Serhii Nedilko, and Kateryna Terebilenko. "Luminescent converters based on nanocellulose + K3Tb(PO4)2:Eu composite films." Naukovij žurnal «Tehnìka ta energetika» 14, no. 2 (2023): 80–89. http://dx.doi.org/10.31548/machinery/2.2023.80.

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The advantages of cellulose and its derivatives as the latest materials for devices that generate, store, and convert electricity are their low cost, environmental friendliness, ease of recycling and the ability to be manufactured in various ways and from various raw materials, including agricultural waste. This predetermines the relevance of their study as materials for modern technology and electronics. The research aims to determine the luminescent characteristics of composite films made based on nanocellulose and polycrystalline oxide K3Tb0.9Eu0.1(PO4)2. Optical microscopy and the spectral
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12

Huang, Yanlin, Kiwan Jang, Ho Sueb Lee, et al. "Photoluminescence properties of (Ce3+,Tb3+) doped BaZn2(PO4)2 powder phosphor." Physics Procedia 2, no. 2 (2009): 207–10. http://dx.doi.org/10.1016/j.phpro.2009.07.012.

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13

Yang, Zhiping, Qiongyu Bai, Ting Li, et al. "Synthesis, luminescence property and thermal stability of KMgLa(PO4)2:Tb3+ phosphor." Optik 127, no. 20 (2016): 9338–43. http://dx.doi.org/10.1016/j.ijleo.2016.07.031.

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14

Wang, Tao, Yihua Hu, Li Chen, Xiaojuan Wang, and Guifang Ju. "Luminescence properties and energy transfer in Ca3(PO4)2:Ce3+, Tb3+ phosphors." Applied Physics A 120, no. 1 (2015): 301–8. http://dx.doi.org/10.1007/s00339-015-9188-y.

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15

YANG Yan-min, 杨艳民, 李自强 LI Zi-qiang, 焦福运 JIAO Fu-yun, et al. "Hydrothermal Synthesis and Luminescence Properties of KCaY(PO4)2∶Tb3+,Eu3+Phosphor." Chinese Journal of Luminescence 33, no. 8 (2012): 845–50. http://dx.doi.org/10.3788/fgxb20123308.0845.

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16

Guo, Zhaohua, Liying Wang, Huimin Lv, et al. "Preparation and luminescence properties of Tb3+ doped and Tb3+/Sm3+ co-doped Na3Y(PO4)2 crystalline glass ceramics." Materials Science and Engineering: B 272 (October 2021): 115352. http://dx.doi.org/10.1016/j.mseb.2021.115352.

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17

Lammers, M. J. J., H. C. G. Verhaar, and G. Blasse. "Lumine scence of Ce3+ and Tb3+ in M3(PO4)2 (M = Sr,Ba)." Materials Chemistry and Physics 16, no. 1 (1987): 63–66. http://dx.doi.org/10.1016/0254-0584(87)90038-1.

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18

Tingming Jiang, Tingming Jiang, Xue Yu Xue Yu, Xuhui Xu Xuhui Xu, Hongling Yu Hongling Yu, Dacheng Zhou Dacheng Zhou, and Jianbei Qiu Jianbei Qiu. "A strong green-emitting phosphor: K3Gd(PO4)2:Tb3+ for UV-excited white light-emitting-diodes." Chinese Optics Letters 12, no. 1 (2014): 011601–11603. http://dx.doi.org/10.3788/col201412.011601.

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19

CHEN Feng, 陈凤, 袁曦明 YUAN Xi-ming, 谢安 XIE An, 熊小波 XIONG Xiao-bo, and 刘丽 LIU Li. "Preparation and Luminescent Properties of Sr3(PO4)2∶Tb3+, Li+Phosphor for White LED." Chinese Journal of Liquid Crystals and Displays 26, no. 4 (2011): 448–54. http://dx.doi.org/10.3788/yjyxs20112604.0448.

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20

Wang, Zhijun, Panlai Li, Zhiping Yang, Qinglin Guo, and Guoyi Dong. "A white emitting phosphor BaMg2(PO4)2:Ce3+, Mn2+, Tb3+: Luminescence and energy transfer." Ceramics International 40, no. 9 (2014): 15283–92. http://dx.doi.org/10.1016/j.ceramint.2014.07.026.

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21

Xu, Mengjiao, Luxiang Wang, Dianzeng Jia, and Hongyang Zhao. "Photoluminescence properties and energy transfer of color tunable MgZn2(PO4)2:Ce3+,Tb3+ phosphors." Physical Chemistry Chemical Physics 17, no. 43 (2015): 28802–8. http://dx.doi.org/10.1039/c5cp04092b.

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22

Wang, Luxiang, Mengjiao Xu, Hongyang Zhao, and Dianzeng Jia. "Luminescence, energy transfer and tunable color of Ce3+,Dy3+/Tb3+ doped BaZn2(PO4)2 phosphors." New Journal of Chemistry 40, no. 4 (2016): 3086–93. http://dx.doi.org/10.1039/c5nj03148f.

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Tunable emission from blue to bluish white and green can be realized by energy transfer and changing the doping concentrations of Dy<sup>3+</sup> and Tb<sup>3+</sup> in BaZn<sub>2</sub>(PO<sub>4</sub>)<sub>2</sub> phosphors.
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23

Liu, Wei-Ren, Chien-Hao Huang, Chiao-Wen Yeh, Yi-Chen Chiu, Yao-Tsung Yeh, and Ru-Shi Liu. "Single-phased white-light-emitting KCaGd(PO4)2:Eu2+,Tb3+,Mn2+ phosphors for LED applications." RSC Advances 3, no. 23 (2013): 9023. http://dx.doi.org/10.1039/c3ra40471d.

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24

Tong, Miaohui, Yujun Liang, Peng Yan, Qiang Wang, and Guogang Li. "Synthesis and luminescence properties of a bluish-green emitting phosphor Ba3(PO4)2: Ce3+, Tb3+." Optics & Laser Technology 75 (December 2015): 221–28. http://dx.doi.org/10.1016/j.optlastec.2015.07.007.

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25

Qin, Dan, and Wanjun Tang. "Crystal structure, tunable luminescence and energy transfer properties of Na3La(PO4)2:Tb3+,Eu3+phosphors." RSC Advances 7, no. 5 (2017): 2494–502. http://dx.doi.org/10.1039/c6ra26164g.

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A series of Tb<sup>3+</sup>and/or Eu<sup>3+</sup>doped Na<sub>3</sub>La(PO<sub>4</sub>)<sub>2</sub>phosphors were successfully synthesized and their crystal structure and photoluminescence (PL) properties were investigated in detail.
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26

Zhang, Shaoan, Wenxian Lin, Quanfeng Li, et al. "Highly bright multicolor-tunable KSrLu(PO4)2:Ce3+, Tb3+, Mn2+ phosphors via efficient energy transfer." Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy 219 (August 2019): 110–20. http://dx.doi.org/10.1016/j.saa.2019.04.037.

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27

Wang, Yingsai, Nini Li, Bin Cui та ін. "Multifunctional γ-Fe2O3@Ca3(PO4)2@YPO4:Tb3+,Ce3+ nanocomposites as a potential drug carrier". Materials Chemistry and Physics 146, № 3 (2014): 330–36. http://dx.doi.org/10.1016/j.matchemphys.2014.03.032.

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28

Zhu, Zizhong, Guangsheng Fu, Yong Yang, Zhiping Yang, and Panlai Li. "Energy transfer, tunable luminescence, and thermal stability of Tb3+–Sm3+-codoped Na3Bi(PO4)2 phosphors." Journal of Materials Science 51, no. 14 (2016): 6944–54. http://dx.doi.org/10.1007/s10853-016-9982-8.

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29

Guo, Yanan, Qianwen Wang, Xiaoyu Zhao, et al. "Preparation and luminescence properties of Tb3+-Sm3+ co-doped K3Gd(PO4)2 crystalline glass ceramics." Optical Materials 148 (February 2024): 114830. http://dx.doi.org/10.1016/j.optmat.2024.114830.

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30

Zhang, Xinguo, Liya Zhou, Jianxin Shi, and Menglian Gong. "Luminescence and energy transfer of a color tunable phosphor Tb3+, Eu3+ co-doped KCaY(PO4)2." Materials Letters 137 (December 2014): 32–35. http://dx.doi.org/10.1016/j.matlet.2014.08.112.

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31

Xie, Meiling, Minghao Fang, Zhaohui Huang, Yan'gai Liu, Xiaowen Wu, and Xin Min. "Synthesis and photoluminescence properties of Ce3+ and Tb3+ doped Na3Gd(PO4)2 phosphors for white LEDs." Microelectronics Reliability 148 (September 2023): 115146. http://dx.doi.org/10.1016/j.microrel.2023.115146.

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32

Dung, Nguyen Van, Nguyen Huy Khiem, and Phan Xuan Le. "White Light-Emitting Diode Coated with K3Lu(PO4)2: Tb3+, Eu3+ Nanocrystal Films Enveloped by SiO2." International Journal of Technology 16, no. 3 (2025): 748. https://doi.org/10.14716/ijtech.v16i3.6022.

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33

Hu X., Piccinelli F., and Bettinelli M. "31-21." Optics and Spectroscopy 132, no. 1 (2022): 93. http://dx.doi.org/10.21883/eos.2022.01.52992.31-21.

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In this work the optical spectroscopy and the energy transfer processes involving the Tb3+and Tm3+ ions, have been studied in eulytite double phosphate hosts of the type Sr3Y(PO4)3 doped with various amounts of the two Ln ions. It has been found that several energy transfer and cross-relaxation processes are active in this class of materials, upon excitation in the 5D4 level of Tb, and in the 1G4 one of Tm. In particular, a Tb→Tm transfer of excitation has been found to quench strongly the 5D4 level of Tb. This process occurs with a transfer efficiency increasing from 0.08 to 0.62, for a donor
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34

Hu, Xiaowu, Fabio Piccinelli та Marco Bettinelli. "Процессы передачи энергии в эвлитите Sr-=SUB=-3-=/SUB=-Y(PO-=SUB=-4-=/SUB=-)-=SUB=-3-=/SUB=-, по отдельности и одновременно легированном ионами Tb-=SUP=-3+-=/SUP=- и Tm-=SUP=-3+-=/SUP=-". Оптика и спектроскопия 130, № 1 (2022): 99. http://dx.doi.org/10.21883/os.2022.01.51895.31-21.

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In this work the optical spectroscopy and the energy transfer processes involving the Tb3+and Tm3+ ions, have been studied in eulytite double phosphate hosts of the type Sr3Y(PO4)3 doped with various amounts of the two Ln ions. It has been found that several energy transfer and cross-relaxation processes are active in this class of materials, upon excitation in the 5D4 level of Tb, and in the 1G4 one of Tm. In particular, a Tb→Tm transfer of excitation has been found to quench strongly the 5D4 level of Tb. This process occurs with a transfer efficiency increasing from 0.08 to 0.62, for a donor
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35

Li, Wanli, Zhaoyang Chen, Pengjun Zhao, and Yanwei Fan. "Luminescence and energy transfer of color-tunable Tb3+/Sm3+co-doped BaZn2(PO4)2 glass-ceramic phosphors." Optical Materials 122 (December 2021): 111782. http://dx.doi.org/10.1016/j.optmat.2021.111782.

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36

Yu, Xiaofang, Peng Yang, Wanda Kang, Ruyan Song, Yongqing Zheng, and Xiaoyun Mi. "Color-tunable luminescence and energy transfer properties of Ca1.5Sr1.5(PO4)2: Dy3+, Tb3+ phosphor via hydrothermal synthesis." Journal of Luminescence 241 (January 2022): 118478. http://dx.doi.org/10.1016/j.jlumin.2021.118478.

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37

WANG, Ting, Xuhui XU, Dacheng ZHOU, Jianbei QIU, and Xue YU. "Tunable color emission in K3Gd(PO4)2:Tb3+,Sm3+ phosphor for n-UV white light emitting diodes." Journal of Rare Earths 33, no. 4 (2015): 361–65. http://dx.doi.org/10.1016/s1002-0721(14)60427-0.

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38

Mi, Wanxin, Jun Zheng, Peng Qiao, Lili Cao, Siqi Chu, and Hongping Ma. "Tunable luminescence, energy transfer and excellent thermal stability of SrMg2(PO4)2:Ce3+,Tb3+ phosphors for LEDs." Journal of Rare Earths 39, no. 1 (2021): 19–25. http://dx.doi.org/10.1016/j.jre.2019.12.008.

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39

Long, Jinqiao, Zhirong Luo, Tianman Wang, et al. "Enhanced photoluminescence and energy transfer in the novel red emitting phosphors SrZn2(PO4)2:Eu3+, Tb3+, Li+." Journal of Materials Science: Materials in Electronics 28, no. 1 (2016): 657–60. http://dx.doi.org/10.1007/s10854-016-5571-5.

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40

Zhang, Mengfei, Yujun Liang, Miaohui Tong, et al. "Photoluminescence properties and energy transfer of a novel bluish-green tunable KSrY(PO4)2:Ce3+, Tb3+ phosphor." Ceramics International 40, no. 7 (2014): 10407–13. http://dx.doi.org/10.1016/j.ceramint.2014.03.011.

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41

Mo, Fuwang, Xinguo Zhang, Zishan Sun, Zhenpeng Zhu, Ziying Guo, and Zhan-chao Wu. "Luminescence of K2BaCa(PO4)2: Ce3+, Tb3+ dual-emitting phosphor and its application as ratiometric optical thermometer." Ceramics International 45, no. 9 (2019): 12319–24. http://dx.doi.org/10.1016/j.ceramint.2019.03.147.

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42

Chen, Si, Yuhua Wang, Jia Zhang, Lei Zhao, Qian Wang, and Lili Han. "Luminescent properties of novel K3R(PO4)2:Tb3+ (R=Y and Gd) phosphors for displays and lightings." Journal of Luminescence 150 (June 2014): 46–49. http://dx.doi.org/10.1016/j.jlumin.2014.01.021.

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43

Shi, Lin-Ying, Dan Zhao, Rui-Juan Zhang, and Qing-Xia Yao. "Multi-color emitting luminescence in an Eu3+/Tb3+ co-doping borate-phosphate system CsNa2Tb2-(BO3)(PO4)2:xEu3+." Journal of Alloys and Compounds 877 (October 2021): 160308. http://dx.doi.org/10.1016/j.jallcom.2021.160308.

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44

Zhang, Zhi-Jun, Jun-Lin Yuan, Xiao-Jun Wang, et al. "Luminescence properties of CaZr(PO4)2:RE (RE = Eu3+, Tb3+, Tm3+) under x-ray and VUV–UV excitation." Journal of Physics D: Applied Physics 40, no. 7 (2007): 1910–14. http://dx.doi.org/10.1088/0022-3727/40/7/012.

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45

Zhang, Mengfei, Yujun Liang, Wenzhu Huang, et al. "A novel single-composition tunable color emission KSrY(PO4)2:Ce3+, Tb3+, Mn2+ phosphor based on energy transfer." Materials Research Bulletin 57 (September 2014): 231–37. http://dx.doi.org/10.1016/j.materresbull.2014.06.009.

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46

Zhang, Wansong, Yanlin Huang, and Hyo Jin Seo. "Luminescence properties and efficient energy transfer in Ce3+ and Tb3+ co-doped Mg2La3[SiO4]2[PO4]O phosphor." Ceramics International 39, no. 4 (2013): 4313–19. http://dx.doi.org/10.1016/j.ceramint.2012.11.013.

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47

Zhao, Lei, Deyin Wang, Yuhua Wang, and Ye Tao. "Visible Quantum Cutting and Energy Transfer in Tb3+ -Doped KSr(Gd,Y)(PO4 )2 Under VUV-UV Excitation." Journal of the American Ceramic Society 97, no. 12 (2014): 3913–17. http://dx.doi.org/10.1111/jace.13235.

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48

JIANG, Yu, Wei LIU, Xiyu CAO, Ge SU, Lixin CAO та Rongjie GAO. "Synthesis and luminescence of β-SrGe(PO4)2:RE (RE=Eu2+,Eu3+,Tb3+) phosphors for UV light-emitting diodes". Journal of Rare Earths 35, № 2 (2017): 142–48. http://dx.doi.org/10.1016/s1002-0721(17)60892-5.

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49

Wu, Xiulan, Wenni Bai, Ou Hai, Qiang Ren, Jinle Zheng, and Yuhan Ren. "Tunable color of Tb3+/Eu3+/Tm3+-coactivated K3La(PO4)2 via energy transfer: A single-phase white-emitting phosphor." Optics & Laser Technology 115 (July 2019): 176–85. http://dx.doi.org/10.1016/j.optlastec.2019.02.021.

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50

Li, Kai, Mengmeng Shang, Dongling Geng та ін. "Synthesis, Luminescence, and Energy-Transfer Properties of β-Na2Ca4(PO4)2(SiO4):A (A = Eu2+, Dy3+, Ce3+/Tb3+) Phosphors". Inorganic Chemistry 53, № 13 (2014): 6743–51. http://dx.doi.org/10.1021/ic500545y.

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