Academic literature on the topic 'Nuclephilic addition'

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Journal articles on the topic "Nuclephilic addition"

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MIYATA, Okiko, Tetsuro SHINADA, Takeaki NAITO, and Ichiya NINOMIYA. "Stereospecific nuclephilic addition reaction of thiophenol to .ALPHA.,.BETA.-unsaturated esters." CHEMICAL & PHARMACEUTICAL BULLETIN 37, no. 11 (1989): 3158–60. http://dx.doi.org/10.1248/cpb.37.3158.

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Lencina, María M. Soledad, Franco L. Redondo, Camila Müller та ін. "A Straightforward Methodology for the Synthesis of α,ω-Telechelic Poly(dimethylsiloxane)s". Australian Journal of Chemistry 71, № 3 (2018): 160. http://dx.doi.org/10.1071/ch17508.

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In this work we report the synthesis of α,ω-telechelic poly(dimethylsiloxane)s (α,ω-PDMS) by employing a novel bifunctional initiator obtained from a commercially available siloxane precursor, diglycidylether-terminated poly(dimethylsiloxane) (PDMS-DGE). The synthetic strategy was easily followed by different colour changes, and involved the high-vacuum reaction of sec-Bu−Li+ with 1,1′-diphenylethylene (DPE) to afford the addition adduct (bright red) that was subsequently reacted with PDMS-DGE, promoting the nuclephilic ring-opening from epoxide-end chains. The resulting bifunctional initiator
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Kaboudin, Babak, Hamideh Haghighat, Saied Alaie та Tsutomu Yokomatsu. "Novel Method for the Synthesis of α-Amino-α′-hydroxyalkylphosphinic Acids and Bis(α-aminoalkyl)phosphinic Acids: Nuclephilic Addition of α-Hydroxy-H-phosphinic Acids to Diimines". Synlett 23, № 13 (2012): 1965–69. http://dx.doi.org/10.1055/s-0032-1316706.

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Mosteiro, Roberto, Alberto Fernández, Margarita López-Torres, et al. "Versatile nuclephilic Michael addition to chelated (Ph2P)2CCH2 (vdpp) in Schiff base cyclometallated palladium(II) compounds: C–C, C–O and C–N bond formation, dinuclear palladacycles and geometrical isomerism." Journal of Organometallic Chemistry 720 (December 2012): 30–37. http://dx.doi.org/10.1016/j.jorganchem.2012.07.021.

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Hu, Mengjie, Liying Ru, Mengjiao Zhu, et al. "Tandem [5,5]-/[3,3]- rearrangements of aryl sulfoxides with allyl nitriles." Synthesis, June 5, 2024. http://dx.doi.org/10.1055/a-2338-9005.

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Tandem aromatic rearrangements can redirect the regioselectivity of original rearrangement and increase the complexity of products. Despite their obvious synthetic value, only few protocols of tandem aromatic rearrangements are reported. In this Article, we describe two new tandem aromatic rearrangements by using sulfonium rearrangements. Specifically, [5,5]-rearrangement of phenyl sulfoxides with allyl nitriles followed by [3,3]-Cope rearrangement forges the tandem [5,5]-/[3,3]-rearrangements which affords ortho-functionalized phenyl sulfides as products. The other tandem rearrangement procee
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PIKUL, S., and J. JURCZAK. "ChemInform Abstract: Stereochemical Consequences of Nuclephilic Additions to 2,3-O-Isopropylideneglyceraldehyd." Chemischer Informationsdienst 17, no. 9 (1986). http://dx.doi.org/10.1002/chin.198609084.

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Dissertations / Theses on the topic "Nuclephilic addition"

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Marradi, Marco. "New chiral nitrones for stereoselective syntheses of biologically active natural products and their analogues." Doctoral thesis, 2005. http://hdl.handle.net/2158/1161177.

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Use of carbohydrates (chiral pool) in organic synthesis through their transformation into chiral nitrones, as intermediates for the preparation of biologically active molecules (analogues of alkaloids)
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