Academic literature on the topic 'Ni-Cr-W Alloy'

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Journal articles on the topic "Ni-Cr-W Alloy"

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Zhang, Qing Quan, Ming Yang Li, Ran Wei, Hui Yun Wu, and Zhen Rui Li. "Research on Effect of Alloy Elements on Equilibrium and Properties of Ni-Cr-Co Type Nickel-Based Superalloy." Materials Science Forum 849 (March 2016): 513–19. http://dx.doi.org/10.4028/www.scientific.net/msf.849.513.

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Ni-Cr-Co type Nickel-based super alloy Inconel 740H was studied. The effect of Nb, Al and Ti on the equilibrium of this alloy was analyzed by JMatPro software. The amount of Ti and Nb should be controlled by 1.50wt.%, and meanwhile, Al should be 1.0-2.0wt.%. If Mo and W were added the amount of Mo should be in the range of 1.0-2.0wt. %, and W should be about 1.0wt.%. Based on these results, three types of new alloys were designed, which contain Ni-Cr-Co-Mo type (1#), Ni-Cr-Co-W type (2#) and Ni-Cr-Co-Mo-W type (3#). Compared with the Ni-Cr-Co type Inconel 740H alloy, the room temperature strength, high temperature strength and high temperature durable performance of the three new alloys improved, which can provide the evidence and reference to optimize the chemical composition of Inconel 740H alloy, i.e., adding 1.50wt.% Mo and 1.0wt.% W individually or together.
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Razumovskiy, V. I., D. Scheiber, I. M. Razumovskii, et al. "New Cr-Ni-Base Alloy for High-Temperature Applications Designed on the Basis of First Principles Calculations." Advances in Condensed Matter Physics 2018 (July 9, 2018): 1–8. http://dx.doi.org/10.1155/2018/9383981.

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We use ab initio calculations to analyze the influence of 4d and 5d transition metal alloying elements on cohesive properties of the bulk and a representative grain boundary in Cr within the framework of the Rice–Thomson–Wang approach. The results obtained for Cr are combined with the analogous results for Ni to select Ta and Nb as promising alloying additions to dual-phase (α/γ) Cr-Ni-base high-temperature alloys. Ta and Nb are added to the alloying system of an existing alloy I (Cr-Ni-W-V-Ti) in an attempt to design a chemical composition of a new alloy II (Cr-Ni-W-V-Ti) + (Ta-Nb). Investigation of the microstructure of the Ta-bearing Cr-Ni-alloy reveals a Ta enrichment of large γ-areas near GBs in α-matrix that we consider as potency to increase the cohesive strength of GBs and the cohesive energy of the bulk in γ-phase. Mechanical testing of alloys I and II demonstrates that the alloy II has improved tensile strength and creep resistance at high temperatures.
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Jiang, Diyou, Musheng Wu, Desheng Liu, Fangfang Li, Minggang Chai, and Sanqiu Liu. "Structural Stability, Electronic Structures, Mechanical Properties and Debye Temperature of Transition Metal Impurities in Tungsten: A First-Principles Study." Metals 9, no. 9 (2019): 967. http://dx.doi.org/10.3390/met9090967.

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The structural stability, electronic structures, mechanical properties and Debye temperature of W-TM (TM = Cr, Cu, Fe, Mn, Mo and Ni, respectively) alloys have been investigated by first principles method. The lattice constant, cell volume, formation energy and cohesive energy of W-TM alloys are calculated. W-TM alloys still maintain bcc lattice, and have no structural phase transformation. It is shown that W-Mo and W-Mn alloys have better alloying ability with strong interactions between W and Mo/Mn atoms. However, the alloying ability of W-Cu, W-Fe, W-Cr and W-Ni is poor, and there is a weak chemical interaction between W and Cu/Cr/Fe/Ni atoms. Using the optimized lattice, the elastic constants are calculated, and the elastic moduli and other mechanical parameters are derived. Results show that the mechanical strength of W-TM alloys is lower than that of pure W, especially W-Cu and W-Ni alloys. However, the B/G ratio and Poisson’s ratio of W-TM alloys are higher than that of pure W, indicating that TM alloying can significantly improve the ductility of pure W. The metallicity of pure W can be enhanced by doping Fe or Mn, while doping Cr, Cu, Mo and Ni reduces the metallicity of pure W, of which W-Cu alloy has worst metallicity.
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Jiang, Hui, Li Jiang, Yi Ping Lu, Tong Min Wang, Zhi Qiang Cao, and Ting Ju Li. "Microstructure and Mechanical Properties of the W-Ni-Co System Refractory High-Entropy Alloys." Materials Science Forum 816 (April 2015): 324–29. http://dx.doi.org/10.4028/www.scientific.net/msf.816.324.

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The elements Mo, Cr and V were added to the W-Ni-Co system high entropy alloys, the effects of these added elements on microstructure and mechanical properties of these alloys were studied. The alloys were produced by vacuum arc melting. The compositions were W0.5Ni2Co2VMo0.5,W0.5Ni2Co2VCr0.5and W0.5Ni2Co2CrMo0.5(denoted as Alloy 1, Alloy 2 and Alloy 3) respectively. The theoretical melting temperatures were higher than 2000 K. X-ray diffraction, SEM and energy dispersive spectroscopy (EDS) results indicated that the matrix of the alloys is face-centered cubic (FCC) solid-solution, the alloys showed dendrite crystal structure. Ni, Co elements were enriched in the dendrite areas, the W, Mo were enriched in the inter-dendrite regions ,while V, Cr elements were uniform distribution. The Vickers hardness of these alloys was 376.1 HV, 255.88 HV and 306.8 HV, respectively. The yield strength values (σ0.2) of Alloy 1, Alloy 2 and Alloy 3 were approximately 1000MPa, 750MPa, 250MPa, respectively. The alloys show good compression plasticity deformation capacity at RT.
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Sudbrack, Chantal K., Dieter Isheim, Ronald D. Noebe, Nathan S. Jacobson, and David N. Seidman. "The Influence of Tungsten on the Chemical Composition of a Temporally Evolving Nanostructure of a Model Ni-Al-Cr Superalloy." Microscopy and Microanalysis 10, no. 3 (2004): 355–65. http://dx.doi.org/10.1017/s1431927604040589.

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The influence of W on the temporal evolution of γ′ precipitation toward equilibrium in a model Ni-Al-Cr alloy is investigated by three-dimensional atom-probe (3DAP) microscopy and transmission electron microscopy (TEM). We report on the alloys Ni-10 Al-8.5 Cr (at.%) and Ni-10 Al-8.5 Cr-2 W (at.%), which were aged isothermally in the γ + γ′ two-phase field at 1073 K, for times ranging from 0.25 to 264 h. Spheroidal-shaped γ′ precipitates, 5–15 nm diameter, form during quenching from above the solvus temperature in both alloys at a high number density (∼1023m−3). As γ′ precipitates grow with aging at 1073 K, a transition from spheriodal- to cuboidal-shaped precipitates is observed in both alloys. The elemental partitioning and spatially resolved concentration profiles across the γ′ precipitates are obtained as a function of aging time from three-dimensional atom-by-atom reconstructions. Proximity histogram concentration profiles (Hellman et al., 2000) of the quaternary alloy demonstrate that W concentration gradients exist in γ′ precipitates in the as-quenched and 0.25-h aging states, which disappear after 1 h of aging. The diffusion coefficient of W in γ′ is estimated to be 6.2 × 10−20m2s−1at 1073 K. The W addition decreases the coarsening rate constant, and leads to stronger partitioning of Al to γ′ and Cr to γ.
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Kim, Yonghyeon, Hyeokjoo Choi, Seokhun Kwon, Seokwon Lee, Hyunil Kang, and Wonseok Choi. "Thermal Analysis of Energy Storage Capacity According to Thickness of Nickel/Chromium Alloy Layer." Energies 14, no. 11 (2021): 3217. http://dx.doi.org/10.3390/en14113217.

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This paper examines a microconstruction consisting of nickel (Ni)/chromium (Cr) alloy thin-film. The total length of the microconstruction was 28 mm, the width was 0.2 mm, and the height was designed to be 1 μm. A thin-film of Ni/Cr alloy was co-sputtered on a silicon dioxide wafer patterned with photoresist via a RF magnetron sputtering system. The RF power ratios applied to the 4 inch target of Ni and Cr were 300 W:100 W (3:1), 300 W:150 W (2:1), and 150 W:150 W (1:1). The electrical resistance of the manufactured microconstruction was calculated and measured through Hall measurements. The temperature generated by applying 1–10 V to the microconstruction electrode was observed by using an infrared camera, and was summarized using a linear equation according to the power applied to each sample.
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Qu, Xia, Ying Chun Wang, Xing Wang Cheng, Shuang Zan Zhao, and Shu Kui Li. "Effect of Austenizing Temperature on Microstructures and Mechanical Properties of Cr-W-Ni-Alloy Steel." Applied Mechanics and Materials 248 (December 2012): 26–30. http://dx.doi.org/10.4028/www.scientific.net/amm.248.26.

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An investigation was made to determine the effect of austenizing temperature on microstructure and tensile properties of Cr-W-Ni-alloy steel. Correlations of microstructure tensile properties and austenizing temperature parameters were established. Analysis of optical and scanning electron microscope show that there were a lot of coarse spherical undissolved carbides dispersed on the lath martensitic matrix in as-quenched specimens when austenized at 900°C while there were only very little nanometer carbides when austenized at 1000°C and 1100°C. The tensile properties show that austenizing temperature had large effect on the mechanical property of the Cr-W-Ni-alloy steel. Oil quenching after austenized at 1100°C for 26 minutes followed with tempering at 260°C for 3h, Cr-W-Ni-alloy steel obtained best strength and ductility match.
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Chen, Huaican, Yang Hai, Renduo Liu, et al. "The irradiation hardening of Ni-Mo-Cr and Ni-W-Cr alloy under Xe26+ ion irradiation." Nuclear Instruments and Methods in Physics Research Section B: Beam Interactions with Materials and Atoms 421 (April 2018): 50–58. http://dx.doi.org/10.1016/j.nimb.2018.02.018.

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Byadretdinova, M. A., R. G. Ivanova, N. A. Iofis, and B. V. Molotilov. "Artificial heart valve made of Co-Cr-W-Ni alloy." Biomedical Engineering 20, no. 1 (1986): 21–24. http://dx.doi.org/10.1007/bf00564052.

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Matsumaru, Hiroyuki, Shigenari Hayashi, and Toshio Narita. "Interdiffusion between Ni Based Superalloy and Diffusion Barrier Coatings at 1423K." Materials Science Forum 522-523 (August 2006): 285–92. http://dx.doi.org/10.4028/www.scientific.net/msf.522-523.285.

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A diffusion couple study was carried out with Ni-based superalloy / γ’-Ni3Al with or without a Re-based alloy layer. The Re-based alloy containing Re, W, Cr, and Ni was formed on a second generation, single crystal Ni-based superalloy by using electroplating processes to form films of 70at%Re-Ni and Ni-20at%W, followed by Cr-pack cementation at 1573K for 36ks. The superalloy with or without the Re-based alloy layer was bonded to a γ’−Ni3Al alloy in vacuum. Diffusion couples were annealed in an evacuated quartz ampoule at 1423 K for 90 and 360ks. After the 360ks diffusion treatment the Re-based alloy remained sound and suppressed inward Al diffusion from the γ’-Ni3Al, it was further found that outward diffusion of alloying elements from the alloy substrate to the γ’-Ni3Al was also significantly reduced by the Re-based alloy layer.
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Dissertations / Theses on the topic "Ni-Cr-W Alloy"

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Wang, Wei. "Etude des mécanismes de recristallisation de nouveaux alliages à base de Ni." Phd thesis, Université Paris Sud - Paris XI, 2014. http://tel.archives-ouvertes.fr/tel-01024285.

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Les travaux portent sur deux nuances d'alliages Ni-Cr-W, l'une contenant des précipités de W (EM722) et l'autre non (EM721). Les matériaux forgés, fournis par Aubert & Duval, présentaient des microstructures hétérogènes avec de très gros grains. Dans un premier temps, une procédure thermomécanique a été développée afin d'obtenir un état de référence avec une microstructure homogène avec une faible taille de grains et une texture relativement peu accusée. A partir de cet état de référence, l'évolution de la texture, au cours du laminage à froid (différents taux de réduction), a été analysée par diffraction des neutrons et a montré un renforcement de la texture de type Laiton. Les mécanismes de déformation ont été étudiés en microscopie électronique en transmission et par EBSD (Electron BackScatter Diffraction) afin de comprendre la formation de ce type de texture. Les bandes de cisaillement sont supposées être un facteur important pour la formation de ce type de texture. A partir des états déformés, la cinétique de recristallisation a été déterminée pour deux températures (700°C et 900°C) à partir de mesures de microdureté et par EBSD. Les mécanismes de recristallisation ont été étudiés par MET. Le mécanisme de SIBM (Strain Induced grain Boundary Migration) est le mécanisme prépondérant pour la nuance EM721. Pour l'autre nuance, EM722, possédant des précipités de W, le mécanisme de SIBM est présent, mais en plus, un second mécanisme de PSN (Particle Stimulated Nucleation) a été mis en évidence. De plus, quel que soit le mécanisme de recristallisation, une fois que les germes sont formés, ils maclent très rapidement. Par conséquent, une étude complémentaire sur l'évolution des joints de macle pendant la recristallisation primaire a été réalisée, en employant l'EBSD et surtout le système ASTAR installé dans un MET. Il a alors été montré que cette évolution dépend à la fois de la taille des grains et de l'énergie stockée par les grains pendant la déformation. Enfin, une simulation de la recristallisation primaire de type Monte-Carlo a également été mise en œuvre. Son originalité réside notamment dans sa capacité à rendre compte de la formation des joints de macles cohérents et rectilignes.
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Royer, Agnès. "Evolutions thermique et mécanique de la microstructure de superalliages monocristallins étudiées par diffusion centrale et diffraction (neutrons, rayons [gamma])." Grenoble 1, 1993. http://www.theses.fr/1993GRE10097.

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Les experiences de diffraction et de diffusion des rayonnements gamma et neutron nous ont permis d'etudier la microstructure du superalliage monocristallin am1 ainsi que son evolution en fonction de la temperature. Ces experiences ont pour la plupart ete realisees in situ en temperature et nos resultats qui sont relatifs a un grand nombre de precipites, ne sont pas sensibles aux heterogeneites locales de composition chimique. Nous avons analyse la morphologie des precipites gamma prime a l'aide d'experiences de diffusion aux petits angles des neutrons, au cours des phenomenes de precipitation et de coalescence des precipites gamma prime. La remise en solution de ces precipites a ete etudiee par diffraction neutron jusqu'a complete dissolution. Afin de mieux comprendre les mecanismes qui regissent l'evolution de la morphologie des precipites, nous avons etudie en temperature differents parametres microstructuraux. Par diffraction gamma, nous avons mis en evidence une distorsion tetragonale au sein du materiau et le desaccord parametrique entre les deux phases a pu etre mesure par diffraction neutrons a grands angles de bragg. La synthese des resultats obtenus au cours de ces differentes experiences, nous a permis d'etablir un modele qui prevoit l'evolution des parametres de maille des phases gamma et gamma prime en fonction de la temperature lors de recuits thermiques et sous contrainte
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Gao, Yu-han, and 高鈺涵. "A Study of Microstructure and Wear Behaviors on Ti-6Al-4V Alloy with B4C and Alloying Elements (Ni、Cr、Si、W)." Thesis, 2009. http://ndltd.ncl.edu.tw/handle/82415844631501298773.

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碩士
國立臺灣科技大學
機械工程系
97
In this study, ceramic material (B4C) and ceramic material mixed with different alloying elements (Ni, Cr, Si, W) were cladded on the surface of Ti-6Al-4V alloy with gas tungsten arc welding (GTAW). The wear resistance of cladding layers are evaluated by the wear test of cylinder-on-plate method. The microstructure of cladding layers are determined by SEM, EDS, EPMA and XRD. In addition, the major factors that influence wear performance of cladding layers can be found by the analysis of composites and microstructure. According to results, the B4C cladding layers are classified to precipitation strengthening, the major reinforcement phases are TiB2, TiB and TiC. Ni is dissolved in matrix phase in the B4C-Ni cladding layer, which can be inferred to solid solution strengthening. In the B4C-Si cladding layer, there were not only the reinforcements which were reacted by B4C and Ti alloy but also plate-like Ti5Si3 can be found. Under the low sliding speed (0.11m/s) in the wear test, the wear resistance of B4C-Ni and B4C- Si cladding layers are better than pure B4C cladding layer; under the high sliding speed (0.22m/s), the wear resistance of B4C-Ni, B4C- Si and B4C-Cr cladding layers were better than pure B4C cladding layer; and the B4C-W cladding layer shows the worst wear resistance under the low or high sliding speed in the wear test.
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Book chapters on the topic "Ni-Cr-W Alloy"

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Rodionov, D. P., I. V. Gervasyeva, Yu V. Khlebnikova, and V. A. Kazantsev. "Epitaxial Substrates from Ni-Based Ternary Alloys with Cr and W." In Ceramic Transactions Series. John Wiley & Sons, Inc., 2008. http://dx.doi.org/10.1002/9780470444214.ch2.

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Yamanaka, Kenta, Manami Mori, and Akihiko Chiba. "Effects of Carbon Addition on Mechanical Properties and Microstructures of Ni-Free Co–Cr–W-Based Dental Alloys." In Interface Oral Health Science 2014. Springer Japan, 2015. http://dx.doi.org/10.1007/978-4-431-55192-8_19.

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Zhang, Lifeng, Jianwei Gao, Lucas Nana Wiredu Damoah, and David G. Robertson. "Iron: Removal from Aluminum." In Encyclopedia of Aluminum and Its Alloys. CRC Press, 2019. http://dx.doi.org/10.1201/9781351045636-140000434.

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In this paper, the Fe-rich phases in and their detrimental effect on aluminum alloys are summarized. The existence of brittle platelet β-Fe-rich phases lowers the mechanical properties of aluminum alloys. The methods to neutralize the detrimental effect of iron are discussed. The use of high cooling rate, solution heat treatment, and addition of elements such as Mn, Cr, Be, Co, Mo, Ni, V, W, Cu, Sr, or the rare earth elements Y, Nd, La, and Ce are reported to modify the platelet Fe-rich phases in aluminum alloys. The mechanism of the modification is briefly described. Technologies to remove iron from aluminum are reviewed extensively. The precipitation and removal of Fe-rich phases (sludge) are discussed. The dense phases can be removed by methods such as gravitational separation, electromagnetic (EM) separation, and centrifuge. Other methods include electrolysis, electro-slag refining, fractional solidification, and fluxing refining. The expensive three-layer cell electrolysis process is the most successful technique to remove iron from aluminum so far.
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Conference papers on the topic "Ni-Cr-W Alloy"

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Valtsev, N. V., O. A. Chikova, and A. F. Ryzhkov. "Microstructure and mechanical properties in submicrovolumes of Ni–25 % Cr–15 % W alloy with Ni–Cr–Al powder coating." In PHYSICS, TECHNOLOGIES AND INNOVATION (PTI-2019): Proceedings of the VI International Young Researchers’ Conference. AIP Publishing, 2019. http://dx.doi.org/10.1063/1.5134221.

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Pike, L. M., and S. K. Srivastava. "Long Term Thermal Stability of Several Gas Turbine Alloys." In ASME Turbo Expo 2005: Power for Land, Sea, and Air. ASMEDC, 2005. http://dx.doi.org/10.1115/gt2005-68959.

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Ever increasing demands for lower gas turbine operating costs have led to the need for longer lasting components. This in turn, requires the availability of alloys which are reliable to such long lifetimes. In the mill produced condition, most alloys have desirable microstructures and mechanical properties. However, after exposure to the harsh temperatures found in gas turbine engines, the microstructures of most alloys will begin to change. The effects on the mechanical properties of such microstructural changes can range from mild deterioration to significant degradation. In this paper, the effects of thermal exposures at temperatures from 1200 to 1600°F for durations up to one year on the mechanical properties of three wrought gas turbine alloys will be reported. The alloys will include HAYNES® 188 alloy (Co-Ni-Cr-W), HAYNES 230® alloy (Ni-Cr-W), and HAYNES HR-120® alloy (Fe-Ni-Cr-Nb-N).
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Yamamoto, Y., M. P. Brady, G. Muralidharan, et al. "Development of Creep-Resistant, Alumina-Forming Ferrous Alloys for High-Temperature Structural Use." In ASME 2018 Symposium on Elevated Temperature Application of Materials for Fossil, Nuclear, and Petrochemical Industries. American Society of Mechanical Engineers, 2018. http://dx.doi.org/10.1115/etam2018-6727.

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This paper overviews recent advances in developing novel alloy design concepts of creep-resistant, alumina-forming Fe-base alloys, including both ferritic and austenitic steels, for high-temperature structural applications in fossil-fired power generation systems. Protective, external alumina-scales offer improved oxidation resistance compared to chromia-scales in steam-containing environments at elevated temperatures. Alloy design utilizes computational thermodynamic tools with compositional guidelines based on experimental results accumulated in the last decade, along with design and control of the second-phase precipitates to maximize high-temperature strengths. The alloys developed to date, including ferritic (Fe-Cr-Al-Nb-W base) and austenitic (Fe-Cr-Ni-Al-Nb base) alloys, successfully incorporated the balanced properties of steam/water vapor-oxidation and/or ash-corrosion resistance and improved creep strength. Development of cast alumina-forming austenitic (AFA) stainless steel alloys is also in progress with successful improvement of higher temperature capability targeting up to ∼1100°C. Current alloy design approach and developmental efforts with guidance of computational tools were found to be beneficial for further development of the new heat resistant steel alloys for various extreme environments.
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Arsenault, B., J. G. Legoux, and H. Hawthorne. "Slurry Erosion of High Velocity Oxy-fuel Thermal Sprayed Coatings." In ITSC 1997, edited by C. C. Berndt. ASM International, 1997. http://dx.doi.org/10.31399/asm.cp.itsc1997p0097.

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Abstract Improvement of the high velocity oxy-fuel deposition (HVOF) process in the last decade has enhanced the microstructure of coatings in order to better perform against wear and corrosion. Indeed cermet and metal HVOF coatings are reliable and have excellent performance under slurry erosion and provide therefore an alternative to the use of high-priced material. This paper presents the results of a study undertaken within the core research program of the National Research Council of Canada technology group in surface engineering, "SURFTEC", in which the performance of ten HVOF erosion-resistant coatings was evaluated. Ten different types of HVOF coatings were studied including: six grades of WC with either Co or a Ni based matrix, one grade of Cr3C2 in a Ni-Cr matrix, and three grade of metallic alloy: Ni alloy, Co alloy and a SS 316- L. The performance of coatings was evaluated with respect to: the volume ratio and composition of metallic binder in carbide coatings, type of carbide, coating microstructure, impinging angle and the size of the erodent particles. All coatings were produced using the HVOF JP-5000 system controlled by the Hawcs-ll controller. Slurry erosion tests were conducted with a jet impingement rig with a 10 %w/w alumina particle/water slurry. The volume loss of material under various slurry erosion conditions was related to the coating properties and microstructure. Results indicate that the behavior of HVOF sprayed materials is dependent on the erodent particle size, to the erosion impinging angle to some extent and to the corrosion resistance of the cermet matrix.
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Huang, Xiao. "Microstructure and Oxidation Behaviour of NGB and WGB Joints With Boron/Silicon Free Nickel Base Braze Alloys." In ASME Turbo Expo 2020: Turbomachinery Technical Conference and Exposition. American Society of Mechanical Engineers, 2020. http://dx.doi.org/10.1115/gt2020-14017.

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Abstract In this study, the microstructure and solidus and liquidus of several Ni-Co-Hf-Zr-Ti-Al braze alloys were first examined with the objective to develop a B and Si free low melting braze alloy for narrow gap (NGB) and wide gap brazing (WGB) and turbine component repair applications. Among various alloys examined, DSC was used to measure the solidus and liquidus during heating and cooling cycles. Following the measurements of liquidus and solidus, the microstructure was evaluated using SEM. Equations for calculating solidus and liquidus based on alloy’s compositions were established and the functions of each elements on these two characteristic temperatures were discussed. One selected alloy with a liquidus of 1201 °C was further employed for NGB and WGB experiments. The results showed that it was able join CMSX-4 at 1240°C without interfacial voids; and with the use of externally applied pressure and extended homogenization treatment the interfacial intermetallic compounds were substantially removed. Furthermore, the same braze alloy was used to fill a large artificial cavity in a WGB scheme at a reduced temperature of 1200°C. The braze alloy was able to fully bond the filler powder alloy in addition to join the two alloys to a IN 738 substrate. Finally, oxidation test was conducted at 1050°C (isothermal in static air) for 100 hours after NGB of CMSX-4 and WGB of IN 738. The results showed that the oxide formed on the standalone braze alloy is very dense and there is no sign of spallation. It contained primarily NiO (+CoO) with no other elements measured. For the NGB joints, large amount of scale spallation was observed on base alloy CMSX-4 while the NGB joint remained spallation free. The oxide formed on the NGB was NiO with partitions of Co, Al, Ti, Cr, and W. The WGB joint region in IN 738 showed oxide scale spallation on the IN 738 substrate side, leaving behind steps and depression on the sample surface. In the WGB joint itself, there were three notable phases after oxidation test, however, no scale spallation could be found. For the majority part of the surface, a Ni-rich oxide covered the surface. There were areas of smaller oxide particles with higher Cr content. Overall, the new boron/silicon free braze alloy was found to be able to join several superalloys in both WGB and NGB schemes without occurrence of defects and the oxidation resistance was superior to both substrate alloys examined in this study.
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Farmer, J. C., J. J. Haslam, S. D. Day, et al. "Corrosion Resistance of Iron-Based Amorphous Metal Coatings." In ASME 2006 Pressure Vessels and Piping/ICPVT-11 Conference. ASMEDC, 2006. http://dx.doi.org/10.1115/pvp2006-icpvt-11-93835.

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New amorphous-metal thermal-spray coatings have been developed recently that may provide a viable coating option for spent nuclear fuel & high-level waste repositories [Pang et al. 2002; Shinimiya et al. 2005; Ponnambalam et al. 2004; Branagan et al. 2000–2004]. Some Fe-based amorphous-metal formulations have been found to have corrosion resistance comparable to that of high-performance alloys such as Ni-based Alloy C-22 [Farmer et al. 2004–2006]. These materials rely on Cr, Mo and W for enhanced corrosion resistance, while B is added to promote glass formation and Y is added to lower the critical cooling rate (CCR). Materials discussed in this paper include yttrium-containing SAM1651 with CCR ∼ 80 K/s and yttrium-free Formula 2C with CCR ∼ 600 K/s. While nickel-based Alloy C-22 and Type 316L stainless steel lose their resistance to corrosion during thermal spraying, Fe-based SAM1651 and Formula 2C amorphous-metal coatings can be applied with thermal spray processes without any significant loss of corrosion resistance. In the future, such corrosion-resistant thermal-spray coatings may enable the development of less expensive containers for spent nuclear fuel (SNF) and high-level waste (HLW), including enhanced multipurpose containers (MPCs), protected closure welds, and shields to protect containers from drips and falling rocks. These materials are extremely hard and provide enhanced resistance to abrasion and gouges from backfill operations. For example, Type 316L stainless steel has a hardness of approximately 150 VHN, Alloy C-22 has a hardness of approximately 250 VHN, while the Fe-based amorphous metals typically have hardness values of 1100–1300 VHN. Both Formula 2C and SAM1651 have high boron content which allow them to absorb neutrons, and therefore be used for enhanced criticality control. Cost savings can also be realized through the substitution of Fe-based alloy for Ni-based materials. Applications are also envisioned in oil & gas industry.
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Arsenault, B., J. G. Legoux, J. P. Immarigeon, V. R. Parameswaran, and H. Hawthorne. "Slurry and Dry Erosion of High Velocity Oxy-Fuel Thermal Sprayed Coatings." In ITSC 1998, edited by Christian Coddet. ASM International, 1998. http://dx.doi.org/10.31399/asm.cp.itsc1998p0231.

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Abstract Improvement of the high velocity oxy-fuel deposition (HVOF) process in the last decade has led to coatings with significant improved microstructures for better protection against wear and corrosion. HVOF coatings of cermet and metallic materials provide protection against erosion and are therefore good alternatives to the use of high-priced material. This paper presents the results of a study undertaken within the core research program of the National Research Council of Canada technology group in surface engineering, "SURFTEC", in which the performance of ten HVOF erosion-resistant coatings were evaluated under both dry and slurry erosion. Ten different types of HVOF coatings were studied including: six grades of WC with either Co or a Ni based matrix, one grade of Cr3C2 in a Ni-Cr matrix, and three grades of metallic alloy: Ni alloy, Co alloy and a SS 316-L. Coatings performance was evaluated with respect to the volume ratio and composition of metallic binder in carbide coatings, type of carbide, coating microstructure, impinging angle and the size of the erodent particles. All coatings were produced using the HVOF IP5000 system controlled by the Hawcs-II controller. Slurry jet erosion tests were conducted using a 10 %w/w alumina particle/water slurry. Two alumina particle sizes, 320 and 80 grit (nominal grain diameters 35 μm and 200 μm, respectively) were used. The nominal impact velocity of the slurry was 15 m/s and the nozzle-specimen distance 100 mm. Dry erosion tests were conducted using 50 μm diameter alumina particles projected onto coated flat test coupons through a carbide nozzle of diameter 1.14mm with a particle velocity of 84 m/s at a feed rate of 2 ±1 g/min. let impingement angles of 90° and 20° were used for both dry and slurry erosion tests. The volume loss of material under various erosion conditions was related to the coating properties and microstructure. Results indicate that the coating behavior is dependent on the erodent particle size, the erosion impinging angle to some extent and for slurry erosion, to the corrosion resistance of the cermet matrix.
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8

Cheruvu, N. S. "Development of a Corrosion Resistant Directionally Solidified Material for Land Based Turbine Blades." In ASME 1997 International Gas Turbine and Aeroengine Congress and Exhibition. American Society of Mechanical Engineers, 1997. http://dx.doi.org/10.1115/97-gt-425.

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Advanced turbines with improved efficiency require materials that can operate at higher temperatures. Availability of these materials would minimize cooling flow requirements and thus, improve the efficiency of a turbine. Advanced processing such as directional solidification (DS), can improve temperature capability of the majority of Ni based superalloys. However, results of earlier work on IN-738 reveal that the DS process does not significantly improve temperature capability of this alloy. A research program was initiated to develop a corrosion resistant Ni-based DS blade material for land-based turbines. In this program, eight heats with varied Cr, Al, Ti, Ta, and W contents were selected for evaluation. Screening tests performed on these heats in the DS condition include tensile, creep, and corrosion. The results of experimental heats were compared with those of IN-738 in the equiaxed condition. From these results, two chemistries offering approximately 100°F temperature advantage at typical row 1 turbine blade operating stress, were selected for castability and further mechanical property evaluation. Several row 1 solid and cored turbine blades were successfully cast. The blades were evaluated for grain structure and mechanical properties. Tests were also conducted to evaluate the effects of withdrawal rates on properties. These results are summarized in this paper.
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9

Huang, Xiao, Scott Yandt, Doug Nagy, and Matthew Yao. "Effect of Ruthenium, Rhenium and Yttria Additions on the Microstructure of Wide Gap Brazing of IN738." In ASME Turbo Expo 2007: Power for Land, Sea, and Air. ASMEDC, 2007. http://dx.doi.org/10.1115/gt2007-27129.

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Modern gas and steam turbine components are subject to severe thermomechanical loads and extremely high temperature in order to provide increased performance and efficiency. Most high temperature turbine components are made of superalloys specifically developed for high temperature and high mechanical stress applications but at considerable cost. Defects may occur during manufacturing of superalloy castings as well as after service. Repair of these components, rather than replacement, helps to reduce the life cycle cost. Wide gap brazing is a cost effective and reliable means to repair gas turbine hot section components with defect sizes exceeding 0.3 mm. With proper control of the braze alloy and brazing cycle, the repaired region has been reported to posses mechanical properties approaching that of the parent materials. In order to further improve the mechanical properties of the repaired region and to explore the possibility of employing the wide gap brazing method to repair single crystal components in the future, three alloying additions, Ruthenium (Ru), Rhenium (Re) and yttria (Y2O3), were incorporated into the braze filler metal by mechanical alloying. The microstructures of the wide gap brazed joints with Ru, Re and yttria additions were studied and compared to a braze joint with standard wide gap braze alloys of IN738 and AWS BNi-9. It has been found that two types of borides formed in all braze alloys, namely eutectic γ-Ni-rich and boride phases and discrete boride containing primarily Cr and W (or Ru). The addition of Ru to the filler metal did not seem to modify the microstructural constituents after brazing. However, Ru partitioned strongly to the discrete borides. No isolated elemental Ru region was observed. On the other hand, Re addition was found to change the occurrence and distribution of both types of borides. The eutectic boride constituent was significantly reduced and finer discrete boride particles were observed. The addition of yttria did not change the boride formation but led to the generation of more voids in the brazed joint.
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10

Santella, Michael. "Influence of Chemical Compositions on Lower Ferrite-Austenite Transformation Temperatures in 9Cr Steels." In ASME 2010 Pressure Vessels and Piping Division/K-PVP Conference. ASMEDC, 2010. http://dx.doi.org/10.1115/pvp2010-25748.

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Computational thermodynamics approach was used to predict the ranges of the lower ferrite-austenite transformation temperatures, A1’s, in three 9% Cr steels. The predicted A1 ranges were: 766–856°C for SA387 Grade 91, 775–863°C for SA213 Grade T92, and 676–862°C for the weld metal SFA-5.23 B9 (2004). For Grade 91 and Grade T92 using the highest tempering temperature permitted by ASME Code, 800°C, would permit certain alloys conforming to the chemical composition specification to be tempered above their A1, thereby risking the formation of untempered martensite. Similar circumstances exist for weld metal conforming to the SFA-5.23 B9 specification. Linear regression analyses were performed to develop simplified expressions capable of representing the thermodynamically predicted relationships between chemical compositions and A1’s. These are, Grade 91/SFA-5.23 B9 (2004): 805°C + 2.5(%Cr) + 18.1(%Mo) + 19.1(%Si) + 37.1(%V) + 19.2(%Nb) − 63.7(%C) − 130.6(%N) − 60.5(%Mn) − 72.3(%Ni); Grade T92: 778°C + 4.9(%Cr) + 22.6(%Mo) + 10.8(%W) + 22.9(%Si) + 43.6(%V) + 20.2(%Nb) − 80.6(%C) − 150.7(%N) − 55.1(%Mn) − 68.0(%Ni).
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Reports on the topic "Ni-Cr-W Alloy"

1

NA. KINETICS OF CATHODIC REDUCTION OF OXYGEN ON NI-CR-MO-W ALLOY. Office of Scientific and Technical Information (OSTI), 2006. http://dx.doi.org/10.2172/886552.

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2

D. Zagidulin, P. Jakupi, J.J. Noel, and D.W. Shoesmith. Evaluation of an Oxide Layer on NI-CR-MO-W Alloy Using Electrochemical Impedance Spectroscopy and Surface Analysis. Office of Scientific and Technical Information (OSTI), 2006. http://dx.doi.org/10.2172/899320.

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