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Relevant bibliographies by topics / Nitrosyl group

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Academic literature on the topic 'Nitrosyl group'

Author: Grafiati

Published: 5 June 2025

Last updated: 15 July 2025

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Journal articles on the topic "Nitrosyl group"

1

Kostin, Gennadiy A., Ruslan Kozlov, Artem Bogomyakov, Svyatoslav Tolstikov, Dmitriy Sheven, and Sergey Korenev. "New Ruthenium Nitrosyl Complexes Combining Potentially Photoactive Nitrosyl Group with the Magnetic Nitroxide Radicals as Ligands." International Journal of Molecular Sciences 24, no. 17 (2023): 13371. http://dx.doi.org/10.3390/ijms241713371.

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Two ruthenium nitrosyl complexes of Na[RuNOCl4L] with nitronyl nitroxide radicals coordinated to ruthenium with N-donor pyridine rings were prepared and described. The crystal structure of both complexes is 1D or 2D polymeric, due to the additional coordination of sodium cation by bridging the chloride ligands or oxygen atoms of nitroxides. Partially, the oligomeric forms remain in the solutions of the complexes in acetonitrile. The magnetic measurements in the solid state demonstrate the presence of antiferromagnetic interactions through the exchange channels, with the distance between parama

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Li, Guoliang, Limei Wen, and R. Bruce King. "Heterobimetallic Chromium Manganese Carbonyl Nitrosyls: Comparison with Isoelectronic Homometallic Binuclear Chromium Carbonyl Nitrosyls and Manganese Carbonyls." Inorganics 7, no. 10 (2019): 127. http://dx.doi.org/10.3390/inorganics7100127.

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The heterometallic chromium-manganese carbonyl nitrosyls CrMn(NO)(CO)n (n = 9, 8) have been investigated by density functional theory. The lowest energy CrMn(NO)(CO)9 structures have unbridged staggered conformations with a ~2.99 Å Cr–Mn single bond similar to the experimental and lowest energy structures of the isoelectronic Mn2(CO)10 and Cr2(NO)2(CO)8. A significantly higher energy CrMn(NO)(CO)9 isomer has a nearly symmetrical bridging nitrosyl group and a very weakly semibridging carbonyl group. The two lowest energy structures of the unsaturated CrMn(NO)(CO)8 have a five-electron donor bri

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Chin, Teen Teen, Peter Legzdins, James Trotter, and Vivien C. Yee. "Organometallic nitrosyl chemistry. 51. New organometallic nitrosyl cations containing the Group 6 elements." Organometallics 11, no. 2 (1992): 913–22. http://dx.doi.org/10.1021/om00038a062.

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Kia, Reza. "Non-covalent sulfoxide⋯(nitrosyl group) interactions involving coordinated nitrosyl in a Ru(ii) nitrosyl complex with an α-diimine ligand: structural and computational studies". CrystEngComm 22, № 44 (2020): 7532–37. http://dx.doi.org/10.1039/d0ce01063d.

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Inspection of the X-ray structure of the newly prepared Ru–nitrosyl complex bearing an α-diimine ligand revealed for the first time the π-hole interaction involving the coordinated nitrosyl group with DMSO.

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Deb, Alok K., and Sreebrata Goswami. "Oxidation reactions by the coordinated nitrosyl group." Polyhedron 12, no. 11 (1993): 1419–21. http://dx.doi.org/10.1016/s0277-5387(00)84337-5.

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Ambach, Eberhard, та Wolfgang Beck. "Metallkomplexe mit biologisch wichtigen Liganden XXVI : Reaktionen von Bis(α-aminoacidato)platin(II)-Komplexen mit Nitrosylsalzen: Nitrosylplatin-Komplexe[xxx] + X- (X = BF4 , PF6 , SbF6 )/Metal Complexes with Biologically Important Ligands XXXVI : Reaction of Bis(α-aminoacidato) Platinum(II) Complexes with Nitrosyl Salts: Nitrosyl Platinum Complexes[xxx]+X-(X = BF4 , PF6 , SbF 6)". Zeitschrift für Naturforschung B 40, № 2 (1985): 288–91. http://dx.doi.org/10.1515/znb-1985-0224.

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AbstractThe reactions of the glycinato, alaninato, or cyclo-leucinato chelate platinum complexes trans -[xxx] with nitrosyl salts NO+X- (X = BF4, PF6, SbF6) in acetonitrile at -20 °C give the blue nitrosyl compounds {(0N)Pt [xxx] X·nCH3CN. Nitrosation at the amino group is not observed. The spectroscopic data of the nitrosyl complexes (IR, XPE) are reported. [xxx] + PF6- reacts with lithium halides or halogens in DMF to give the platinum (IV) complexes X2Pt(NH2CH2CO2)2 (X = CI, Br, I).

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Legzdins, Peter, and Michelle A. Young. "Nitrosyl N–O Bond Cleavage During Reactions of Organometallic Nitrosyl Complexes of the Group 6 Elements." Comments on Inorganic Chemistry 17, no. 4 (1995): 239–54. http://dx.doi.org/10.1080/02603599508033859.

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Philipp, Gunnar, Sigrid Wocadlo, Werner Massa, et al. "Die Kristallstrukturen von [MoCl2(NO)2(OPEt3)]2, [MoCl3(NO)(OPPh3)2•MoCl4(OPPh3)2], [MoCl2(NO)(PPh3)2(CH3CN)] und [MoCl4(NPPh3)(OPPh3)] / The Crystal Structures of [MoCl2(NO)2(OPEt3)]2, [MoCl3(NO)(OPPh3)2 • MoCl4(OPPh3)2], [MoCl2(NO)(PPh3)2(CH3CN)], and [MoCl4(NPPh3)(OPPh3)]." Zeitschrift für Naturforschung B 50, no. 1 (1995): 1–10. http://dx.doi.org/10.1515/znb-1995-0102.

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The title compounds have been prepared by reactions of MoCl2(NO)2 with PPh3, OPPh3, or Me3SiNPR3 (R = Et, Ph) in dichloromethane and acetonitrile suspension, respectively. All complexes were characterized by IR spectroscopy and by crystal structure determinations. [MoCl2(NO)2(OPEt3)]2: Space group C2/c, Z = 4, 2950 observed unique reflections, R = 0.029. Lattice dimensions at —70 °C: a = 2390.5(11), b = 875.5(5), c = 1399.1(6) pm, β = 113.18(2)°. The complex forms a centrosymmetric dimer with MoCl2Mo bridges, the nitrosyl groups being in a cis-arrangement. The OPEt3 ligand is coordinated in tr

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Chen, Shengchun, Xuejun Feng, Yaoming Xie, R. Bruce King, and Henry F. Schaefer. "Trinuclear and Tetranuclear Ruthenium Carbonyl Nitrosyls: Oxidation of a Carbonyl Ligand by an Adjacent Nitrosyl Ligand." Molecules 29, no. 17 (2024): 4165. http://dx.doi.org/10.3390/molecules29174165.

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Trinuclear and tetranuclear ruthenium carbonyls of the types Ru3(CO)n(NO)2, Ru3(N)(CO)n(NO), Ru3(N)2(CO)n, Ru3(N)(CO)n(NCO), Ru3(CO)n(NCO)(NO), Ru4(N)(CO)n(NO), Ru4(N)(CO)n(NCO), and Ru4(N)2(CO)n related to species observed experimentally in the chemistry of Ru3(CO)10(µ-NO)2 have been investigated using density functional theory. In all cases, the experimentally observed structures have been found to be low-energy structures. The low-energy trinuclear structures typically have a central strongly bent Ru–Ru–Ru chain with terminal CO groups and bridging nitrosyl, isocyanate, and/or nitride ligan

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Kundel, P., and H. Berke. "Chemische Effekte der Nitrosylsubstitution in hexakoordinierten Carbonylwolfram-Verbindungen/ Chemical Effects of Nitrosyl Substitution in Hexacoordinated Carbonyl Tungsten Complexes." Zeitschrift für Naturforschung B 42, no. 8 (1987): 993–99. http://dx.doi.org/10.1515/znb-1987-0811.

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AbstractThe reaction of mer-tricarbonyl-nitrosyl-bis(triisopropylphosphite)tungsten hexafluorophosphate (1a) with MeMgl or Bu4NI affords tricarbonyl-iodonitrosyl-(triisopropylphosphite)tungsten (2). Similarly, a carbonyl group of la can be replaced by a fluoride ion resulting in transdicarbonyl- fluoronitrosyl-bis(triisopropylphosphite)tungsten (3). Oxygen nucleophiles like OPh- , OCH3- or OH- either substitute or attack a carbonyl group in la and cause formation of dicarbonyl-nitrosyl-bis(triisopropylphosphite)tungsten phenoxide. methoxide or formate derivatives (4, 5 or 7). respectively. Nit

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Dissertations / Theses on the topic "Nitrosyl group"

1

Sharp, William Brett. "Synthesis and ligand reactivity of group 6 organometallic nitrosyl complexes." Thesis, National Library of Canada = Bibliothèque nationale du Canada, 2001. http://www.collectionscanada.ca/obj/s4/f2/dsk3/ftp04/NQ61173.pdf.

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Richter-Addo, George Bannerman. "Synthetic utilization of the redox properties of some group 6 organometallic nitrosyl complexes." Thesis, University of British Columbia, 1988. http://hdl.handle.net/2429/29174.

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The redox behavior of a series of organometallic complexes containing Cp'M(NO) groups (Cp' = ƞ⁵-C₅H₅(Cp) or ƞ⁵-C₅Me₅(Cp*) ; M = Mo or W) has been investigated both by cyclic voltammetry and by chemical means. The neutral 16-electron Cp'Mo(N0)X₂ compounds (X = CL, Br or I) undergo a single, essentially reversible, one-electron reduction in CH₂CL₂/O.1M [n-Bu₄N]PF₆ at relatively low potentials (<-0.1 V vs SCE). The electrochemically observed reductions can be effected on a preparative scale by employing CP₂C0 as the chemical reductant. The isolable 17-electron [Cp'Mo (NO)X₂]•⁻ radical anions are

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Scheibel, Markus. "Metal-Nitrogen Multiple Bonds with Square-Planar Group 9 Transition Metal PNP Pincer Complexes." Doctoral thesis, Niedersächsische Staats- und Universitätsbibliothek Göttingen, 2014. http://hdl.handle.net/11858/00-1735-0000-0023-9944-4.

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Zhou, Yang. "DEVELOPMENT OF PHOTOACTIVATABLE NITROXYL (HNO) DONOR MOLECULES USING PHOTOLABILE PROTECTING GROUPS." Kent State University / OhioLINK, 2017. http://rave.ohiolink.edu/etdc/view?acc_num=kent1501350106636151.

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Adas, Sonya K. "Part 1 Synthesis and Structural Investigation of Group 11 1,3-Dicyclohexyl-2,2-diethylguanidinate Complexes.Part 2 Synthesis and Kinetic Studies of N-Hydroxysulfonamide Nitrosyl Hydride Donor Molecules and their Reactions with Cob(III)alamin." Kent State University / OhioLINK, 2016. http://rave.ohiolink.edu/etdc/view?acc_num=kent1460141806.

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Afshar, Raman Khosrow. "Iron nitrosyls derived from polypyridine ligands with carboxamide groups(s) : syntheses, structures, photolability of NO, and S-nitrosylation of thiols and papain /." Diss., Digital Dissertations Database. Restricted to UC campuses, 2005. http://uclibs.org/PID/11984.

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Fischer, Arnaud. "Synthèse de nouveaux copolymères amphiphiles cationiques a blocs par voie radicalaire contrôlée et examen de leurs propriétés physico-chimiques en solution aqueuse." Vandoeuvre-les-Nancy, INPL, 2000. http://www.theses.fr/2000INPL069N.

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L'essor récent de la polymérisation radicalaire contrôlée par les radicaux nitroxyle nous a conduits a appliquer cette technique a la synthèse de copolymères amphiphiles cationiques à blocs. Une première étude a permis de démontrer que la 4-vinyl-pyridine (4vp) polymérisait de manière contrôlée en présence de 2,2,6,6-tetramethylpiperidinyl-1-oxy (tempo). La copolymérisation de n,n-dimethylacrylamide (dmaa) amorcée par un premier bloc poly(4vp) s'est révélée fructueuse, conduisant à des copolymères de faible polymolécularité. Une série de biblocs a ainsi été préparée, moyennant une dernière éta

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Brouwer, Eric B. "Heterocumulene insertions with group 6 Diaryl Nitrosyl complexes." Thesis, 1992. http://hdl.handle.net/2429/2203.

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Treatment of the 16-electron complexes Cp*M(NO)(aryl)2 (Cp* = i5-05Me5; M =Mo, W; aryl = phenyl, o-tolyl, p-tolyl) with the heterocumulenes carbon dioxide, p-tolylisocyanate, and carbon disulfide leads to the i2-carboxylate-, i2-amide-, and i2-thiocarboxylate-containing complexes, respectively, in 10-50% yields. Treatment with a fourth member of the heterocumulene class, diphenylketene, does not result in an isolable inserted complex, although spectroscopic data suggest that insertion has taken place. Cp*M(NO)(aryl)2 complexes thus insert one heterocumulene molecule into a metal-aryl bond; the

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Sharp, William Brett. "Synthesis and ligand reactivity of group 6 organometallic nitrosyl complexe." Thesis, 2001. http://hdl.handle.net/2429/13416.

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Reaction of Cp*WR₂(NO) (R = CH₂SiMe₃ , CH₂Ph) complexes with HBF₄ yields the nitrosyl-borane adduct species Cp*WR₂ (NOBF₃) via degradation of the tetrafluoroborate counterion. The similar materials, Cp*WR₂(NOB(C₆F₅)₃), can be prepared by the addition of perfluorophenylborane to the metallonitrosyl complex. The reaction of a protic acid containing a very weakly coordinating anion ([H(OEt₂)₂][B(3,5-(CF₃)C₆H₃)₄]) with the tungsten nitrosyl species yields the first complexes containing a terminal hydroxylimido ligand, [Cp*WR₂ (NOH)]⁺. These complexes have been characterised by single crystal X-ray

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Lundmark, Penelope J. "Synthesis, characterization and reactivity of Group 6 alkoxo nitrosyl complexes." Thesis, 1993. http://hdl.handle.net/2429/1832.

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Three new classes of alkoxo nitrosyl complexes of the type Cp*M(NO)(OR)X (Cp* =C5Me5; M = Mo, W; R = alkyl, aryl; X = CI, OR, alkyl), all of which have been fully characterized, are prepared by metathesis reactions. The molecular structures ofCp*W(NO)(OCMe3)2 and Cp*W(NO)(OCH2Ph)2 have been established by X-ray crystallographic analyses. While in general the above metathesis reactions are straightforward, two interesting bimetallic complexes, [Cp*W(N0)(CH2SiMe3)][Cp*W(C1)(0)]-(112-il:T12-NC(H)SiMe3) and [Cp*W(N0)(CH2SiMe3)C1][Cp*W(C1)(i2-N{0){H)CH2SiMe3)]-(1.t-N), are produced in attempts to p

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Books on the topic "Nitrosyl group"

1

Patai, Saul, ed. The Chemistry of Amino, Nitroso, Nitro and Related Groups. John Wiley & Sons, Ltd, 1996. http://dx.doi.org/10.1002/047085720x.

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Saul, Patai, ed. The chemistry of amino, nitroso, nitro, and related groups. Wiley, 1996.

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Great Britain. Working Party on Nitrate and Related Compounds in Food. and Great Britain. Ministry of Agriculture, Fisheries and Food., eds. Nitrate, nitrite and N-nitroso compounds in food: The twentieth report of the Steering Group on Food Surveillance, the Working Party on Nitrate and Related Compounds in Food. H.M.S.O., 1987.

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Steering Group on Chemical Aspects of Food Surveillance. Working Party on Nitrate and Related Compounds in Food. Nitrate, nitrite and n-nitroso compounds in food: Second report : the thirty-second report of the Steering Group on Chemical Aspects of Food Surveillance. H.M.S.O., 1992.

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Food, Steering Group on Food Surveillance Working Party on Nitrate and Related Compounds in. Nitrate, nitrite and n-nitroso compounds in food: The twentieth report of the Steering Group on Food Surveillance, the Working Party on Nitrate and Related Compounds in Food. H.M.S.O., 1987.

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Feuer, Henry. Chemistry of the Nitro and Nitroso Group. Wiley & Sons, Limited, John, 2010.

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Patai, Saul. Chemistry of Amino, Nitroso, Nitro and Related Groups: Supplement F2. Wiley & Sons, Incorporated, John, 1996.

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Patai, Saul. Chemistry of Amino, Nitroso, Nitro and Related Groups, Supplement F2. Wiley & Sons, Incorporated, John, 2000.

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Patai, Saul. Chemistry of Amino, Nitroso, Nitro and Related Groups, Supplement F2. Wiley & Sons, Limited, John, 2009.

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Rappoport, Zvi, and Saul E. Patai. Chemistry of Amino, Nitroso, Nitro and Related Groups, Supplement F2. Wiley & Sons Australia, Limited, John, 2003.

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Book chapters on the topic "Nitrosyl group"

1

Yokoshima, Satoshi. "Construction of Quinoline N-Oxides and Synthesis of Aurachins A and B: Discovery, Application, and Mechanistic Insight." In Modern Natural Product Synthesis. Springer Nature Singapore, 2024. http://dx.doi.org/10.1007/978-981-97-1619-7_17.

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AbstractA method to synthesize 3-hydroxyquinoline N-oxides from ketones having a 2-nitrophenyl group at the α-position relative to the carbonyl group was developed. The substrates were easily prepared via a SNAr reaction or a Sonogashira coupling, and treatment with sodium tert-butoxide in dimethyl sulfoxide produced the corresponding quinoline N-oxides. The method was successfully applied to the total synthesis of aurachins A and B. On the basis of the quinoline N-oxide synthesis, related reactions of α-(2-nitrophenyl)ketones, including nitrone formation and photoinduced rearrangement, were also investigated. These investigations provided clues about the reaction mechanism, and the following mechanism for the quinoline N-oxide synthesis is proposed: Deprotonation of the α-position of α-(2-nitrophenyl)ketone with tert-butoxide generates an enolate, which reacts with a nitro group via single-electron transfer to form an α-hydroxyketone having a nitroso group. An intramolecular alkoxide-mediated hydride shift reduces the nitroso group, and condensation of the resultant hydroxylamine and diketone moieties produces a 3-hydroxyquinoline N-oxide.

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2

Eisenbrand, G., and C. Janzowski. "Potential Mechanism of Action of Nitrosamines with Hydroxy, Oxo, or Carboxy Groups." In Nitrosamines and RelatedN-Nitroso Compounds. American Chemical Society, 1994. http://dx.doi.org/10.1021/bk-1994-0553.ch015.

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Bailey, Patrick D., and Keith M. Morgan. "Nitro compounds." In Organonitrogen Chemistry. Oxford University Press, 2022. http://dx.doi.org/10.1093/hesc/9780198557753.003.0017.

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This chapter focuses on nitroso compounds. It refers to nitroso compounds as tautomeric with oximes that are thermodynamically more stable. The chapter shares diagrams to reference the bonding. C-nitroso compounds are readily turned to the corresponding oxime if there is a hydrogen-? linked to the nitroso group. Additionally, the chapter discusses the synthesis of aliphatic C-nitroso compounds, aromatic C-nitroso compounds, α-diketones via nitrosis compounds, N-nitroso compounds, and O-nitroso compounds. It mentions how aliphatic C-nitroso compounds tautomerizse to the oxime if an α-hydrogen is present. The α-chloro and acyl Cnitroso compounds are useful in terms of achieving the Diels-Alder reaction.

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Sandler, Stanley R., and Wolf Karo. "C-NITROSO COMPOUNDS." In Organic Functional Group Preparations. Elsevier, 1986. http://dx.doi.org/10.1016/b978-0-08-092557-8.50020-3.

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Sandler, Stanley R., and Wolf Karo. "N-NITROSO COMPOUNDS." In Organic Functional Group Preparations. Elsevier, 1986. http://dx.doi.org/10.1016/b978-0-08-092557-8.50021-5.

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Volodarsky, Leonid B., Vladimir A. Reznikov, and Victor I. Ovcharenko. "Complexes with Metal-Nitroxyl Group Coordination." In Synthetic Chemistry of Stable Nitroxides. CRC Press, 2017. http://dx.doi.org/10.1201/9780203710159-4.

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Sasano, Y., and Y. Iwabuchi. "1.8 Copper-Catalyzed Aerobic Oxidation of Alcohols." In Base-Metal Catalysis 1. Georg Thieme Verlag KG, 2023. http://dx.doi.org/10.1055/sos-sd-238-00150.

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AbstractThe oxidation of alcohols to carbonyl compounds is one of the most important reactions in organic synthesis. Owing to current environmental concerns, catalytic alcohol oxidation using molecular oxygen as the terminal oxidant has been actively investigated. Copper is frequently used as an aerobic oxidation catalyst in organic syntheses, as well as in biological systems. Co-catalysts acting in coordination with copper to promote the aerobic oxidation of alcohols have been extensively investigated, and in this context the use of nitroxyl radicals has been identified as a promising strategy. Through the efforts of many researchers, nitroxyl radical/copper catalyst systems that efficiently oxidize traditionally more challenging aliphatic alcohols under mild conditions have recently been discovered. Methods for the synthesis of esters, imines, nitriles, amides, and imides by nitroxyl radical/copper-catalyzed aerobic alcohol oxidation in the presence of other alcohols, amines, and amides have also been developed. Nitroxyl radical/copper-catalyzed aerobic alcohol oxidation exhibits outstanding chemoselectivity, and efficiently converts alcohols bearing oxidation-prone functional groups that cannot be efficiently oxidized using conventional methods.

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Jahn, U. "Nitroso Group Exchange by Nitration." In Nitro, Nitroso, Azo, Azoxy, and Diazonium Compounds, Azides, Triazenes, and Tetrazenes. Georg Thieme Verlag KG, 2010. http://dx.doi.org/10.1055/sos-sd-041-00431.

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Eagle, P. A. C. "Tetra(nitroaryl)plumbanes from Di(nitroaryl)plumbyl Halides and Hydrazine." In Compounds of Group 14 (Ge, Sn, Pb). Georg Thieme Verlag KG, 2003. http://dx.doi.org/10.1055/sos-sd-005-00790.

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Grimmett, M. R. "Reactions of Nitroso Groups." In Five-Membered Hetarenes with Two Nitrogen or Phosphorus Atoms. Georg Thieme Verlag KG, 2002. http://dx.doi.org/10.1055/sos-sd-012-00635.

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Conference papers on the topic "Nitrosyl group"

1

Gerunov, Taras, Marina Gonokhova, Tatyana Boyko, and Vladimir Gerunov. "Pathomorphological Changes in the Organs and Tissues of Animals During Acute Intoxication with Neonicotinoids Containing Nitroso or Cyano Group." In Proceedings of the International Scientific Conference The Fifth Technological Order: Prospects for the Development and Modernization of the Russian Agro-Industrial Sector (TFTS 2019). Atlantis Press, 2020. http://dx.doi.org/10.2991/assehr.k.200113.174.

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Reports on the topic "Nitrosyl group"

1

Boyer, J. H. Nitrolysis of the CN Single Bond and Related Chemistry of Nitro and Nitroso Groups. Defense Technical Information Center, 1985. http://dx.doi.org/10.21236/ada151753.

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