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Journal articles on the topic 'Nitrosyl chloride'

Author: Grafiati

Published: 4 June 2021

Last updated: 26 July 2025

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1

Rahman, Md Hafizur, and Michael D. Ryan. "Investigation of solvation and solvent coordination effects in iron porphyrin nitrosyls by infrared spectroelectrochemistry and DFT calculations." Journal of Porphyrins and Phthalocyanines 23, no. 06 (2019): 639–44. http://dx.doi.org/10.1142/s1088424619500317.

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Visible and infrared spectroelectrochemistry of Fe(OEPone)(NO) (H2OEPone = octaethylporphinone) were examined in methylene chloride and THF. The visible spectra of Fe(OEPone)(NO) were similar in both solvents. Unlike other ferrous porphyrin nitrosyls, a six-coordinate complex was formed with THF as a ligand. This led to two nitrosyl bands in the infrared spectrum. The absorbance of these bands depended on the concentration of THF in the solution. Solvation and coordination effects on the carbonyl and nitrosyl bands were observed for both the nitrosyl and reduced-nitrosyl complexes. DFT calcula

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2

Hallou, A., L. Schriver-Mazzuoli, A. Schriver, and P. Chaquin. "Matrix photochemistry of nitrosyl chloride." Chemical Physics 237, no. 3 (1998): 251–64. http://dx.doi.org/10.1016/s0301-0104(98)00238-9.

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3

McDonald, Joseph K., Victor F. Kalasinsky, Thomas J. Geyer, and James R. Durig. "Rotational analysis of nitrosyl chloride." Mikrochimica Acta 95, no. 1-6 (1988): 429–31. http://dx.doi.org/10.1007/bf01349802.

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4

Pirnat, J., Z. Trontelj, and H. Borrmann. "Chlorine NQR and Phase Transitions in NOCl." Zeitschrift für Naturforschung A 51, no. 5-6 (1996): 736–38. http://dx.doi.org/10.1515/zna-1996-5-663.

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Abstract Chlorine NQR studies of solid nitrosyl chloride NOCl at temperatures below 200 K were undertaken. They indicate an ionic character of the N-Cl chemical bond and confirm the phase transition near 140 K. Thermal hysteresis of the transition temperature was observed.

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5

Pekshev, A. V., A. B. Vagapov, N. A. Sharapov, and A. F. Vanin. "High- dose nitric oxide gas inhalation for HIV infection." Биофизика 68, no. 5 (2023): 1074–80. http://dx.doi.org/10.31857/s0006302923050289.

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Therapeutic effect of high-dose nitric oxide gas inhalation (NO concentration was not less than than 1000 ppm) on two patients with HIV infection was shown. Inhaled NO therapy led to a rapid decrease in viral load to an undetectable level which was persistent even after analytical treatment interruption. It is suggested that HIV infection is controlled by nitrosonium (NO+) cations, the oxidized form of neutral NO molecules that enter the blood. Subsequent conversion of NO+ cations into nitrite anions due to a reaction with hydroxyl ions is inhibited by the binding of NO+ cations and chloride a

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6

Kostin, Gennadiy A., Ruslan Kozlov, Artem Bogomyakov, Svyatoslav Tolstikov, Dmitriy Sheven, and Sergey Korenev. "New Ruthenium Nitrosyl Complexes Combining Potentially Photoactive Nitrosyl Group with the Magnetic Nitroxide Radicals as Ligands." International Journal of Molecular Sciences 24, no. 17 (2023): 13371. http://dx.doi.org/10.3390/ijms241713371.

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Two ruthenium nitrosyl complexes of Na[RuNOCl4L] with nitronyl nitroxide radicals coordinated to ruthenium with N-donor pyridine rings were prepared and described. The crystal structure of both complexes is 1D or 2D polymeric, due to the additional coordination of sodium cation by bridging the chloride ligands or oxygen atoms of nitroxides. Partially, the oligomeric forms remain in the solutions of the complexes in acetonitrile. The magnetic measurements in the solid state demonstrate the presence of antiferromagnetic interactions through the exchange channels, with the distance between parama

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7

Houtgraaf, H., and A. M. de Roos. "The binary system of nitrosyl chloride with aluminium chloride." Recueil des Travaux Chimiques des Pays-Bas 72, no. 11 (2010): 963–77. http://dx.doi.org/10.1002/recl.19530721107.

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8

Ellern, Arkady, and Konrad Seppelt. "The Structures of Nitrosyl Fluoride and Nitrosyl Chloride in the Solid State." Zeitschrift für anorganische und allgemeine Chemie 627, no. 2 (2001): 234–37. http://dx.doi.org/10.1002/1521-3749(200102)627:2<234::aid-zaac234>3.0.co;2-k.

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9

Ketelaar, J. A. A. "The dipole moment and the constitution of nitrosyl chloride and nitrosyl bromide." Recueil des Travaux Chimiques des Pays-Bas 62, no. 5 (2010): 289–92. http://dx.doi.org/10.1002/recl.19430620503.

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10

Schio, Luca, Cui Li, Susanna Monti, et al. "NEXAFS and XPS studies of nitrosyl chloride." Physical Chemistry Chemical Physics 17, no. 14 (2015): 9040–48. http://dx.doi.org/10.1039/c4cp05896h.

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The electronic structure of nitrosyl chloride (ClNO) has been investigated in the gas phase by X-ray Photoelectron (XPS) and Near Edge X-ray Absorption Fine Structure (NEXAFS) spectroscopy at the Cl 2p, Cl 2s, N 1s and O 1s edges in a combined experimental and theoretical study.

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11

WANG, PENGQIAN. "ELECTRON IMPACT DISSOCIATIVE IONIZATION OF NITROSYL CHLORIDE." Modern Physics Letters B 26, no. 11 (2012): 1250065. http://dx.doi.org/10.1142/s0217984912500650.

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Electron impact dissociative ionization of nitrosyl chloride ( ClNO ) has been studied at the electron beam energy of 200 eV. The dissociation channels of up to triply ionized ClNO are investigated by two- and three-dimensional covariance mapping methods. The absolute cross-sections for the different dissociation channels are measured. No stable ClNO + or ClNO 2+ ions are observed in the mass spectrum. The most possible pathway for the dissociation of ClNO + is ClNO + → NO + + Cl . The total double ionization cross-section of ClNO is found to be 6.3% compared to the total single ionization cro

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12

Schriver-Mazzuoli, L., A. Hallou, and A. Schriver. "Infrared Spectrum of the Nitrosyl Chloride Monomer and Dimer in Solid Nitrogen: Temperature-Induced Mobility of Nitrosyl Chloride." Journal of Physical Chemistry A 102, no. 48 (1998): 9772–78. http://dx.doi.org/10.1021/jp982992p.

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13

Pirnat, J., Z. Trontelj, and H. Borrmann. "NQR View of Solid Phases of NOCl." Zeitschrift für Naturforschung A 53, no. 6-7 (1998): 537–41. http://dx.doi.org/10.1515/zna-1998-6-742.

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Abstract Chlorine NQR studies of solid nitrosyl chloride NOC1 between 110 and 212 K are reported. In the temperature dependence an order-disorder phase transition near 145 K, found by X-ray diffraction, is confirmed. Unusual hysteretic NQR signal behaviour indirectly proves also the low temperature phase transition below 100 K. In the measured temperature region fast relaxing mechanisms are present. The upper limit of the expected 14N NQR frequency is estimated using the Townes-Dailey approach.

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14

Ellern, Arkady, and Konrad Seppelt. "ChemInform Abstract: The Structures of Nitrosyl Fluoride and Nitrosyl Chloride in the Solid State." ChemInform 32, no. 17 (2001): no. http://dx.doi.org/10.1002/chin.200117009.

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15

Rafiuddin, Ansari M., and Shakir Husain. "Reaction of Nitrosyl Chloride Gas with Unsaturated Steroids." Bulletin of the Chemical Society of Japan 60, no. 9 (1987): 3411–14. http://dx.doi.org/10.1246/bcsj.60.3411.

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16

Scheer, V., A. Frenzel, W. Behnke, et al. "Uptake of Nitrosyl Chloride (NOCl) by Aqueous Solutions." Journal of Physical Chemistry A 101, no. 49 (1997): 9359–66. http://dx.doi.org/10.1021/jp972143m.

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17

Ford, Thomas A. "The molecular complexes of boron trifluoride with nitrosyl fluoride and nitrosyl chloride. Ion-pair formation." Journal of Molecular Structure 1090 (June 2015): 7–13. http://dx.doi.org/10.1016/j.molstruc.2014.11.047.

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18

Nesbitt, Fred L., David F. Nava, Walter A. Payne, and Louis J. Stief. "Absolute rate constant for the reaction of atomic chlorine(2P) with nitrosyl chloride." Journal of Physical Chemistry 91, no. 20 (1987): 5337–40. http://dx.doi.org/10.1021/j100304a039.

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19

Saavedra, Joseph E. "Synthesis of 2,2-disubstituted N-nitrosooxazolidines with nitrosyl chloride." Journal of Organic Chemistry 50, no. 13 (1985): 2379–80. http://dx.doi.org/10.1021/jo00213a037.

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20

Bondarenko, O. B., A. Yu Gavrilova, L. G. Saginova, and N. V. Zyk. "Synthesis of 4,5-Dihydroisoxazoles from Arylcyclopropanes and Nitrosyl Chloride." Russian Journal of Organic Chemistry 39, no. 7 (2003): 1021–24. http://dx.doi.org/10.1023/b:rujo.0000003196.89457.a4.

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21

Finlayson-Pitts, B. J., M. J. Ezell, S. Z. Wang, and C. E. Grant. "Reaction of hydroxyl with nitrosyl chloride: kinetics and mechanisms." Journal of Physical Chemistry 91, no. 9 (1987): 2377–82. http://dx.doi.org/10.1021/j100293a036.

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22

Cooksey, Catherine C., Kevin J. Johnson, and Philip J. Reid. "Femtosecond Pump−Probe Studies of Nitrosyl Chloride Photochemistry in Solution." Journal of Physical Chemistry A 110, no. 28 (2006): 8613–22. http://dx.doi.org/10.1021/jp062069k.

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23

Bechara, J., T. Morrow, and W. D. McGrath. "The flash photodissociation of nitrosyl chloride: Vibrational energy-transfer processes." Chemical Physics Letters 122, no. 6 (1985): 605–11. http://dx.doi.org/10.1016/0009-2614(85)87279-1.

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24

McDonald, J. K., J. A. Merritt, V. F. Kalasinsky, H. L. Heusel, and J. R. Durig. "Raman and infrared spectra of gaseous and solid nitrosyl chloride." Journal of Molecular Spectroscopy 117, no. 1 (1986): 69–88. http://dx.doi.org/10.1016/0022-2852(86)90093-7.

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25

Jones, L. H., and B. I. Swanson. "Infrared studies of matrix-isolated and neat solid nitrosyl chloride." Journal of Physical Chemistry 95, no. 1 (1991): 86–90. http://dx.doi.org/10.1021/j100154a020.

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26

Durig, J. R., T. J. Geyer, Young Hae Kim, V. F. Kalasinsky, and J. K. McDonald. "Far-infrared spectra and ab initio calculations of nitrosyl chloride." Journal of Molecular Structure 244 (April 1991): 103–15. http://dx.doi.org/10.1016/0022-2860(91)80151-s.

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27

SCHEER, V., A. FRENZEL, W. BEHNKE, et al. "ChemInform Abstract: Uptake of Nitrosyl Chloride (NOCl) by Aqueous Solutions." ChemInform 29, no. 12 (2010): no. http://dx.doi.org/10.1002/chin.199812013.

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28

Gatehouse, Bethany, Holger S. P. Müller, Nils Heineking, and Michael C. L. Gerry. "Structure, harmonic force field and hyperfine coupling constants of nitrosyl chloride." J. Chem. Soc., Faraday Trans. 91, no. 19 (1995): 3347–55. http://dx.doi.org/10.1039/ft9959103347.

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29

Killough, Patrick M., Basil I. Swanson, and Stephen F. Agnew. "Molecular and ionic phases of solid nitrosyl chloride at low temperature." Journal of Physical Chemistry 93, no. 23 (1989): 7953–56. http://dx.doi.org/10.1021/j100360a041.

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30

Marquez, Antonio, Julio Anguiano, and Javier Fernandez Sanz. "An ab initio CASSCF study of the hydroxyl + nitrosyl chloride reaction." Journal of Physical Chemistry 96, no. 5 (1992): 2115–18. http://dx.doi.org/10.1021/j100184a019.

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31

Mackey, Jeffrey L., Bruce R. Johnson, Carter Kittrell, Linh D. Le, and James L. Kinsey. "Resonance Raman spectroscopy in the dissociative A band of nitrosyl chloride." Journal of Chemical Physics 114, no. 15 (2001): 6631–40. http://dx.doi.org/10.1063/1.1355656.

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32

Peer, H. G., and A. Schors. "Chemistry of propadiene. III. The addition of nitrosyl chloride to propadiene." Recueil des Travaux Chimiques des Pays-Bas 86, no. 2 (2010): 167–70. http://dx.doi.org/10.1002/recl.19670860207.

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33

Ashok, R. F. N., M. Gupta, K. S. Arulsamy та U. C. Agarawala. "Cyclopentadienyl ruthenium complexes. Part II. Reactivity of some η5-cyclopentadienylbis(triphenylphosphine)ruthenium(II) complexes with nitrosyl chloride and nitrosyl bromide". Inorganica Chimica Acta 98, № 3 (1985): 169–79. http://dx.doi.org/10.1016/s0020-1693(00)87600-8.

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34

Handl, J. "Transfer From Soil to Plants of 106Ru As Nitrosyl and As Chloride." Health Physics 54, no. 1 (1988): 83–87. http://dx.doi.org/10.1097/00004032-198801000-00007.

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35

Jain, Ravi, and Jerome S. Schultz. "Light-assisted transport of nitric oxide across membranes containing nitrosyl chloride solutions." Journal of Membrane Science 26, no. 3 (1986): 313–26. http://dx.doi.org/10.1016/s0376-7388(00)82115-8.

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36

Kostyanovskii, R. G., O. G. Nabiev, and M. A. Shakhgel'diev. "Synthesis of N-nitrosoamines by the cleavage of aminals with nitrosyl chloride." Bulletin of the Academy of Sciences of the USSR Division of Chemical Science 36, no. 3 (1987): 635. http://dx.doi.org/10.1007/bf00955866.

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37

JONES, L. H., and B. I. SWANSON. "ChemInform Abstract: IR Studies of Matrix-Isolated and Neat Solid Nitrosyl Chloride." ChemInform 22, no. 13 (2010): no. http://dx.doi.org/10.1002/chin.199113007.

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38

Fenske, Dieter, Udo Demant, and Kurt Dehnicke. "Chloronitrosylkomplexe von Ruthenium(II) Die Kristallstruktur von (PPh3Me)2[Ru(NO)Cl4]2-2 CH2Cl2 / Chloro Nitrosyl Complexes of Ruthenium (II) The Crystal Structure of (PPh3Me)2 [Ru(NO)Cl4]2 • 2 CH2Cl2." Zeitschrift für Naturforschung B 40, no. 12 (1985): 1672–76. http://dx.doi.org/10.1515/znb-1985-1213.

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Abstract Ruthenium trichloride, obtained from its hydrate with thionyl chloride, reacts with excess trichloronitrom ethane yielding polymer [Ru(NO)Cl3]; by addition of triphenylmethylphosphonium chloride in dichlorom ethane (PPh3Me)2[Ru(NO)Cl4]2 · 2 CH2Cl2 is obtained, the IR spectrum of which is reported and assigned. Its crystal structure was determined with X-ray diffraction data (6404 independent observed reflexions, R = 0.068). Crystal data at -90 °C: a = 1145, b = 1591, c = 1406 pm, β = 96,0°, Z = 2, space group P21/C. The structure consists of PPh3Me⊕ cations, centrosymmetric anions [Ru

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39

Klimochkin, Yuri, Ilya Tkachenko, and Victor Rybakov. "Convenient Synthesis of Ethyl 5-Oxohomoadamantane-4-carboxylate: A Useful Precursor of Polyfunctional Homoadamantanes." Synthesis 51, no. 06 (2018): 1482–90. http://dx.doi.org/10.1055/s-0037-1610312.

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A facile and convenient synthesis of ethyl 5-oxohomoadamantane-4-carboxylate is reported, and its chemical properties as a cage analogue of acetoacetic ester are investigated. Various derivatives of homoadamantane were synthesized through the reaction of 5-oxohomoadamantane-4-carboxylate with electrophilic agents, binucleophiles, and hydrazoic acid. Some new unusual products were obtained by the reaction of that β-keto ester with nitric acid and nitrosyl chloride. Cage compounds synthesized could be used as precursors for the diverse condensed heterocyclic compounds with potential viral ion ch

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40

Sousa, Iran L., Pedro A. M. Vazquez, and Nelson H. Morgon. "Electronic Spectra of Nitrosyl Chloride: A Reinvestigation Using Coupled Cluster and DFT Calculations." Revista Processos Químicos 9, no. 18 (2015): 125–27. http://dx.doi.org/10.19142/rpq.v9i18.276.

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41

Khan, M. Ishaque, and U. C. Agarwala. "Synthesis of ammonium ions and nitrosylation reactions using nitrosyl chloride and alkyl nitrites." Journal of the Chemical Society, Dalton Transactions, no. 6 (1989): 1139. http://dx.doi.org/10.1039/dt9890001139.

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42

Lebl, René, David Cantillo, and C. Oliver Kappe. "Continuous generation, in-line quantification and utilization of nitrosyl chloride in photonitrosation reactions." Reaction Chemistry & Engineering 4, no. 4 (2019): 738–46. http://dx.doi.org/10.1039/c8re00323h.

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The reagent is prepared from stable, inexpensive and readily available starting materials. In-line UV/vis monitoring enables determination of the reagent's concentration after a continuous extraction and liquid–liquid separation sequence.

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43

Kalaiselvan, Anbarasan, Ponnambalam Venuvanalingam, Jordi Poater, and Miquel Solà. "Ab initio and DFT modeling of stereoselective deamination of aziridines by nitrosyl chloride." International Journal of Quantum Chemistry 102, no. 2 (2005): 139–46. http://dx.doi.org/10.1002/qua.20364.

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44

Yao, Li, Mao-Fa Ge, Dian-Xun Wang, Cheng-Yin Wu, Nan Xu, and Qi-Huang Gong. "Ionization and Dissociation of Nitrosyl Chloride Molecule in the Intense Femtosecond Laser Field." Chinese Journal of Chemistry 24, no. 7 (2006): 867–71. http://dx.doi.org/10.1002/cjoc.200690165.

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45

Bedjanian, Yuri. "Experimental Study of the Reactions of Br Atoms with Thiirane and Nitrosyl Chloride." Molecules 30, no. 9 (2025): 2058. https://doi.org/10.3390/molecules30092058.

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The kinetics of Br-atom reactions with C2H4S and ClNO were studied as a function of temperature at a total pressure of 2 Torr of helium using a discharge–flow system combined with mass spectrometry: Br + C2H4S → SBr + C2H4 (1) and Br + ClNO →BrCl + NO (2). The rate constant of reaction (1) was determined at T = 340–920 K by absolute measurements under pseudo-first-order conditions, either by monitoring the kinetics of Br-atom or C2H4S consumption in excess of C2H4S or of Br atoms, respectively, and by using a relative rate method: k1 = (6.6 ± 0.7) × 10−11 exp(−(2946 ± 60)/T) cm3molecule−1s−1 (

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46

Field, Leslie D., Trevor W. Hambley, Taian He,, Anthony F. Masters, and Peter Turner. "The Structures of the Decaphenylmetallocenium Cations of Chromium and Cobalt." Australian Journal of Chemistry 50, no. 11 (1997): 1035. http://dx.doi.org/10.1071/c97075.

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Decaphenylchromocenium and decaphenylcobaltocenium cations [M(η5-C5Ph5)2]+, M = Cr and Co, were synthesized by oxidation of the corresponding neutral decaphenylchromocene and decaphenylcobaltocene respectively with nitrosyl tetrafluoroborate. The complexes are air-stable and were fully characterized; decaphenylchromocenium tetrafluoroborate (1) and decaphenylcobaltocenium tetrafluoroborate (2) were structurally characterized by X-ray crystallography. Crystals of (1) (as a water/methylene chloride solvate), C70·5H50BClCrF4O0·5, M 1079·42, are triclinic, space group P -1 (No. 2), a 13·634(5), b

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47

Titov, Vladimir, Anatoly Osipov, and Anatoly Vanin. "The Ability of Blood Plasma to Inhibit Catalase in the Presence of Chloride is a Highly Sensitive Indicator of Deposited Nitric Oxide and Leukocyte Activation." Current Enzyme Inhibition 16, no. 2 (2020): 172–80. http://dx.doi.org/10.2174/1573408016999200429123919.

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Aims: To find out the origin of so-called nitrite - like substance (NLS) that appears in the blood plasma in patients with inflammatory diseases and the mechanism of its occurrence. To justify the possibility of registering its appearance in the blood as a highly sensitive indicator of leukocyte activation. Background: The need for a simple, sensitive and specific method of early diagnosis of inflammation, the key stage of which is the activation of white blood cells. Objective: To find out the origin of so-called nitrite - like substance (NLS) that appears in the blood plasma in patients with

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48

Hayton, Trevor W., Brian O. Patrick, Peter Legzdins, and W. Stephen McNeil. "The solid-state molecular structure of W(NO)3Cl3 and the nature of its WNO bonding." Canadian Journal of Chemistry 82, no. 2 (2004): 285–92. http://dx.doi.org/10.1139/v03-206.

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The monomeric trinitrosyl complex, W(NO)3Cl3, can be prepared by the treatment of WCl6 in CH2Cl2 with NO gas, and its identity has been unambiguously confirmed by a single-crystal X-ray diffraction analysis. The complex crystallizes in the space group Pmn21 as a three-component twin (a = 10.4280(4) Å, b = 6.3289(2) Å, c = 5.6854(2) Å, Z = 2, R1 = 0.065, wR2 = 0.176). Its solid-state molecular structure consists of a tungsten centre bound to three chloride ligands and three linear nitrosyl ligands in a fac-octahedral stereochemistry. In addition, the structure contains a crystallographically im

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49

Legzdins, Peter, Kevin M. Smith, and Steven J. Rettig. "Synthesis, characterization, and properties of some cyclopentadienyl molybdenum nitrosyl benzyl complexes." Canadian Journal of Chemistry 79, no. 5-6 (2001): 502–9. http://dx.doi.org/10.1139/v00-158.

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Reaction of CpMo(NO)(CH2Ph)Cl with Me2Mg, Ph2Mg, or PhCCLi reagents in THF affords the corresponding alkyl, aryl, or alkynyl CpMo(NO)(CH2Ph)R (R = hydrocarbyl) complexes as orange powders in good yields. Unlike related 16-electron CpMo(NO)R2 complexes, these 18-electron species exhibit good thermal stability due to their η2-benzyl-Mo interactions. Treatment of CpMo(NO)(CH2Ph)Cl with Na(DME)Cp provides dark green Cp2Mo(NO)(CH2Ph), whose solid-state molecular structure has been established by a single-crystal X-ray crystallographic analysis. The two Cp rings display different binding modes to th

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50

MIYAHARA, MAKOTO. "Substituent effects on nitrosation of 1,3-diarylureas with nitrosyl chloride, dinitrogen trioxide, and dinitrogen tetroxide." CHEMICAL & PHARMACEUTICAL BULLETIN 34, no. 5 (1986): 1950–60. http://dx.doi.org/10.1248/cpb.34.1950.

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