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Journal articles on the topic 'Nitrobenzylidene'

Author: Grafiati

Published: 5 June 2025

Last updated: 1 August 2025

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1

Glidewell, Christopher, R. Alan Howie, John N. Low, Janet M. S. Skakle, Solange M. S. V. Wardell та James L. Wardell. "Nine isomeric nitrobenzylidene-iodoanilines: interplay of C—H...O hydrogen bonds, iodo...nitro interactions and aromatic π...π stacking interactions". Acta Crystallographica Section B Structural Science 58, № 5 (2002): 864–76. http://dx.doi.org/10.1107/s0108768102009941.

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Nine isomeric nitrobenzylidene-iodoanilines, O2NC6H4CH= NC6H4I [(I)–(IX)], have been synthesized and the structures of all except 4-nitrobenzylidene-4′-iodoaniline (IX) have been analyzed. 2-Nitrobenzylidene-2′-iodoaniline (I) contains isolated molecules, while 3-nitrobenzylidene-2′-iodoaniline (II) and 2-nitrobenzylidene-3′-iodoaniline (IV) both contain chains of molecules linked by C—H...O hydrogen bonds: similar chains in 4-nitrobenzylidene-2′-iodoaniline (III) are further linked by aromatic π...π stacking interactions, forming sheets. In both 3-nitrobenzylidene-3′-iodoaniline and 4-nitrobe

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2

Mini, R., T. Joselin Beaula, P. Muthuraja та V. Bena Jothy. "Supramolecular Assembly Interceded by C-H···O Hydrogen Bonds and Nitro···π(arene) Interactions of Antibacterial 4-Methyl-(2-nitro benzylidene)aniline using DFT and its Spectral Studies". Asian Journal of Chemistry 32, № 5 (2020): 1048–58. http://dx.doi.org/10.14233/ajchem.2020.22517.

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4-Methyl-(2-nitrobenzylidene)aniline (MNBA) was grown and its structural as well as spectral analyses (FT-IR, FT-Raman, UV and NMR) using experimental and DFT computations were performed to understand its biological applications. Stability of molecule, charge delocalization, charge analysis and charge transfer interactions had been explored to examine the structural analysis. Docking studies also suggested that 4-methyl-(2-nitrobenzylidene)aniline exhibit antibacterial activity. Supramolecular assembly of 4-methyl-(2-nitrobenzylidene)aniline molecule was interceded by C-H···O hydrogen bonds an

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3

Kulikov, M. A., and S. G. Khudyakov. "2-(4-BROMO-3-NITROBENZYLIDENE)-6-[4-(DIMETHYLAMINO)-3- NITROBENZYLIDENE]CYCLOHEXANONE." Herald Of Technological University 26, no. 2 (2023): 5–8. http://dx.doi.org/10.55421/1998-7072_2023_26_2_5.

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4

Arzyamova, Ekaterina M., Diana N. Ibragimova, Olga V. Fedotova, and Nina V. Pchelintseva. "5-(R)BENZYLIDENE-2,2-DIMETHYL-1,3-DIOXANE-4,6-DIONES IN SYNTHESIS OF AROMATIC OXIMES, THIOSEMICARBAZONES AND HYDRAZONES." IZVESTIYA VYSSHIKH UCHEBNYKH ZAVEDENII KHIMIYA KHIMICHESKAYA TEKHNOLOGIYA 64, no. 6 (2021): 20–24. http://dx.doi.org/10.6060/ivkkt.20216406.6353.

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The behavior of some derivatives of Meldrum's acid, namely, 5-(R)benzylidene-2,2-dimethyl-1,3-dioxane-4,6-diones (a well-known synthetic platform) was studied with mono- and biazanucleophiles (hydrochloric hydroxylamine, thiosemicarbazide, hydrazine hydrate). The reaction of the reagents was carried out in acetic acid in a 1:1 molar ratio at 75 °C for 6-8 h, which resulted in aromatic oximes, thiosemicarbazones and hydrazones. The synthesis of (E)-4-chlorobenzaldoxime, (E)-N-(4-nitrobenzylidene) hydroxylammonium chloride, (E)-2-(4-chloro)- and (E)-2-(4-nitrobenzylidene) hydrazine-1-carbothioam

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5

Naveen, S., K. Anil Kumar, D. Channe Gowda, M. A. Sridhar, and J. Shashidhara Prasad. "N-(2-Nitrobenzylidene)aniline." Acta Crystallographica Section E Structure Reports Online 62, no. 9 (2006): o3790—o3791. http://dx.doi.org/10.1107/s1600536806031102.

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6

Chang, Ming-Jen, Tzu-Chien Fang, Hsing-Yang Tsai, Ming-Hui Luo, and Kew-Yu Chen. "2-(4-Nitrobenzylidene)malononitrile." Acta Crystallographica Section E Structure Reports Online 68, no. 4 (2012): o957. http://dx.doi.org/10.1107/s1600536812008896.

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In the title compound, C10H5N3O2, the benzylidenemalononitrile unit is nearly planar, with a maximum deviation of 0.129 (2) Å for a terminal N atom; the nitro group is approximately coplanar with the benzene ring [dihedral angle = 8.8 (3)°]. An intramolecular C—H...N hydrogen bond stabilizes the molecular conformation.

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7

Zaheer, Muhammad, Zareen Akhter, Michael Bolte, and Humaira M. Siddiqi. "N-(3-Nitrobenzylidene)aniline." Acta Crystallographica Section E Structure Reports Online 64, no. 12 (2008): o2381—o2382. http://dx.doi.org/10.1107/s1600536808036970.

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8

Deng, Peng-Fei, Guo-Bing Chen, Ya-Qing Feng, and Jian Song. "Isopropyl 2-(3-nitrobenzylidene)acetoacetate." Acta Crystallographica Section E Structure Reports Online 63, no. 8 (2007): o3532. http://dx.doi.org/10.1107/s1600536807030322.

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9

Thenmozhi, S., S. Ranjith, A. SubbiahPandi, V. Dhayalan, and A. K. MohanaKrishnan. "Diethyl 2-(2-nitrobenzylidene)malonate." Acta Crystallographica Section E Structure Reports Online 65, no. 9 (2009): o2209. http://dx.doi.org/10.1107/s1600536809032668.

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10

Yang, Wen, Yan Zhang, and De-Chun Zhang. "N-(3-Nitrobenzylidene)-p-toluidine." Acta Crystallographica Section E Structure Reports Online 61, no. 9 (2005): o2964—o2966. http://dx.doi.org/10.1107/s160053680502581x.

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11

Tunc˛, Tuncay, Habibe Tezcan, Musa Sarı, Orhan Büyükgüngör, and Rahmi Yaǵbasan. "N-(4-Nitrobenzylidene)-N′-phenylhydrazine." Acta Crystallographica Section C Crystal Structure Communications 59, no. 9 (2003): o528—o529. http://dx.doi.org/10.1107/s0108270103016019.

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12

Quail, J. Wilson, Umashankar Das, and Jonathan R. Dimmock. "2,6-Bis(4-nitrobenzylidene)cyclohexanone." Acta Crystallographica Section E Structure Reports Online 61, no. 4 (2005): o1150—o1152. http://dx.doi.org/10.1107/s1600536805008871.

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13

Yang, Q. C., Y. Q. Tang, W. J. Yang, and H. Y. Chen. "N-(3-Nitrobenzylidene)-p-phenylenediamine." Acta Crystallographica Section C Crystal Structure Communications 54, no. 10 (1998): 1532–34. http://dx.doi.org/10.1107/s0108270198004818.

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14

Sebej, Peter, Tomas Solomek, L’ubica Hroudna, Pavla Brancova, and Petr Klan. "Photochemistry of 2-Nitrobenzylidene Acetals." Journal of Organic Chemistry 74, no. 22 (2009): 8647–58. http://dx.doi.org/10.1021/jo901756r.

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15

A., P. Mishra, Kumar Krishna, and R. Pandey L. "Synthesis and structural studies of complexes of 2-nitrobenzaldehyde derived Schiff bases with some bivalent transition metal ions." Journal of Indian Chemical Society Vol. 83, Jan 2006 (2006): 16–19. https://doi.org/10.5281/zenodo.5815114.

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Inorganic Research Laboratories. Department of Chemistry, Dr. H. S. Gour University, Sagar-470 003, Madhya Pradesh, India <em>E-mail :</em> apm19@rediffmail.com <em>Manuscript received 20 August 2003, revised 22 August 2005, accepted 29 August 2005</em> Complexes of Co<sup>II</sup>, Ni<sup>II</sup> and Cu<sup>II</sup> with the Schiff bases 2-nitrobenzylidene-2,6-dichloro-4-nitroaniline (NDCA) and 2-nitrobenzylidene-2-amino-4-chlorophenol (NACPh) have been synthesized and characterized with the help of microanalytical data, UV-vis, IR, ESR spectroscopy, conductance and magnetic measurements. Li

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16

Mishchenko, M. V., S. Yu Shtrygol’, A. V. Lozynskyi, and R. B. Lesyk. "Psychotropic properties of a potential anticonvulsant of 5-[(Z)-(4-nitrobenzylidene)]-2- (thiazol-2-ylimino)-4-thiazolidinone." News of Pharmacy, no. 2(102) (October 19, 2021): 96–103. http://dx.doi.org/10.24959/nphj.21.53.

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Aim. To study the range of psychotropic properties of a new original compound of 5-[(Z)-(4-nitrobenzylidene)]-2-(thiazol-2-ylimino)-4 thiazolidinone with the anticonvulsant activity. Materials and methods. Adult nonlinear white mice of both sexes weighing 20-27 g were used in the experiments. The locomotor, exploratory, emotional activities were studied in the open field test. The elevated plus maze was used to study anxiety. The effect of the compound on depressive behavior was studied by the tail suspension test. The passive avoidance test was used to study memory. The influence of the compo

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17

Rahman, Mohammed M., Mohammad Musarraf Hussain, Muhammad N. Arshad, Md Rabiul Awual, and Abdullah M. Asiri. "Arsenic sensor development based on modification with (E)-N′-(2-nitrobenzylidine)-benzenesulfonohydrazide: a real sample analysis." New Journal of Chemistry 43, no. 23 (2019): 9066–75. http://dx.doi.org/10.1039/c9nj01567a.

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(E)-N′-(2-Nitrobenzylidene)-benzenesulfonohydrazide was prepared from 2-nitrobenzaldehyde and benzenesulfonylhydrazine by using a condensation method and applied as a selective As<sup>3+</sup> sensor.

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18

Zhou, Cong-Shan, and Tao Yang. "2-Chloro-N′-(4-nitrobenzylidene)benzohydrazide." Acta Crystallographica Section E Structure Reports Online 66, no. 2 (2010): o290. http://dx.doi.org/10.1107/s1600536809055330.

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19

Zhi, Feng. "N′-(2-Chloro-5-nitrobenzylidene)isonicotinohydrazide." Acta Crystallographica Section E Structure Reports Online 65, no. 3 (2009): o623. http://dx.doi.org/10.1107/s1600536809006588.

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20

Dong, Wen-Kui, Yin-Xia Sun, Jun-Feng Tong, Hai-Hong Zhao, and Li Wang. "1,3-Bis[(4-nitrobenzylidene)aminooxy]propane." Acta Crystallographica Section E Structure Reports Online 65, no. 9 (2009): o2141—o2142. http://dx.doi.org/10.1107/s1600536809031316.

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21

Zheng, Peng-Wu, Wei Wang, and Xue-Min Duan. "N,N′-Bis(3-nitrobenzylidene)hydrazine." Acta Crystallographica Section E Structure Reports Online 61, no. 10 (2005): o3485—o3486. http://dx.doi.org/10.1107/s1600536805030631.

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22

Yusnita, Juahir, Hapipah M. Ali, Subramaniam Puvaneswary, Ward T. Robinson, and Seik Weng Ng. "N′-(2-Hydroxy-5-nitrobenzylidene)benzenesulfonohydrazide." Acta Crystallographica Section E Structure Reports Online 64, no. 8 (2008): o1583. http://dx.doi.org/10.1107/s1600536808022691.

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23

Ren, Xiao-Yan, and Fang-Fang Jian. "4-Methoxy-N-(2-nitrobenzylidene)aniline." Acta Crystallographica Section E Structure Reports Online 64, no. 10 (2008): o2027. http://dx.doi.org/10.1107/s1600536808025117.

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24

Li, Huan-Qiu, Yin Luo, Xuan Qin, and Hai-Liang Zhu. "(E)-Benzyl 3-(3-nitrobenzylidene)dithiocarbazate." Acta Crystallographica Section E Structure Reports Online 65, no. 12 (2009): o3080. http://dx.doi.org/10.1107/s1600536809045723.

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25

Shan, Shang, Yu-Liang Tian, Wen-Long Wang, and Shan-Heng Wang. "(E)-Methyl 3-(2-nitrobenzylidene)dithiocarbazate." Acta Crystallographica Section E Structure Reports Online 64, no. 1 (2007): o53. http://dx.doi.org/10.1107/s160053680706059x.

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26

Mendoza, Angel, Ruth Meléndrez-Luevano, Blanca M. Cabrera-Vivas, Claudia Acoltzi-X, and Marcos Flores-Alamo. "(E)-1-(4-Nitrobenzylidene)-2,2-diphenylhydrazine." Acta Crystallographica Section E Structure Reports Online 68, no. 11 (2012): o3238. http://dx.doi.org/10.1107/s1600536812043681.

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27

Feizi, Samaneh, Ali Hossein Rezayan, Soroush Sardari, and Behrouz Notash. "(E)-1-(2-Nitrobenzylidene)-4-phenylthiosemicarbazide." Acta Crystallographica Section E Structure Reports Online 68, no. 7 (2012): o2154. http://dx.doi.org/10.1107/s1600536812026803.

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28

Akkurt, Mehmet, Aliasghar Jarrahpour, Malihe Aye, Mustafa Gençaslan, and Orhan Büyükgüngör. "3,4-Dimethoxy-N-(4-nitrobenzylidene)aniline." Acta Crystallographica Section E Structure Reports Online 64, no. 11 (2008): o2087. http://dx.doi.org/10.1107/s1600536808032042.

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29

Akkurt, Mehmet, Ali Asghar Jarrahpour, Malihe Aye, Mustafa Gençaslan, and Orhan Büyükgüngör. "3,4-Dimethoxy-N-(3-nitrobenzylidene)aniline." Acta Crystallographica Section E Structure Reports Online 64, no. 11 (2008): o2175—o2176. http://dx.doi.org/10.1107/s1600536808034193.

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30

Shan, Shang, Yan-Lan Huang, Han-Qi Guo, Deng-Feng Li, and Jian Sun. "Benzyl 3-[(E)-2-nitrobenzylidene]dithiocarbazate." Acta Crystallographica Section E Structure Reports Online 67, no. 8 (2011): o2107. http://dx.doi.org/10.1107/s1600536811028686.

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31

Hou, Jin-Long. "4-Hydroxy-N′-(3-nitrobenzylidene)benzohydrazide." Acta Crystallographica Section E Structure Reports Online 68, no. 5 (2012): o1352. http://dx.doi.org/10.1107/s1600536812014778.

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32

Hou, Jin-Long, and Ye Bi. "4-Methoxy-N′-(3-nitrobenzylidene)benzohydrazide." Acta Crystallographica Section E Structure Reports Online 68, no. 6 (2012): o1725. http://dx.doi.org/10.1107/s1600536812020454.

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In the title compound, C15H13N3O4, the dihedral angle between the benzene rings is 3.1 (3)°. The molecule displays an E conformation about the C=N bond. In the crystal, molecules are linked via N—H...O hydrogen bonds, generating chains that propagate along the b-axis direction. There is also a C—H...O interaction present.

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33

Tang, Chun-Bao. "2-Methyl-N′-(4-nitrobenzylidene)benzohydrazide." Acta Crystallographica Section E Structure Reports Online 66, no. 11 (2010): o2715. http://dx.doi.org/10.1107/s1600536810038869.

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34

Zhou, Wei, Wei-Xiao Hu, and Chun-Nian Xia. "10-(4-Hydroxy-3-nitrobenzylidene)anthrone." Acta Crystallographica Section E Structure Reports Online 63, no. 1 (2006): o51—o53. http://dx.doi.org/10.1107/s1600536806049051.

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35

Li, Yu-Guang, Hai-Liang Zhu, Xin-Zhi Chen, and Yu Song. "N,N′-Bis(2-nitrobenzylidene)ethylenediamine." Acta Crystallographica Section E Structure Reports Online 61, no. 12 (2005): o4156—o4157. http://dx.doi.org/10.1107/s1600536805037153.

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36

Shad, Hazoor Ahmad, M. Nawaz Tahir, Muhammad Ilyas Tariq, Muhammad Sarfraz, and Shahbaz Ahmad. "(E)-1-(2-Nitrobenzylidene)-2-phenylhydrazine." Acta Crystallographica Section E Structure Reports Online 66, no. 8 (2010): o1955. http://dx.doi.org/10.1107/s1600536810025882.

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37

Wu, Chuanbing. "3-(3-Nitrobenzylidene)pentane-2,4-dione." Acta Crystallographica Section E Structure Reports Online 65, no. 1 (2008): o210. http://dx.doi.org/10.1107/s1600536808043456.

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38

Gomes, Ligia R., John Nicolson Low, Ana S. M. C. Rodrigues, James L. Wardell, Camillo H. da Silva Lima, and Marcus V. N. de Souza. "FiveN′-benzylidene-N-methylpyrazine-2-carbohydrazides." Acta Crystallographica Section C Crystal Structure Communications 69, no. 5 (2013): 549–55. http://dx.doi.org/10.1107/s0108270113010056.

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The compoundsN′-benzylidene-N-methylpyrazine-2-carbohydrazide, C13H12N4O, (IIa),N′-(2-methoxybenzylidene)-N-methylpyrazine-2-carbohydrazide, C14H14N4O2, (IIb),N′-(4-cyanobenzylidene)-N-methylpyrazine-2-carbohydrazide dihydrate, C14H11N5O·2H2O, (IIc),N-methyl-N′-(2-nitrobenzylidene)pyrazine-2-carbohydrazide, C13H11N5O3, (IId), andN-methyl-N′-(4-nitrobenzylidene)pyrazine-2-carbohydrazide, C13H11N5O3, (IIe), have dihedral angles between the pyrazine rings and the benzene rings in the range 55–78°. These methylated pyrazine-2-carbohydrazides have supramolecular structures which are formed by weak

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39

Unver, Hüseyin, Aslí Karakas, and Tahsin Nuri Durlu. "Syntheses, Structures and Second-order Nonlinear Optical Behavior of (E)-N-(4-Nitrobenzylidene)-3,4-dimethylaniline and (E)-N-(3-Nitrobenzylidene)-3,4-dimethylaniline." Zeitschrift für Naturforschung B 65, no. 2 (2010): 185–90. http://dx.doi.org/10.1515/znb-2010-0215.

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(E)-N-(4-Nitrobenzylidene)-3,4-dimethylaniline (1) and (E)-N-(3-nitrobenzylidene)-3,4-dimethylaniline (2) have been synthesized, and their crystal structures have been determined by X-ray diffraction analysis. Linear optical characteristics have been evaluated experimentally using UV/Vis spectroscopy and theoretically using the configuration interaction (CI) method. The maximum onephoton absorption (OPA) wavelengths of the studied compounds are shorter than 450 nm, giving rise to good optical transparency in the visible and near IR regions. The ab initio quantum-mechanical calculations (finite

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40

A., P. Mishra, and Kumar Krishna. "Synthesis, characterization and antimicrobial studies of some 3d-metal complexes of chemotherapeutic importance." Journal of Indian Chemical Society Vol. 86, Nov 2009 (2009): 1150–55. https://doi.org/10.5281/zenodo.5820709.

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Biocoordination and Synthetic Inorganic Laboratories, Chemistry Department, Dr. H. S. Gaur University, Sagar-470 003, Madhya Pradesh, India <em>E-mai</em>l: apm19@rediffmail.com, apmishrasagar@gmail.com <em>Manuscript received 17 December 2007, revised 16 April 2009, accepted 7 July 2009</em> Complexes of Co<sup>II</sup>, Ni<sup>II</sup> and Cu<sup>II</sup> with the Schiff bases 3-nitrobenzylidene-2,4-dinitroaniline (NDA), 3- nitrobenzylidene-4-aminoacetanilide (NAA) and 2-furfurylidene-2-nitroaniline (FNA) have been synthesized and their characterization have been done by microanaly

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41

Ferguson, George, Christopher Glidewell, John N. Low, Janet M. S. Skakle, and James L. Wardell. "Solvent-dependent polymorphism in isomericN-(nitrobenzylidene)iodoanilines." Acta Crystallographica Section C Crystal Structure Communications 61, no. 7 (2005): o445—o449. http://dx.doi.org/10.1107/s0108270105016239.

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42

Jia, Bing, Shaomin Shi, Feihua Luo, and Zongqiu Hu. "2,2′-Bis(2-nitrobenzylidene)pyridine-2,6-dicarbohydrazide." Acta Crystallographica Section E Structure Reports Online 62, no. 8 (2006): o3326—o3327. http://dx.doi.org/10.1107/s1600536806026407.

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43

Yang, De-Suo. "N′-(5-Hydroxy-2-nitrobenzylidene)-2-methoxybenzohydrazide." Acta Crystallographica Section E Structure Reports Online 65, no. 11 (2009): o2864. http://dx.doi.org/10.1107/s1600536809043840.

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44

Li, Huan-Qiu, Yin Luo, Dong-Dong Li, and Hai-Liang Zhu. "(E)-4-Chlorobenzyl 3-(3-nitrobenzylidene)dithiocarbazate." Acta Crystallographica Section E Structure Reports Online 65, no. 12 (2009): o3101. http://dx.doi.org/10.1107/s1600536809047953.

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45

Ban, Hong-Yan, and Cong-Ming Li. "(E)-2-Methoxy-N′-(4-nitrobenzylidene)benzohydrazide." Acta Crystallographica Section E Structure Reports Online 65, no. 12 (2009): o3272. http://dx.doi.org/10.1107/s160053680905079x.

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46

Tan, Yi-Han, Siang Guan Teoh, Wan-Sin Loh, and Hoong-Kun Fun. "4-[(2-Hydroxy-5-nitrobenzylidene)amino]benzenesulfonamide." Acta Crystallographica Section E Structure Reports Online 66, no. 10 (2010): o2610—o2611. http://dx.doi.org/10.1107/s1600536810036949.

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47

Wu, Hong-Yun, Hong-Yan Ban, Jia-Bo Wang, and Li-Hua Zhang. "(E)-2-Fluoro-N′-(4-nitrobenzylidene)benzohydrazide." Acta Crystallographica Section E Structure Reports Online 67, no. 1 (2010): o160. http://dx.doi.org/10.1107/s1600536810052268.

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48

Xu, Shu-Qing. "(E)-4-Amino-N′-(3-nitrobenzylidene)benzohydrazide." Acta Crystallographica Section E Structure Reports Online 68, no. 5 (2012): o1320. http://dx.doi.org/10.1107/s1600536812014110.

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49

Hu, Hua-Nan, and Shi-Yong Liu. "(E)-4-Methyl-N′-(3-nitrobenzylidene)benzohydrazide." Acta Crystallographica Section E Structure Reports Online 68, no. 6 (2012): o1613. http://dx.doi.org/10.1107/s1600536812019198.

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In the title compound, C15H13N3O3, the dihedral angle between the benzene rings is 1.01 (3)° and that between the nitro group and its attached ring is 5.99 (15)°. In the crystal, molecules are linked by N—H...O hydrogen bonds generating C(4) chains along [010].

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50

Shi, Zhong-Feng, and Jia-Ming Li. "(E)-4-Amino-N′-(2-nitrobenzylidene)benzohydrazide." Acta Crystallographica Section E Structure Reports Online 68, no. 6 (2012): o1726. http://dx.doi.org/10.1107/s1600536812020855.

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Abstract:

The title Schiff base compound, C14H12N4O3, displays an E conformation with respect to the C=N double bond [1.268 (3) Å]. The dihedral angle between the benzene rings is 3.2 (5)°, consistent with an essentially planar molecule. In the crystal, N—H...O and N—H...N hydrogen bonds, as well as C—H...O interactions, link the molecules into layers that stack along the c axis.

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