Academic literature on the topic 'Nitro compounds. Diels-Alder reaction'

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Journal articles on the topic "Nitro compounds. Diels-Alder reaction"

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Wu, Qiong, Qinnan Hu, Mingquan Li, Zewu Zhang, and Weihua Zhu. "Effectively improving the energy of monocyclic imidazoles to a high level by the introduction of bridge-rings and nitro groups through different kinds of Diels–Alder reactions: a DFT study." Molecular Systems Design & Engineering 5, no. 10 (2020): 1679–90. http://dx.doi.org/10.1039/d0me00075b.

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Jasiński, Radomir, Oskar Koifman, and Andrzej Barański. "A B3LYP/6-31G(d) study of Diels-Alder reactions between cyclopentadiene and (E)-2-arylnitroethenes." Open Chemistry 9, no. 6 (2011): 1008–18. http://dx.doi.org/10.2478/s11532-011-0088-5.

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AbstractThe B3LYP/6-31G(d) simulations of competing CDA and HDA reactions between cyclopentadiene and (E)-2-arylnitroethenes prove that regardless of the medium polarity, the processes leading to respective 5-nitro-6-aryl-bicyclo-[2,2,0]-hept-2-enes 3,4 (paths A and B) should be most favoured, and the more electrophilic (E)-2-(p-nitrophenyl)-nitroethene should be more reactive than the less electrophilic (E)-2-(p-methoxyphenyl)-nitroethene. Asymmetry of the transition complexes on the favoured pathways increases with increase of medium polarity, but not sufficiently to enforce the zwitterionic
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Macías, M. A., J. A. Henao, Arnold R. Romero Bohórquez, and Vladimir V. Kouznetsov. "Synthesis and X-ray powder diffraction data of cis-4-(4-methoxyphenyl)-3-methyl-6-nitro-2-phenyl-1,2,3,4-tetrahydroquinoline." Powder Diffraction 28, no. 4 (2013): 307–11. http://dx.doi.org/10.1017/s0885715613000651.

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The 2,4-diaryl 1,2,3,4-tetrahydroquinoline derivative (1), described in the title (Chemical formula: C23H22N2O3), was synthesized via the “one-pot” three-component imino Diels–Alder reaction catalyzed by Cu(OTf)2. Molecular characterization was performed by 1H and 13C NMR, Fourier transform-infrared, and gas chromatography-mass spectrometry. The X-ray powder diffraction pattern for the title compound was analyzed and found to be crystallized in an orthorhombic system with space group P212121 (No. 19) and refined unit-cell parameters a = 8.6415(8) Å, b = 12.679(2) Å, c = 17.601(2) Å, and V = 19
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Ono, Noboru, Akio Kamimura, and Aritsune Kaji. "Regioselective preparation of cyclohexadienes or aromatic nitro compounds by Diels-Alder reactions of .beta.-sulfonylnitroolefins or .beta.-sulfinylnitroethylene." Journal of Organic Chemistry 53, no. 2 (1988): 251–58. http://dx.doi.org/10.1021/jo00237a005.

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Arlegui, Aitor, Zoubir El-Hachemi, Joaquim Crusats, and Albert Moyano. "5-Phenyl-10,15,20-Tris(4-sulfonatophenyl)porphyrin: Synthesis, Catalysis, and Structural Studies." Molecules 23, no. 12 (2018): 3363. http://dx.doi.org/10.3390/molecules23123363.

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A convenient protocol for the preparation of 5-phenyl-10,15,20-tris(4-sulfonatophenyl)porphyrin, a water-soluble porphyrin with unique aggregation properties, is described. The procedure relies on the one-pot reductive deamination of 5-(4-aminophenyl)-10,15,20-tris(4-sulfonatophenyl)porphyrin, that can be in turn easily obtained from 5,10,15,20-tetraphenylporphyrin by a known three-step sequence involving mononitration, nitro to amine reduction and sulfonation of the phenyl groups. This method provides the title porphyrin in gram scale, and compares very favorably with the up to now only descr
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Fujita, Reiko, Sota Wakayanagi, Hideaki Wakamatsu, and Hisao Matsuzaki. "Novel Diels–Alder Reaction of 4-Nitro-1(2H)-isoquinolones." CHEMICAL & PHARMACEUTICAL BULLETIN 54, no. 2 (2006): 209–12. http://dx.doi.org/10.1248/cpb.54.209.

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Brummond, Kay M., and Lingfeng You. "Consecutive Rh(I)-catalyzed Alder-ene/Diels–Alder/Diels–Alder reaction sequence affording rapid entry to polycyclic compounds." Tetrahedron 61, no. 26 (2005): 6180–85. http://dx.doi.org/10.1016/j.tet.2005.03.141.

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Sogani, Nidhi, and R. Bansal. "Catalytic Hetero-Diels-Alder Reaction of the Carbonyl Compounds." Current Catalysis 6, no. 1 (2017): 3–24. http://dx.doi.org/10.2174/2211544705666161013121637.

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Zukerman-Schpector, J., I. Caracelli, Mauricio Vega, Mauricio Gomes Constantino, Adilson Beatriz, and Gil Valdo da Silva. "Two polycyclic compounds derived from a Diels–Alder reaction." Acta Crystallographica Section C Crystal Structure Communications 57, no. 5 (2001): 646–48. http://dx.doi.org/10.1107/s0108270101003365.

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Hao, Feiyue, and Nagatoshi Nishiwaki. "Recent Progress in Nitro-Promoted Direct Functionalization of Pyridones and Quinolones." Molecules 25, no. 3 (2020): 673. http://dx.doi.org/10.3390/molecules25030673.

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Nitro group is one of the most important functional groups in organic syntheses because its strongly electron-withdrawing ability activates the scaffold, facilitating the reaction with nucleophilic reagents or the Diels–Alder reaction. In this review, recent progress in the nitro-promoted direct functionalization of pyridones and quinolones is highlighted to complement previous reviews.
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Dissertations / Theses on the topic "Nitro compounds. Diels-Alder reaction"

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Murray, James K. Wade Peter A. "[Alpha] [Greek small letter alpha]-nitrosulfones : synthetic and mechanistic studies /." Philadelphia : Drexel University, 2003. http://dspace.library.drexel.edu/handle/1721.1/101.

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Gomes, Maria Goretti. "Diels-alder reactions of a cyclopentadienone derivative." Diss., Columbia, Mo. : University of Missouri-Columbia, 2007. http://hdl.handle.net/10355/4670.

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Thesis (Ph. D.)--University of Missouri-Columbia, 2007.<br>The entire dissertation/thesis text is included in the research.pdf file; the official abstract appears in the short.pdf file (which also appears in the research.pdf); a non-technical general description, or public abstract, appears in the public.pdf file. Title from title screen of research.pdf file (viewed on February 13, 2008) Vita. Includes bibliographical references.
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D’Aurizio, Antonio <1978&gt. "Microwave-Mediated Hetero Diels-Alder reaction: Synthesis of biologically active compounds." Doctoral thesis, Alma Mater Studiorum - Università di Bologna, 2009. http://amsdottorato.unibo.it/1641/.

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Heterocyclic compounds represent almost two-thirds of all the known organic compounds: they are widely distributed in nature and play a key role in a huge number of biologically important molecules including some of the most significant for human beings. A powerful tool for the synthesis of such compounds is the hetero Diels-Alder reaction (HDA), that involve a [4+2] cycloaddition reaction between heterodienes and suitable dienophiles. Among heterodienes to be used in such six-membered heterocyclic construction strategy, 3-trialkylsilyloxy-2-aza-1,3-dienes (Fig 1) has been demonstrated parti
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Eberlin, Ludovic. "Novel applications of polyfunctionalised organoboron and nitroso compounds." Thesis, Rennes 1, 2016. http://www.theses.fr/2016REN1S078/document.

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Cette thèse présente la réactivité de diènes polyfonctionnalisés incorporant un atome de bore (diènes borylés) en présence de composés de type nitroso. La première partie est une étude de la réactivité des diènes borylés en présence de dérivés arylnitroso. Le produit formé ainsi que l'efficacité de la réaction est dépendant de la substitution sur l'atome de bore ainsi que du solvant utilisé pour la réaction. Suivant les conditions employées, la formation de composés avec différentes structures; pyrroles, oxazines substitués par un atome de bore, ou nitrones a été obtenue. Une stratégie one-pot
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Zhao, Dalian. "Syntheses and the Structures of Polymethylpolycyclic and Polycyclic "Cage" Molecules." Thesis, University of North Texas, 1989. https://digital.library.unt.edu/ark:/67531/metadc500344/.

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The structures of Diels-Alder cycloaddition of cyclopentadiene to 2,6-dimethyl-p-benzoquinone and methylcyclopentadiene to 2,6-dimethyl-p-benzoquinone were assigned by analysis of 1-D and 2-D proton and carbon-13 NMR spectra. The structures of the cycloadduct of methylcyclopentadiene to 2,6-dimethyl-p-benzoquinone and that of the corresponding intramolecular [2+2] photocyclization product were also obtained by single crystal X-ray structural analysis. As the second part of the study, a new polycyclic "cage" molecule, a substituted trishomocubane isomer, was synthesized. In this synthesis, redu
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Chumachenko, Natasha. "[Beta]-acryloyloxysulfonyl tethers for intramolecular Diels-Alder cycloaddition reactions." [Kent, Ohio] : Kent State University, 2005. http://rave.ohiolink.edu/etdc/view?acc%5Fnum=kent1135392557.

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Thesis (Ph.D.)--Kent State University, 2005.<br>Title from PDF t.p. (viewed July 28, 2005). Author's first name appears on the abstract page as: Nataliya. Advisor: Paul Sampson. Keywords: b-hydroxysulfones; [beta]-hydroxysulfones; epoxide opening; intramolecular Diels-Alder reaction; vinylsulfones. Includes bibliographical references (p.194- 202).
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Jump, Joseph M. "Synthesis and use of chiral dienes in the asymmetric diels-alder reaction." Diss., Georgia Institute of Technology, 1990. http://hdl.handle.net/1853/30292.

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Banerjee, Siddthartha. "Photo retro Diels-Alder reaction of the adducts of tetracyanoethylene and polyaromatic compounds." Master's thesis, University of Central Florida, 2011. http://digital.library.ucf.edu/cdm/ref/collection/ETD/id/4842.

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Thermally induced retro-Diels Alder (rDA) reaction has been extensively used for the preparation of many reactive intermediates in organic synthesis. But the uses of photo-retro Diels-Alder (PrDA) reaction in organic synthesis were sparingly reported in literature. Due to its spatial and temporal control, PrDA can be used in making of photosensitive materials, in drug delivery and also for mechanistic studies. Diels-Alder adducts of tetracyanoethylene (TCNE) and polyaromatic compounds (anthracene, napthacene, pentacene and phencyclone) were synthesized and were subjected to PrDA reaction throu
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Stone, Charles. "Preparation and reactivity of heterosubstituted 1,3-Dienes." Thesis, University of British Columbia, 1988. http://hdl.handle.net/2429/29433.

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The chemoselective hydrozirconation reaction of a series of 1-ene-3-yne molecules 51a-d, using the commercially available hydride reagent, Cp₂ZrCl(H) 1, provides an efficient route to the syntheses of 1,3-dienes 55a-d, substituted at the 1-position by the Cp₂ZrCl moiety. Similar chemoselectivity was observed in the hydrozirconation reaction of α, β-unsaturated nitriles, to generate the corresponding 1-azadienyl complexes 68-71. The complexes 55a-d were found to be useful general precursors in the preparation of other heterosubstituted 1,3-dienes. Thus, corresponding tin-, phosphorus-, boron-,
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Zhang, Ruoxin. "Toward the synthesis of polycyclic aromatic compounds as nano-carbon cages." Morgantown, W. Va. : [West Virginia University Libraries], 2008. https://eidr.wvu.edu/etd/documentdata.eTD?documentid=5617.

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Thesis (M.S.)--West Virginia University, 2008.<br>Title from document title page. Document formatted into pages; contains vii, 45 p. : ill. Includes abstract. Includes bibliographical references (p. 24-26).
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Books on the topic "Nitro compounds. Diels-Alder reaction"

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Boger, Dale L. Hetero Diels-Alder methodology inorganic synthesis. Academic Press, 1987.

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Boger, Dale L. Hetero Diels-Alder methodology in organic synthesis. Academic Press, 1987.

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Maier, Martin. Hetero-Diels-Alder Reaktionen mit inversem Elektronenbedarf zur Synthese von Hexopyranosiden. Hartung-Gorre, 1985.

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Santelli, Maurice. Lewis acids and selectivity in organic synthesis. CRC Press, 1996.

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Powers, Timothy S. Asymmetric Diels-Alder and aldol reactions using Fischer carbene complexes. 1993.

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Book chapters on the topic "Nitro compounds. Diels-Alder reaction"

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Urgaonkar, S., and J. G. Verkade. "Asymmetric Diels–Alder Reaction." In Organophosphorus Compounds (incl. RO-P and RN-P). Georg Thieme Verlag KG, 2009. http://dx.doi.org/10.1055/sos-sd-042-01119.

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Ooi, T., and K. Maruoka. "The Diels–Alder Reaction." In Compounds of Groups 13 and 2 (Al, Ga, In, Tl, Be...Ba). Georg Thieme Verlag KG, 2004. http://dx.doi.org/10.1055/sos-sd-007-00132.

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Bubnov, Y. "From 1,3-Dienylboranes via Diels–Alder Reaction." In Boron Compounds. Georg Thieme Verlag KG, 2005. http://dx.doi.org/10.1055/sos-sd-006-00857.

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Abu Ali, H., V. M. Dembitsky, and M. Srebnik. "Diels–Alder Reaction of Alkenylboranes and Alkenylboronates." In Boron Compounds. Georg Thieme Verlag KG, 2005. http://dx.doi.org/10.1055/sos-sd-006-00753.

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Toyota, S., and T. Iwanaga. "Diels–Alder Reaction of Organotungsten Compounds." In Monocyclic Arenes, Quasiarenes, and Annulenes. Georg Thieme Verlag KG, 2010. http://dx.doi.org/10.1055/sos-sd-045-00699.

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Ooi, T., and K. Maruoka. "The Hetero-Diels–Alder Reaction." In Compounds of Groups 13 and 2 (Al, Ga, In, Tl, Be...Ba). Georg Thieme Verlag KG, 2004. http://dx.doi.org/10.1055/sos-sd-007-00131.

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Albrecht, K., and D. E. Kaufmann. "Formation of Cyclohexenylboronates via the Diels–Alder Reaction." In Boron Compounds. Georg Thieme Verlag KG, 2005. http://dx.doi.org/10.1055/sos-sd-006-00657.

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Quirion, J. C., E. Leclerc, and P. Jubault. "Aza-Diels–Alder Reaction of 1-Azadienes." In Ene-X Compounds (X=S, Se, Te, N, P). Georg Thieme Verlag KG, 2007. http://dx.doi.org/10.1055/sos-sd-033-00660.

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Blakemore, P. R. "Hetero-Diels–Alder Reaction of Acyl Nitroso Compounds." In Three Carbon-Heteroatom Bonds: Esters and Lactones; Peroxy Acids and R(CO)OX Compounds; R(CO)X, X=S, Se, Te. Georg Thieme Verlag KG, 2005. http://dx.doi.org/10.1055/sos-sd-021-00886.

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Oshima, K. "Diels–Alder Reaction of (1-Buta-1,3-dienyl)trimethylsilanes." In Compounds of Groups 15 (As, Sb, Bi) and Silicon Compounds. Georg Thieme Verlag KG, 2002. http://dx.doi.org/10.1055/sos-sd-004-00812.

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