Relevant bibliographies by topics / Nickel Laterites

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Academic literature on the topic 'Nickel Laterites'

Author: Grafiati
Published: 4 June 2021
Last updated: 1 February 2022

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Journal articles on the topic "Nickel Laterites"

1

Gleeson, S. A., C. R. M. Butt, and M. Elias. "Nickel Laterites: A Review." SEG Discovery, no. 54 (July 1, 2003): 1–18. http://dx.doi.org/10.5382/segnews.2003-54.fea.

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ABSTRACT Nickel laterite deposits are formed by the prolonged and pervasive weathering of Ni silicate-bearing ultramafıc rocks, generally in tropical to subtropical climates. The deposits can be further classifıed as hydrous silicate deposits (e.g., SLN Operations, New Caledonia), clay silicate deposits (e.g., Murrin Murrin, Australia), and oxide deposits (e.g., Moa Bay, Cuba; Cawse, Australia) on the basis of the ore mineralogy. The physical and chemical nature of a nickel laterite deposit is a function of many factors, including the composition of the parent rock, the tectonic setting, climate, topography (specifıcally, laterite morphology), and drainage. Nickel laterite ore is extracted using both selective and bulk mining methods in open cast mining operations. The mined ore has traditionally been processed either by hydrometallurgical leaching technology (pressure acid leach or Caron processes) to produce oxides of nickel and cobalt or mixed Ni-Co sulfıdes for market, or by pyrometallurgical smelting to produce ferronickel granules or nickel matte. However, recent advances in high-pressure acid leaching and continued testing of atmospheric leach technology should lead to a reduction in overall operating costs and increased exploitation of Ni laterite resources in the future.
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Stanković, Srdjan, Srećko Stopić, Miroslav Sokić, Branislav Marković, and Bernd Friedrich. "Review of the past, present, and future of the hydrometallurgical production of nickel and cobalt from lateritic ores." Metallurgical and Materials Engineering 26, no. 2 (July 22, 2020): 199–208. http://dx.doi.org/10.30544/513.

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Laterite ores are becoming the most important global source of nickel and cobalt. Pyrometallurgical processing of the laterites is still a dominant technology, but the share of nickel and cobalt produced by the application of various hydrometallurgical technologies is increasing. Hydrometallurgy is a less energy-demanding process, resulting in lower operational costs and environmental impacts. This review covers past technologies for hydrometallurgical processing of nickel and cobalt (Caron), current technologies (high-pressure acid leaching, atmospheric leaching, heap leaching), developing technologies (Direct nickel, Neomet) as well as prospective biotechnologies (Ferredox process).
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McDonald, Robbie G., and Jian Li. "The High Temperature Co-Processing of Nickel Sulfide and Nickel Laterite Sources." Minerals 10, no. 4 (April 14, 2020): 351. http://dx.doi.org/10.3390/min10040351.

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The pressure oxidation of low-grade nickel sulfide concentrate with high iron sulfides content generates significant amounts of sulfuric acid that must be neutralized. This acid can be utilized to leach metal values from ores such as nickel laterites. The present study demonstrates the use of a low-grade nickel concentrate generated from Poseidon Nickel Mt Windarra ore to enable additional nickel and cobalt extraction from a Bulong Nickel Operation nickel laterite blend. The co-processing of these materials at 250 °C, with oxygen overpressure, using total pulp densities of 30% or 40% w/w, and a range of nickel concentrate to nickel laterite mass ratios between 0.30–0.53, yielded base metal extractions of 95% or greater. The final free acid range was between 21.5–58.5 g/L, which indicates that enough in situ sulfuric acid was generated during co-processing. The acid was shown from mineralogical analysis to be efficiently utilized to dissolve the laterite ore, which indicates that the primary iron hydrolysis product was hematite, while the aluminum-rich sodium alunite/jarosite phase that formed hosts approximately 5% of the hydrolyzed iron.
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Tupaz, Carmela Alen J., Yasushi Watanabe, Kenzo Sanematsu, Takuya Echigo, Carlo Arcilla, and Cherisse Ferrer. "Ni-Co Mineralization in the Intex Laterite Deposit, Mindoro, Philippines." Minerals 10, no. 7 (June 27, 2020): 579. http://dx.doi.org/10.3390/min10070579.

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The Intex laterite deposit in Mindoro, Philippines is derived from the weathering of the ultramafic rocks under a tropical climate. This study investigates the several types of serpentines and the effect of the degree of chemical weathering of ultramafic rocks and laterites on the enrichment of Ni in the deposit. The five types of serpentines are differentiated based on their textural features and Raman spectral data. Type I, type II, type III, and type IV serpentines contain a low amount of NiO (average 0.15 wt%), and their formation is linked to the previous exhumation of the ultramafic body. Conversely, type V serpentines show the highest NiO contents (average 1.42 wt%) and have the composition of serpentine-like garnierites, indicating a supergene origin. In the limonite horizon, goethite is the main ore mineral and shows high NiO contents of up to 1.68 wt%, whereas the Mn-oxyhydroxides (i.e., asbolane and lithiophorite–asbolane intermediate) display substantial amounts of CoO (up to 11.3 wt%) and NiO (up to 15.6 wt%). The Ultramafic Index of Alteration (UMIA) and Index of Lateritization (IOL) are used to characterize the different stages of weathering of rocks and laterites. The calculated index values correspond to a less advanced stage of weathering of the Intex laterites compared with the Berong laterites. The Berong deposit is a Ni-Co laterite deposit in the Philippines, which is formed from the weathering of the serpentinized peridotite. The less extreme degree of weathering of the Intex laterites indicates less advanced leaching, and thereby the re-distribution of Ni, Si, and Mg from the limonite towards the saprolite horizon may have resulted in the poor precipitation of talc-like (kerolite-pimelite) and sepiolite-like (sepiolite-falcondoite) phases in the studied saprolite horizon. Nickel in the Intex deposit has undergone supergene enrichment similar to other humid tropical laterite deposits.
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Oxley, Anne, Mark E. Smith, and Omar Caceres. "Why heap leach nickel laterites?" Minerals Engineering 88 (March 2016): 53–60. http://dx.doi.org/10.1016/j.mineng.2015.09.018.

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Bustamante Rúa, Moises Oswaldo, Sindy Dayanis Gonzalez Arias, and Pablo Bustamante Baena. "Nickel laterite concentration through a non-conventional method with surface sulfidization." DYNA 87, no. 215 (October 1, 2020): 18–27. http://dx.doi.org/10.15446/dyna.v87n215.85981.

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Nickel ores are found mainly as sulfides and laterites in oxidized ores, such as iron oxides, which are usually “Ni-bearing”. This investigation determined the physical-chemical conditions necessary to increase the tenor and recovery in lateritic deposits, with the implementation of a new technology that allows the increase of the tenor (a process called “up-grading”). The froth flotation is proposed as a concentrating process to increase the Nickel content in the lateritic deposits. By means of sulfidization and direct flotation, specific hydrophobicity of the mineral is achieved, substantially improving the nickel concentrations in the process, with recoveries close to 86%, which, compared with conventional direct and inverse floats without effecting this activation with Na2S, results in recoveries of 70% and 16%, respectively. The reverse flotation also increases the Nickel content with an approximate recovery of 70%; however, the froth flotation, with activation Na2S is still better.
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Pho, Nguyen Van, Pham Tich Xuan, and Pham Thanh Dang. "Occurrence of supergene nickel ores in the Ha Tri Massive, Hoa An District, Cao Bang Province." VIETNAM JOURNAL OF EARTH SCIENCES 40, no. 2 (January 19, 2018): 154–65. http://dx.doi.org/10.15625/0866-7187/40/2/11676.

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Nickel (Ni) laterites are regolith materials derived from ultramafic rocks and play an important role in the world's Ni production. Ni-laterite deposits are the supergene enrichment of Ni formed from the intense chemical and mechanical weathering of ultramafic parental rocks. In Vietnam, the weathering profile containing Ni laterite was first discovered in the Ha Tri massive (Cao Bang). This profile develops on the Ha Tri serpentinized peridotite rocks classified to the Cao Bang mafic-ultramafic complex (North Vietnam) and exhibits thick weathered zone (10 - 15m). This work carried out a detailed study of the weathering profile at the center of Ha Tri massive. Samples from different horizons of the profile were collected and analyzed in detail by XRF, XRD and SEM-EDX methods to establish the relationship between the Ni-rich supergene products and the parental peridotites (lherzolite) rocks in Ha Tri massive. The results show that the saprolite horizon is most Ni-rich in the weathering profile in Ha Tri. In this horizon, Ni-silicate minerals of garnierite group such as pimelite, nepouite and other Mg-Ni silicates have been found. The appearance of minerals of garnierite group is due to the exchange of Mg by Ni during weathering of peridotite minerals, especially olivine, which leads to the enrichment of the supergene Ni. The occurrence of Ni silicates suggests the existence of the supergene Ni ore in the weathering profile of the Ha Tri massive.References Bosio N.J., Hurst J.V., Smith R.L., 1975. Nickelliferousnontronite, a 15 Å garnierite, at Niquelandia, Goias Brazil. Clays Clay Miner., 23, 400-403. Brand N.W., Butt C.R.M., Elias M., 1998. Nickel Laterites: Classification and features. AGSO Journal of Australian Geology & Geophysics, 17(4), 81-88. Bricker O.P., Nesbitt H.W. and Gunter W.D., 1973. The stability of talc. American Mineralogist, 58, 64-72. Brindley G.W. and Hang P.T., 1973. The nature of garnierites. Structures, chemical composition and color characteristics. Clay and Clay Minerals, 21, 27-40. Brindley G.W. and Maksimovic Z., 1974. The nature and nomenclature of hydrous nickel-containing silicates. Clay Minerals, 10, 271-277. Brindley G.W. and Wan H.M., 1975. Composition structures and thermal behavior of nickel containing minerals in thelizardite-ne´pouite series. American Mineralogist, 60, 863-871. Brindley G.W., Bish D.L. and Wan H.M., 1979. Compositions, structures and properties of nickel containing minerals in the kerolite-pimelite series. American Mineralogist, 64, 615-625. Cluzel D. and Vigier B., 2008. Syntectonic mobility of supergene nickel ores from New Caledonia (Southwest Pacific). Evidence from faulted regolith and garnierite veins. Resource Geology, 58, 161-170. Colin F., Nahon D., Trescases J.J., Melfi A.J., 1990. Lateritic weathering of pyroxenites at Niquelandia, Goais, Brazil: The supergene behavior ofnickel: Economic Geology, 85, 1010-1023. Das S.K., Sahoo R.K., Muralidhar J., Nayak B.K., 1999. Mineralogy and geochemistry of profilesthrough lateritic nickel deposits at Kansa,Sukinda, Orissa. Joural of Geoogical. SocietyIndia, 53, 649-668. Decarreau A., Colin F., Herbillon A., Manceau A., Nahon D., Paquet H., Trauth-Badaud D.,Trescases J.J., 1987. Domain segregation in NiFe-Mg-Smectites. Clay Minerals, 35, 1-10. Freyssinet P., Butt C.R.M. and Morris R.C., 2005. Oreforming processes related to lateritic weathering. Economic Geology, 100th aniversary volume, 681-722.Garnier J., Quantin C., Martins E.S., Becquer T., 2006. Solid speciation and availability of chromium in ultramafic soils from Niquelandia, Brazil. Journal of Geochemical Exploration, 88, 206-209. Garnier J., Quantin C., Guimarães E., Becquer T., 2008. Can chromite weathering be a source of Cr in soils? Mineralogy Magazine, 72, 49-53. Gleeson S.A., Butt C.R. and Elias M., 2003. Nickel laterites: A review. SEG Newsletter, 54, 11-18. Gleeson S.A., Butt C.R., Wlias M., 2003. Nickellaterites: a review. SEG Newsletter, Society of Economic Geology, 54. Available from www.segweb.org. Golightly J.P., 1981. Nickeliferous laterite deposits. Economic Geology, 75th Anniversary volume, 710-735. Golightly J.P., 2010. Progress in understanding the evolution of nickel laterite. Society of Economic Geology, In Special Publication, 15, 451-485. Manceau A. and Calas G., 1985. Heterogeneous distribution of nickel in hydrous silicates from New Caledonia ore deposits. American Mineralogist, 70, 549-558. Nguyen Van Pho, 2013. Tropic weathering in Vietnam (in Vietnamese). Pubisher Science and Technology, 365p.Ngo Xuan Thanh, Tran Thanh Hai, Nguyen Hoang, Vu Quang Lan, S. Kwon, Tetsumaru Itaya, M. Santosh, 2014. Backarc mafic-ultramafic magmatism in Northeastern Vietnam and its regional tectonic significance. Journal of Asian Earth Sciences, 90, 45-60.Pelletier B., 1983. Localisation du nickel dans les minerais ‘‘garnieritiques’’ de Nouvelle-Caledonie. Sciences Ge´ologique: Me´moires, 73, 173-183.Pelletier B., 1996. Serpentines in nickel silicate ores from New Caledonia. In Grimsey E.J., and Neuss I. (eds): Nickel ’96, Australasian Institute of Miningand Metallurgy, Melbourne, Publication Series 6(9), 197-205. Proenza J.A., Lewis J.F., Galı´ S., Tauler E., Labrador M., Melgarejo J.C., Longo F. and Bloise G., 2008. Garnierite mineralization from Falcondo Ni-laterite deposit (Dominican Republic). Macla, 9, 197-198. Soler J.M., Cama J., Galı´ S., Mele´ndez W., Ramı´rez, A., andEstanga, J., 2008. Composition and dissolution kinetics ofgarnierite from the Loma de Hierro Ni-laterite deposit,Venezuela. Chemical Geology, 249, 191-202. Springer G., 1974. Compositional and structural variations ingarnierites. The Canadian Mineralogist, 12, 381-388. Springer G., 1976. Falcondoite, nickel analogue of sepiolite. The Canadian Mineralogist, 14, 407-409.Svetlitskaya T.V., Tolstykh N.D., Izokh A.E., Phuong Ngo Thi, 2015. PGE geochemical constraints on the origin of the Ni-Cu-PGE sulfide mineralization in the Suoi Cun intrusion, Cao Bang province, Northeastern Vietnam. Miner Petrol, 109, 161-180.Tran Trong Hoa, Izokh A.E., Polyakov G.V., Borisenko A.S., Tran Tuan Anh, Balykin P.A., Ngo Thi Phuong, Rudnev S.N., Vu Van Van, Bui An Nien, 2008. Permo-Triassic magmatism and metallogeny of Northern Vietnam in relation to the Emeishan plume. Russ. Geol. Geophys., 49, 480-491.Trescases J.J., 1975. L'évolution supergene des roches ultrabasiques en zone tropicale: Formation de gisements nikelifères de Nouvelle Caledonie. Editions ORSTOM, Paris, 259p.Tri T.V., Khuc V. (eds), 2011. Geology and Earth Resources of Vietnam. Publishing House for Science and Technology, 645p (in English). Villanova-de-Benavent C., Proenza J.A., GalíS., Tauler E., Lewis J.F. and Longo F., 2011. Talc- and serpentine-like ‘‘garnierites’’ in the Falcondo Ni-laterite deposit, Dominican Republic. ‘Let’s talk ore deposits’, 11th Biennial Meeting SGA 2011, Antofagasta, Chile, 3p.Wells M.A., 2003. Goronickel laterite deposit. New Caledonia. CRC LEME, p.3.
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Ndlovu, Sehliselo, Geoffrey S. Simate, and Mariekie Gericke. "The Microbial Assisted Leaching of Nickel Laterites Using a Mixed Culture of Chemolithotrophic Microorganisms." Advanced Materials Research 71-73 (May 2009): 493–96. http://dx.doi.org/10.4028/www.scientific.net/amr.71-73.493.

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Nickel laterite contains metal values but is not capable of participating in the primary chemolithotrophic bacterial oxidation because it contains neither Fe2+ iron nor substantial amount of reduced sulphur. Its metal value can, however, be recovered by allowing the primary oxidation of FeS2, or similar iron/sulphur minerals to provide H2SO4 acid solutions, which solubilise the metal content. This study investigated the possibility of treating nickel laterites using chemolithotrophic microorganisms. Preliminary studies conducted using H2SO4 acid, citric acid and acidified Fe2(SO4)3 gave an insight on the use of chemolithotrophic bacteria in this process,. Results showed that H2SO4 acid performed better, in terms of nickel recovery, than citric acid or acidified Fe2(SO4)3. In the bacterial leaching test works, mixed cultures of Acidithiobacillus ferrooxidans, Acidithiobacillus caldus and Leptospirillum ferrooxidans were used in the presence of elemental sulphur and FeS2 as energy sources. The sulphur substrate exhibited better effects in terms of bacterial growth, acidification and nickel recovery than the FeS2 substrate. Using response surface methodology, the theoretical optimum conditions for maximum nickel recovery (79.8%) within the conditions studied was an initial pH of 2.0, 63μm particle size and 2.6% pulp density.
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McDonald, R. G., and B. I. Whittington. "Atmospheric acid leaching of nickel laterites review." Hydrometallurgy 91, no. 1-4 (March 2008): 35–55. http://dx.doi.org/10.1016/j.hydromet.2007.11.009.

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Torries, Thomas F. "Comparative costs of nickel sulphides and laterites." Resources Policy 21, no. 3 (September 1995): 179–87. http://dx.doi.org/10.1016/0301-4207(96)89788-1.

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Dissertations / Theses on the topic "Nickel Laterites"

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Thorne, Robert L. "Nickel laterites, origin and climate." Thesis, University of Southampton, 2011. https://eprints.soton.ac.uk/191955/.

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Nickel laterites account for ?40 % of global nickel production and contain 60 % of the world's total land based nickel resources. Despite the importance of these deposits published studies, detailing their morphology and formation processes are relatively few and the interaction of variables responsible for the formation of different nickel laterites are poorly understood. To better understand the process of nickel laterite formation, the Caldag and Bitincke paleodeposits were studied and their geological history established. The Caldag laterite, western Turkey, formed by intense chemical weathering of a serpentinite protolith in a region with a high water table and relatively low topography, resulting in the formation of an oxide deposit. In addition silica precipitation is common in the upper horizons of the deposit, where it creates an indurated layer, protecting the deposit from erosion. The Bitincke Nickel laterite, Albania is composed of two distinct zones characterized by silicate nickel and iron oxide phases. At Bitincke laterite formation and variations in thickness were controlled by the interaction between topography, faulting and protolith fracture density. The morphological and geochemical study of the Caldag and Bitincke paleodeposits indicates that there is a complex interplay between structures, topography, water table height and climate. Therefore nickel laterite deposits developed on very similar protoliths can form deposits with distinct and different characteristics. By comparing climatic data for regions where suitable ultramafic rocks are exposed and defining the climatic conditions favourable for the formation of nickel laterite deposits, the optimum temperatures and precipitation rates for nickel laterite development can be identified. A compilation of paleoclimatic data from western Turkey and Albania allows for the optimum periods of laterite formation within these regions to be established. Calculation of temperatures of formation from goethite oxygen and hydrogen isotopes could provide additional data on paleoclimaitc conditions. However due to the heterogeneity of laterite deposits and an extended weathering history, data gained from goethite appears not to provide a robust measure of paleotemperature. The study of the Caldag and Bitincke deposits combined with the analysis of the optimum conditions for nickel laterite formation has shown that there are four main factors which effect laterite formation: 1) Exposure of a suitable protolith; 2) Optimum climatic condition; 3) Geological variables; 4) Environment of preservation. Knowledge of these variables will assist in future laterite studies and will improve predictability of the location of new deposits.
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Secen, Berk. "Pressure Leaching Of Sivrihisar-yunus Emre Nickel Laterites." Master's thesis, METU, 2011. http://etd.lib.metu.edu.tr/upload/12613437/index.pdf.

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The aim of this thesis study was to extract nickel and cobalt from Sivrihisar limonitic nickel laterite ore by high pressure acid leaching (HPAL) method under most economical operating parameters. Optimizing the conditions to yield a saleable quality mixed hydroxide product from the pregnant leach solution (PLS) was also investigated. To extract high amounts of nickel and cobalt from the laterite matrix
leaching duration, leaching temperature and sulfuric acid/ore ratio were studied at fixed conditions of -850 µ
limonitic ore particle size and 40% solids concentration. The Sivrihisar limonitic nickel laterite ore was found to be readily leachable. It was found that 95.4% of Ni and 91.5% of Co were extracted at the optimized conditions of 235oC, 0.23 acid/ore ratio in 60 minutes. The real pregnant leach solution produced at the optimized conditions of HPAL was purified in two iron removal stages under the determined optimum conditions. Nearly all of the Al and Cr were removed from the PLS in the two stages of iron removal. Then, nickel and cobalt were taken out from the PLS in the form of mixed hydroxide precipitates (MHP) in two stages. A MHP 1 product containing 33.41 wt.% Ni, 2.93 wt.% Co was obtained with a Mn contamination of 3.69 wt.% at the optimized conditions of pH=7, 50oC and 60 minutes. The MHP 1 product was also contaminated with Fe (2.83 wt.%) since it could not be completely removed from the PLS without the critical losses of nickel and cobalt during the two iron removal stages.
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Goveli, Ahmet. "Nickel Extraction From Gordes Laterites By Hydrochloric Acid Leaching." Master's thesis, METU, 2006. http://etd.lib.metu.edu.tr/upload/12607738/index.pdf.

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Leaching is the most widely used process for extraction of nickel metal from lateritic ores. In this study, nickel extraction from Manisa-Gö
rdes region laterites by hydrochloric acid leaching is aimed. The mineralogical analysis of sample showed that hematite, goethite, dolomite, quartz and smectite are the main minerals in the ore. Attrition scrubbing, cycloning and magnetic separation with permroll were used as preconcentration processes but results were unsatisfactory. HCl leaching experiments were conducted both at room temperature and at elevated temperatures. The effects of various parameters such as leaching duration, particle size, concentration of HCl, pulp density, Cl- concentration and temperature on nickel recovery were examined. The results showed that under the optimised leaching conditions (particle size: 100 % -1 mm, HCl concentration: 3 N, leaching duration: 3 hours, leaching temperature: 100 oC, pulp density: 1/30 solid to liquid ratio by volume) it was possible to extract 87.26 % of nickel in the ore.
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Kaya, Serif. "High Pressure Acid Leaching Of Turkish Laterites." Master's thesis, METU, 2011. http://etd.lib.metu.edu.tr/upload/12612896/index.pdf.

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ABSTRACT HIGH PRESSURE ACID LEACHING OF TURKISH LATERITES Kaya, Serif M.Sc., Department of Metallurgical and Materials Engineering Supervisor: Prof. Dr. Yavuz A. Topkaya January 2011, 91 pages The aim of this thesis study was to investigate and find the most cost effective way of extracting nickel and cobalt into the pregnant leach solution (PLS) from Gö
rdes lateritic nickel and cobalt ore by means of sulphuric acid leaching under high temperature and high pressure conditions.The high pressure acid leach (HPAL) experiments were conducted with nontronitic and limonitic types of Gö
rdes lateritic nickel ore, respectively. Leaching experiments of nontronite ore have shown that almost all of the nickel and cobalt contained in the nontronitic ore were easily extracted into the (PLS). Therefore, the rest of the experiments were concentrated on difficult to leach limonitic sample when compared with the nontronitic one, and higher nickel and cobalt extractions were aimed to be obtained. By taking economic and technical considerations into account, the basic (HPAL) process parameters for the limonitic sample were optimized as
leaching at 255 °
C with a particle size of 100% -850 &mu
with 0.30 sulphuric acid to ore weight ratio in 1 hour of leaching duration. The experiments were conducted with 30% solids ratio and it was found that 87.3% of nickel and 88.8% of cobalt present in the limonitic ore could be extracted into the pregnant leach solution. Nevertheless, these results were found to be below the desired values. Therefore, the possible reasons of this behavior were investigated and the presence of hematite mineral in the limonitic ore was found to be the most probable one. Therefore, in order to dissolve the nickel and cobalt present in the hematite mineral, the additions of HCl, ferrous ions, cuprous ions and sulphur were tried, respectively and they were found to be beneficial in order to increase the degree of nickel and cobalt extractions.
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Nikoloski, Aleksandar N. "The electrochemistry of the leaching of pre-reduced nickel laterites in ammonia-ammonium carbonate solution." Murdoch University, 2002. http://wwwlib.murdoch.edu.au/adt/browse/view/adt-MU20060818.132232.

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A fundamental study was undertaken in order to establish the mechanisms of the leaching of pre-reduced nickel laterites in ammonia-ammonium carbonate solution. Although the process has undergone various improvements since it was first introduced, the total recoveries are still relatively low, averaging at 80% for nickel and 45-50% for cobalt. The lack of sound fundamental information regarding the mechanisms and the kinetics of the dissolution of nickel and cobalt from iron-alloy grains produced by the reduction roasting of lateritic ores is seen as the main obstacle to establishing the reasons for the lack of adequate recovery and to defining alternative processing strategies which would lead to improved extraction and better process optimisation. Based on fimdamental electrochemical studies and bench scale leaching tests, as well as on-site measurements at an industrial plant where this process is applied, the work presented in the thesis introduces significant new evidence and sheds more light on the understanding of the mechanism of the dissolution process and on the reasons for the low extractions of nickel and cobalt. It has been established that the oxidative dissolution of the iron-alloy grains formed during the reduction roasting takes place primarily via a reaction involving reduction of dissolved cobalt (111) to cobalt (11), and also that the reduction of water is not a significant component of the reactions involved in the dissolution process. Open-circuit potential measurements with various metals and iron-alloys selected to model the reduced material in various solutions which simulated the leaching conditions were also conducted and revealed that passivation takes place during the leaching process. This brings to light a possible new reason for the low recoveries of nickel and cobalt which has not been previously considered. In addition, a kinetic study was conducted, in which the dissolution rates for the various metals, iron-alloys and solutions were measured as a function of time, and the results of which shed more light on the development of the process of passivation. The passivation itself is attributed to formation of iron-oxide on the surface of the dissolving iron-alloy grains, which restricts the transfer of electrons to the reduced metal and brings the oxidative leaching reaction to an end. It has been shown that the passivation can occur in two ways. On the one hand, particularly high concentration of dispersed and dissolved oxygen in the leaching reactors causes passivation by overcoming the limiting current density for the oxidation of iron to divalent iron ions and taking the potential to the region where the direct oxidation to trivalent ions becomes favourable resulting in the formation of an iron-oxide film on the surface. On the other hand, in normally aerated solutions, the passivation of the dissolving ironalloy grains occurs due to the formation of a cobalt and nickel sulphide layer, as a byproduct of the reduction of thiosulphate on the metal surface, which in turn gradually shrinks the area available for the oxidation of iron, again leading to a situation where the oxidising agents present in the solution under standard aerated conditions become sufficient to shift the mixed potential to the region where the iron-oxide forming reaction becomes favourable. The presence of thiosulphate has a decisive role in the second type of passivation. What is more, besides preventing further dissolution of the nickel and cobalt locked in the iron-alloy matrix, the loss of nickel and cobalt by precipitation in the presence of thiosulphate can further reduce the recovery of these metals. For this reason, a method was developed for the oxidation and removal of thiosulphate fkom the actual plant liquor.
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Azevedo, Luiz Otavio Roffee. "Infra-Red Spectrophotometry and X-Ray Diffractometry as Tools in the Study of Nickel Laterites." Thesis, The University of Arizona, 1985. http://hdl.handle.net/10150/231213.

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Nickel silicate laterite deposits developed on ultra-mafic rocks are similar in many general respects but they vary considerably in detail. The mineralogy of these surficial deposits is very complex and difficult to determine because of the fine grained nature and solid solution characteristics of the hydrous secondary minerals and because many of the phases are actually mineraloids that are poorly ordered or amorphous. To try some new approaches toward clarification of these phases, 24 samples from New Caledonia and Puerto Rico ranging from the ophiolite-ultramafic olivine-pyroxene-chromite-serpentine substrate rocks upward through intermediate phases of weathering to the final oxide -hydroxide iron cap phase were analyzed with the infrared spectrophotometer (IR -10) and with the automated X –ray diffractometer. Four limonite samples were also mineralogically analyzed. Goethite, secondary quartz, cryptomelane, hematite, chromite, talc, thuringite, and garnierite have been identified in various samples as weathering profile products.
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Bourget, Cyril Christian Henri. "Recovery of metals from nickeliferous laterites : liquid-liquid extraction of cobalt and nickel from acidic leachates." Thesis, University of Hertfordshire, 1998. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.263027.

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Gencturk, Bilgehan. "Nickel Resource Estimation And Reconciliation At Turkmencardagi Laterite Deposits." Master's thesis, METU, 2012. http://etd.lib.metu.edu.tr/upload/12614978/index.pdf.

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In recent years nickel is mostly produced from lateritic ore deposits such as nontronite, limonite, etc. Resource estimation is difficult for laterite deposits as they have a weak and heterogeneous form. 3D modeling software are rather suitable for deposits having tabular or vein type ores. In this study the most appropriate estimation technique for resource estimation of nickel laterite deposits was investigated. One of the known nickel laterite deposits in Turkey is located at Tü
rkmenç
ardagi - Gö
rdes region. Since the nickel (Ni) grade recovered from drilling studies seem to be very low, a reconciliation pit having dimensions of 40 m x 40 m x 15 m in x-y-z directions was planned by Meta Nikel Kobalt Mining Company (META), the license owner of the mine, to produce nickel ore. 13 core drilling and 13 reverse circulation drilling (RC) and 26 column samplings adjacent to each drillholes were located in this area. Those three sampling results were compared to each other and as well as the actual production values obtained from reconciliation pit. On the other side 3D computer modeling was also used to model the nickel resource in Tü
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ardagi - Gö
rdes laterites. The results obtained from both inverse distance weighting and kriging methods were compared to the results of actual production to find out the applicability of 3D modeling to laterite deposits. Modeling results showed that Ni grade of the reconciliation pit in Tü
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ardagi - Gö
rdes, considering 0.5% Ni cut-off value, by using drillholes data, inverse distance weighting method estimates 622 tonnes with 0.553% Ni and kriging method estimates 749 tonnes with 0.527% Ni. The actual production pit results provided 4,882 tonnes of nickel ore with 0.649% Ni grade. These results show that grade values seem to be acceptable but in terms of tonnage, there are significant differences between theoretical estimated values and production values.
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Aiglsperger, Thomas Hans. "Mineralogy and geochemistry of the platinum group elements (PGE), rare earth elements (REE) and scandium in nickel laterites." Doctoral thesis, Universitat de Barcelona, 2015. http://hdl.handle.net/10803/396340.

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Ni laterites are considered worthy targets for critical metals (CM) exploration as rare earth elements (REE), Sc and platinum group elements (PGE) can be concentrated during weathering as a result of residual and secondary enrichment. In this investigation geochemical and mineralogical data of CM from two different nickel laterite types (i) from the Moa Bay mining area in Cuba (oxide type) and (ii) from the Falcondo mining area in the Dominican Republic (hydrous Mg silicate type) are presented. Emphasis is given on examining their potential to accumulate CM and on processes involved. Results show that CM are concentrated towards the surface in specific zones: (i) REE in clay minerals rich horizons and within zones composed of secondary Mn oxide(s) (ii) Sc within zones rich in secondary Fe and Mn bearing oxide(s) and (iii) PGE in zones with high concentrations of residual chromian spinel and secondary Fe and Mn bearing oxide(s) at upper levels of the Ni laterite profiles. Concentration factors involve (i) residual enrichment by intense weathering (ii) mobilization of CM during changing Eh and pH conditions with subsequent reprecipitation at favourable geochemical barriers (iii) interactions between biosphere and limonitic soils at highest levels of the profile (critical zone) with involved neoformation processes. Total contents of CM in both Ni laterite types are low when compared with conventional CM ore deposits but are of economic significance as CM have to be seen as cost inexpensive by-products during the Ni (+Co) production. Innovative extraction methods currently under development are believed to boost the significance of Ni laterites as future unconventional CM ore deposits. Two Ni laterite profiles from the Falcondo mining area have been compared for their platinum group element (PGE) geochemistry and mineralogy. One profile (Loma Peguera) is characterized by PGE-enriched (up to 3.5 ppm total PGE) chromitite bodies incorporated within the saprolite, whereas the second profile is chromitite-free (Loma Caribe). Total PGE contents of both profiles slightly increase from parent rocks (36 and 30 ppb, respectively) to saprolite (-50 ppb) and reach highest levels within the limonite zone (640 and 264 ppb, respectively). Chondrite-normalized PGE patterns of saprolite and limonite reveal rather flat shapes with positive peaks of Ru and Pd. Three types of platinum group minerals (PGM) were found by using an innovative hydroseparation technique: (i) primary PGM inclusions in fresh Cr-spinel (laurite and bowieite), (ii) secondary PGM (e.g., Ru-Fe-Os-Ir compounds) from weathering of preexisting PGM (e.g., serpentinization and/or laterization), and (iii) PGM precipitated after PGE mobilization within the laterite (neoformation). Results provide evidence that (i) PGM occurrence and PGE enrichment in the laterite profiles is independent of chromitite incorporation; (ii) PGE enrichment is residual on the profile scale; and (iii) PGE are mobile on a local scale leading to in situ growth of PGM within limonite, probably by bioreduction and/or electrochemical metal accretion. Free grains of PGM with delicate morphologies were discovered in limonite hosted chromitite samples (“floating chromitites”) from highest levels in the Falcondo Ni laterite deposit (Dominican Republic). Textural and chemical evidence obtained via SEM and EMP analysis points to a multistage formation: (i) primary PGM formation at magmatic stage; (ii) transformation to highly porous secondary Os-Ru PGM during serpentinization; (iii) neoformation of Ir-Fe-Ni-(Pt) mineral phases during early stages of lateritization; (iv) neoformation of Pt-(Ir) mineral phases within the critical zone of the profile resulting in nugget shaped accumulation of rounded particulates during late stages of lateritization. The observation of accumulations of most likely biogenic mediated in situ growth of Pt rich nanoparticles in supergene environments could help to explain (i) why Pt bearing nuggets are the most abundant PGM found in surface environments, (ii) why Pt nuggets from placer deposits generally surpass the grain sizes of Pt grains found in parent rocks by several orders of magnitude (few micrometers vs. several millimeters) and (iii) how anthropogenic PGE contamination may affect our biosphere. Osmium chromitite, saprolite and limonite (Falcondo mining area), suggest that serpentinization of the Loma Caribe peridotite has not significantly affected the Re-Os system in Os-rich PGM. This is noted by the fact, that primary PGM formed at magmatic stage and secondary Ru-Os-Mg- isotope characteristics from primary and secondary PGM, separated from Si PGM formed due desulphurization of primary PGM with significant incorporation of Mg silicates, have almost identical Os isotope characteristics, typical of the mantle. However, the Re-Os system can be significantly disturbed during stages of lateritization when porous secondary PGM react with Fe-rich fluids, thus forming hexaferrum and magnetite in the 187 188 interstices of secondary PGM. Here presented data indicate that more radiogenic ratios in higher levels of the weathering profile are linked to steady mobilization of PGE within secondary PGM resulting in subsequent loss of Os counterbalanced by the incorporation of Fe. Os/ Os In this investigation presented data clearly states that PGE are neither noble nor inert in surface environments, at least in those related to tropical Ni laterites from the Northern Caribbean.
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10

Goodall, Graeme. "Nickel recovery from reject laterite." Thesis, McGill University, 2007. http://digitool.Library.McGill.CA:80/R/?func=dbin-jump-full&object_id=99763.

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Falconbridge Dominicana C. Por A. operating in the Dominican Republic produces nickel as an iron-nickel alloy from laterite ore. Material that is rejected from their mining operations due to its incompatible chemistry is currently being stockpiled against mine depletion. Recent interest in recuperating nickel from this reject material led to the examination of the suitability of carbothermic reduction followed by magnetic separation for nickel recovery from this reject ore. Five parameters were considered in a Design of Experiment framework, namely: heating time; temperature; material type, coke addition and oxygen partial pressure. Magnetic separation was conducted with a Davis Tube and a low intensity hand magnet.
It was found that this reject material can successfully be treated using a carbothermic reduction process to produce 50 to 75 mum diameter metallic components within a gangue matrix. The recovery of nickel ranged from 61.7% to 21.9% to 16.4% in the high, low and non magnetic fractions, respectively, separated from the reduced material. The grade of nickel ranged from 1.97 wt% Ni to 1.58% to 0.75 wt% Ni in the high, low and non magnetic fractions, respectively.
Heating temperature had the greatest positive influence on the performance of the process followed by material type and heating time. Oxygen activity and coke addition were seen not to influence the performance. The Boudouard reaction was considered to be the rate controlling step and a maximum possible operating temperature was considered to depend on the physical properties of the material, specifically the softening temperature.
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Books on the topic "Nickel Laterites"

1

Burger, Peter. ALTA Nickel/cobalt laterites project development: May 15, 1996, Hyatt Hotel Perth, Western Australia. Victoria: Alta Metallurgical Services, 1996.

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P, Imrie William, Lane David M, Minerals, Metals and Materials Society. Extraction and Processing Division., Society for Mining, Metallurgy, and Exploration (U.S.), and Minerals, Metals and Materials Society. Meeting, eds. International Laterite Nickel Symposium--2004: Proceedings of symposium held during the 2004 TMS Annual Meeting in Charlotte, North Carolina, U.S.A., March 14-18, 2004. Warrendale, Pa: TMS, 2004.

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Anderson, William Thomas. Reduction studies on low iron lateritic nickel ores. Ottawa: National Library of Canada, 1995.

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Georgiou, Dimitri. Kinetics of nickel dissolution during sulphuric acid pressure leaching for a limonitic laterite. Ottawa: National Library of Canada, 1995.

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Services, ALTA Metallurgical, ed. ALTA Nickel/cobalt laterites: The how to's of project development. Victoria: Alta Metallurgical Services, 1995.

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Cheung, Miranda. Modelling of the nickel and cobalt kinetics during pressure acid leaching of laterites using Aspen Plus 11.1TM and OLI. 2004.

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(Editor), W. P. Imrie, and David M. Lane (Editor), eds. International Laterite Nickel Symposium--2004: Proceedings of Symposium Sponsored by the Extraction and Processing Division (Epd) of Tms (The Minerals, Metals, & Materials Society). Minerals, Metals, & Materials Society, 2004.

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Book chapters on the topic "Nickel Laterites"

1

Taylor, Alan. "Laterites — Still a Frontier of Nickel Process Development." In Ni-Co 2013, 3–23. Cham: Springer International Publishing, 2013. http://dx.doi.org/10.1007/978-3-319-48147-0_1.

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White, David T., and James D. Gillaspie. "Acid Leaching of Nickel Laterites with Jarosite Precipitation." In Ni-Co 2013, 75–95. Cham: Springer International Publishing, 2013. http://dx.doi.org/10.1007/978-3-319-48147-0_4.

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Taylor, A. "Laterites - Still a Frontier of Nickel Process Development." In Ni-Co 2013, 1–23. Hoboken, NJ, USA: John Wiley & Sons, Inc., 2013. http://dx.doi.org/10.1002/9781118658826.ch1.

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White, David T., and James D. Gillaspie. "Acid Leaching of Nickel Laterites with Jarosite Precipitation." In Ni-Co 2013, 74–95. Hoboken, NJ, USA: John Wiley & Sons, Inc., 2013. http://dx.doi.org/10.1002/9781118658826.ch4.

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Keskinkilic, Ender, Saeid Pournaderi, Ahmet Geveci, and Yavuz A. Topkaya. "A Study on the Characterization of Nickel Laterites of Central Anatolia." In 7th International Symposium on High-Temperature Metallurgical Processing, 403–10. Hoboken, NJ, USA: John Wiley & Sons, Inc., 2016. http://dx.doi.org/10.1002/9781119274643.ch50.

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Keskinkilic, Ender, Saeid Pournaderi, Ahmet Geveci, and Yavuz A. Topkaya. "A Study on the Characterization of Nickel Laterites of Central Anatolia." In 7th International Symposium on High-Temperature Metallurgical Processing, 403–10. Cham: Springer International Publishing, 2016. http://dx.doi.org/10.1007/978-3-319-48093-0_50.

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Agatzini-Leonardou, S., and D. Dimaki. "Heap leaching of poor nickel laterites by sulphuric acid at ambient temperature." In Hydrometallurgy ’94, 193–208. Dordrecht: Springer Netherlands, 1994. http://dx.doi.org/10.1007/978-94-011-1214-7_11.

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Simate, G. S., and Sehliselo Ndlovu. "Characterisation of Factors in the Bacterial Leaching of Nickel Laterites Using Statistical Design of Experiments." In Advanced Materials Research, 66–69. Stafa: Trans Tech Publications Ltd., 2007. http://dx.doi.org/10.4028/0-87849-452-9.66.

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Mystrioti, Christiana, Nymphodora Papassiopi, Anthimos Xenidis, and Konstantinos Komnitsas. "Comparative Evaluation of Sulfuric and Hydrochloric Acid Atmospheric Leaching for the Treatment of Greek Low Grade Nickel Laterites." In The Minerals, Metals & Materials Series, 1753–64. Cham: Springer International Publishing, 2018. http://dx.doi.org/10.1007/978-3-319-95022-8_145.

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Li, Tao, Xuan Chen, Bo Zhang, and Xin Hong. "Characterization of Laterite Nickel Ore." In Characterization of Minerals, Metals, and Materials 2014, 541–48. Hoboken, NJ, USA: John Wiley & Sons, Inc., 2014. http://dx.doi.org/10.1002/9781118888056.ch63.

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Conference papers on the topic "Nickel Laterites"

1

Vilarinho, Cândida, José Teixeira, Jorge Araújo, and Joana Carvalho. "Effect of Time and Acid Concentration on Metal Extraction From Galvanic Sludges." In ASME 2017 International Mechanical Engineering Congress and Exposition. American Society of Mechanical Engineers, 2017. http://dx.doi.org/10.1115/imece2017-71370.

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Galvanic sludge is a solid waste produced by the surface treatment industry, classified as hazardous because of their high concentration of heavy metals, which in its final destination is disposed in waste disposal facilities, with economic costs to the holders. Through hydrometallurgical processing, it is possible to extract valuable metals, with low costs involved, while the hazardous level of the residue is reduced. In the present work, the heap leaching method was studied as a solution to the treatment of these residues, which in order to consist in a valuable option, processing and operation costs must be kept as low as possible. For the experimental testing, a closed loop lixiviation column for hydrometallurgical treatment of galvanic sludge with possibility of continuous flow of the leachate (and static process as well) was constructed, simulating the heap leaching process. The galvanic waste in study, delivered by a local surface treatment company, was both chemically and physically characterized, proving to be rich in valuable metals like Nickel, Chromium and Copper. The waste material was characterized both for physical parameters (grain size) and chemical composition. The lixiviation trials, with a maximum duration of 1 week, were conducted. The influence upon the extraction rate of metals such as Nickel, Chromium and Copper, of parameters such as the concentration of the leaching agent (sulfuric acid) and time were tested. In order to quantify the leachate circulation effect, a static trial was conducted as well. Extraction rates of 35.5 % of Nickel, 14% of Copper and 13.6 % of Chromium were obtained after 6 hours in a dynamic trial, with 100 g/L sulfuric acid solution concentration. The acid consumption rate was correlated with the metal extraction. Finally, the results were compared with others obtained in previous galvanic sludge agitation lixiviation and laterites heap leaching works.
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Sofrà, Fiona. "Understanding Feed Rheology in Nickel Laterite Processing." In International Seminar on Paste and Thickened Tailings. Australian Centre for Geomechanics, Perth, 2005. http://dx.doi.org/10.36487/acg_repo/563_2.

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Francke, Jan C., and David C. Nobes. "Preliminary evaluation of GPR for nickel laterite exploration." In 8th International Conference on Ground Penetrating Radar, edited by David A. Noon, Glen F. Stickley, and Dennis Longstaff. SPIE, 2000. http://dx.doi.org/10.1117/12.383544.

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Choi, Yuri, Insung Lee, and Jihun Lee. "Mineralization of Garnierite in Morowali Nickel Laterite Deposit, Indonesia." In Goldschmidt2020. Geochemical Society, 2020. http://dx.doi.org/10.46427/gold2020.434.

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Wang, Xiaoping, Tichang Sun, Chao Chen, and Tianyang Hu. "Current Studies of Treating Processes for Nickel Laterite Ores." In 2nd International Conference on Mechatronics Engineering and Information Technology (ICMEIT 2017). Paris, France: Atlantis Press, 2017. http://dx.doi.org/10.2991/icmeit-17.2017.27.

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Rhamdani, Ahmad Rizky, Himawan T. B. M. Petrus, and Moh Fahrurrozi. "Characterization of nickel laterite reduction from Pomalaa, Sulawesi Tenggara." In INTERNATIONAL CONFERENCE OF CHEMICAL AND MATERIAL ENGINEERING (ICCME) 2015: Green Technology for Sustainable Chemical Products and Processes. AIP Publishing LLC, 2015. http://dx.doi.org/10.1063/1.4938348.

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Lisdiana, Anisya, Solihin, and Djulia Onggo. "Potential application of lateritic nickel as nickel(II) triazole complexes: Electronic spectral studies." In PROCEEDINGS OF THE 3RD INTERNATIONAL SEMINAR ON METALLURGY AND MATERIALS (ISMM2019): Exploring New Innovation in Metallurgy and Materials. AIP Publishing, 2020. http://dx.doi.org/10.1063/5.0001453.

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Aswad, Sabrianto, Yudi Surawan, Muh Altin Massinai, and Wanni. "Scenario to optimize nickel laterite exploration using ERT with gradient configuration." In Proceedings of the 12th SEGJ International Symposium, Tokyo, Japan, 18-20 November 2015. Society of Exploration Geophysicists and Society of Exploration Geophysicists of Japan, 2015. http://dx.doi.org/10.1190/segj122015-052.

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Wang, Weiwei, Shangchao Du, Guo Liu, Jianwen Tang, Yeda Lu, and Dong Lv. "Extraction of nickel from Ramu laterite by sulphation roasting-water leaching." In 3RD INTERNATIONAL CONFERENCE ON CHEMICAL MATERIALS AND PROCESS (ICCMP 2017). Author(s), 2017. http://dx.doi.org/10.1063/1.5000474.

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"Taguchi Optimization for Nickel-Cobalt Extraction Process using Cyanex 272 from Laterite." In Bali 2017 International Conference Proceeding. EIRAI, 2017. http://dx.doi.org/10.17758/eirai.iae1017101.

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