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Dissertations / Theses on the topic 'Nitrate anion'

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1

Cryer, Nicholas Colin. "The cloning and characteristion of anion influx and efflux transports from higher plants." Thesis, Royal Holloway, University of London, 2002. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.269798.

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2

Boisson, Jean. "Sur l'interaction eau/anion : les caractères structurants et déstructurants, la rupture de symétrie du nitrate." Phd thesis, Université Pierre et Marie Curie - Paris VI, 2008. http://tel.archives-ouvertes.fr/tel-00363808.

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Nous étudions l'hydratation des ions fluorures et iodures, paradigmes des ions structurants et déstructurants, grâce ` a une étude structurale et dynamique. Concernant la structure, nous observons l'opposé de ce que la définition classique des structurants/déstructurants suggère (F- déforme le réseau de liaisons hydrogènes et I- l'améliore). Ensuite, nous calculons les temps de vie des liaisons hydrogènes halogénures-eau ainsi que les temps de résidence et de réorientation des molécules d'eau de la première couche des anions. Ces mesures confirment la grande stabilité, induite par la force de
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3

Plusquellec, Gilles. "Analyse in situ de suspensions de silicate de calcium hydraté : application aux interactions ioniques à la surface des particules." Thesis, Dijon, 2014. http://www.theses.fr/2014DIJOS046/document.

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Cette étude a pour objectif d’étudier expérimentalement les interactions entre différents anions (chlorure, bromure, nitrate et sulfate) et le silicate de calcium hydraté (C-S-H) afin de construire un modèle thermodynamique capable de prédire cette interaction. Des suspensions de C-S-H synthétisées ont été mises en contact avec différents types de sel (sel de calcium ou d’alcalins). L’influence de la température et de l’incorporation d’aluminium au sein de la structure du C-S-H ont également été prises en compte.L’utilisation d’une méthode d’analyse classique de ce type de système (c’est-à-dir
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4

Kim, Dohyun. "Micromachined chronocoulometric nitrate sensor and parallel-plate Donnan-dialytic sample-preparation system using anion-exchange membrane." Diss., Restricted to subscribing institutions, 2008. http://proquest.umi.com/pqdweb?did=1785254321&sid=2&Fmt=2&clientId=1564&RQT=309&VName=PQD.

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5

Le, Goff Thierry. "Development of novel sensors for anions of environmental interest." Thesis, University of Plymouth, 2000. http://hdl.handle.net/10026.1/1134.

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A range of ion-selective electrodes (ISEs) for the determination of nitrate has been produced based upon rubbery membranes having covalently bound betaine salt sensor molecules. The best performing electrode contained N,N,N-triallyl leucine betaine (6.5 % m/m) covalently bound to polystyrene-block-polybutadiene-block-polystyrene (SBS) (43.5% m/m), with 2-nitrophenyIoctyl ether (2-NPOE) as solvent mediator (40 % m/m) and dicumyl peroxide (DCP) as free radical initiator (10% m/m). The Nemstian slope was -59.1 mV per decade over a linear range of 1 x 10'^-5 x 10"^ mol dm'^ nitrate, a limit of det
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6

Stoltz, Chad Alan. "Synthesis of layered group IV nitride materials by soft chemical anion metathesis." College Park, Md. : University of Maryland, 2005. http://hdl.handle.net/1903/2178.

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Thesis (Ph. D.)--University of Maryland, College Park, 2005.<br>Thesis research directed by: Chemistry. Title from t.p. of PDF. Includes bibliographical references. Published by UMI Dissertation Services, Ann Arbor, Mich. Also available in paper.
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7

Subedi, Gaurav. "Biological reduction of selenium oxyanions in the presence of nitrate anions using anaerobic microbes." Thesis, University of British Columbia, 2016. http://hdl.handle.net/2429/58435.

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Biological selenium reduction has emerged as a viable solution for the removal of toxic selenium from the environment. However, the presence of nitrate hinders selenium reduction by acting as a competitive electron acceptor. The present thesis investigated the use of local mine-impacted sediment as an inoculum for selenium reduction and studied the affect of nitrate on the removal of selenium. Sediment samples, impacted by mining activities, were collected from two vastly different sites of the Elk River Valley. These sediments namely; Goddard Marsh and Mature Tailing Coal, were enriched for s
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8

Nguyen, Trang Thi Thu. "Hydrogen release and absorption in mixed anion lithium amide/lithium ternary nitride systems." Thesis, University of Birmingham, 2016. http://etheses.bham.ac.uk//id/eprint/6671/.

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In this work, reactions of either LiBH\(_4\), ZnCl\(_2\) or Zn\(_3\)N\(_2\) with LiNH\(_2\) have been studied. The presence of CoO significantly affected the products and hydrogen release on heating mixtures of χLiBH\(_4\)-γLiNH\(_2\). The ratios of the l4\(_1\)/amd and the P2\(_1\)/c polymorphs of Li\(_3\)BN\(_2\) in the products have been changed under different conditions studied. On addition of CoO, the temperature of hydrogen release from the χLiBH\(_4\)-γLiNH\(_2\) systems was greatly reduced, starting from 100°C and peaking around 250°C, much lower than 240°C and 330°C without catalyst.
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9

Keino, Oscar Kipruto. "Investigations of Mixed-Anion Analogs of Manganite Perovskites and Bimetallic Group II Nitride Fluorides." Youngstown State University / OhioLINK, 2017. http://rave.ohiolink.edu/etdc/view?acc_num=ysu1515618873224784.

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10

BONAL, CHRISTINE. "Etude thermodynamique de la complexation des cations lanthanide trivalents par les anions nitrate en solution aqueuse." Clermont-Ferrand 2, 1997. http://www.theses.fr/1997CLF21913.

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La microcalorimetrie a ete appliquee pour la premiere fois a l'etude de la complexation de toute la serie des cations lanthanide (a l'exception du promethium) par l'anion nitrate dans l'eau. Les valeurs d'enthalpie libre, d'enthalpie et d'entropie de complexation ont ete determinees a une force ionique donnee. Les enthalpies de formation des complexes lnno#3#2#+ ont egalement ete estimees en utilisant un modele base sur la comparaison des chaleurs de dilution des nitrates et des perchlorates de lanthanides dans l'eau donnees dans la litterature. Les grandeurs ainsi calculees sont en bon accord
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11

Edge, Graham J. "Studies into the photochemistry of steroidal nitronate anions and N-alkyloxaziridines." Thesis, Loughborough University, 1985. https://dspace.lboro.ac.uk/2134/11237.

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The photochemistry of nitro-compounds is well documented in the literature. However the photochemical behaviour of nitronate anions has not been widely reported. We have studied the photochemical behaviour of a number of steroidal nitronate anions and found that the major products are hydroxamic acid. ketone and alkene. It was found that the yield of products is influenced by the position of the nitro-group. The hydroxamic acids were found to be the major products in the photolysis of 17-nitronate anions. However, it was observed that in these systems the yield of hydroxamic acid was influence
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12

ELKACEMI, KACEM. "Etude electrochimique de divers conducteurs organiques." Paris 6, 1986. http://www.theses.fr/1986PA066399.

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Etude electrochimique des sels de radicaux ioniques organiques, des complexes par transfert de charge et des radicaux ioniques. Donnees sur les composes conducteurs, formes par oxydation du tetrathiofulvalene (ttf) en presence de differents anions (scn**(-), no::(3)**(-) et mncl::(3)**(-)), par oxydation de tmttf dans l'acetonitrile en presence de scn**(-) et par reduction de tcnq en presence de differents cations. Donnees, aussi, sur les proprietes optiques et electrochimiques des films conducteurs de polyaniline
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13

Netto, André Maciel. "Transfert d'eau et de solutés dans un sol agricole hétérogène : analyse de différents types de mesures, de la variabilité spatiale et modélisation monodimensionnelle." Phd thesis, Université Joseph Fourier (Grenoble), 1998. http://tel.archives-ouvertes.fr/tel-00801928.

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L'objectif de cette étude était de caractériser les transferts d 'eau et de solutés dans un sol hétérogène pour prédire le devenir de polluants dans le sol et vers l'aquifère sous-jacente. Une série d'essais a été conduite sur le site observatoire de La Côte Saint-André. Les variabilités spatio-temporelles des variables hydriques et des concentrations de différentes molécules ( isotope de l'eau, anions, pesticide, nitrate) ont été mesurées selon différentes méthodes: suivi stationnel (sonde à neutrons, tensiomètres, cellules de prélèvements), percolation à travers un Iysimètre, prélèvements de
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14

Chi-Cheng, Huang. "Indium Nitride Based Anion Sensor." 2006. http://www.cetd.com.tw/ec/thesisdetail.aspx?etdun=U0016-1303200709301637.

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15

Huang, Chi-Cheng, and 黃啟政. "Indium Nitride Based Anion Sensor." Thesis, 2006. http://ndltd.ncl.edu.tw/handle/18492657832449816018.

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碩士<br>國立清華大學<br>電子工程研究所<br>94<br>InN is a remarkable material for solar cell application in the last few years because the energy band gap of InN is about 0.7 V. Recently, the large intrinsic surface charge accumulation near InN surface is discovered and this phenomenon results in the positively charged surface states. From the chemical of view, such surface states act as the acidic ligands which can adsorb basic ligands. Based on this property, this thesis investigated the sensing property of InN based anion sensor for the acid, salt and base solutions for the first time. The results show
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16

Ziegler, Michael. "Understanding the Effect of Cation and Solvation on the Structure and Reactivity of Nitrile Anions." 2011. http://digital.library.duq.edu/u?/etd,154091.

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This Ph.D. dissertation is focused on the investigation the structure of nitrile anion containing molecules and how the structure and reactivity of those molecules are affected by solvation and counter ion. A systematic approach was employed in this investigation, beginning with an evaluation of the accuracy of three commonly used model chemistries (Hartree-Fock (HF), Second-order Møller-Plesset perturbation theory (MP2), the Becke three-parameter exchange functional coupled with the nonlocal correlation functional of Lee, Yang, and Parr (B3LYP), all paired with the 6-31+G(d) basis set). A s
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17

Atkovska, Kalina. "Computational study of the molecular details of ion permeation across the formate-nitrite transporters." Doctoral thesis, 2016. http://hdl.handle.net/11858/00-1735-0000-0028-87B5-B.

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18

Lau, Chan Tong. "Rhodium-catalyzed Addition of Arylboronic Acids to Nitriles: Application in the Synthesis of Unsymmetrical Polysubstituted Pyridines." Thesis, 2011. http://hdl.handle.net/1807/31293.

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Investigations pertaining to the rhodium(I)-catalyzed addition of arylboronic acids to (arylsulfonyl)acetonitriles were undertaken. The resulting carbon-carbon bond forming reaction has led to the efficient synthesis of novel stereoselective (Z)-β-sulfonylvinylamines, which upon acidic hydrolysis, afford useful β-keto sulfones possessing a diverse range of aryl and sulfonyl substituents. The synthetic utility of these (Z)-β-sulfonylvinylamines was subsequently explored by generating the corresponding 1-aza-allyl anion equivalents under basic conditions. This interesting anionic intermediate wa
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19

張家銘. "The Synthesis and Characterization of Organic Receptors for Anions and Molecular Models of the Active Site of Fe-Containing Nitrile Hydratase." Thesis, 2011. http://ndltd.ncl.edu.tw/handle/90286939199271582335.

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碩士<br>國立彰化師範大學<br>化學系<br>99<br>To better understand the electronic structure of the iron(Ⅲ) center in the active site of NHase, we used a low-spin iron(Ⅲ) complex, [PPN][Fe(PyImS)2], synthesized and characterized previously in our lab. The oxidation of [PPN][Fe(PyImS)2] with different equivalent ratio of O-atom tranfer agent, N-sulfonyloxaziridine, gave three unique complexes: [PPN][Fe(PyImS)(PyImSO)](1)、[PPN][Fe(PyImS)(PyImSO2)](2) and [PPN][Fe(PyImSO)(PyImSO2)](3). The partial characterizations of 1~3 by EPR、X-ray、UV-vis and ESI Mass were also included in this report. An organic receptor (L2
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20

(10702308), Cory J. Conder. "INVESTIGATION OF THE PYROLYSIS OF LIGNIN BY USING COLLISION-INDUCED DISSOCIATION CHARGE-REMOTE FRAGMENTATION MASS SPECTROMETRY." Thesis, 2021.

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Mass spectrometry of negative ions is a convenient method for generating, isolating, and analyzing reactive intermediates that would otherwise be too short lived to detect. This ion approach is especially useful for studying the chemical properties of radicals. In this work, a negative charge-carrying group was attached to lignin model compounds and combined with collision-induced dissociation (CID) to generate and characterize radical species involved in the primary pyrolysis of lignin. The charge-tag served to increase the sensitivity of the model compounds using electrospray ionization mass
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