Academic literature on the topic 'Nanostructured Transition Metal Clusters'

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Journal articles on the topic "Nanostructured Transition Metal Clusters"

1

Reetz, Manfred T., and Wolfgang Helbig. "Size-Selective Synthesis of Nanostructured Transition Metal Clusters." Journal of the American Chemical Society 116, no. 16 (1994): 7401–2. http://dx.doi.org/10.1021/ja00095a051.

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2

Scharfe, Sandra, and Thomas F. Fässler. "Polyhedral nine-atom clusters of tetrel elements and intermetalloid derivatives." Philosophical Transactions of the Royal Society A: Mathematical, Physical and Engineering Sciences 368, no. 1915 (2010): 1265–84. http://dx.doi.org/10.1098/rsta.2009.0270.

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Homoatomic polyanions have the basic capability for a bottom-up synthesis of nanostructured materials. Therefore, the chemistry and the structures of polyhedral nine-atom clusters of tetrel elements [E 9 ] 4− is highlighted. The nine-atom Zintl ions are available in good quantities for E = Si–Pb as binary alkali metal (A) phases of the composition A 4 E 9 or A 12 E 17 . Dissolution or extraction of the neat solids with aprotic solvents and crystallization with alkali metal-sequestering molecules or crown ethers leads to a large variety of structures containing homoatomic clusters with up to 45
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3

Adams, Brian D., Robert M. Asmussen, Aicheng Chen, and Robert C. Mawhinney. "Interaction of carbon monoxide with small metal clusters: a DFT, electrochemical, and FTIR study." Canadian Journal of Chemistry 89, no. 12 (2011): 1445–56. http://dx.doi.org/10.1139/v11-120.

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The adsorption of CO molecules onto small metal clusters was studied using density functional theory (DFT) calculations, and experimental electrochemical and attenuated total reflection-Fourier transform infrared spectroscopic (ATR-FTIR) techniques were used to examine CO adsorbed onto nanostructures of similar composition. The adsorption strengths and CO vibrational stretching frequencies were calculated and analyzed for clusters of the form M–CO for all of the period 4, 5, and 6 d-block transition metals. A direct link between the νCO and the population of d orbitals of the metal was observe
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4

Bulgakov, Alexander V., Nikolay Y. Bykov, Alexey I. Safonov, Yuri G. Shukhov, and Sergey V. Starinskiy. "Silver Vapor Supersonic Jets: Expansion Dynamics, Cluster Formation, and Film Deposition." Materials 16, no. 13 (2023): 4876. http://dx.doi.org/10.3390/ma16134876.

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Supersonic jets of metal vapors with carrier gas are promising for producing nanostructured metal films at relatively low source temperatures and high deposition rates. However, the effects of the carrier gas on the jet composition and expansion dynamics, as well as on film properties, remain virtually unexplored. In this work, the free-jet expansion of a mixture of silver vapor with helium in a rarefied regime at an initial temperature of 1373 K is investigated through mass spectrometry and direct-simulation Monte Carlo methods. Introducing the carrier gas into the source is found to result i
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5

Jiang, Ning, Yulong Bai, Bo Yang, Dezhi Wang, and Shifeng Zhao. "Switchable metal–insulator transition in core–shell cluster-assembled nanostructure films." Nanoscale 12, no. 35 (2020): 18144–52. http://dx.doi.org/10.1039/d0nr04681g.

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6

MELINON, P., V. PAILLARD, V. DUPUIS, et al. "FROM FREE CLUSTERS TO CLUSTER-ASSEMBLED MATERIALS." International Journal of Modern Physics B 09, no. 04n05 (1995): 339–97. http://dx.doi.org/10.1142/s021797929500015x.

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In this paper the specific properties of free clusters and the formation of new cluster-assembled materials using the low energy cluster beam deposition (LECBD) technique are discussed. Recent results obtained for free clusters are summarized with special attention to new observed structures. As for the specific structures and properties of cluster-assembled materials, two main aspects are specially emphasized: the memory effect of the free cluster properties leading to the formation of new phases and the effect of the specific nanostructure of the cluster-assembled materials related to the ra
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7

Lu, Xizhao, Lei Kang, Binggong Yan, et al. "Evolution of a Superhydrophobic H59 Brass Surface by Using Laser Texturing via Post Thermal Annealing." Micromachines 11, no. 12 (2020): 1057. http://dx.doi.org/10.3390/mi11121057.

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To fabricate an industrial and highly efficient super-hydrophobic brass surface, annealed H59 brass samples have here been textured by using a 1064 nm wavelength nanosecond fiber laser. The effects of different laser parameters (such as laser fluence, scanning speed, and repetition frequency), on the translation to super-hydrophobic surfaces, have been of special interest to study. As a result of these studies, hydrophobic properties, with larger water contact angles (WCA), were observed to appear faster than for samples that had not been heat-treated (after an evolution time of 4 days). This
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8

Soldatov, Mikhail, Kirill Lomachenko, Nikolay Smolentsev, and Alexander Soldatov. "Determination of the local structure in metal-complexes by combining XAS and XES." Acta Crystallographica Section A Foundations and Advances 70, a1 (2014): C1521. http://dx.doi.org/10.1107/s2053273314084782.

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Nanoscale local atomic structure determines most of unique properties of novel materials without long range order. To study its fine details one has to use both computer nanodesign and advanced experimental methods for nanodiagnostics. The status of modern theoretical analysis of the experimental x-ray absorption spectra to extract structural parameters is presented. Novel in-situ technique for nanodiagnostics - extracting of 3D structure parameters on the basis of advanced quantitative analysis of X-ray absorption near edge structure (XANES) - has been developed. The possibility to extract in
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9

Miras, Haralampos N., Cole Mathis, Weimin Xuan, De-Liang Long, Robert Pow, and Leroy Cronin. "Spontaneous formation of autocatalytic sets with self-replicating inorganic metal oxide clusters." Proceedings of the National Academy of Sciences 117, no. 20 (2020): 10699–705. http://dx.doi.org/10.1073/pnas.1921536117.

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Here we show how a simple inorganic salt can spontaneously form autocatalytic sets of replicating inorganic molecules that work via molecular recognition based on the {PMo12} ≡ [PMo12O40]3– Keggin ion, and {Mo36} ≡ [H3Mo57M6(NO)6O183(H2O)18]22– cluster. These small clusters are able to catalyze their own formation via an autocatalytic network, which subsequently template the assembly of gigantic molybdenum-blue wheel {Mo154} ≡ [Mo154O462H14(H2O)70]14–, {Mo132} ≡ [MoVI72MoV60O372(CH3COO)30(H2O)72]42– ball-shaped species containing 154 and 132 molybdenum atoms, and a {PMo12}⊂{Mo124Ce4} ≡ [H16MoV
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10

Dupuis, V., J. P. Perez, J. Tuaillon, et al. "Magnetic properties of nanostructured thin films of transition metal obtained by low energy cluster beam deposition." Journal of Applied Physics 76, no. 10 (1994): 6676–78. http://dx.doi.org/10.1063/1.358165.

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