Academic literature on the topic 'Nitriles – Synthesis'

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Journal articles on the topic "Nitriles – Synthesis"

1

Ren, Yun-Lai, Jianji Wang, Xinzhe Tian, Fangping Ren, Xinqiang Cheng, and Shuang Zhao. "Direct Conversion of Benzyl Ethers into Aryl Nitriles." Synlett 29, no. 18 (2018): 2444–48. http://dx.doi.org/10.1055/s-0037-1611062.

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A direct method was developed for the conversion of benzyl ethers into aryl nitriles by using NH4OAc as the nitrogen source and ­oxygen as the terminal oxidant with catalysis by TEMPO/HNO3; the method is valuable for both the synthesis of aromatic nitriles and for the deprotection of ether-protected hydroxy groups to form nitrile groups in multistep organic syntheses.
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2

Robertson, Dan E., Jennifer A. Chaplin, Grace DeSantis, et al. "Exploring Nitrilase Sequence Space for Enantioselective Catalysis." Applied and Environmental Microbiology 70, no. 4 (2004): 2429–36. http://dx.doi.org/10.1128/aem.70.4.2429-2436.2004.

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ABSTRACT Nitrilases are important in the biosphere as participants in synthesis and degradation pathways for naturally occurring, as well as xenobiotically derived, nitriles. Because of their inherent enantioselectivity, nitrilases are also attractive as mild, selective catalysts for setting chiral centers in fine chemical synthesis. Unfortunately, <20 nitrilases have been reported in the scientific and patent literature, and because of stability or specificity shortcomings, their utility has been largely unrealized. In this study, 137 unique nitrilases, discovered from screening of >600
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3

Neugebauer, Witold, Eric Pinet, Munsok Kim, and Paul R. Carey. "Modified method of synthesis of N-substituted dithioesters of amino acids and peptides in the Pinner reaction." Canadian Journal of Chemistry 74, no. 3 (1996): 341–43. http://dx.doi.org/10.1139/v96-038.

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An improved method for the synthesis of dithioesters of amino acids and peptides has been developed. The syntheses have been carried out from the nitriles. The addition of thiol to the nitrile derivative in the Pinner step of dithioester synthesis was activated with hydrogen fluoride. A few examples of dithioester synthesis using liquid HF are described. Some novel dithioesters, which are model compounds for resonance Raman spectroscopic studies of dithioacylpapain intermediates, are described. Key words: dithioesters, amino acids, Pinner reaction, HF, isotopes.
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4

Marquez, Carlos, Matthieu Corbet, Simon Smolders, Philippe Marion, and Dirk De Vos. "Double metal cyanides as heterogeneous Lewis acid catalysts for nitrile synthesis via acid-nitrile exchange reactions." Chemical Communications 55, no. 86 (2019): 12984–87. http://dx.doi.org/10.1039/c9cc05382d.

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5

Bartmann, E., J. Krause та E. Merck. "Synthesis of α,α-difluoro-nitriles from α-oxo-nitriles". Journal of Fluorine Chemistry 54, № 1-3 (1991): 384. http://dx.doi.org/10.1016/s0022-1139(00)83893-2.

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6

Danek, Stefan K., David P. Kelly, Algirdas K. Serelis, and Peter J. Steel. "Stereospecific synthesis of azo nitriles." Journal of Organic Chemistry 52, no. 13 (1987): 2911–19. http://dx.doi.org/10.1021/jo00389a047.

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7

Brackman, W., and P. J. Smit. "A new synthesis of nitriles." Recueil des Travaux Chimiques des Pays-Bas 82, no. 8 (2010): 757–62. http://dx.doi.org/10.1002/recl.19630820803.

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8

Chavan, Prashant, Suhas Pednekar, Ramesh Chaughule, and Anushree Lokur. "Microwave-assisted Efficient One-pot Synthesis of Nitriles Using Recyclable Magnetite (Fe3O4) Nanoparticles as Catalyst and Water as Solvent: A Greener Approach." Nanoscience & Nanotechnology-Asia 10, no. 4 (2020): 507–17. http://dx.doi.org/10.2174/2210681209666190218144322.

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Background: There has been an increasing curiosity over the past few years to carry out organic reactions over heterogeneous nanocatalysts. Microwave activation coupled with a nanocatalyst along with water as a reaction medium makes the process further green. Microwave activation as a green process reduces reaction times, enhances product purity and improves chemical yield. Methods: Nitrile group chemistry has been explored by many researchers across the globe owing to its interesting properties and its importance in synthetic chemistry. Despite several methods being available for the synthesi
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9

Selvam, Nagarajan Panneer, Sundar Saranya, and Paramasivan T. Perumal. "A convenient and efficient protocol for the synthesis of symmetrical N,N′-alkylidine bisamides by sulfamic acid under solvent-free conditions." Canadian Journal of Chemistry 86, no. 1 (2008): 32–38. http://dx.doi.org/10.1139/v07-134.

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A simple and convenient approach to the synthesis of symmetrical N,N′-alkylidine bisamides is described. Aromatic and aliphatic nitriles react with aromatic aldehydes in the presence of sulfamic acid to give the corresponding bisamides in moderate yields.Key words: alkylidine bisamides, nitrile, sulfamic acid.
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10

Stuart, John G., та Kenneth M. Nicholas. "Cobalt-Mediated Synthesis of Propargyl Nitriles and α-Alkoxy Propargyl Nitriles". Synthesis 1989, № 06 (1989): 454–55. http://dx.doi.org/10.1055/s-1989-27287.

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