Academic literature on the topic 'Nitrosonium ions'

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Journal articles on the topic "Nitrosonium ions"

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Bering, Luis, and Andrey P. Antonchick. "Reactive nitrogen species: Nitrosonium ions in organic synthesis." Tetrahedron 75, no. 9 (2019): 1131–43. http://dx.doi.org/10.1016/j.tet.2019.01.036.

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Elsenbaumer, Ronald L. "Preparation of nitronium tetrafluoroborate free of nitrosonium ions." Journal of Organic Chemistry 53, no. 2 (1988): 437–39. http://dx.doi.org/10.1021/jo00237a043.

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Morakinyo, Moshood K., Itai Chipinda, Justin Hettick, et al. "Detailed mechanistic investigation into the S-nitrosation of cysteamine." Canadian Journal of Chemistry 90, no. 9 (2012): 724–38. http://dx.doi.org/10.1139/v2012-051.

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The nitrosation of cysteamine (H2NCH2CH2SH) to produce cysteamine-S-nitrosothiol (CANO) was studied in slightly acidic medium by using nitrous acid prepared in situ. The stoichiometry of the reaction was H2NCH2CH2SH + HNO2 → H2NCH2CH2SNO + H2O. On prolonged standing, the nitrosothiol decomposed quantitatively to yield the disulfide, cystamine: 2H2NCH2CH2SNO → H2NCH2CH2S–SCH2CH2NH2 + 2NO. NO2 and N2O3 are not the primary nitrosating agents, since their precursor (NO) was not detected during the nitrosation process. The reaction is first order in nitrous acid, thus implicating it as the major ni
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Butler, Anthony R., Frederick W. Flitney, and D. Lyn H. Williams. "NO, nitrosonium ions, nitroxide ions, nitrosothiols and iron-nitrosyls in biology: a chemist's perspective." Trends in Pharmacological Sciences 16, no. 1 (1995): 18–22. http://dx.doi.org/10.1016/s0165-6147(00)88968-3.

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Vanin, Anatoly F. "Physico-Chemistry of Dinitrosyl Iron Complexes as a Determinant of Their Biological Activity." International Journal of Molecular Sciences 22, no. 19 (2021): 10356. http://dx.doi.org/10.3390/ijms221910356.

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In this article we minutely discuss the so-called “oxidative” mechanism of mononuclear form of dinitrosyl iron complexes (M-DNICs) formations proposed by the author. M-DNICs are proposed to be formed from their building material—neutral NO molecules, Fe2+ ions and anionic non-thiol (L−) and thiol (RS−) ligands based on the disproportionation reaction of NO molecules binding with divalent ion irons in pairs. Then a protonated form of nitroxyl anion (NO−) appearing in the reaction is released from this group and a neutral NO molecule is included instead. As a result, M-DNICs are produced. Their
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Nishiyama, Akihide, Yuki Tanaka, Shigeki Mori, Hiroyuki Furuta, and Soji Shimizu. "Oxidative nitration reaction of antiaromatic 5,15-dioxaporphyrin." Journal of Porphyrins and Phthalocyanines 24, no. 01n03 (2020): 355–61. http://dx.doi.org/10.1142/s108842461950113x.

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Upon oxidation of 20[Formula: see text]-electron antiaromatic 5,15-dioxaporphyrin (DOP) using nitrosonium ions as oxidants, a tetrakis-[Formula: see text]-nitrated compound was formed instead of the expected 18[Formula: see text]-electron aromatic dication species via an oxidative nitration reaction mechanism. Compared with the original DOP, this tetranitro DOP product exhibited a blue shift of absorption and downfield shifts of the [Formula: see text]-pyrrolic proton signals. The unique antiaromatic electronic structure of the tetranitro DOP was disclosed experimentally by electrochemistry an
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GORELIK, M. V., V. I. LOMZAKOVA, E. A. KHAMIDOVA, V. YA SHTEIMAN, and M. G. KUZNETSOVA. "ChemInform Abstract: Nitration of Anilinium Ions in Concentrated Sulfuric Acid Catalyzed by Nitrosonium Hydrogensulfate." ChemInform 27, no. 2 (2010): no. http://dx.doi.org/10.1002/chin.199602117.

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Wincel, H., R. H. Fokkens та N. M. M. Nibbering. "Gas‒phase reactions of NO+with Glu and γ‒Glu–Met". Spectroscopy 14, № 4 (2000): 247–57. http://dx.doi.org/10.1155/2000/781283.

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The reactivity of the nitrosonium ion, NO+, with the amino acid Glu and the dipeptide γ‒Glu–Met in the gas phase has been investigated using the combination of chemical ionisation mass spectrometry and MS/MS. It is shown that NO+reacts efficiently with both Glu and Glu–Met leading to the formation of the nitroso‒group containing ions atm/z159 and 288.The formation ofm/z159, (GluNO‒18)+, is rationalized by a mechanism involving an electrophilic attack of NO+upon the carbonyl oxygen atom of one of the carboxylic groups of Glu and the N‒terminal carboxylic group of Glu–Met leading to the neutral
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Boughriet, A., and M. Wartel. "Electron-transfer kinetics and activation barriers for the reductions of nitrosonium and nitronium ions in aprotic solvents." International Journal of Chemical Kinetics 25, no. 5 (1993): 383–97. http://dx.doi.org/10.1002/kin.550250507.

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Vanin, Anatoly F. "What is the Mechanism of Nitric Oxide Conversion into Nitrosonium Ions Ensuring S-Nitrosating Processes in Living Organisms." Cell Biochemistry and Biophysics 77, no. 4 (2019): 279–92. http://dx.doi.org/10.1007/s12013-019-00886-1.

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Dissertations / Theses on the topic "Nitrosonium ions"

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Patzig-Klein, Sebastian. "Untersuchungen zum Reaktionsverhalten kristalliner Siliziumoberflächen in HF-basierten Ätzlösungen." Doctoral thesis, TU Bergakademie Freiberg, 2009. https://tubaf.qucosa.de/id/qucosa%3A22706.

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Die vorliegende Arbeit befasst sich mit der grundlegenden Untersuchung von Reaktionsmustern kristalliner Si-Oberflächen in HF-basierten Lösungen. Ausgehend von den industriell genutzten HF-HNO3-H2O-Gemischen wurden wisher wenig untersuchte HF/HNO3-Konzentrationsverhältnisse, die durch gelöste Stickoxide bedingten Folgereaktionen sowie der PH-Wert als Steuerparameter zur Aufarbeitung feinkörniger Si-Rohstoffe (Korngröße ≤ 0,5 mm) identifiziert. Die in diesem Kontext zentrale Rolle der NO+-Ionen wurde durch Untersuchung der spezifischen Reaktionsmuster an kristallinen as-cut und hydrophobierten
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Patzig-Klein, Sebastian. "Untersuchungen zum Reaktionsverhalten kristalliner Siliziumoberflächen in HF-basierten Ätzlösungen." Doctoral thesis, Technische Universitaet Bergakademie Freiberg Universitaetsbibliothek "Georgius Agricola&quot, 2010. http://nbn-resolving.de/urn:nbn:de:bsz:105-qucosa-27118.

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Die vorliegende Arbeit befasst sich mit der grundlegenden Untersuchung von Reaktionsmustern kristalliner Si-Oberflächen in HF-basierten Lösungen. Ausgehend von den industriell genutzten HF-HNO3-H2O-Gemischen wurden wisher wenig untersuchte HF/HNO3-Konzentrationsverhältnisse, die durch gelöste Stickoxide bedingten Folgereaktionen sowie der PH-Wert als Steuerparameter zur Aufarbeitung feinkörniger Si-Rohstoffe (Korngröße ≤ 0,5 mm) identifiziert. Die in diesem Kontext zentrale Rolle der NO+-Ionen wurde durch Untersuchung der spezifischen Reaktionsmuster an kristallinen as-cut und hydrophobierten
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Book chapters on the topic "Nitrosonium ions"

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Firouzabadi, H., and N. Iranpoor. "Using Electrophilic Nitrosonium or Nitronium Ions." In Acetals: O/N, S/S, S/N, and N/N and Higher Heteroatom Analogues. Georg Thieme Verlag KG, 2007. http://dx.doi.org/10.1055/sos-sd-030-00426.

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Wakefield, B. J. "Use of the Nitrosonium Ion as the N—O Component." In Five-Membered Hetarenes with One Chalcogen and One Additional Heteroatom. Georg Thieme Verlag KG, 2002. http://dx.doi.org/10.1055/sos-sd-011-00381.

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