Log in

Relevant bibliographies by topics / Non-innocent / Dissertations / Theses

To see the other types of publications on this topic, follow the link: Non-innocent.

Dissertations / Theses on the topic 'Non-innocent'

Author: Grafiati

Published: 4 June 2021

Last updated: 4 February 2022

Create a spot-on reference in APA, MLA, Chicago, Harvard, and other styles

Select a source type:

Consult the top 33 dissertations / theses for your research on the topic 'Non-innocent.'

Next to every source in the list of references, there is an 'Add to bibliography' button. Press on it, and we will generate automatically the bibliographic reference to the chosen work in the citation style you need: APA, MLA, Harvard, Chicago, Vancouver, etc.

You can also download the full text of the academic publication as pdf and read online its abstract whenever available in the metadata.

Browse dissertations / theses on a wide variety of disciplines and organise your bibliography correctly.

1

Jacq, Clément. "Categorical combinatorics for non-déterministic innocent strategies." Thesis, Université de Paris (2019-....), 2019. http://www.theses.fr/2019UNIP7122.

Full text

Abstract:

Il y a vingt-cinq ans, Hyland et Ong ont résolu le problème de l’abstaction pour le langage PCF en construisant une sémantique des jeux basées sur la notion fondamentale de stratégie innocente. Dans cette thèse, nous continuons leurs travaux et construisons une bicatégorie de stratégies innocentes et non-déterministes étendant leur modèle original de jeux déterministiques et innocents.Notre point de départ est fourni par l’approche combinatoire des stratégies innocentes développée par Harmer, Hyland et Melliès dans un article publié il y a douze ans. Dans ces travaux, ils élaborent une descrip

APA, Harvard, Vancouver, ISO, and other styles

2

Aguirre, Fondevila Adiran de. "Non-innocent ligands: from proton shuttle to photo-activation." Doctoral thesis, Universitat Rovira i Virgili, 2019. http://hdl.handle.net/10803/668399.

Full text

Abstract:

En la majoria dels exemples clàssics de catàlisis homogènia, el focus cau en el centre metàl·lic, el qual és el que duu a terme la reacció, mentre que els lligands juguen un rol principalment d'espectadors. Així, l'aproximació inicial per modificar la reactivitat dels sistemas era reemplaçar el metall. Aquest ha sigut el punt inicial en la majoria dels treballs en catálisis homogènia amb complexos organometàl·lics. La modificació de les propietats estèriques o electròniques dels lligands afecta el metall, i pot tindre un gran impacte en el resultat de la reacció: rendiment més alt, millor sele

APA, Harvard, Vancouver, ISO, and other styles

3

Reinhardt, Maxwell James. "Metal complexes containing non-innocent ligands for functional materials." Thesis, University of Edinburgh, 2013. http://hdl.handle.net/1842/11723.

Full text

Abstract:

The existence of complexes of that display non-innocence has been of interest in the field of coordination chemistry since the investigations of square-planar dithiolene complexes of the late transition metals in the 1960s. The ligands used in these systems are termed “non-innocent” when bound to a number of the late transition metals, because the orbital energy levels are similar to those of the central metal ion. This allows there to be significant electron delocalisation over the complex with the potential for the complexes to exist in a number of electronic states due to the combined elect

APA, Harvard, Vancouver, ISO, and other styles

4

Schorpp, Marcel [Verfasser], and Ingo [Akademischer Betreuer] Krossing. "Synthesis and application of novel innocent and non-innocent oxidant WCA salts for the synthesis of reactive main-group cations." Freiburg : Universität, 2020. http://d-nb.info/1237220653/34.

Full text

APA, Harvard, Vancouver, ISO, and other styles

5

Jin, Guanghua. "Coordination chemistry and catalysis at iron : from non-innocent ligands to CO2 transformation." Thesis, Toulouse 3, 2015. http://www.theses.fr/2015TOU30155/document.

Full text

Abstract:

L'utilisation du fer en chimie de coordination et en catalyse suscite un intérêt croissant de par son abondance et sa faible toxicité. Dans le premier chapitre, une étude bibliographique présente deux domaines d'applications du fer : i) l'utilisation de complexes de fer comportant des ligands " non innocent " pour différentes applications en catalyse, et ii) l'utilisation de complexes de fer pour des transformations stœchiométriques et catalytiques du CO2. Dans le chapitre 2, la synthèse et la caractérisation de complexes de fer portant un ligand coopératif non-innocent sont présentées. Le com

APA, Harvard, Vancouver, ISO, and other styles

6

Blusch, Lina K. [Verfasser]. "The Siamese-Twin Porphyrin and Its Copper and Nickel Complexes: A Non-Innocent Twist." Cham : Springer International Publishing, 2013. http://d-nb.info/1042998450/34.

Full text

APA, Harvard, Vancouver, ISO, and other styles

7

Wong, Yuna Huh. "Ignoring the innocent non-combatants in urban operations and in military models and simulations /." Santa Monica, CA : RAND, 2006. http://www.rand.org/pubs/rgsd_issertations/RGSD201/.

Full text

APA, Harvard, Vancouver, ISO, and other styles

8

MUSTIELES, MARÍN Irene. "Oxidation of phosphasalen complexes." Thesis, Université Paris-Saclay (ComUE), 2017. http://www.theses.fr/2017SACLX078/document.

Full text

Abstract:

Les ligands phosphasalen développés au sein du laboratoire peuvent être considérés comme les analogues phosphorés des ligands salen dont ils diffèrent par la présence de groupements iminophosphorane à la place des imines. L’introduction de ces fonctions a d’importantes conséquences sur les propriétés de ces ligands, qui sont plus électrodonneurs et plus flexibles que les dérivés salen correspondants, capables de stabiliser des métaux à haut degré d’oxydation. Ces ligands ont également un caractère redox non-innocent, une propriété très étudiée de nos jours tant en chimie de coordination qu’en

APA, Harvard, Vancouver, ISO, and other styles

9

Rungtanapirom, Wasupol. "Diverse reactivity of chelating and xanthine-derived copper-N-heterocyclic carbenes : catalytic activity, electrochemical reactivity and non-innocent behaviour." Thesis, University of Leeds, 2018. http://etheses.whiterose.ac.uk/21273/.

Full text

Abstract:

This thesis involves the preparation and exploration of the reactivity of a variety of organocopper complexes with N-heterocyclic carbene (NHC) ligands. The ligands contain either pyridyl/picolyl/allyl N-substituents or a xanthine-derived backbone. Structural modifications were made to the NHC ligands which were investigated for their catalytic activity when coordinated with Cu(I) in situ in an Ullmann-type etherification reaction. The ligand found to be the most active in catalysis was 1 allyl-3-picolylbenzimidazol-2-ylidene. The catalytic reaction was studied in more detail to assess deactiv

APA, Harvard, Vancouver, ISO, and other styles

10

Mondal, Sudipta [Verfasser], and Wolfgang [Akademischer Betreuer] Kaim. "Transition metal complexes with 1,2-dicarbonylhydrazine : a study on mixed-valency and non-innocent ligand behaviour / Sudipta Mondal ; Betreuer: Wolfgang Kaim." Stuttgart : Universitätsbibliothek der Universität Stuttgart, 2018. http://d-nb.info/1169653715/34.

Full text

APA, Harvard, Vancouver, ISO, and other styles

11

Salanouve, Elise. "Complexes de métaux non-nobles de fer et de nickel portant des ligands redox non-innocents et leurs applications en catalyse : de l'activation C-H aux réactions de couplages croisés." Thesis, Paris 6, 2014. http://www.theses.fr/2014PA066620/document.

Full text

Abstract:

Ce travail de thèse s’est intéressé au développement de complexes de métaux non-nobles portant des ligands non-innocents et leurs applications en catalyse comme alternatives efficaces aux complexes de métaux nobles dans un contexte de fortes préoccupations économiques et environnementales. Ainsi, nous avons synthétisé et caractérisé des complexes de fer et de nickel portant des ligands non-innocents, à l’aide de différentes techniques spectroscopiques. Ces ligands pourraient moduler la réactivité du métal et étendre ainsi le champ d’applications de ces métaux de transition. Dans le but de déve

APA, Harvard, Vancouver, ISO, and other styles

12

Irwin, Mark Robert Floyd. "The synthesis and characterisation of metal complexes containing chemically reduced bipyridyl ligand systems." Thesis, University of Oxford, 2013. http://ora.ox.ac.uk/objects/uuid:44dd8d43-01cf-4a2a-ab66-c7cab1d9201f.

Full text

Abstract:

This thesis describes the synthesis and characterisation of metal complexes that contain chemically reduced bipyridyl ligands. The crystal structures of twenty-six novel complexes are reported alongside detailed discussions on the electronic and spectroscopic effects and trends associated with the different oxidation states within these species. Chapter One introduces the isomers of bipyridine and their redox chemistry, the concept of non-innocent ligands and the spectroscopic techniques that are currently used in determining ligand oxidation states. Subsequently, examples of main group, trans

APA, Harvard, Vancouver, ISO, and other styles

13

Das, Hari Sankar [Verfasser], and Biprajit [Akademischer Betreuer] Sarkar. "Ruthenium complexes with non-innocent quinonoid, quinoline-5,8-dione and iminoquinone ligands : synthesis, structure, redox properties and electron distribution / Hari Sankar Das. Betreuer: Biprajit Sarkar." Stuttgart : Universitätsbibliothek der Universität Stuttgart, 2012. http://d-nb.info/102604331X/34.

Full text

APA, Harvard, Vancouver, ISO, and other styles

14

Mele, Andrea. "Preparation and study of diiron complexes, featuring redox ligands, inspired by the active site of [FeFe]-Hydrogenases." Thesis, Brest, 2019. http://www.theses.fr/2019BRES0100.

Full text

Abstract:

L’hydrogénase [FeFe] est une enzyme capable de catalyser efficacement la réduction des protons en hydrogène moléculaire. La structure du site actif, appelé le cluster-H a été élucidée à la fin des années 90. Depuis, plusieurs systèmes modèles ont été synthétisés en essayant de reproduire ses caractéristiques uniques. Le cluster {4Fe4S}, présent dans le site actif joue un rôle crucial en tant que cofacteur redox, lié de manière covalente à un système difer qui est le site de la conversion H+/H2. Il se comporte comme un réservoir d'électrons capable d'accepter et de partager des électrons avec l

APA, Harvard, Vancouver, ISO, and other styles

15

Fabre, Muriel. "Complexes dinucléaires Ruthénium-cyanamides : composés modèles pour l'étude de la communication électronique à longue distance." Phd thesis, Université Paul Sabatier - Toulouse III, 2006. http://tel.archives-ouvertes.fr/tel-00171709.

Full text

Abstract:

La communication électronique dans des complexes dinucléaires du ruthénium peut être caractérisée soit par le couplage électronique Vab dans le système à valence mixte (RuII-RuIII), soit par le couplage magnétique J dans le système homovalent paramagnétique (RuIII-RuIII). L'objectif de ce travail était d'obtenir une famille de composés en faisant varier la longueur du ligand pontant et de mesurer les interactions électronique et magnétique afin d'établir une corrélation entre J et Vab.<br />Une première famille de complexes dinucléaires du ruthénium [{RuII(tpy)(acac)}2(µ-L)] (où tpy = 2,2'-6',

APA, Harvard, Vancouver, ISO, and other styles

16

Francisco, Thiago dos Santos. "Complexos FosfÃnicos de RutÃnio: SÃntese, CaracterizaÃÃo, ImobilizaÃÃo e Atividade CatalÃtica." Universidade Federal do CearÃ, 2015. http://www.teses.ufc.br/tde_busca/arquivo.php?codArquivo=16311.

Full text

Abstract:

CoordenaÃÃo de AperfeÃoamento de Pessoal de NÃvel Superior<br>Os resultados apresentados neste trabalho envolvem a sÃntese de compostos de coordenaÃÃo contendo fosfinas e ligantes redox ativos (ligantes nÃo-inocentes) na esfera de coordenaÃÃo do rutÃnio. Este trabalho estÃ inserido em uma linha de pesquisa do Grupo de BioinorgÃnica que visa, como objetivo final, a aplicaÃÃo dos compostos isolados na catÃlise de reaÃÃes de hidrogenaÃÃo. Durante o desenvolvimento das atividades de doutorado, perÃodo de marÃo de 2010 a janeiro de 2015, foram sintetizados seis (06) compostos inÃditos na literatura

APA, Harvard, Vancouver, ISO, and other styles

17

Brunel, Paul. "Complexes pince et cooperativité métal/ligand : application en catalyse." Thesis, Toulouse 3, 2018. http://www.theses.fr/2018TOU30275/document.

Full text

Abstract:

Ce travail de thèse porte sur la chimie organométallique des complexes pince indényle/indénediide de palladium et de platine et leurs applications en catalyse coopérative métal-ligand. Le premier chapitre de ce manuscrit fait un point bibliographique non-exhaustif du domaine de la coopérativité métal-ligand, des travaux de Noyori sur l'hydrogénation asymétrique, jusqu'aux récents travaux de Milstein avec les ligands désaromatisés. Les ligands pince sont également présentés. Du premier exemple PCP décrit par Shaw jusqu'au CNC développé par Bezuidenhout. La versatilité de ces ligands est illustr

APA, Harvard, Vancouver, ISO, and other styles

18

Katari, Madanakrishna. "Formation and Characterization of Reduced Metal Complexes in the Gas Phase." Thesis, Université Paris-Saclay (ComUE), 2016. http://www.theses.fr/2016SACLX091/document.

Full text

Abstract:

La caractérisation complète d’intermédiaires réactionnels intervenants dans des procédés de catalyse homogène est une tâche ardue en raison de leur réactivité et de leur faible concentration. Ceci est particulièrement vrai pour les espèces radicalaires telles que les complexes organométalliques réduits, qui sont des intermédiaires en photocatalyse ou lorsque ces complexes possèdent des ligands non-innocents. Par conséquent, leur structure électronique est encore mal comprise, sachant que l'électron ajouté peut être situé sur différents sites de la molécule.Dans ce contexte, nous avons développ

APA, Harvard, Vancouver, ISO, and other styles

19

Tsou, Yu-Chi, and 鄒語騏. "Theoretical CO2 Reduction Mechanism by Ru-Polypyridyl Complexes: An Innocent and Non-Innocent Comparison." Thesis, 2016. http://ndltd.ncl.edu.tw/handle/16940705372412671158.

Full text

Abstract:

碩士<br>國立臺灣師範大學<br>化學系<br>104<br>Koji Tanaka is one of the few scientists who use organometallic complexes as a catalyst for multi-electron reduction reactions. In 1993, Tanaka reported that RuII(bpy)(trpy)(CO) (bpy = 2,2 '-bipyridine, trpy = 2,2': 6',2"-terpyridine) acts as a catalyst, at −1.7V (vs. NHE), for the reduction of CO2 to generate products of economic value like CO, HCOOH, CH3OH, HC(O)H, and products involving C–C bond formation like H(O)CCOOH and HOCH2COOH. In 1994, Tanaka speculated a complete catalytic cycle; however, the detailed information was not available on each intermediat

APA, Harvard, Vancouver, ISO, and other styles

20

Yang, Yu-Wei, and 楊于薇. "Theoretical Studies of the difference between Ruthenium complex with Non-Innocent and Innocent Ligands for Water Oxidation Reaction." Thesis, 2011. http://ndltd.ncl.edu.tw/handle/50887824410066474604.

Full text

Abstract:

碩士<br>國立臺灣師範大學<br>化學系<br>100<br>The non-innocent ligand (NIL) has been reported to play an important role on molecular water-oxidation catalysis. The first NIL catalyst was introduced by Tanaka and coworkers where the electrochemical property of quinone in [Ru2(OH)2(3,6-tBu2Q)2(btpyan)]2+ (tBu2Q, 3,6-di-tert-butyl-1,2-benzoquinone; btpyan, 1,8-bis(2,2′:6′,2′′-terpyridyl)anthracene) is believed to be responsible for its novel catalytic ability. The current study focuses on a systematic comparison between two Ruthenium complexes with Non-innocent ligand(NIL) and innocent ligand from the perspect

APA, Harvard, Vancouver, ISO, and other styles

21

SHU-YI, CHU, and 朱書儀. "Theoretical Pourbiax Diagrams of Ru-Polypyridyl Complexes: A Innocent and Non-innocent Ligand Comparison for Water Oxidation Catalysis." Thesis, 2014. http://ndltd.ncl.edu.tw/handle/28930637507261564334.

Full text

Abstract:

碩士<br>國立臺灣師範大學<br>化學系<br>102<br>Water oxidation is a key half-reaction (2H2O → O2 + 4H+ + 4e−) employed in solar-fuel-based energy conversion, and it is dominated by proton-coupled electron transfer (PCET), given its multi-electron, multi-proton character. Mononuclear Ru-based water oxidation catalysts (WOCs) are a valuable class of WOCs used for water splitting. Noninnocent ligands (NILs) have three oxidation states, NILOx, NIL•, and NILRed, that have an electron redox transformation in common. NILs can help disperse the electron density at the metal center and keep the metal center in low ox

APA, Harvard, Vancouver, ISO, and other styles

22

"Synthesis and Reactivity of Group 9 Complexes Featuring Redox Non-Innocent Ligands." Master's thesis, 2016. http://hdl.handle.net/2286/R.I.38406.

Full text

Abstract:

abstract: The addition of aminoalkyl-substituted 2,6-bis(imino)pyridine (or pyridine diimine, PDI) ligands to [(COD)RhCl]2 (COD = 1,5-cyclooctadiene) resulted in the formation of rhodium monochloride complexes with the general formula (NPDI)RhCl (NPDI = iPr2NEtPDI or Me2NPrPDI). The investigation of (iPr2NEtPDI)RhCl and (Me2NPrPDI)RhCl by single crystal X-ray diffraction verified the absence of amine arm coordination and a pseudo square planar geometry about rhodium. Replacement of the chloride ligand with an outer-sphere anion was achieved by adding AgBF4 directly to (iPr2NEtPDI)RhCl to form

APA, Harvard, Vancouver, ISO, and other styles

23

Low, Choon Heng (Marcus). "Hemilabile, Non-Innocent (Poly)arylene Donors for Accessing Novel Reactivity at Transition Metal Centers." Thesis, 2019. https://thesis.library.caltech.edu/11527/20/Thesis_catenated.pdf.

Full text

Abstract:

<p>Understanding the effects that ligands have on the coordination environment and reactivity of metal complexes is an endeavor that drives much of the field of inorganic chemistry. The use of ligands capable of flexible binding modes and redox states further enriches the chemistry of these complexes. This dissertation describes studies on metal complexes bearing pendant (poly)arylene donors that demonstrate hemilability and redox non-innocence. Within this context, conditions that result in coordination mode change and the multi-electron bond transformation that is made possible by the hemila

APA, Harvard, Vancouver, ISO, and other styles

24

"Biomimetic Models of [FeFe]-hydrogenase: Utilization of peptides and redox non-innocent ligands in synthetic catalysts." Doctoral diss., 2013. http://hdl.handle.net/2286/R.I.18826.

Full text

Abstract:

abstract: [FeFe]-hydrogenases are enzymes for the reduction of protons to hydrogen. They rely on only the earth abundant first-row transition metal iron at their active site (H cluster). In recent years, a multitude of diiron mimics of hydrogenases have been synthesized, but none of them catalyzes hydrogen production with the same exquisite combination of high turnover frequency and low activation energy as the enzymes. Generally, model complexes fail to include one or both of two features essential to the natural enzyme: an intricate array of outer coordination sphere contacts that constrain

APA, Harvard, Vancouver, ISO, and other styles

25

Zhang, Cai-Xing, та 張財興. "Exploring the non-innocent Character of Electron Rich π-extended 8-oxyquinolate Ligands in Ruthenium(II) Bipyridyl Complexes". Thesis, 2014. http://ndltd.ncl.edu.tw/handle/333a4r.

Full text

Abstract:

碩士<br>國立臺灣師範大學<br>化學系<br>104<br>The enhancement of the photoelectric conversion efficiency of dye-sensitized solar cells(DSSC) has been a consistently significant topic to scientist. In this work, we analyze the electron transfer of [Ru(dcbpy)2(8-OQN)]+ (dcbpy=4,4'-dicarboxy-2,2' bipyridyl, and 8-OQN=8-oxyquinolate) with I- , Simulating the reaction mechanism of dye and redox couple (I- /I3- ). Also, we change the complex to [Ru(dcbpy)2(5,7-di-X-8-OQN)]+ (X=H, F, Cl, Br, I, Me) to study the difference of the barrier of electron transfer with different electron push-pull functionalities.

APA, Harvard, Vancouver, ISO, and other styles

26

Horak, Kyle Tadashi. "The Design and Synthesis of Transition Metal Complexes Supported by Non-innocent Ligand Scaffolds for Small Molecule Activation." Thesis, 2016. https://thesis.library.caltech.edu/9560/108/Intro.pdf.

Full text

Abstract:

<p>This dissertation focuses on the incorporation of non-innocent or multifunctional moieties into different ligand scaffolds to support one or multiple metal centers in close proximity. Chapter 2 focuses on the initial efforts to synthesize hetero- or homometallic tri- or dinuclear metal carbonyl complexes supported by para-terphenyl diphosphine ligands. A series of [M<sub>2</sub>M’(CO)<sub>4</sub>]-type clusters (M = Ni, Pd; M’ = Fe, Co) could be accessed and used to relate the metal composition to the properties of the complexes. During these studies it was also found that non-innocent beha

APA, Harvard, Vancouver, ISO, and other styles

27

Presow, Shaun Richard [Verfasser]. "An experimental study of five-coordinate iron complexes containing non-innocent aminobenzenethiol based ligands / presented by Shaun Richard Presow." 2008. http://d-nb.info/99080318X/34.

Full text

APA, Harvard, Vancouver, ISO, and other styles

28

Khusniyarov, Marat M. [Verfasser]. "Metal complexes with non-innocent N-donor ligands : molecular and electronic structures, reactivity, and application / vorgelegt von Marat M. Khusniyarov." 2006. http://d-nb.info/98145528X/34.

Full text

APA, Harvard, Vancouver, ISO, and other styles

29

"Evaluation of κ4-Diimine Nickel and Cobalt Hydrofunctionalization Catalysts". Doctoral diss., 2018. http://hdl.handle.net/2286/R.I.51706.

Full text

Abstract:

abstract: The search for highly active, inexpensive, and earth abundant replacements for existing transition metal catalysts is ongoing. Our group has utilized several redox non-innocent ligands that feature flexible arms with donor substituents. These ligands allow for coordinative flexibility about the metal centre, while the redox non-innocent core helps to overcome the one electron chemistry that is prevalent in first row transition metals. This dissertation focuses on the use of Ph2PPrDI, which can adopt a κ4-configuration when bound to a metal. One reaction that is industrially useful is

APA, Harvard, Vancouver, ISO, and other styles

30

"Development of Homogeneous Manganese and Iron Catalysts for Organic Transformations and Renewable Fuel Production." Doctoral diss., 2016. http://hdl.handle.net/2286/R.I.39403.

Full text

Abstract:

abstract: The late first row transition metals, being inexpensive and environmentally benign, have become very attractive for sustainable catalyst development. However, to overcome the detrimental one electron redox processes exhibited by these metals, the employment of redox non-innocent chelates turned out to be very useful. The Trovitch group has designed a series of pentadentate bis(imino)pyridine ligands (pyridine diimine, PDI) that are capable of binding the metal center beyond their 3-N,N,N core and also possess coordination flexibility. My research is focused on developing PDI-support

APA, Harvard, Vancouver, ISO, and other styles

31

Das, Atanu Kumar [Verfasser]. "Structural, electron transfer and spectroscopic studies of transition metal complexes with redox-active non-innocent ligands / vorgelegt von Atanu Kumar Das." 2009. http://d-nb.info/995067260/34.

Full text

APA, Harvard, Vancouver, ISO, and other styles

32

Moscattini, Joshua. "Exploiting the Non-innocent Ligand Reactivity of Metal Bis-dithiolenes: Towards the Catalytic Synthesis of Chiral Thioether Ligands and other Synthetic Targets." Thesis, 2012. http://hdl.handle.net/1807/33457.

Full text

Abstract:

Asymmetric catalysis is one of the most effective ways to control a target molecule’s stereochemistry. Through the development of a wide variety of chiral transition metal complexes, synthetic chemists are given the tools they need to synthesize the desired enantiomer of numerous compounds. This work focuses on exploiting the non-innocent ligand reactivity of metal bis-dithiolenes with multiple conjugated π systems in order to synthesize chiral ligands. Recent work has shown that platinum bis-dithiolene reacts with dienes stereoselectively to form a racemic mix of C2 -chiral thioether ligands.

APA, Harvard, Vancouver, ISO, and other styles

33

Chun-KangLo and 羅淳剛. "Studies of high-valent vanadium complexes binding with non-innocent thiolato ligands / the cleavage of strong C-O and O-H bonds with assistance of hydrogen bonds." Thesis, 2014. http://ndltd.ncl.edu.tw/handle/02628105393853398997.

Full text

Abstract:

碩士<br>國立成功大學<br>化學系<br>103<br>In our effort to understanding high-valent vanadium sulfur chemistry, two tris(thiolato)phosphine ligands, [PS3”]H3 and [PS3*]H3 has been untilized to interact with high-valent vanadium species.([PS3”]H3=[P(C6H3-3-Me3Si-2-S)3]3-. [PS3*]H3=[P(C6H3-3-Ph-2-S)3]3-). At this work, several five vanadium-thiolate complexes have been obtained and characterized. They are [V(PS3”)2][NEt4] (1a), [V(PS3*)2][NPr4] (1b),[VIV(PS2”SH)(PS3”)][PPh4] (2a), [VIV(PS3*)(PS2*SH)][NPent4] (2b), and [VIV(PS3*)2] [(NPr4)2] (3). The reactivity of them with air has been explored. The eviden

APA, Harvard, Vancouver, ISO, and other styles

We offer discounts on all premium plans for authors whose works are included in thematic literature selections. Contact us to get a unique promo code!