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Relevant bibliographies by topics / Nitrogen heterocycle synthesis

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Academic literature on the topic 'Nitrogen heterocycle synthesis'

Author: Grafiati

Published: 4 June 2021

Last updated: 15 February 2022

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Journal articles on the topic "Nitrogen heterocycle synthesis"

1

Naito, Takeaki. "Heterocycle synthesis via radical reactions." Pure and Applied Chemistry 80, no. 4 (2008): 717–26. http://dx.doi.org/10.1351/pac200880040717.

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A novel synthetic method for the preparation of nitrogen-containing heterocycles via the route involving domino-type radical addition/cyclization reaction of oxime ethers is described. Alkyl radical addition/cyclization of oxime ethers carrying an appropriate leaving group proceeded smoothly to form the alkylated nitrogen-containing heterocyclic compounds. Additionally, tin-mediated radical addition/cyclization/elimination (RACE) reaction of oxime ethers is newly found and successfully applied to an asymmetric total synthesis of (-)-martinellic acid.

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Slivka, Mikhailo, and Mikhailo Onysko. "The Use of Electrophilic Cyclization for the Preparation of Condensed Heterocycles." Synthesis 53, no. 19 (2021): 3497–512. http://dx.doi.org/10.1055/s-0040-1706036.

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AbstractCondensed heterocycles are well-known for their excellent biological effects and they are undeniably important compounds in organic chemistry. Electrophilic cyclization reactions are widely used for the synthesis of mono-heterocyclic compounds. This review highlights the utility of electrophilic cyclization reactions as an effective generic tool for the synthesis of various condensed heterocycles containing functional groups that are able to undergo further chemical transformations, such as nucleophilic substitution, elimination, re-cyclization, cleavage, etc. This review describes the

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3

Gupta, Vivek Kumar, Baljeet Kaur, Amandeep Kaur, Amanpreet Kaur, and Monika Gupta. "Synthesis and Biological Evaluation of 1,3,4-Oxadiazolyl benzenesulphonyl benzimidazole derivatives." Indian Journal of Pharmaceutical and Biological Research 6, no. 02 (2018): 64–71. http://dx.doi.org/10.30750/ijpbr.6.2.10.

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Oxadiazoles are a class of heterocyclic aromatic chemical compound of azole family. Oxadiazole is five membered heterocycle having two carbons, two nitrogen, one oxygen and two double bonds. Oxadiazole exists in four isomeric forms depending upon the position of nitrogen atom in the ring. Benzimidazole is a heterocyclic aromatic compound. This bicyclic compound consists of fusion of benzene and imidazole. Benzimidazole may also be considered as cyclic analogues of imidines due to tautomerism effect. In the present study involves synthesis of1,3,4-oxadiazolyl benzenesulphonylbenzimidazole deriv

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4

Sundermeyer, Jörg, Herbert W. Roesky, and Mathias Noltemeyer. "Synthesis of a new unsaturated 16-membered heterocycle with alternating CC and NS building blocks." Canadian Journal of Chemistry 67, no. 11 (1989): 1785–87. http://dx.doi.org/10.1139/v89-276.

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The reaction between C6H4(SCl)23 and (PhC=NSiMe3)24 leads to the 16-membered heterocycle (SC6H4SN=CPhCPh=N)25. The X-ray structure analysis of 5 shows a nonplanar macrocyclic system with alternating CC and NS units. Keywords: 16-membered heterocycle, X-ray structure, sulphur–nitrogen.

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5

Vaughan, Keith, Ronald J. LaFrance, York Tang, and Donald L. Hooper. "Open-chain nitrogen compounds. Part VIII. 1-(2′-Acetylphenyl)-3-alkyltriazenes with reactive substituents in the alkyl group: synthons for five- and six-membered nitrogen heterocycles." Canadian Journal of Chemistry 63, no. 9 (1985): 2455–61. http://dx.doi.org/10.1139/v85-406.

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The synthesis of a series of 1-(2′-acetylphenyl)-3-alkyltriazenes, with electron-withdrawing α-substituents in the alkyl moiety, is described. The structure of the products from the reaction of 2-acetylbenzenediazonium ion (1) with methylamine has been reinvestigated using high field (360 MHz) nmr spectroscopy. The 2-acetylphenyltriazenes undergo cyclization to five-or six-membered heterocycles, depending on the substituent present in the alkyl group. Attack by N-3 of the triazene on the ortho-acetyl group leads to a 4-methylenetriazine, which can undergo oxidation to a benzotriazinone or acid

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Mahesh, V. K., Mamta Maheswari, Rakesh Sharma, and Rashmi Sharma. "Analogs of cannabinoids: synthesis of some 7H-indolo-, 5H-imidazolo, 7H-benzimidazolo[1,2-c] [1,3]benzoxazines – novel ring systems." Canadian Journal of Chemistry 63, no. 3 (1985): 632–35. http://dx.doi.org/10.1139/v85-103.

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Tetrahydrocannabinol 1, the active constituent of CannabissativaLinn, is a well-known CNS-active compound and introduction of a nitrogen atom at the ring junction of the pyran and alicyclic ring is of considerable interest. This prompted the synthesis of 7H-indolo[1,2-c] [1,3]-, 5H-imidazolo[1,2-C] [1,3],- and 7H-benzimidazolo[1,2-c] [1,3]-benzoxazine, a novel heterocyclic system. 2-(2′-Hydroxyphenyl) indoles, 2-(2′-hydroxyphenyl) imidazoles, and 2-(2′-hydroxyphenyl) benzimidazoles are suitable intermediates for the preparation of this type of benzoxazines, as the second heterocycle (ring B) c

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7

Philkhana, Satish Chandra, Fatimat O. Badmus, Isaac C. Dos Reis, and Rendy Kartika. "Recent Advancements in Pyrrole Synthesis." Synthesis 53, no. 09 (2021): 1531–55. http://dx.doi.org/10.1055/s-0040-1706713.

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AbstractThis review article features selected examples on the synthesis of functionalized pyrroles that were reported between 2014 and 2019. Pyrrole is an important nitrogen-containing aromatic heterocycle that can be found in numerous compounds of biological and material significance. Given its vast importance, pyrrole continues to be an attractive target for the development of new synthetic reactions. The contents of this article are organized by the starting materials, which can be broadly classified into four different types: substrates bearing π-systems, substrates bearing carbonyl and ot

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8

Duttwyler, S., S. Chen, M. K. Takase, K. B. Wiberg, R. G. Bergman, and J. A. Ellman. "Proton Donor Acidity Controls Selectivity in Nonaromatic Nitrogen Heterocycle Synthesis." Science 339, no. 6120 (2013): 678–82. http://dx.doi.org/10.1126/science.1230704.

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9

Yoshida, Zen-ichi, Hideo Hirai, Sadao Miki, and Shigeo Yoneda. "Trithiocyclopropenium ion as a building block for nitrogen heterocycle synthesis." Tetrahedron 45, no. 10 (1989): 3217–31. http://dx.doi.org/10.1016/s0040-4020(01)80147-2.

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Hu, Bao, and Stephen G. DiMagno. "Reactivities of vinyl azides and their recent applications in nitrogen heterocycle synthesis." Organic & Biomolecular Chemistry 13, no. 13 (2015): 3844–55. http://dx.doi.org/10.1039/c5ob00099h.

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This review categorizes the active intermediates generated from denitrogenation of vinyl azides under different reaction conditions, and highlights newly discovered transformations of vinyl azides that lead to convenient syntheses of N-heterocycles.

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Dissertations / Theses on the topic "Nitrogen heterocycle synthesis"

1

Qaddo, Akram. "Enantiospecific nitrogen heterocycle synthesis." Thesis, University of Sheffield, 2016. http://etheses.whiterose.ac.uk/15791/.

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Wagland, A. M. "The application of the Diels-Alder reaction in the synthesis of some nitrogen heterocycles." Thesis, University of Southampton, 1987. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.377952.

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Counceller, Carla Marie. "Development of Novel Methodologies for the Synthesis and Functionalization of Nitrogen Heterocycles." The Ohio State University, 2010. http://rave.ohiolink.edu/etdc/view?acc_num=osu1275047798.

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4

Arnold, Jeffrey Scott. "Rhodium-catalyzed asymmetric amination of trichloroacetimidates with application to nitrogen heterocycle synthesis." Diss., University of Iowa, 2014. https://ir.uiowa.edu/etd/4565.

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Chiral quaternary centers possessing a bond to nitrogen are an important class of amine compounds, however, methods for their enantioselective preparation remain sparse. The focus of my graduate research described herein has been the development of a novel rhodium-catalyzed regio- and enantioselective allylic aryl amination of tertiary trichloroacetimidates for the synthesis of amine-bearing quaternary centers (also termed α,α-disubstituted amines). Prior to our work, allylic carbonates and acetates had been successfully utilized in transition-metal catalyzed substitution reactions with anilin

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5

Moore, Stephen. "New reactions of lithiated aziridines and pyrrolidines : applications in nitrogen heterocycle synthesis." Thesis, University of York, 2008. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.485840.

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This PhD thesis describes the original developments of new reactions of lithiated aziridines and pyrrolidines and their use in nitrogen heterocycle synthesis. Chapter one represents a comprehensive overview of the literature covering the different modes of reactivity of lithiated epoxides and aziridines. These include: (i) carbenoid insertion into CH bonds and transannular CH bond insertions, (ii) carbenoid insertion into organolithium reagents (also known as reductive alkylation) and (iii) electrophilic trapping. Chapter two describes the development of a new route to aza-spirocycle-containin

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6

Morin, Marie. "Applications of new phosphorus-based 1,3-dipolar cycloaddition reagents in nitrogen heterocycle synthesis." Thesis, McGill University, 2013. http://digitool.Library.McGill.CA:80/R/?func=dbin-jump-full&object_id=117088.

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This thesis describes the study of phospha-Münchnones, a new class of 1,3-dipole. These 1,3-dipoles have been previously demonstrated to be accessible in a one-pot reaction of imines, acid chlorides and organophosphorus reagents, and participate in 1,3-dipolar cycloaddition reactions. The objective of the research described in this thesis is to both understand the reactivity of these dipoles, and exploit their cycloaddition with alkynes and alkenes to synthesize pyrroles and 2-pyrrolines with high regio-, diastereo- and enantioselectivity. Chapter 2 focuses on understanding the factors that co

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7

Chen, Tao. "Synthesis and X-ray Diffraction Structure of 8,9-Dichloropyrrolo[1,2-a]perimidin-10-one." Thesis, University of North Texas, 2003. https://digital.library.unt.edu/ark:/67531/metadc4268/.

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Treatment of dichloromaleic anhydride and 1,8-diaminonaphthalene in either benzene or toluene under refluxing conditions gives low yields of the new heterocyclic compound 8,9-dichloropyrrolo[1,2-a]perimidin-10-one. This product has been isolated and characterized in solution by NMR, IR, and UV/vis spectroscopies, and the solid-state structure of 8,9-dichloropyrrolo[1,2-a]perimidin-10-one has been established by X-ray crystallography. The nature of the HOMO and LUMO levels of 8,9-dichloropyrrolo[1,2-a]perimidin-10-one has been studied by extended Hückel molecular orbital calculations.

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8

Mauger-Chalaye, Hélène. "Réactions des nitrones avec les noyaux indoliques : nouvelles approches synthétiques d'alcaloïdes indoliques bio-actifs." Université Joseph Fourier (Grenoble), 1999. http://www.theses.fr/1999GRE10047.

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Parmi les composes naturels possedant des proprietes antivirales et/ou antitumorales, les alcaloides indoliques font l'objet d'un interet particulier. Afin de former le motif (3-indolyl)methylamine, base structurale de certains de ces derives bio-actifs, nous avons etudie la reactivite des nitrones vis-a-vis des noyaux indoliques. Utilisant 2 modes differents d'activation des nitrones, nous avons pu acceder a deux classes de produits : les n-hydroxylamines indoliques, et les 3,3-diindolylalcanes. Chacune des deux methodologies mises au point a par la suite ete exploitee pour synthetiser d'une

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9

Jones, A. D. "Novel syntheses of nitrogen heterocycles." Thesis, University of Nottingham, 1997. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.388287.

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10

Wong, Yung-Sing. "Nouveaux intermediaires chiraux de type 1,4-dihydropyridine et equivalents de sels de 3,4-dihydropyridinium pour la synthese asymetrique de piperidines polysubstituees. Application a la synthese enantioselective du 3-ppp et de l'indolizidine 195b." Paris 11, 1994. http://www.theses.fr/1994PA112105.

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L'application de la reaction de zincke a des amines primaires enantiomeriquement pures a donne des sels de pyridinium portant un centre asymetrique directement fixe sur l'azote, a partir de la pyridine correspondante, substituee ou non en position 3. L'etude de la reduction par le dithionite de sodium de ces sels a conduit de maniere efficace a de nouveaux intermediaires 1,4-dihydropyridines chiraux. La reduction des sels n-substitues par une chaine phenylethanol donne des 1,4-dihydropyridines qui s'isomerisent en 3,7,8,8a-tetrahydro-2h-oxazolo3,2-apyridines. Une etude structurale a ete entrep

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Books on the topic "Nitrogen heterocycle synthesis"

1

Asymmetric synthesis of nitrogen heterocycles. Wiley-VCH, 2009.

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1962-, El-Nemr Ahmed, ed. Synthesis of naturally occurring nitrogen heterocycles from carbohydrates. Blackwell Pub., 2005.

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3

Filik, Robert Paul. Synthesis of nitrogen containing heterocycles via radical cyclisation. typescript, 2000.

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El Ashry, El Sayed H., and Ahmed El Nemr, eds. Synthesis of Naturally Occurring Nitrogen Heterocycles from Carbohydrates. Blackwell Publishing Ltd, 2005. http://dx.doi.org/10.1002/9780470988619.

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5

Hatton, Kevin Brian. Studies on the synthesis of nitrogen and oxygen heterocycles. University of East Anglia, 1986.

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Vicario, Jose L., Dolores Badia, and Luisa Carrillo. New methods for the asymmetric synthesis of nitrogen heterocycles 2005. Research Signpost, 2005.

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7

Rees, Anthony John. The synthesis and reactions of some fluorinated nitrogen-containing heterocycles. University of Birmingham, 1996.

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8

McWilliams, Andrew Robert. The synthesis, novel reactivity and polymerization behavior of boron- and sulfur-nitrogen-phosphorus heterocycles. National Library of Canada, 1999.

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9

Rali, Topul. Approaches to the synthesis of 5- and 6-membered nitrogen containing heterocyclic natural products. University of East Anglia, 1985.

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10

Royer, Jacques, and H. P. Husson. Asymmetric Synthesis of Nitrogen Heterocycles. Wiley & Sons, Incorporated, John, 2009.

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Book chapters on the topic "Nitrogen heterocycle synthesis"

1

Chemler, Sherry R. "Stereoselective Nitrogen Heterocycle Synthesis Mediated by Chiral Metal Catalysts." In Catalytic Methods in Asymmetric Synthesis. John Wiley & Sons, Inc., 2011. http://dx.doi.org/10.1002/9781118087992.ch16.

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2

Li, Lixin, Xiaolei Ji, and Hanmin Huang. "Pd-Catalyzed Synthesis of Nitrogen-Containing Heterocycles." In Transition Metal-Catalyzed Heterocycle Synthesis via CH Activation. Wiley-VCH Verlag GmbH & Co. KGaA, 2016. http://dx.doi.org/10.1002/9783527691920.ch2.

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3

Muralirajan, Krishnamoorthy, and Chien-Hong Cheng. "Rh-Catalyzed Synthesis of Nitrogen-Containing Heterocycles." In Transition Metal-Catalyzed Heterocycle Synthesis via CH Activation. Wiley-VCH Verlag GmbH & Co. KGaA, 2016. http://dx.doi.org/10.1002/9783527691920.ch5.

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4

Beagle, Judit K. "Benzotriazole-Mediated Synthesis of Nitrogen-Containing Heterocycles." In Topics in Heterocyclic Chemistry. Springer International Publishing, 2015. http://dx.doi.org/10.1007/7081_2015_178.

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Besson, Thierry, and Valérie Thiéry. "Microwave-Assisted Synthesis of Sulfur and Nitrogen-Containing Heterocycles." In Topics in Heterocyclic Chemistry. Springer Berlin Heidelberg, 2006. http://dx.doi.org/10.1007/7081_008.

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6

Kim, Byeong Hyo, Yoon Seok Lee, Yong Rack Choi, Sun Kyong Kim, Young Moo Jun, and Woonphil Baik. "Chemical and Electrochemical Reductive Cyclizations of O-Nitroarenes Toward Nitrogen Containing Heterocycles." In Novel Trends in Electroorganic Synthesis. Springer Japan, 1998. http://dx.doi.org/10.1007/978-4-431-65924-2_97.

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7

van den Broek, Sebastiaan Bas A. M. W., Silvie A. Meeuwissen, Floris L. van Delft, and Floris P. J. T. Rutjes. "Natural Products Containing Medium-Sized Nitrogen Heterocycles Synthesized by Ring-Closing Alkene Metathesis." In Metathesis in Natural Product Synthesis. Wiley-VCH Verlag GmbH & Co. KGaA, 2010. http://dx.doi.org/10.1002/9783527629626.ch2.

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Arcadi, Antonio. "Gold-Catalyzed Synthesis of Nitrogen Heterocyclic Compounds via Hydroamination Reactions." In Topics in Heterocyclic Chemistry. Springer International Publishing, 2015. http://dx.doi.org/10.1007/7081_2015_5001.

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Fülöpová, Veronika, and Miroslav Soural. "Solid-Phase Synthesis of Seven-Membered Heterocycles with Two Nitrogen Atoms." In Topics in Heterocyclic Chemistry. Springer International Publishing, 2017. http://dx.doi.org/10.1007/7081_2016_2.

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Lei, Jian, Dengke Li, and Qiang Zhu. "Synthesis of Nitrogen-Containing Heterocycles via Imidoyl or Iminyl Radical Intermediates." In Topics in Heterocyclic Chemistry. Springer International Publishing, 2017. http://dx.doi.org/10.1007/7081_2017_9.

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Conference papers on the topic "Nitrogen heterocycle synthesis"

1

Tabolin, Andrey, Vladimir Motornov, Valentine Nenajdenko та Sema Ioffeа. "α-FLUORONITROALKENES IN THE SYNTHESIS OF FLUORINATED HETEROCYCLES". У Chemistry of nitro compounds and related nitrogen-oxygen systems. LLC MAKS Press, 2019. http://dx.doi.org/10.29003/m735.aks-2019/123-125.

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Silva, Gabriela D. da, Piero Bagnaresi, and Rodrigo L. O. R. Cunha. "Organoselenium functionalized nitrogen heterocycles: a proposition for new antimalarials." In 15th Brazilian Meeting on Organic Synthesis. Editora Edgard Blücher, 2013. http://dx.doi.org/10.5151/chempro-15bmos-bmos2013_20131014142313.

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Efimova, Tatyana, Olga Ozerova, Maria Ivanova, and Tamara Novikova. "1-AMINO-2-NITROGUANIDINE IN THE SYNTHESIS OF NITROGEN HETEROCYCLES." In Chemistry of nitro compounds and related nitrogen-oxygen systems. LLC MAKS Press, 2019. http://dx.doi.org/10.29003/m733.aks-2019/112-118.

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Voinkov, E., E. Ulomsky, and V. Rusinova. "STABLE NITROACETONITRILE POTASSIUM SALT IN SYNTHESIS OF NITROGEN-CONTAINING HETEROCYCLES." In Chemistry of nitro compounds and related nitrogen-oxygen systems. LLC MAKS Press, 2019. http://dx.doi.org/10.29003/m784.aks-2019/319-321.

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Gutierrez, Margarita, Yorley Duarte, Barbara Arevalo, et al. "NITROGEN HETEROCYCLES AS POTENTIAL ANTIBACTERIAL AGENTS." In The 17th International Electronic Conference on Synthetic Organic Chemistry. MDPI, 2013. http://dx.doi.org/10.3390/ecsoc-17-a035.

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Glukhacheva, Vera, and Sergey Ilꞌyasov. "SYNTHESIS AND PROPERTIES OF NITRO DERIVATIES OF HETEROCYCLIC ANTRACENES." In Chemistry of nitro compounds and related nitrogen-oxygen systems. LLC MAKS Press, 2019. http://dx.doi.org/10.29003/m729.aks-2019/97-99.

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Savateev, Konstantin, Evgeny Ulomsky, and Vladimir Rusinova. "CHLORODEOXYGENATION OF NITROAZOLOPYRIMIDINES AS A PROMISING METHOD FOR SYNTHESIS OF HETEROCYCLES WITH USEFUL BIOLOGICAL ACTIVITY." In Chemistry of nitro compounds and related nitrogen-oxygen systems. LLC MAKS Press, 2019. http://dx.doi.org/10.29003/m734.aks-2019/119-122.

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Drokin, R., D. Gazizov, D. Tiufiakov, et al. "POTASSIUM SALTS OF NITROCARBONYL COMPOUNDS IN THE SYNTHESIS OF NITROGEN-CONTAINING HETEROCYCLIC COMPOUNDS." In Chemistry of nitro compounds and related nitrogen-oxygen systems. LLC MAKS Press, 2019. http://dx.doi.org/10.29003/m749.aks-2019/187-189.

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Dowlati, Bahram, and Mohamed Rozali Othman. "An electrochemical procedure coupled with a Schiff base method; application to electroorganic synthesis of new nitrogen-containing heterocycles." In THE 2013 UKM FST POSTGRADUATE COLLOQUIUM: Proceedings of the Universiti Kebangsaan Malaysia, Faculty of Science and Technology 2013 Postgraduate Colloquium. AIP Publishing LLC, 2013. http://dx.doi.org/10.1063/1.4858752.

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Pogorzelska, Aneta, Jarosław Sławiński, Anna Kawiak, and Joanna Jasińska. "Novel N-(2-Mercaptobenzenesulfonyl)guanidine Derivatives Modified by Nitrogen-containing Heterocycles – Synthesis and Antiproliferative Activity Against Human Cancer Cell Lines." In 3rd International Electronic Conference on Medicinal Chemistry. MDPI, 2017. http://dx.doi.org/10.3390/ecmc-3-04675.

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