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Dissertations / Theses on the topic 'Naphthalenol'

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1

Hibbeln, Kim Sabine. "Effect of kaolinite and cadmium on the biodegradation of naphthalene and substituted naphthalenes." Thesis, McGill University, 1996. http://digitool.Library.McGill.CA:80/R/?func=dbin-jump-full&object_id=24011.

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The objectives of this study were to look at the effect of kaolinite and cadmium on the biodegradation of naphthalene and substituted naphthalenes. The kaolinite mineral is present in many Quebec soils and is a primary constituent of tropical soils. Since kaolinite is also a well defined mineral, experiments were performed to examine the effect kaolinite might play on the degradation of naphthalene, 2-methyl naphthalene, and 2-naphthol in the presence and absence of cadmium. Furthermore, the results from these analyses were used to interpret the behaviour in the mineralization experiments of e
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2

Glass, Adam Cameron 1983. "The Synthesis of Novel and Sterically Demanding Tetra-ortho-substituted Aryl Naphthalenes." Thesis, University of Oregon, 2011. http://hdl.handle.net/1794/11978.

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xiv, 326 p. : ill. (some col.)<br>Tetra-ortho -substituted aryl naphthalenes (TOANs) are a motif of great importance, being present in biologically active natural products, chiral ligands, and building blocks relevant to materials science. The synthesis of sterically demanding and enantioenriched TOANs continues to be a challenge for current synthetic methods. Herein, we describe the highly effective synthesis of a variety of sterically demanding and enantioenriched TOANs through a rearrangement-based method. Our method utilizes a cyclopropyl carbinol moiety as the key rearrangement precurs
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3

Quinn, Samuel. "Colouring naphthalene diimides." Thesis, University of Nottingham, 2018. http://eprints.nottingham.ac.uk/50038/.

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Naphthalene diimides have been explored in a wide variety of ways; They are a promising candidate for organic electronics, boasting the ability to form n-type semiconductor materials, the stability of their anions further aiding in this regard. Their electron poor aromatic core can be used in host guest chemistry to generate interlocked species. The ability to tune their electronic properties and how this could be manipulated to create photovoltaic devices is primarily focus of this thesis. A series of naphthalene diimides substituted at the core with morpholine moieties have been synthesized
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4

Swigelaar, Wendell Peter. "The synthesis of 3-allyl-4-ethyl-2- (1'-hydroxyethyl)-1-methoxynaphthalene and its behaviour towards base- and palladium-promoted cyclisation under aerobic and anaerobic conditions." Thesis, University of the Western Cape, 2005. http://etd.uwc.ac.za/index.php?module=etd&amp.

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Over the years, Giles and co-workers have established that, upon treatment with potassium tert-butoxide, tetra-substituted naphthalenes undergo cyclisations to afford naphthopyrans. It was suggested that these base-induced cyclisations was as a result of the reacting centers being forced into close proximity as a consequence of steric crowding.<br /> <br /> This thesis describes the synthesis of 3-allyl-4-ethyl-2-(1&prime<br>-hydroxyethyl)-1-methoxy-naphthalene 177 and its behaviour towards Pd(0) and potassium tert-butoxide under aerobic and anaerobic conditions, to verify whether the base-pro
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5

Nehls, Benjamin S. "Naphthalene based conjugated materials." [S.l.] : [s.n.], 2005. http://deposit.ddb.de/cgi-bin/dokserv?idn=976731363.

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6

Kim, Michelle B. "The Hydrolysis of Naphthalene Diimides." Digital Archive @ GSU, 2007. http://digitalarchive.gsu.edu/chemistry_theses/7.

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The hydrolyses of naphthalene diimides (NDIs) bearing aliphatic side chains with N-methylpyrrolidinium groups placed two (1) and three (5) atoms from the central core were studied. The Ka values for the first and second hydrolyses for 1 were 2.5 ± 0.2 x 105 M-1 and 2.0 ± 0.1 x 102 M-1, respectively; for 5 they were 1.4 ± 0.1 x 105 M-1 and 44 ± 2 M-1, respectively. NDI 1 hydrolyzed 6.8 times faster than did 5. The rates for the first and second hydrolyses of 1 at 100 mM hydroxide measured by stopped-flow were 17.0 ± 0.2 s-1 and 53.0 ± 0.1 x 10-2 s-1, respectively. NMR showed both the syn and an
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7

黃文菁 and Man-ching Wong. "Synthesis of the naturally occurring 1, 2-naphthalenedione, azanzoneA." Thesis, The University of Hong Kong (Pokfulam, Hong Kong), 1993. http://hub.hku.hk/bib/B31211033.

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8

Wong, Man-ching. "Synthesis of the naturally occurring 1, 2-naphthalenedione, azanzone A /." [Hong Kong : University of Hong Kong], 1993. http://sunzi.lib.hku.hk/hkuto/record.jsp?B13457093.

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9

Gubellini, Federico. "Designing heterogeneous catalysts for naphthalene isopropylation." Master's thesis, Alma Mater Studiorum - Università di Bologna, 2020. http://amslaurea.unibo.it/20659/.

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2,6 di-isopropylnaphthalene is a plant growth regulator and it is used for the manufacturing of products intended to prevent sprouting of stored potatoes; despite that in the last decades it has been mainly produced as a precursor of the corresponding dicarboxylic acid (2,6-naphthalene dicarboxylic acid) which is, with ethylene glycol, the monomer for polyethylene naphthalate (PEN) polymerization. PEN results appealing for many uses for which PET is more commonly utilized; the most relevant, higher glass transition temperature (PEN 122°C, PET 80°C), higher Young’s modulus (PEN 5200 MPa, PET 3
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10

Bakker, M. G. "ESR studies on some naphthalene derivatives." Thesis, University of Canterbury. Chemistry, 1985. http://hdl.handle.net/10092/8639.

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ESR Spectroscopy has been used to study conformational interconversion and addivity relationships in a number of series of naphthalene derivatives. Oscillation of the alkyl rings in 1,2,3,6,7,8-hexahydropyrene ions, and the ions of the related 5, 6 and 7 membered ring compounds has been studied. The temperature dependance of the ESR spectra have been used to assign the coupling constants. The aromatic ring coupling constants in the asymmetric compounds have been assigned on the basis of an additivity relationship. The ESR spectra of a number of methylnaphthalene anions have been recorded and
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11

Carey, Michelle Jocelyn. "The photophysics of naphthalene containing synthetic polymers." Thesis, Imperial College London, 1995. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.320273.

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12

Senior, Kerry Charles. "Biotreatment of industrial effluents containing naphthalene sulphonate." Thesis, University of Kent, 2003. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.270819.

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13

Ashram, Muhammad. "Synthesis of calix(4)naphthalenes and their properties." Thesis, National Library of Canada = Bibliothèque nationale du Canada, 1997. http://www.collectionscanada.ca/obj/s4/f2/dsk3/ftp04/nq25765.pdf.

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14

Zhang, Guang. "SYNTHESIS AND CHARACTERIZATION OF FUNCTIONALIZED NAPHTHALENES AND ANTHRACENES." UKnowledge, 2012. http://uknowledge.uky.edu/chemistry_etds/3.

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Organic electronics have received significant development in the last few decades. p- Type materials are much more in availability than n-type now. There are only a few examples of air-stable n-type materials. The design and synthesis of novel air-stable ntype materials is still a focus of research. Herein is described a study to evaluate the effectiveness of a novel electron-withdrawing group, composed of three electronwithdrawing groups connected in series, to impart material properties known to be favorable for obtaining air-stable n-types. The smaller acenes, naphthalene and anthracene, ca
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15

Knight, Lorraine Shirley. "The synthesis of derivatives of naturally occurring naphthalenes." Doctoral thesis, University of Cape Town, 1988. http://hdl.handle.net/11427/17082.

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Includes bibliographical references.<br>The ansamycins are a large group of natural products which have attracted considerable attention, largely as a result of their range of biological activity. The laboratory synthesis of an ansamycin has been simplified into the independent construction of the aromatic nucleus and the ansa chain, followed by their combination to form the macrocyle. The project described in Chapter 1 was designed to devise a novel, convenient, and efficient synthesis of a substituted 1,4-naphthoquinone which would function as a model for the naphthoquinonoid nucleus of the
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16

YANG, JUN. "Thermal Decomposition and Growth of Short Alkylated Naphthalenes." University of Cincinnati / OhioLINK, 2007. http://rave.ohiolink.edu/etdc/view?acc_num=ucin1172807217.

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17

Smith, Timothy Andrew David. "Conformational analysis studies in NMR spectroscopy." Thesis, University of Liverpool, 1997. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.243220.

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18

LaPlante, Troy David. "Supercritical fluid extraction of naphthalene from soil slurries." Thesis, National Library of Canada = Bibliothèque nationale du Canada, 1998. http://www.collectionscanada.ca/obj/s4/f2/dsk2/tape17/PQDD_0003/MQ31844.pdf.

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19

Sullivan, Michelle A. Pfaender Frederic K. "A microscale investigation of naphthalene dissolution and biodegradation." Chapel Hill, N.C. : University of North Carolina at Chapel Hill, 2006. http://dc.lib.unc.edu/u?/etd,494.

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Thesis (M.S.)--University of North Carolina at Chapel Hill, 2006.<br>Title from electronic title page (viewed Oct. 10, 2007). "... in partial fulfillment of the requirements for the degree of Master of Science in the Department Environmental Sciences and Engineering, School of Public Health." Discipline: Environmental Sciences and Engineering; Department/School: Public Health.
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20

Carvallo, Sergio Luis Fuenmayor. "Catabolism of naphthalene by Pseudomonas sp. strain U2." Thesis, Bangor University, 1998. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.263318.

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21

Supanpaiboon, Wisa. "Percutaneous absorption and metabolism of naphthalene and phenanthrene." Thesis, University of Newcastle Upon Tyne, 2001. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.364851.

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22

Miller, Chandra Tier. "The design, synthesis and screening of naphthalene diimides with antibacterial activity /." Digital version accessible at:, 1999. http://wwwlib.umi.com/cr/utexas/main.

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23

Colbert, Crystal. "Functional Neural Toxicity and Endocrine Responses in Mice Following Naphthalene Exposure." Thesis, University of North Texas, 2010. https://digital.library.unt.edu/ark:/67531/metadc31529/.

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Polycyclic aromatic hydrocarbons (PAHs) are a well studied and diverse class of environmental toxicants. PAHs act via the aryl hydrocarbon receptor (AhR), and studies have suggested that PAHs may elicit neurological and estrogenic effects. Doses of PAHs between 50 to 150 ppm may elicit neurotoxicity in rodent models. The present study investigated the effects of naphthalene on in vivo steroidogenesis in Swiss Webster male mice, and in vitro neural function of Balb-C/ICR mice frontal cortex neurons. These data suggest that naphthalene may not elicit steroidogenic effects at concentrations ran
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24

Charron, Martin. "Novel naphthalene-2,3-diol antioxidants: Design, synthesis and reactivity." Thesis, University of Ottawa (Canada), 2005. http://hdl.handle.net/10393/26866.

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Antioxidants, which are molecules capable of inhibiting or quenching free radicals, are believed to be very important molecules for preventing and limiting ''oxidative stress'' in human cells. This oxidative stress is caused by unwanted reactions between free radicals and cell's vital constituents, such as DNA, proteins and lipids. These reactions are responsible for lipid peroxidation, DNA and proteins breakage and mutations that are today known to be associated with degenerative diseases such as Parkinson's and Alzheimer's disease as well as with aging. The design and development of new anti
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25

Salim, Paul Hartawan. "Mass transfer study of naphthalene in supercritical CO¦2." Thesis, National Library of Canada = Bibliothèque nationale du Canada, 1997. http://www.collectionscanada.ca/obj/s4/f2/dsk3/ftp04/nq20769.pdf.

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26

Roberts, S. D. "Regioselective electrophilic aromatic substitution reactions of naphthalene over solids." Thesis, Swansea University, 2000. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.638685.

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Chapter 1 highlights the many advantages of heterogeneous inorganic solids as catalysts, and summarises the various microporous and mesoporous solids that have been employed as catalysts. The synthesis and characterisation of the mesoporous materials that were used in the study are described. Chapter 2 focuses on the nitration of naphthalene. An introduction to nitration is given, and the results of nitration over a range of solids are presented. Unusual dinitronaphthalene product ratios were achieved over Al-MCM-41. Reactions catalysed by heteropoly acid immobilised within the pores of mesopo
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27

Chen, S. "Organisation and regulation of naphthalene catabolic genes in Rhodococci." Thesis, Queen's University Belfast, 2004. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.403265.

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28

Somisara, Dhanasekara M. U. K. "Synthetic studies into phosphorus and arsenic peri-substituted naphthalene." Thesis, University of St Andrews, 2011. http://hdl.handle.net/10023/3106.

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The rac- and meso- forms of “all carbon” 1,2-diphosphonium dications with the naphthalene -1,8-diyl backbone were synthesised in good yields and purity by double alkylation of the parent diphosphine (1,2-diphenyl-1,2-diphosphaacenaphthene) using strong alkylating agents. Pure rac- and meso- forms of 1,2-diphosphoniums were obtained diastereospecifically by using methyl triflate and trimethyloxonium tetrafluoroborate respectively. It was found that the equilibrium between the rac- and meso- forms at room temperature in acetonitrile solutions effectively depends on the anion present. A reaction
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29

Saar, Brooklynd Dawn. "Fluorescence Quenching of PPV-SO and Bodipy-Naphthalene Systems." W&M ScholarWorks, 2012. https://scholarworks.wm.edu/etd/1539626932.

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30

Fuller, Amy L. "Applications of X-ray crystallography : studies into the structural perturbations of peri-substituted naphthalene derivatives /." St Andrews, 2009. http://hdl.handle.net/10023/826.

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31

Tagg, Woo Chiat, and n/a. "Novel fluorescent organometallic materials." University of Otago. Department of Chemistry, 2009. http://adt.otago.ac.nz./public/adt-NZDU20090430.133100.

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This thesis describes the synthesis and properties of some extended donor-acceptor dyads with the donor being a ferrocenyl moiety and a fluorescent naphthalimide group as the acceptor. Two series of extended ferrocenyl-naphthalimide dyads were prepared in reasonable yield depending on the synthetic route. The first are a series of three ferrocenyl-CH=CH-spacer-C[triple bond]C-naphthalimide dyads in which the spacers are phenyl, biphenyl and anthryl and the second are a series of three ferrocenyl-C[triple bond]C-spacer-C[triple bond]C-naphthalimide dyads in which the spacers are 2,2� -bithiophe
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32

Forsyth, S. R. "Chlorination of aromatic compounds by two phase electrolysis." Thesis, University of Southampton, 1987. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.377797.

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33

Ponnuswamy, Nandhini. "Supramolecular chemistry of naphthalenediimides." Thesis, University of Cambridge, 2012. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.610852.

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34

Fuller, Amy L. "Applications of X-ray crystallography : studies into the structural perturbations of peri-substituted naphthalene derivatives." Thesis, University of St Andrews, 2010. http://hdl.handle.net/10023/826.

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The majority of research in this thesis uses X-ray crystallography to investigate the structural features of peri-substituted naphthalene compounds. X-ray crystallography is introduced in chapter one, followed by a discussion on modes of distortion peri-substituted naphthalene derivatives can undergo, in chapter two. In chapter three, compounds having non-bonded -SPh and -EPh (E = S, Se, or Te) peri-substituents are compared. These similar compounds react differently when oxidized with bromine. The oxidation products are used to discuss a recently proposed mechanism and a more specific mechani
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35

Johnson, Sean M. "Toward the Synthesis of Naphthalene-Bridged Bis-Triazole Bimetallic Complexes." Scholar Commons, 2017. http://scholarcommons.usf.edu/etd/6872.

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Bimetallic complexes are known to have unique electronic properties and are used in a variety of organic transformations as catalysts. The use of naphthalene-bridged bis- triazoles (NBT) for bimetallic complexes is unknown. NBTs have the unique property of being fluorescent stemming from a twisted intramolecular charge transfer. With the non- coplanar geometry and the distance between the 1,2,3-triazole rings, we hypothesized that 1,8-bis(4-phenyl-2H-1,2,3-triazol-2-yl)naphthalene (12) would be a suitable ligand to synthesize a bimetallic complex. The synthesis of 12 was optimized for large sc
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36

Lipscomb, D. A. "Characterisation of a naphthalene dioxygenase system in 'Rhodococcus' sp.' NCIMB12038." Thesis, Queen's University Belfast, 2006. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.432663.

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37

Newbould, E. C. "Catabolism of naphthalene sulphonic acids by three strains of bacteria." Thesis, University of Kent, 1987. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.379697.

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38

Clark, G. R. "Studies on syntheses of cyclic derivatives of biphenylene and naphthalene." Thesis, University of Bristol, 1985. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.371991.

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39

Pitterle, Mark Thomas. "Push-pull Tests to Quantify In-situ Naphthalene Phytoremediation Rates." Thesis, Virginia Tech, 2004. http://hdl.handle.net/10919/41282.

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Ten strategically placed push-pull wells were installed to determine in-situ degradation rates at a creosote contaminated site and to assess the contribution of hybrid poplar trees to polynuclear aromatic hydrocarbon (PAH) remediation. Well positioning enabled comparison between contaminated and non-contaminated locations, as well as comparisons between locations with and without trees. Comparison of areas with and without trees enabled an improved understanding of the role that the phytoremediation system has on the overall degradation of PAHs at the site. Bromide, a conservative, non-reac
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40

Banceu, Claudia. "Reactions of methylated naphthalenes with hydroxyl radicals under simulated atmospheric conditions." Thesis, National Library of Canada = Bibliothèque nationale du Canada, 2000. http://www.collectionscanada.ca/obj/s4/f2/dsk1/tape4/PQDD_0016/MQ55651.pdf.

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41

Douglas, Judy E. "Design, synthesis and characterization of naphthalene-based poly(aryl ether)s." Thesis, National Library of Canada = Bibliothèque nationale du Canada, 1998. http://www.collectionscanada.ca/obj/s4/f2/dsk2/ftp02/NQ32333.pdf.

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42

Li, Hao. "Anaerobic biodegradation of naphthalene and anthracene using different terminal electron acceptors." Thesis, National Library of Canada = Bibliothèque nationale du Canada, 2001. http://www.collectionscanada.ca/obj/s4/f2/dsk3/ftp04/mq55916.pdf.

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43

ABRAMOWITZ, ROBERT. "ESTIMATION OF THE MELTING POINT OF RIGID ORGANIC COMPOUNDS (COSOLVENT, NAPHTHALENE)." Diss., The University of Arizona, 1986. http://hdl.handle.net/10150/183935.

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The melting points of rigid, hydrogen bonding, and non-hydrogen bonding organic compounds have been estimated from their chemical structure. The estimation was accomplished through the use of both additive and non-additive non-constitutive properties of the molecule. The melting points of the aforementioned compounds can be estimated by the equation: TM = TMPN + TIHBN + TPACK + 8.9*EXPAN + 73.1*SIGMAL + 196.3 where the dependent variable, TM, is the melting point of the compound in Kelvin, SIGMAL is the logarithm of the symmetry number for the molecule, EXPAN is the eccentricity of the molecul
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44

Burgos, William David. "Reversible and irreversible adsorption of naphthalene and α-naphthol to soil". Diss., Virginia Tech, 1995. http://hdl.handle.net/10919/38186.

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Experiments were performed with naphthalene and a-naphthol to compare the processes involved in the sorption of a polycyclic aromatic hydrocarbon (PAH) and its metabolite, respectively, and to assess the bioavailability of these two compounds adsorbed to two sandy soils with different organic carbon contents. Adsorption conditions were varied to estimate the extent that biologically-mediated and chemically-induced oxidative coupling, and rate-limited diffusive processes contributed to the apparent irreversible adsorption of these compounds. The purposes of this research were to: (1) investigat
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45

Huang, Zhong-Xiang, and 黃重祥. "Aniline Oligomers as Coating Materials in Solid-Phase Microextraction Fiber for Naphthalene(PAH), 1-naphthalenol, 2-naphthalenol, 1.6-diisorpropylnaphthalene, and Anthrone analysis using GC/MS." Thesis, 2016. http://ndltd.ncl.edu.tw/handle/95173582801531473469.

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46

LIN, YI-CANG, and 林怡蒼. "Study on The Tautomerization of 1-Aryldiazo-2-naphthalenol Derivatives by Using The Spectroscopic Technique." Thesis, 2016. http://ndltd.ncl.edu.tw/handle/85644351672906327063.

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博士<br>靜宜大學<br>應用化學系<br>104<br>The substituent effect on azo-hydrazone tautomerization of 1-aryldiazo-2-naphthalenol is studied by means of NMR and MS analysis. Among the 13C chemical shifts, the C(2) of this series compound is the most sensitive to the variation in the nature of substituent on the phenyl ring. Therefore, the variation in the chemical shifts of C(2) is used to probe the substituent effect by using the substituent chemical shifts and free energy vs. Hammett’s constant (σ+). Both methods give a negative correlation slope, which are ρ=-8.74 and ρ=-1.38 , indicating the electron-wi
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47

Chen, Ze Huai. "The synthesis of naphthalene derivatives and their adsorption at the grahite-water interface." 1994. http://arrow.unisa.edu.au:8081/1959.8/83889.

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48

Chen, Yi-Han, and 陳逸涵. "Study on the Cyclization Reaction of Enediynes to Naphthalene Derivatives, and Optoelectronic of Naphthalene Compounds." Thesis, 2018. http://ndltd.ncl.edu.tw/handle/c4a72k.

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碩士<br>國立中山大學<br>化學系研究所<br>106<br>This dissertation describes a new synthetic method of naphthalene derivatives by using palladium-catalyzed cyclization of enediyne compounds . Meanwhile, we discussed the optimization conditions for this cyclization reaction. Furthermore, we synthesized a series of naphthalene derivatives bearing different substituents . After reducing naphthalene derivatives to amine and reacting it with a hypervalent iodine reagent, a naphthalene compounds with benzisoxazole skeletons was obtained. We studied the physical properties of these materials. The experimented result
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49

張偉昱, Wei-Yu Chang, and 張偉昱. "A Novel Synthesis of Substituted Naphthalenes." Thesis, 2011. http://ndltd.ncl.edu.tw/handle/38348572607754306324.

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碩士<br>中國醫藥大學<br>藥學系碩士班<br>99<br>For many years naphthalenes have been an interesting structural class of compounds, which have found many uses in the field of medicinal chemistry. In pharmaceuticals, it was confirmed that naphthalenes have good biological actives targeted towards various therapeutic endpoints. For example, the highly substituted naphthalenes are biological active with anticancer and anti-malaria effects. Due to its wide applications in the field of pharmaceuticals, this type of compounds has attracted our attention. We developed an efficient method to synthesize 2-phenyl napht
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50

Ribeiro, Filipe Miguel da Silva. "Thermodynamic properties of Mono-Halogenated Naphthalenes." Master's thesis, 2013. https://repositorio-aberto.up.pt/handle/10216/68965.

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