Relevant bibliographies by topics / Nucleophilie

Contents

  1. Journal articles
  2. Dissertations / Theses
  3. Books
  4. Book chapters
  5. Conference papers
  6. Reports

Academic literature on the topic 'Nucleophilie'

Author: Grafiati
Published: 4 June 2021
Last updated: 7 February 2022

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Journal articles on the topic "Nucleophilie"

1

Tumanov, Vasily V, Alexander A Tishkov, and Herbert Mayr. "Nucleophilie-Parameter von Alkyl- und Arylisocyaniden." Angewandte Chemie 119, no. 19 (2007): 3633–36. http://dx.doi.org/10.1002/ange.200605205.

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Tsuji, Yutaka, and John P. Richard. "Swain–Scott relationships for nucleophile addition to ring-substituted phenonium ions." Canadian Journal of Chemistry 93, no. 4 (2015): 428–34. http://dx.doi.org/10.1139/cjc-2014-0337.

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The products of the reactions of 2-(4-methoxyphenyl)ethyl tosylate (MeO-1-OTs) and 2-(4-methyphenyl)ethyl tosylate (Me-1-OTs) with nucleophilic anions were determined for reactions in 50:50 (v/v) trifluoroethanol (TFE) / water at 25 °C. In many cases, the nucleophile selectivity kNu/ks ((mol/L)−1) for reactions of nucleophile and solvent, calculated from the ratio of product yields, depends upon [Nu−]. This demonstrates the existence of competing reaction pathways, which show different selectivities for reactions with nucleophiles. A 13C NMR analysis of the products of the reactions of substra
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Barham, Joshua P., Matthew P. John, and John A. Murphy. "One-pot functionalisation of N-substituted tetrahydroisoquinolines by photooxidation and tunable organometallic trapping of iminium intermediates." Beilstein Journal of Organic Chemistry 10 (December 12, 2014): 2981–88. http://dx.doi.org/10.3762/bjoc.10.316.

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Nucleophilic trapping of iminium salts generated via oxidative functionalisation of tertiary amines is well established with stabilised carbon nucleophiles. The few reports of organometallic additions have limited scope of substrate and organometallic nucleophile. We report a novel, one-pot methodology that functionalises N-substituted tetrahydroisoquinolines by visible light-assisted photooxidation, followed by trapping of the resultant iminium ions with organometallic nucleophiles. This affords 1,2-disubstituted tetrahydroisoquinolines in moderate to excellent yields.
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Yuasa, Hideya, Yujiro Kamata, and Hironobu Hashimoto. "Relative Nucleophilie der beiden Schwefelatome in 1,5-Dithioglucopyranosiden." Angewandte Chemie 109, no. 8 (1997): 907–9. http://dx.doi.org/10.1002/ange.19971090825.

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Yamashita, Makoto. "Nucleophilie des Borzentrums in Base-stabilisierten Borol-Anionen." Angewandte Chemie 122, no. 14 (2010): 2524–26. http://dx.doi.org/10.1002/ange.201000386.

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Phan, Thanh Binh, Martin Breugst, and Herbert Mayr. "Auf dem Weg zu einer allgemeinen Nucleophilie-Skala?" Angewandte Chemie 118, no. 23 (2006): 3954–59. http://dx.doi.org/10.1002/ange.200600542.

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Friedrich, Jens. "Einfluß von Nucleophilie und Basizität bei Additions- und Substitutionsreaktionen." CHEMKON 4, no. 4 (1997): 187–93. http://dx.doi.org/10.1002/ckon.19970040406.

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Selimović, Enisa, and Tanja Soldatović. "Study on the reactions between dichlorido[2,2′:6′,2″-terpyridine] zinc(II) and biologically relevant nucleophiles in aqueous solution." Progress in Reaction Kinetics and Mechanism 44, no. 2 (2019): 105–13. http://dx.doi.org/10.1177/1468678319825724.

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Substitution reactions of square-pyramidal [ZnCl2(terpy)] complex (terpy = 2,2′:6′,2″-terpyridine) with biologically relevant nucleophiles such as imidazole, glutathione, 1,2,4-triazole, and pyrazine were investigated at pH 7.0 as a function of nucleophile concentration. The reactions were followed under pseudo first-order conditions by UV-Vis spectrophotometry. The substitution reactions comprised two steps of consecutive displacement of chlorido ligands. Different reaction pathways for the first reaction step of nucleophilic substitution were defined. The order of reactivity of the investiga
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Um, Ik-Hwan, Ji-Youn Lee, Sun-Young Bae та Erwin Buncel. "Effect of modification of the electrophilic center on the α effect". Canadian Journal of Chemistry 83, № 9 (2005): 1365–71. http://dx.doi.org/10.1139/v05-157.

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We report on a nucleophilic study of esters R-C(=X)-Y-Ar in which the electrophilic center has been modified by replacing O by S in the leaving group or carbonyl center: 4-nitrophenyl acetate (1), S-4-nitrophenyl thioacetate (2), 4-nitrophenyl benzoate (3), and O-4-nitrophenyl thionobenzoate (4). The studies include O– and S– nucleophiles as well as α nucleophiles in H2O at 25.0 ± 0.1 °C. The sulfur nucleophile (4-chlorothiophenoxide, 4-ClPhS–) exhibits significant enhanced reactivity for the reactions with thiol and thione esters 2 and 4 compared with their oxygen analogues 1 and 3. On the co
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Vilotijevic, Ivan, Markus Lange, and You Zi. "Latent (Pro)Nucleophiles in Enantioselective Lewis Base Catalyzed Allylic Substitutions." Synlett 31, no. 13 (2020): 1237–43. http://dx.doi.org/10.1055/s-0040-1707130.

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The use of latent nucleophiles, which are molecules that are not nucleophilic but can be activated to act as a nucleophile at an opportune time during the reaction, expands the scope of Lewis base catalyzed reactions. Here, we provide an overview of the concept and show examples of applications to N- and C-centered nucleophiles in allylic substitutions. N- and C-silyl compounds are superior latent (pro)nucleophiles in Lewis base catalyzed reactions with allylic fluorides in which the formation of the strong Si–F bond serves as the driving force for the reactions. The latent (pro)nucleophiles e
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Dissertations / Theses on the topic "Nucleophilie"

1

Lucius, Roland. "Kinetische Untersuchungen zur Nucleophilie stabilisierter Carbanionen." Diss., [S.l.] : [s.n.], 2001. http://deposit.ddb.de/cgi-bin/dokserv?idn=963933760.

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Venier, Olivier. "Etude de la nucleophilie intramoleculaire du groupe boc : nouvelles cyclisations en synthese asymetrique." Paris 6, 1997. http://www.theses.fr/1997PA066573.

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Le traitement des n-boc aminoalcools par le chlorure de tosyle conduit au moyen d'une reaction de cyclisation aux oxazolidin-2-ones correspondantes. Une heterocyclisation similaire est observee avec des analogues soufres des carbamates : les dithiocarbamates. Un effet thorpe-ingold peu courant est observe et est etudie au moyen de calculs am1. Par ailleurs, des epoxyoxazolidines enantiopures sont obtenues en deux etapes a partir d'alcenyloxazolidines. L'etape-cle de ces syntheses est une reaction de cyclocarbamation. L'ouverture de ces epoxydes au moyen de differents nucleophiles (azoture, cup
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GRELLIER, MARY. "Nucleophilie des amines tertiaires vis-a-vis des complexes eta#3-allylpalladium : application a la synthese d'heterocyles." Université Louis Pasteur (Strasbourg) (1971-2008), 1996. http://www.theses.fr/1996STR13116.

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La reaction des amino-olefines en presence d'une quantite stoechiometrique de pd(ii) et d'une base conduit a la formation de composes eta#3-allylpalladium. Un traitement de ces complexes avec un exces de pph#3 provoque une demetallation induisant la formation selectivement d'un heterocycle et de pd(o). L'utilisation de quantite catalytique de pd(ii), implique l'emploi de 1,4-benzoquinone permettant l'oxydation du pd(o), produit au cours de l'etape de demetallation des complexes eta#3-allylpalladium, en pd(ii). La catalyse, utilisant le pd(o), implique la modification des reactifs. Il faut intr
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Koller, Stephan G. [Verfasser], Carsten [Akademischer Betreuer] Strohmann, and Klaus [Gutachter] Jurkschat. "Wechselspiel zwischen Basizität und Nucleophilie von Alkyllithiumverbindungen: ungewöhnliche Reaktionen an Organosilanen / Stephan G. Koller. Betreuer: Carsten Strohmann. Gutachter: Klaus Jurkschat." Dortmund : Universitätsbibliothek Dortmund, 2015. http://d-nb.info/111166871X/34.

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Antonsson, Rositha. "Nucleophilic aromatic substitutions using ethyl 3-mercaptopropionate as nucleophile : Scope and limitations." Thesis, Södertörn University College, School of Life Sciences, 2008. http://urn.kb.se/resolve?urn=urn:nbn:se:sh:diva-1517.

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<p>The scope and limitations of nucleophilic substitutions of aryl halides have been studied using ethyl 3-mercaptopropionate as nucleophile and microwave heating. A diversity of aromatic compounds have been investigated according to different types of leaving groups, regio isomers and substituents. Experimental design has been used as a tool to optimize the reaction. An electron-withdrawing group in ortho or para position of the leaving group proved to be necessary for a positive outcome of the reaction. Fluorine was, without competition, the best leaving group. Some examples of how the synth
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Annandale, Michael Thomas. "NMR spectroscopic studies of nucleophilic attack on dinitroaniline herbicides, reactions of selected nucleophiles with trifluralin and benefin." Thesis, National Library of Canada = Bibliothèque nationale du Canada, 1997. http://www.collectionscanada.ca/obj/s4/f2/dsk2/ftp04/mq22268.pdf.

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Omakor, Emegbero John. "The reaction mechanism and Ã-effect in nucleophilic displacement at the phosphorus center of the pesticide, fenitrothion, by oxygen nucleophiles in aqueous medium." Thesis, National Library of Canada = Bibliothèque nationale du Canada, 1998. http://www.collectionscanada.ca/obj/s4/f2/dsk2/ftp04/mq22373.pdf.

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Harris, David T. "New Nucleophilic Organocatalysts." Thesis, The University of Arizona, 2011. http://hdl.handle.net/10150/144597.

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Acyl-transfer reactions have become commonplace in organic synthesis and organocatalysis of these reactions is becoming increasingly popular. 4-Dimethylaminopyridine has proven to be very useful in acylations; over the recent years chiral and more reactive analogs have received much attention. Interestingly, catalysis of acyl-transfers by diamines has also been shown to be effective. We present the synthesis of several DMAP analogs containing heteroatoms near the nucleophilic nitrogen. These analogs of DMAP vary from basic amidines, oxazolines, and amines, to alcohols, and fluoro-derivatives a
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Thompson, Claire. "Aromatic nucleophilic nitration." Thesis, University of Exeter, 1996. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.390199.

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Lees, Inez Nancy Lloyd. "Nucleophilic polymers for scavenging." Thesis, University of Cambridge, 2007. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.613095.

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Books on the topic "Nucleophilie"

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Terrier, François. Modern Nucleophilic Aromatic Substitution. Wiley-VCH Verlag GmbH & Co. KGaA, 2013. http://dx.doi.org/10.1002/9783527656141.

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N, Charushin Valery, and Plas, H. C. van der., eds. Nucleophilic aromatic substitution of hydrogen. Academic Press, 1994.

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Liddle, J. Vicarious nucleophilic substitution of hydrogen. UMIST, 1996.

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Lemmerer, Miran. Chemoselective Nucleophilic α-Amination of Amides. Springer Fachmedien Wiesbaden, 2020. http://dx.doi.org/10.1007/978-3-658-30020-3.

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Henderson, Colin M. Nucleophilic additions to C-aryl, N-arylsulphonyl methyleneimines. The Author], 1992.

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Nucleophilic aromatic displacement: The influence of the nitro group. VCH Publishers, 1991.

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Cozens, Andrew John. Studies in heterocyclic-mediated nucleophilic displacements in aryl systems. University of East Anglia, 1985.

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Mieczkowski, Józef Bogusław. Zastosowanie reakcji substytucji nukleofilowej do pełnych syntez wybranych alkaloidów i nowych układów heterocyklicznych. Wydawnictwa Uniwersytetu Warszawskiego, 1990.

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El-Naby, Sultan Ahmed Abd. A study of the reactions of nucleophiles with [(Indenyl)Fe(CO)2([eta]1-dppa)]BF4 a=m,e,p. University College Dublin, 1997.

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Murray, Paul Edward. [ Beta]-nucleophilic substitution in indoles: The synthesis of Chartellamide A. University of Manchester, 1994.

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Book chapters on the topic "Nucleophilie"

1

Leisering, Stefan, and Christoph A. Schalley. "Nucleophile SubstitutionSubstitution nucleophile en." In Tutorium Reaktivität und Synthese. Springer Berlin Heidelberg, 2017. http://dx.doi.org/10.1007/978-3-662-53852-4_4.

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Gooch, Jan W. "Nucleophile." In Encyclopedic Dictionary of Polymers. Springer New York, 2011. http://dx.doi.org/10.1007/978-1-4419-6247-8_8022.

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Iwaoka, Michio. "Nucleophilic Selenium." In Organoselenium Chemistry. Wiley-VCH Verlag GmbH & Co. KGaA, 2011. http://dx.doi.org/10.1002/9783527641949.ch2.

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Iwaoka, Michio, and Shuji Tomoda. "Nucleophilic Selenium." In Organoselenium Chemistry. Springer Berlin Heidelberg, 2000. http://dx.doi.org/10.1007/3-540-48171-0_3.

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Vančik, Hrvoj. "Nucleophilic Additions." In Basic Organic Chemistry for the Life Sciences. Springer International Publishing, 2014. http://dx.doi.org/10.1007/978-3-319-07605-8_6.

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Carey, Francis A., and Richard J. Sundberg. "Nucleophilic Substitution." In Advanced Organic Chemistry. Springer US, 1990. http://dx.doi.org/10.1007/978-1-4613-9795-3_5.

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Bodanszky, Miklos, and Agnes Bodanszky. "Nucleophilic Displacement." In The Practice of Peptide Synthesis. Springer Berlin Heidelberg, 1994. http://dx.doi.org/10.1007/978-3-642-85055-4_18.

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Went, Charles. "Nucleophilic Substitution." In Ionic Organic Mechanisms. Macmillan Education UK, 1986. http://dx.doi.org/10.1007/978-1-349-07964-3_5.

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Lemmerer, Miran. "Introduction". У Chemoselective Nucleophilic α-Amination of Amides. Springer Fachmedien Wiesbaden, 2020. http://dx.doi.org/10.1007/978-3-658-30020-3_1.

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Lemmerer, Miran. "Results and Discussion". У Chemoselective Nucleophilic α-Amination of Amides. Springer Fachmedien Wiesbaden, 2020. http://dx.doi.org/10.1007/978-3-658-30020-3_2.

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Conference papers on the topic "Nucleophilie"

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Peixoto, Bárbara Pereira, José Walkimar de M. Carneiro, and Rodolfo Goetze Fiorot. "Substituição nucleofílica alifática: qual o mecanismo preferencial? Estudo computacional dos efeitos da estrutura do substrato e solvente." In VIII Simpósio de Estrutura Eletrônica e Dinâmica Molecular. Universidade de Brasília, 2020. http://dx.doi.org/10.21826/viiiseedmol2020122.

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Nucleophilic aliphatic substitution reactions constitute important steps in the synthesis of substances with biological activity and industrial appeal, beyond to participating in steps in biosynthetic routes of natural products. Unimolecular (SN1) and bimolecular (SN2) pathways can be understood as limiting cases of a mechanistic continuum. In between them, borderline mechanisms are proposed. The preference for one path over another depends on several factors, such as the structure of the substrate, the nucleophile and the solvent used. This plurality is still a topic of discussion and needs f
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Kawecki, Robert. "Nucleophilic Additions to 10-Isobornylsulfinimines." In The 1st International Electronic Conference on Synthetic Organic Chemistry. MDPI, 1997. http://dx.doi.org/10.3390/ecsoc-1-02035.

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MARZOCCHI, E., S. GRILLI, L. DELLA CIANA, et al. "NUCLEOPHILIC ACYLATION CATALYSTS EFFECT ON LUMINOL CHEMILUMINESCENCE." In Proceedings of the 15th International Symposium. WORLD SCIENTIFIC, 2008. http://dx.doi.org/10.1142/9789812839589_0030.

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Klein, Jens-Uwe, and Václav Čeřovský. "Enzymatic peptide synthesis – simulation of nucleophile excess." In VIth Conference Biologically Active Peptides. Institute of Organic Chemistry and Biochemistry, Academy of Sciences of the Czech Republic, 1999. http://dx.doi.org/10.1135/css199903094.

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Nurminen, Erkki J., Jorma K. Mattinen, and Harri Lönnberg. "Protolytic and nucleophilic role of phosphoramidite method promoters." In XIIth Symposium on Chemistry of Nucleic Acid Components. Institute of Organic Chemistry and Biochemistry, Academy of Sciences of the Czech Republic, 2002. http://dx.doi.org/10.1135/css200205129.

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Brill, Wolfgang. "Trapping of Nucleophiles by Rink Resin." In The 1st International Electronic Conference on Synthetic Organic Chemistry. MDPI, 1997. http://dx.doi.org/10.3390/ecsoc-1-02053.

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Quattrociocchi, Daniel Garcez Santos, Antonio Rafael de Oliveira, Douglas da Motta Pio, and Vinicius Rangel Campos. "Estudo teórico da formação da isatina e de seus derivados dimetoxilados pelo método Sandmeyer." In VIII Simpósio de Estrutura Eletrônica e Dinâmica Molecular. Universidade de Brasília, 2020. http://dx.doi.org/10.21826/viiiseedmol2020109.

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Isatin has been attracted the researchers attention due the structural versatility and can be used to synthesized other molecules with pharmacological activities. The Sandmeyer method is one of the most common methods for the synthesis of this molecule. Where the reaction with from aniline with chloral hydrate and hydroxyl amine occurs with good yield. When the same reaction is performed with dimethoxylated aniline show low yield or is not observed experimentally. These observations motivate this work and the justification for these facts are given in terms of thermodynamic parameters and by t
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Podraza, Renata, and Mieczyslaw Makosza. "Vicarious Nucleophilc Substitution of Hydrogen in Azulenes." In The 1st International Electronic Conference on Synthetic Organic Chemistry. MDPI, 1997. http://dx.doi.org/10.3390/ecsoc-1-02041.

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Seijas, Julio, M. Vàsquez-Tato, and Luis Barreiro-Castro. "Reactivity of styrene derivatives: Nucleophilic addition versus 1,2-wittig rearrangement." In The 2nd International Electronic Conference on Synthetic Organic Chemistry. MDPI, 1998. http://dx.doi.org/10.3390/ecsoc-2-01670.

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Fleisher, M., D. Jansone, and L. Leite. "Nucleophilic Addition Reaction of Unsaturated Methyl Lactones with Pyridine Aldehydes." In The 1st International Electronic Conference on Synthetic Organic Chemistry. MDPI, 1997. http://dx.doi.org/10.3390/ecsoc-1-02001.

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Reports on the topic "Nucleophilie"

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Harris, J. Milton. Nucleophilic Decontamination Agents. Defense Technical Information Center, 1989. http://dx.doi.org/10.21236/ada210637.

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Cole, Larry L., and John R. Williams. Nucleophilic Displacement Reactions of 4-Substituted-1,2-Dinitrobenzenes with Trialkyl Phosphites. Defense Technical Information Center, 1987. http://dx.doi.org/10.21236/ada185022.

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Geoffroy, G. L. Highly nucleophilic acetylide, vinyl, and vinylidene complexes. Final progress report, 1 January 1991--31 March 1994. Office of Scientific and Technical Information (OSTI), 1994. http://dx.doi.org/10.2172/10184990.

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Lee, Samkeun, and John Cooper. Highly Reduced Carbene Complexes: Formation of an Alkoxymalonate by Coupling of Carbon Dioxide with the Nucleophilic Carbene in (Cr(CO4)=C(OMe)PH)2-. Defense Technical Information Center, 1989. http://dx.doi.org/10.21236/ada215132.

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Padgett, Henry C. DOE SBIR Phase I Grant No. DE-FG02-00ER83067, ''A Flexible and Economical Automated Nucleophilic [{sup 18}F]Fluorination synthesis System for PET Radiopharmaceuticals.'' Final Technical Report. Office of Scientific and Technical Information (OSTI), 2001. http://dx.doi.org/10.2172/808241.

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Highly nucleophilic acetylide, vinyl, and vinylidene complexes. Office of Scientific and Technical Information (OSTI), 1992. http://dx.doi.org/10.2172/6956851.

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Highly nucleophilic acetylide, vinyl, and vinylidene complexes. Office of Scientific and Technical Information (OSTI), 1991. http://dx.doi.org/10.2172/6112343.

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Highly nucleophilic acetylide, vinyl, and vinylidene complexes. Progress report. Office of Scientific and Technical Information (OSTI), 1991. http://dx.doi.org/10.2172/10104885.

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Highly nucleophilic acetylide, vinyl, and vinylidene complexes. Progress report. Office of Scientific and Technical Information (OSTI), 1992. http://dx.doi.org/10.2172/10191892.

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