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1

Goodwin, David G., Huayang Zhu, Andrew M. Colclasure, and Robert J. Kee. "Modeling Electrochemical Oxidation of Hydrogen on Ni–YSZ Pattern Anodes." Journal of The Electrochemical Society 156, no. 9 (2009): B1004. http://dx.doi.org/10.1149/1.3148331.

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2

Yao, W., and E. Croiset. "Investigation of H2, CO and Syngas Electrochemical Performance Using Ni/YSZ Pattern Anodes." ECS Transactions 53, no. 30 (October 6, 2013): 163–72. http://dx.doi.org/10.1149/05330.0163ecst.

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3

Yurkiv, Vitaliy, Annika Utz, André Weber, Ellen Ivers-Tiffée, Hans-Robert Volpp, and Wolfgang G. Bessler. "Elementary Kinetic Numerical Simulation of Electrochemical CO Oxidation on Ni/YSZ Pattern Anodes." ECS Transactions 35, no. 1 (December 16, 2019): 1743–51. http://dx.doi.org/10.1149/1.3570162.

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4

Yao, Weifang, and Eric Croiset. "Stability and electrochemical performance of Ni/YSZ pattern anodes in H2/H2O atmosphere." Canadian Journal of Chemical Engineering 93, no. 12 (October 7, 2015): 2157–67. http://dx.doi.org/10.1002/cjce.22330.

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5

Yurkiv, Vitaliy, Annika Utz, André Weber, Ellen Ivers-Tiffée, Hans-Robert Volpp, and Wolfgang G. Bessler. "Elementary kinetic modeling and experimental validation of electrochemical CO oxidation on Ni/YSZ pattern anodes." Electrochimica Acta 59 (January 2012): 573–80. http://dx.doi.org/10.1016/j.electacta.2011.11.020.

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6

Yao, W., and E. Croiset. "Ni/YSZ pattern anodes fabrication and their microstructure and electrochemical behavior changes in H2–H2O environments." Journal of Power Sources 226 (March 2013): 162–72. http://dx.doi.org/10.1016/j.jpowsour.2012.10.053.

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7

Bai, Shuang, and Jian Liu. "Femtosecond Laser Additive Manufacturing of Multi-Material Layered Structures." Applied Sciences 10, no. 3 (February 3, 2020): 979. http://dx.doi.org/10.3390/app10030979.

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Laser additive manufacturing (LAM) of a multi-material multi-layer structure was investigated using femtosecond fiber lasers. A thin layer of yttria-stabilized zirconia (YSZ) and a Ni–YSZ layer were additively manufactured to form the electrolyte and anode support of a solid oxide fuel cell (SOFC). A lanthanum strontium manganite (LSM) layer was then added to form a basic three layer cell. This single step process eliminates the need for binders and post treatment. Parameters including laser power, scan speed, scan pattern, and hatching space were systematically evaluated to obtain optimal density and porosity. This is the first report to build a complete and functional fuel cell by using the LAM approach.
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8

Singh, Saurabh, Raghvendra Pandey, Sabrina Presto, Maria Paola Carpanese, Antonio Barbucci, Massimo Viviani, and Prabhakar Singh. "Suitability of Sm3+-Substituted SrTiO3 as Anode Materials for Solid Oxide Fuel Cells: A Correlation between Structural and Electrical Properties." Energies 12, no. 21 (October 24, 2019): 4042. http://dx.doi.org/10.3390/en12214042.

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Perovskite anodes, nowadays, are used in any solid oxide fuel cell (SOFC) instead of conventional nickel/yttria-stabilized zirconia (Ni/YSZ) anodes due to their better redox and electrochemical stability. A few compositions of samarium-substituted strontium titanate perovskite, SmxSr1−xTiO3−δ (x = 0.00, 0.05, 0.10, 0.15, and 0.20), were synthesized via the citrate-nitrate auto-combustion route. The XRD patterns of these compositions confirm that the solid solubility limit of Sm in SrTiO3 is x < 0.15. The X-ray Rietveld refinement for all samples indicated the perovskite cubic structure with a P m 3 ¯ m space group at room temperature. The EDX mapping of the field emission scanning electron microscope (FESEM) micrographs of all compositions depicted a lower oxygen content in the specimens respect to the nominal value. This lower oxygen content in the samples were also confirmed via XPS study. The grain sizes of SmxSr1−xTiO3 samples were found to increase up to x = 0.10 and it decreases for the composition with x > 0.10. The AC conductivity spectra were fitted by Jonscher’s power law in the temperature range of 500–700 °C and scaled with the help of the Ghosh and Summerfield scaling model taking νH and σdc T as the scaling parameters. The scaling behaviour of the samples showed that the conduction mechanism depends on temperature at higher frequencies. Further, a study of the conduction mechanism unveiled that small polaron hopping occurred with the formation of electrons. The electrical conductivity, in the H2 atmosphere, of the Sm0.10Sr0.90TiO3 sample was found to be 2.7 × 10−1 S∙cm−1 at 650 °C, which is the highest among the other compositions. Hence, the composition Sm0.10Sr0.90TiO3 can be considered as a promising material for the application as the anode in SOFCs.
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9

Zhang, Yun, Bin Liu, Baofeng Tu, Yonglai Dong, and Mojie Cheng. "Redox Properties of Ni-YSZ Anodes." ECS Transactions 25, no. 33 (December 17, 2019): 97–106. http://dx.doi.org/10.1149/1.3334796.

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10

Kong, Jiangrong, Kening Sun, Derui Zhou, Naiqing Zhang, Ju Mu, and Jinshuo Qiao. "Ni–YSZ gradient anodes for anode-supported SOFCs." Journal of Power Sources 166, no. 2 (April 2007): 337–42. http://dx.doi.org/10.1016/j.jpowsour.2006.12.042.

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11

Szász, Julian, Sascha Seils, Dino Klotz, Heike Störmer, Martin Heilmaier, Dagmar Gerthsen, Harumi Yokokawa, and Ellen Ivers-Tiffée. "High-Resolution Studies on Nanoscaled Ni/YSZ Anodes." Chemistry of Materials 29, no. 12 (June 13, 2017): 5113–23. http://dx.doi.org/10.1021/acs.chemmater.7b00360.

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12

Szasz, J., D. Klotz, H. Stormer, D. Gerthsen, and E. Ivers-Tiffee. "Nanostructured Ni/YSZ Anodes: Fabrication and Performance Analysis." ECS Transactions 57, no. 1 (October 6, 2013): 1469–78. http://dx.doi.org/10.1149/05701.1469ecst.

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13

Keyvanfar, P., A. R. Hanifi, P. Sarkar, T. H. Etsell, and V. Birss. "Enhancing the Stability of Infiltrated Ni/YSZ Anodes." ECS Transactions 68, no. 1 (July 17, 2015): 1255–63. http://dx.doi.org/10.1149/06801.1255ecst.

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14

Maček, J., B. Novosel, and M. Marinšek. "Ni–YSZ SOFC anodes—Minimization of carbon deposition." Journal of the European Ceramic Society 27, no. 2-3 (January 2007): 487–91. http://dx.doi.org/10.1016/j.jeurceramsoc.2006.04.107.

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15

Qiao, Jinshuo, Kening Sun, Naiqing Zhang, Bing Sun, Jiangrong Kong, and Derui Zhou. "Ni/YSZ and Ni–CeO2/YSZ anodes prepared by impregnation for solid oxide fuel cells." Journal of Power Sources 169, no. 2 (June 2007): 253–58. http://dx.doi.org/10.1016/j.jpowsour.2007.03.006.

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16

RINGUEDE, A. "Assessment of Ni/YSZ anodes prepared by combustion synthesis." Solid State Ionics 146, no. 3-4 (February 2002): 219–24. http://dx.doi.org/10.1016/s0167-2738(01)00996-1.

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17

Gewies, Stefan, and Wolfgang G. Bessler. "Physically Based Impedance Modeling of Ni/YSZ Cermet Anodes." Journal of The Electrochemical Society 155, no. 9 (2008): B937. http://dx.doi.org/10.1149/1.2943411.

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18

Sonn, Volker, André Leonide, and Ellen Ivers-Tiffee. "Towards Understanding the Impedance Response of Ni/YSZ Anodes." ECS Transactions 7, no. 1 (December 19, 2019): 1363–72. http://dx.doi.org/10.1149/1.2729240.

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19

Panahi, Ali Keshavarz, Hossein Khoshkish, and Mostafa Rezaee Saraji. "Fabrication of porous Ni–YSZ anodes by PSH-PIM." Ionics 17, no. 8 (May 20, 2011): 733–40. http://dx.doi.org/10.1007/s11581-011-0572-0.

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20

Buyukaksoy, A., and V. Birss. "Stabilization of Ni-YSZ Nanocomposite Anodes by Deposition of a Thin YSZ Overlayer." ECS Transactions 66, no. 2 (May 15, 2015): 267–74. http://dx.doi.org/10.1149/06602.0267ecst.

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21

Tiwari, P. K., and S. Basu. "Comparison of Performance of Ni-CeO2-YSZ and Ni-Nb2O5-YSZ Anodes for Solid Oxide Fuel Cell." ECS Transactions 57, no. 1 (October 6, 2013): 1545–52. http://dx.doi.org/10.1149/05701.1545ecst.

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22

Keyvanfar, P., and V. Birss. "Optimization of Infiltration Techniques Used to Construct Ni/YSZ Anodes." ECS Transactions 57, no. 1 (October 6, 2013): 1627–38. http://dx.doi.org/10.1149/05701.1627ecst.

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23

Marinšek, Marjan, Klementina Zupan, and Jadran Maèek. "Ni–YSZ cermet anodes prepared by citrate/nitrate combustion synthesis." Journal of Power Sources 106, no. 1-2 (April 2002): 178–88. http://dx.doi.org/10.1016/s0378-7753(01)01056-4.

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24

Keyvanfar, Parastoo, and Viola Birss. "Optimization of Infiltration Techniques Used to Construct Ni/YSZ Anodes." Journal of The Electrochemical Society 161, no. 5 (2014): F660—F667. http://dx.doi.org/10.1149/2.056405jes.

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25

Primdahl, S. "Limitations in the Hydrogen Oxidation Rate on Ni/YSZ Anodes." ECS Proceedings Volumes 1999-19, no. 1 (January 1999): 530–40. http://dx.doi.org/10.1149/199919.0530pv.

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26

Cimenti, Massimiliano, Vanesa Alzate-Restrepo, and Josephine M. Hill. "Direct utilization of methanol on impregnated Ni/YSZ and Ni–Zr0.35Ce0.65O2/YSZ anodes for solid oxide fuel cells." Journal of Power Sources 195, no. 13 (July 2010): 4002–12. http://dx.doi.org/10.1016/j.jpowsour.2009.12.119.

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27

Harris, Jeffrey, Elisa Lay-Grindler, Craig Metcalfe, and Olivera Kesler. "Degradation of Metal-Supported Cells with Ni-YSZ or Ni-Ni3Sn-YSZ Anodes Operated with Methane-Based Fuels." ECS Transactions 78, no. 1 (May 30, 2017): 1293–304. http://dx.doi.org/10.1149/07801.1293ecst.

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28

Tiwari, Pankaj, and Suddhasatwa Basu. "Performance studies of electrolyte-supported solid oxide fuel cell with Ni–YSZ and Ni–TiO2–YSZ as anodes." Journal of Solid State Electrochemistry 18, no. 3 (November 24, 2013): 805–12. http://dx.doi.org/10.1007/s10008-013-2326-6.

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29

Timmermann, H., D. Fouquet, A. Weber, E. Ivers-Tiffée, U. Hennings, and R. Reimert. "Internal Reforming of Methane at Ni/YSZ and Ni/CGO SOFC Cermet Anodes." Fuel Cells 6, no. 3-4 (August 2006): 307–13. http://dx.doi.org/10.1002/fuce.200600002.

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30

Xu, Jingxiang, Shandan Bai, Yuji Higuchi, Nobuki Ozawa, Kazuhisa Sato, Toshiyuki Hashida, and Momoji Kubo. "Multi-nanoparticle model simulations of the porosity effect on sintering processes in Ni/YSZ and Ni/ScSZ by the molecular dynamics method." Journal of Materials Chemistry A 3, no. 43 (2015): 21518–27. http://dx.doi.org/10.1039/c5ta05575j.

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The effects of the ceramic type and porosity on the sintering and degradation in Ni/YSZ and Ni/ScSZ anodes are unveiled by a recently developed multi-nanoparticle sintering simulation method based on molecular dynamics simulation.
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31

Chen, Yun, Song Chen, Gregory Hackett, Harry Finklea, John Zondlo, Ismail Celik, Xueyan Song, and Kirk Gerdes. "Microstructure degradation of YSZ in Ni/YSZ anodes of SOFC operated in phosphine-containing fuels." Solid State Ionics 234 (March 2013): 25–32. http://dx.doi.org/10.1016/j.ssi.2012.12.019.

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32

Tu, Baofeng, Xin Su, Yanxia Yin, Fujun Zhang, Xianjun Lv, and Mojie Cheng. "Methane conversion reactions over LaNi-YSZ and Ni-YSZ anodes of solid oxide fuel cell." Fuel 278 (October 2020): 118273. http://dx.doi.org/10.1016/j.fuel.2020.118273.

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33

Jia, Li, Zhe Lu, Jipeng Miao, Zhiguo Liu, Guoqing Li, and Wenhui Su. "Effects of pre-calcined YSZ powders at different temperatures on Ni–YSZ anodes for SOFC." Journal of Alloys and Compounds 414, no. 1-2 (April 2006): 152–57. http://dx.doi.org/10.1016/j.jallcom.2005.03.119.

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34

Ivashutenko, A. S., I. V. Ionov, A. S. Maznoy, A. A. Sivkov, and A. A. Solovyev. "Comparative Evaluation of Spark Plasma and Conventional Sintering of NiO/YSZ Layers for Metal-Supported Solid Oxide Fuel Cells." High Temperature Materials and Processes 37, no. 4 (March 26, 2018): 351–56. http://dx.doi.org/10.1515/htmp-2016-0193.

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AbstractNiO/YSZ anode layers for metal-supported solid oxide fuel cells (MS-SOFCs) were fabricated by spark plasma sintering (SPS). SPS parameters were optimized in order to achive anodes of the desired microstructure. The effect of sintering conditions on microstructure of NiO/YSZ was studied by scanning electron microscopy and X-ray diffractometry. Also NiO/YSZ layers were formed on porous metal supports by a screen-printing method and sintered in inert atmosphere and vacuum by conventional sintering technique. At temperatures above 1,200 °С in inert atmosphere and vacuum nickel oxide dissociation and its massive agglomeration are observed during conventional sintering. SPS process allows sintering of NiO/YSZ granules without NiO dissociation, Ni agglomeration and the metal substrate oxidation at 1,100 °С. SPS sintered anodes demonstrate sufficiently homogeneous distribution of NiO and YSZ making a conduction path for electrons and ions. Well-bonded metal support/anode interface was obtained.
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35

Song, Bowen, Enrique Ruiz-Trejo, Antonio Bertei, and Nigel P. Brandon. "Quantification of the degradation of Ni-YSZ anodes upon redox cycling." Journal of Power Sources 374 (January 2018): 61–68. http://dx.doi.org/10.1016/j.jpowsour.2017.11.024.

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36

Alzate-Restrepo, Vanesa, and Josephine M. Hill. "Carbon deposition on Ni/YSZ anodes exposed to CO/H2 feeds." Journal of Power Sources 195, no. 5 (March 2010): 1344–51. http://dx.doi.org/10.1016/j.jpowsour.2009.09.014.

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37

Ringuedé, A., D. I. Bronin, and J. R. Frade. "Electrochemical Behaviour of Ni/YSZ Cermet Anodes Prepared by Combustion Synthesis." Fuel Cells 1, no. 3-4 (December 2001): 238–42. http://dx.doi.org/10.1002/1615-6854(200112)1:3/4<238::aid-fuce238>3.0.co;2-i.

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38

Mogensen, M. "Relations between Performance and Structure of Ni-YSZ-Cermet SOFC Anodes." ECS Proceedings Volumes 1995-1, no. 1 (January 1995): 657–66. http://dx.doi.org/10.1149/199501.0657pv.

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39

Solov’ev, A. A., N. S. Sochugov, I. V. Ionov, A. V. Shipilova, and A. N. Koval’chuk. "Magnetron formation of Ni/YSZ anodes of solid oxide fuel cells." Russian Journal of Electrochemistry 50, no. 7 (July 2014): 647–55. http://dx.doi.org/10.1134/s1023193514070155.

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40

Singh, Anand, and Venkatesan Krishnan. "Anode Characterization and SOFC Performance using Ni-YSZ Anodes Formed by Ni Impregnation Methods." ECS Transactions 6, no. 21 (December 19, 2019): 25–32. http://dx.doi.org/10.1149/1.2837818.

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41

Bebelis, S. "AC impedance study of Ni–YSZ cermet anodes in methane-fuelled internal reforming YSZ fuel cells." Solid State Ionics 152-153 (December 2002): 447–53. http://dx.doi.org/10.1016/s0167-2738(02)00369-7.

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42

Buyukaksoy, Aligul, Sanoop P. Kammampata, and Viola I. Birss. "Effect of porous YSZ scaffold microstructure on the long-term performance of infiltrated Ni-YSZ anodes." Journal of Power Sources 287 (August 2015): 349–58. http://dx.doi.org/10.1016/j.jpowsour.2015.04.072.

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43

Modena, Stefano, Sergio Ceschini, Andrea Tomasi, Dario Montinaro, and Vincenzo M. Sglavo. "Reduction and Reoxidation Processes of NiO∕YSZ Composite for Solid Oxide Fuel Cell Anodes." Journal of Fuel Cell Science and Technology 3, no. 4 (March 17, 2006): 487–91. http://dx.doi.org/10.1115/1.2349533.

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Solid oxide fuel cells (SOFCs) are an emerging technology in hydrogen-based energy production, thanks to their high performance, high power density, high efficiency, and reduced emissions over conventional power generation technologies. For these reasons, a great attention has been addressed in these years to SOFCs materials and technologies. An important issue related to the utilization of SOFCs as power generators is the capability of SOFCs materials to resist to thermal cycles in different atmospheres. The present work proposes an experimental investigation on the reduction process of NiO∕YSZ anode into Ni∕YSZ cermet, which is the best candidate for anode material in SOFCs, its reoxidation into NiO∕YSZ and the following rereduction into Ni∕YSZ. Anodes with different NiO∕YSZ ratios were analyzed through different physical and chemical techniques, such as scanning electron microscopy (SEM) and porosity measurements. The reduction, reoxidation and rereduction behaviors were studied by thermogravimetric analysis (TGA) in a unique long experiment, at different temperatures in the range of 700–800°C. The kinetics of the processes was studied and thermodynamic parameters such as activation energy were also calculated and correlated to the compositions and microstructure of the materials. The study clears up the effect of anode composition and microstructure on the reduction, reoxidation, and rereduction processes.
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44

Benyoucef, Amel, Didier Klein, Olivier Rapaud, Christian Coddet, and Boumediene Benyoucef. "Thermal stability of atmospheric plasma sprayed (Ni, Cu, Co)–YSZ and Ni–Cu–Co–YSZ anodes cermets for SOFC application." Journal of Physics and Chemistry of Solids 70, no. 12 (December 2009): 1487–95. http://dx.doi.org/10.1016/j.jpcs.2009.09.009.

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45

Lu, Lanying, Chengsheng Ni, Mark Cassidy, and John T. S. Irvine. "Demonstration of high performance in a perovskite oxide supported solid oxide fuel cell based on La and Ca co-doped SrTiO3." Journal of Materials Chemistry A 4, no. 30 (2016): 11708–18. http://dx.doi.org/10.1039/c6ta04074h.

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Perovskite electrodes have been considered as an alternative to Ni-YSZ cermet-based anodes as they afford better tolerance towards coking and impurities and due to redox stability can allow very high levels of fuel utilisation.
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46

Li, Xiaxi, Mingfei Liu, Jung-pil Lee, Dong Ding, Lawrence A. Bottomley, Soojin Park, and Meilin Liu. "An operando surface enhanced Raman spectroscopy (SERS) study of carbon deposition on SOFC anodes." Physical Chemistry Chemical Physics 17, no. 33 (2015): 21112–19. http://dx.doi.org/10.1039/c4cp05176a.

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47

Iwanschitz, Boris, Josef Sfeir, Andreas Mai, and Michael Schütze. "Degradation of SOFC Anodes upon Redox Cycling: A Comparison Between Ni/YSZ and Ni/CGO." Journal of The Electrochemical Society 157, no. 2 (2010): B269. http://dx.doi.org/10.1149/1.3271101.

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48

Hardjo, Eric, Dayadeep S. Monder, and Kunal Karan. "Numerical Modeling of Nickel-Impregnated Porous YSZ-Supported Anodes and Comparison to Conventional Composite Ni-YSZ Electrodes." ECS Transactions 35, no. 1 (December 16, 2019): 1823–32. http://dx.doi.org/10.1149/1.3570171.

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49

IOROI, Tsutomu, Yoshiharu UCHIMOTO, Zempachi OGUMI, and Zen-ichiro TAKEHARA. "Preparation and Characteristics of Ni/YSZ Cermet Anodes by Vapor-phase Deposition." Denki Kagaku oyobi Kogyo Butsuri Kagaku 64, no. 6 (June 5, 1996): 562–67. http://dx.doi.org/10.5796/kogyobutsurikagaku.64.562.

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50

Li, Ying, Yusheng Xie, Jianghong Gong, Yunfa Chen, and Zhongtai Zhang. "Preparation of Ni/YSZ materials for SOFC anodes by buffer-solution method." Materials Science and Engineering: B 86, no. 2 (September 2001): 119–22. http://dx.doi.org/10.1016/s0921-5107(01)00683-3.

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