Log in

Relevant bibliographies by topics / Nitroalkane proton transfer

Contents

Journal articles
Dissertations / Theses

Academic literature on the topic 'Nitroalkane proton transfer'

Author: Grafiati

Published: 4 June 2021

Last updated: 15 February 2022

Create a spot-on reference in APA, MLA, Chicago, Harvard, and other styles

Select a source type:

Consult the lists of relevant articles, books, theses, conference reports, and other scholarly sources on the topic 'Nitroalkane proton transfer.'

Next to every source in the list of references, there is an 'Add to bibliography' button. Press on it, and we will generate automatically the bibliographic reference to the chosen work in the citation style you need: APA, MLA, Harvard, Chicago, Vancouver, etc.

You can also download the full text of the academic publication as pdf and read online its abstract whenever available in the metadata.

Journal articles on the topic "Nitroalkane proton transfer"

1

Major, D. T., A. Heroux, A. M. Orville, M. P. Valley, P. F. Fitzpatrick, and J. Gao. "Differential quantum tunneling contributions in nitroalkane oxidase catalyzed and the uncatalyzed proton transfer reaction." Proceedings of the National Academy of Sciences 106, no. 49 (2009): 20734–39. http://dx.doi.org/10.1073/pnas.0911416106.

Full text

APA, Harvard, Vancouver, ISO, and other styles

2

Ando, Kenichi, Yu Shimazu, Natsuko Seki, and Hiroshi Yamataka. "Kinetic Study of Proton-Transfer Reactions of Phenylnitromethanes. Implication for the Origin of Nitroalkane Anomaly." Journal of Organic Chemistry 76, no. 10 (2011): 3937–45. http://dx.doi.org/10.1021/jo200383f.

Full text

APA, Harvard, Vancouver, ISO, and other styles

3

Galezowski, Wlodzimierz, Iwona Grzeskowiak, and Arnold Jarczewski. "Article." Canadian Journal of Chemistry 77, no. 5-6 (1999): 1042–49. http://dx.doi.org/10.1139/v99-093.

Full text

Abstract:

The rates of proton transfer reactions between C-acids of different types such as 1-(4-nitrophenyl)-1-nitroalkanes, 4-nitrophenylcyanomethanes, and 2,4,6-trinitrotoluene, and organic bases such as 1,1,3,3-tetrametylguanidine, 7-methyl-1,5,7-triazabicyclo[4.4.0]dec-5-ene (MTBD), and tri-n-butylamine have been measured in acetonitrile at pseudo-first-order conditions. A general equation for the rates of proton transfer reactions between C-acids and bases with product existing in two forms, ions and ion pairs, has been derived and its applicability tested. The equation works well except for react

APA, Harvard, Vancouver, ISO, and other styles

4

Ponec, Robert. "Molecular Basis of LFER. Simple Model for the Estimation of Brønsted Exponent in Acid-Base Catalysis." Collection of Czechoslovak Chemical Communications 69, no. 12 (2004): 2121–33. http://dx.doi.org/10.1135/cccc20042121.

Full text

Abstract:

A simple model was proposed allowing to estimate the Brønsted exponents in acid-base catalysis on the basis of the pK values of the species participating in the proton transfer process. The approach was tested using the experimental data on the basically catalyzed halogenation of carbonyl compounds and on the proton removal from nitroalkanes. It has been shown that the model is able to reproduce the Brønsted exponents not only in the case of "ordinary" Brønsted plots with the slope within the expected range 0-1 but also for unusual plots with negative slopes. In addition, the proposed model op

APA, Harvard, Vancouver, ISO, and other styles

5

Sato, Makoto, Yutaka Kitamura, Nobuyoshi Yoshimura, and Hiroshi Yamataka. "Proton-Transfer Reactions of Nitroalkanes: The Role ofaci-Nitro Species." Journal of Organic Chemistry 74, no. 3 (2009): 1268–74. http://dx.doi.org/10.1021/jo8023939.

Full text

APA, Harvard, Vancouver, ISO, and other styles

6

Galezowski, Wlodzimierz, and Arnold Jarczewski. "Kinetics, isotope effects of the reaction of 1-(4-nitrophenyl)-1-nitroalkanes with DBU in tetrahydrofuran and chlorobenzene solvents." Canadian Journal of Chemistry 68, no. 12 (1990): 2242–48. http://dx.doi.org/10.1139/v90-345.

Full text

Abstract:

The kinetics of the reaction of[Formula: see text](R = Me, Et, i-Pr; NPNE, NPNP, MNPNP respectively; L is H or D) with 1,8-diazabicyclo[5.4.0]undec-7-ene (DBU) base in tetrahydrofuran (THF) and chlorobenzene (CB) solvents are reported. The products of these proton transfer reactions are ion pairs absorbing at λmax = 460–480 nm. The equilibrium constants in THF were [Formula: see text]and in CB [Formula: see text]for NPNE, NPNP, MNPNP respectively. The thermodynamic parameters of the reactions are also quoted. The substrate reacts with DBU in both THF and CB solvents in a normal second-order pr

APA, Harvard, Vancouver, ISO, and other styles

7

Grzeskowiak, Iwona, Wtodzimierz Galezowski, and Arnold Jarczewski. "Kinetic study of the proton transfer reaction between 1-nitro-1-(4-nitrophenyl)alkanes and TBD and MTBD bases in acetonitrile solvent." Canadian Journal of Chemistry 79, no. 7 (2001): 1128–34. http://dx.doi.org/10.1139/v01-093.

Full text

Abstract:

The rates of proton transfer reactions between C-acids of the series of nitroalkanes with increasing bulk of R = H, Me, Et, i-Pr substituent as: 4-nitrophenylnitromethane (0), 1-(4-nitrophenyl)-1-nitroethane (1), 1-(4-nitrophenyl)-1-nitropropane (2), 2-methyl-1-(4-nitrophenyl)-1-nitropropane (3) and 1,5,7-triazabicyclo[4.4.0]dec-5-ene (TBD), 7-methyl-1,5,7-triazabicyclo[4.4.0]dec-5-ene (MTBD) have been measured in acetonitrile at pseudo-first-order conditions. The product of the proton transfer reaction with MTBD in acetonitrile is dissociated into free ions while that of the TBD reaction is c

APA, Harvard, Vancouver, ISO, and other styles

8

Galezowski, Wlodzimierz, and Arnold Jarczewski. "Study of the dissociation of the products of some proton transfer reactions in acetonitrile solvent." Canadian Journal of Chemistry 70, no. 3 (1992): 935–42. http://dx.doi.org/10.1139/v92-126.

Full text

Abstract:

The conductometric study of the products of the proton transfer reactions of C-acids (nitriles, nitroalkanes, and 2,4,6-trinitrotoluene) with the strong amine bases (1,1,3,3-tetramethylguanidine (TMG), 1,8-diazabicyclo[5.4.0]undec-7-ene (DBU), 1,8-bis(dimethylamino)naphthalene (DMAN), and piperidine) in acetonitrile shows their large degree of dissociation into free ions. The dissociation constant values have been estimated at 25 °C to be larger than 1 × 10−4 M. This weakens the formalism commonly accepted in spectrophotometric kinetic studies of these systems of reactions, based on the assump

APA, Harvard, Vancouver, ISO, and other styles

9

Binkowska, Iwona, Włodzimierz Gałęzowski, and Arnold Jarczewski. "Equilibrium and kinetic study of the proton transfer reactions between nitroalkanes and strong organic bases — phosphazenes in tetrahydrofuran solvent." Open Chemistry 8, no. 3 (2010): 582–86. http://dx.doi.org/10.2478/s11532-010-0044-9.

Full text

Abstract:

AbstractProton transfer reactions rates between carbon acids 1-nitro-1-(4-nitrophenyl)ethane (NPNE), 2-methyl-1-nitro-1-(4-nitrophenyl)propane (MNPNP)) and phosphazenes (BEMP, BTPP, P1-t-Oct) in tetrahydrofuran have been measured, and the activation parameters were determined. The results are compared with those previously obtained for P1-t-Bu phosphazene, guanidines and amidines.

APA, Harvard, Vancouver, ISO, and other styles

10

Zhao, Yixing, Yun Lu, and Vernon D. Parker. "Proton-Transfer Reactions between Nitroalkanes and Hydroxide Ion under Non-Steady-State Conditions. Apparent and Real Kinetic Isotope Effects." Journal of the American Chemical Society 123, no. 8 (2001): 1579–86. http://dx.doi.org/10.1021/ja003607o.

Full text

APA, Harvard, Vancouver, ISO, and other styles

Dissertations / Theses on the topic "Nitroalkane proton transfer"

1

Li, Zhao. "The Kinetics and Mechanisms of Some Fundamental Organic Reactions of Nitro Compounds." DigitalCommons@USU, 2012. https://digitalcommons.usu.edu/etd/1407.

Full text

Abstract:

The central topic of this dissertation is to seek the answer to the question: Is the single transition state model appropriate for (1) the proton transfer reactions of nitroalkanes and (2) the aromatic nucleophilic reactions of trinitroarenes? If not, what are the real mechanisms? This objective has been accomplished by careful kinetic and mechanistic studies which take advantage of modern digital acquisition of absorbance - time data, combined with extensive new data analysis of results from pseudo-first-order kinetic measurements. Several new analysis procedures for pseudo-first-order kineti

APA, Harvard, Vancouver, ISO, and other styles

We offer discounts on all premium plans for authors whose works are included in thematic literature selections. Contact us to get a unique promo code!