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Relevant bibliographies by topics / O-O diketonates

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Academic literature on the topic 'O-O diketonates'

Author: Grafiati

Published: 2 June 2025

Last updated: 31 July 2025

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Journal articles on the topic "O-O diketonates"

1

Sharutin, V. "Study of the structure of tetraarylantimony b-diketonates Ph4Sb[MeC(O)CHC(O)Ph], p-Tol4Sb[MeC(O)CEtC(O)Me] ∙ 1½PhH, p-Tol4Sb[MeC(O)СHC(O)NHPh]". Bulletin of the South Ural State University series "Chemistry" 16, № 2 (2024): 96–102. http://dx.doi.org/10.14529/chem240210.

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Reaction of pentaphenylantimony and penta(para-tolyl)antimony with -diketones in benzene (100 °C, 1 h) forms tetraarylantimony -diketonates Ph4Sb[MeC(O)CHC(O)Ph] (1), p-Tol4Sb[MeC(O)CEtC(O)Me] ∙ 1½PhH (2), p-Tol4Sb[MeC(O)СHC(O)NHPh] (3), characterized by IR spectra and X-ray diffraction analysis. Crystals 1 [C34H29O2Sb, M 591.32; triclinic system, symmetry group P–1; cell parameters: a = 9.524(13) Å, b = 9.827(10) Å, c = 17.350(18) Å;  = 99.03(3), β = 101.50(6),  = 111.02(4), V = 1438(3) Å3, Z = 2; cal = 1.365 g/cm3], 2 [C44H48O2Sb, M 730.57; triclinic system, symmetry group P–1; cell

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2

Reimer, Mark L. J., John B. Westmore та Manoranjan Das. "Electron ionization mass spectrometry of aryl- and fluoroalkyl-substituted palladium(II) β-diketonates and monothio-β-diketonates". Canadian Journal of Chemistry 72, № 5 (1994): 1302–11. http://dx.doi.org/10.1139/v94-163.

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Positive ion electron ionization mass spectra are presented for palladium(II) β-diketonates and monothio-β-diketonates of the general form PdII[RC(X)CHC(O)R′]2, where R = phenyl, 4-methoxyphenyl, 2-thienyl, or 2-naphthyl; R′ = trifluoromethyl, pentafluoroethyl, or n-heptafluoropropyl; and X = O or S. The mass spectral behavior is in sharp contrast to that of metals of the first transition series. The spectra of the β-diketonates are dominated by metal-containing ions that arise by migration of the R group from the ligand (L) to palladium, but there is no evidence for fluorine-to-metal transfer

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Janković, Nenad, Goran Bogdanović, Nevenka Gligorijević та ін. "Novel organoruthenium complexes containing β-Diketonates: Synthesis, characterization, DNA/HSA interactions, and the impact of biocompatible ionic liquids on biological activities". Journal of Inorganic Biochemistry 270 (23 травня 2025): 112941. https://doi.org/10.1016/j.jinorgbio.2025.112941.

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In order to discover new dual-active agents, novel ruthenium (η6-p-cymene) complexes of the general formula [(η6-p-cym)Ru(O–O)Cl] with O,O-diketo ester ligands ethyl 2-hydroxy-4-aryl-4-oxobut-2-enoate (1–3), were synthesized. The complexes 1–3 were characterized by spectral techniques (UV–Vis, IR, 1H and 13C NMR, andESI-HRMS), elemental analysis, and X-ray crystallography. Based on in vitro DNA/HSA experiments, complex 1 exhibited the highest DNA/HSA-activity, suggesting that the presence of an alkene chain contributes to increased activity. The cytotoxic activi

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4

Szyczewski, A., R. Krzyminiewski, S. Lis, J. Pietrzak та M. Elbanowski. "EPR study of selected gadolinium complexes: β-diketonates and polycarboxylates". Radiation Physics and Chemistry 45, № 6 (1995): 935–38. http://dx.doi.org/10.1016/0969-806x(94)e0049-o.

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5

Semenov, V., N. Zolotareva, and M. Lopatin. "Optical properties of triethylaminium salt of trifluoroacetic acid." Bulletin of the South Ural State University series "Chemistry" 16, no. 2 (2024): 121–26. http://dx.doi.org/10.14529/chem240214.

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. Triethylaminium trifluoroacetate (CH3CH2)3NH+ ‒O(O)C‒CF3, obtained by reacting tri-fluoroacetic acid with triethylamine, is a colorless ionic liquid that passes into the vapor phase when heated to 200–220 °C. The compound has been characterized by elemental analysis, infrared spectroscopy, 1H and 13C nuclear magnetic resonance, mass spectroscopy, thermogravimetry, differential scanning calorimetry, refractometry, electron absorption and emission spectroscopy. In the UV spectrum there is a weak absorption band in the range of 260–340 nm. When excited at 320 nm, the compound shows two photolum

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6

Reimer, Mark L. J., John B. Westmore та Manoranjan Das. "Electron ionization mass spectrometry of aryl- and fluoroalkyl-substituted nickel(II) β-diketonates and monothio-β-diketonates". Canadian Journal of Chemistry 71, № 9 (1993): 1450–62. http://dx.doi.org/10.1139/v93-187.

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Electron ionization positive-ion mass spectra are reported for 18 substituted nickel(II) β-diketonates and monothio-β-diketonates, NiII(RCXCHCOR′)2, where X = O or S; R = phenyl, 2-thienyl, 5-methyl-2-thienyl, or 2-naphthyl; and R′ = difluoromethyl, trifluoromethyl, pentafluoroethyl, or n-heptafluoropropyl. Each mass spectrum contains a prominent molecular ion, [NiL2]+, which, for β-diketonates, fragments mainly by elimination of the odd-electron R′• species; the resulting ion decomposes by losses of one or more even-electron neutral species to yield ions containing nickel(II). In contrast, th

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Lehrich, Steve W., Julia Mahrholdt, Marcus Korb, Alexander Hildebrandt, Jannie C. Swarts та Heinrich Lang. "Synthesis, Characterization, and Electrochemistry of Diferrocenyl β-Diketones, -Diketonates, and Pyrazoles". Molecules 25, № 19 (2020): 4476. http://dx.doi.org/10.3390/molecules25194476.

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The synthesis of FcC(O)CH(R)C(O)Fc (Fc = Fe(η5-C5H4)(η5-C5H5); R = H, 5; nBu, 7; CH2CH2(OCH2CH2)2OMe, 9), [M(κ2O,O′-FcC(O)CHC(O)Fc)n] (M = Ti, n = 3, 10; M = Fe, n = 3, 11; M = BF2, n = 1, 12), and 1-R′-3,5-Fc2-cC3HN2 (R′ = H, 13; Me, 14; Ph, 15) is discussed. The solid-state structures of 5, 7, 9, 12, 13, 15, and 16 ([TiCl2(κ2O,O′-PhC(O)CHC(O)Ph)2]) show that 7 and 9 exist in their β-diketo form. Compound 13 crystallizes as a tetramer based on a hydrogen bond pattern, including one central water molecule. The electrochemical behavior of 5–7 and 9–16 was studied by cyclic and square-wave volta

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Vikulova, Evgeniia S., Taisiya S. Sukhikh, Sergey A. Gulyaev, Igor Yu Ilyin та Natalia B. Morozova. "Structural Diversity of Silver Fluorinated β-Diketonates: Effect of the Terminal Substituent and Solvent". Molecules 27, № 3 (2022): 677. http://dx.doi.org/10.3390/molecules27030677.

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In order to demonstrate the role of the fluorination and some solvents in the structural organization of the Ag(I) coordination polymers with β-diketonate ligands (R1C(O)CαHC(O)R2)− we synthesized a series of the compounds containing tfac- (R1 = CH3, R2 = CF3) and pfpac- (R1 = CH3, R2 = C2F5) anions. Solvent-free [Ag(L)]∞ (L = tfac 1, pfpac 2) compounds and the corresponding acetonitrile and toluene adducts have been characterized by elemental analysis and/or NMR, IR and single-crystal XRD. This series includes five new coordination polymers. Compound 1 is a 3D coordination framework based on

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Rajagopal, K., S. Kannan, V. Venugopal, R. V. Krishnakumar, M. Subha Nandhini та S. Natarajan. "Syntheses and Characterisation of Amide Adducts of Uranyl Bis (β-Diketonates) the Molecular Structure of [UO2(DBM)2.C4H9CON(3-C5H11) (sec-C4H9)]". Journal of Chemical Research 2003, № 8 (2003): 468–69. http://dx.doi.org/10.3184/030823403103174858.

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The first structurally characterised uranyl bis (β-diketonate)-amide adduct compound [UO2(DBM)2. C4H9CON ( 3-C5H11) ( sec-C4H9)] (DBM = dibenzoylmethanate) shows that the amide ligand bonded through its amido oxygen atom to the uranyl group. The average bond distances for U–O(uranyl), U–O(DBM) and U–O(amide) are 1.778(5), 2.346(5) and 2.411(5)Å respectively.

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10

Reimer, Mark L. J., John B. Westmore та Manoranjan Das. "Electron ionization mass spectrometry of cobalt(III) β-diketonates and monothio-β-diketonates possessing aryl and fluorinated alkyl substituents". Canadian Journal of Chemistry 70, № 3 (1992): 952–63. http://dx.doi.org/10.1139/v92-128.

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Electron ionization positive ion mass spectra of 15 substituted cobalt(III) β-diketonates and monothio-β-diketonates, CoIIIL3, where L = RCXCHCOR′, R = phenyl, 2-thienyl, or 2-naphthyl; X = O or S; and R′ = CHF2, CF3, C2F5, or n-C3F7, show a marked dependence on the ligand. Molecular ions, [CoIIIL3]+•, are observed only for some of the more highly fluorinated complexes (R′ = C2F5 or n-C3F7). The [CoIIIL2]+• ion, possibly generated by ionization of CoIIL2 formed by thermal degradation, or by electron ionization of CoIIIL3, typically decomposes by elimination of a radical, i.e., L• or R′•, to yi

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Dissertations / Theses on the topic "O-O diketonates"

1

Oßberger, Manfred. "Synthese und Charakterisierung von Pentoliden, Diketonaten und heteroleptischen Verbindungen der schweren Alkali- und Erdalkalimetalle - Modellverbindungen für die Spaltung von O-C- und O-Si-Bindungen." Diss., lmu, 2004. http://nbn-resolving.de/urn:nbn:de:bvb:19-26164.

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Jesus, Larissa Tavares de. "Estudo espectroscópico de sistemas contendo o íon európio trivalente." Pós-Graduação em Química, 2018. http://ri.ufs.br/jspui/handle/riufs/7940.

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Conselho Nacional de Pesquisa e Desenvolvimento Científico e Tecnológico - CNPq<br>In this work a theoretical study was carried out to investigate the spectroscopic properties of trivalent europium complexes. The study was divided into two parts. The first one was the study of the luminescent efficiency of five complexes which had as ligands β-diketones and pyrazole. Pyrazole modifications were made promoting a gradual increase in the amount of fluorine atoms in the search for systems with greater luminescence. The second part was the study of structural elucidation and luminescent efficiency

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3

Oßberger, Manfred [Verfasser]. "Synthese und Charakterisierung von Pentoliden, Diketonaten und heteroleptischen Verbindungen der schweren Alkali- und Erdalkalimetalle : Modellverbindungen für die Spaltung von O-C- und O-Si-Bindungen / Manfred Oßberger." 2004. http://d-nb.info/972496017/34.

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Conference papers on the topic "O-O diketonates"

1

Branković, Snežana, Filip Grbović, Radmila Glišić та ін. "NEUTRALIZATION OF SEWAGE SLUDGE POLLUTANTS USING β-DIKETONATE". У 54. godišnja konferencija o aktuelnim problemima korišćenja i zaštite voda. Srpsko društvo za zaštitu voda, 2025. https://doi.org/10.46793/voda25.343b.

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This study explores the application of an innovative approach for the neutralization of pollutants from sewage sludge, sampled at the Cvetojevac Wastewater Treatment Plant in Kragujevac. The sludge was treated with β-diketonate at different concentrations (50, 100, and 200 mg/mL), and a bioassay method was applied using red clover seeds (Trifolium pratense L.) as a model for germination. The results indicate that the addition of hummus and treatment with synthesized β-diketonate significantly reduced the inhibitory effects of the sludge. The synthesized β-diketonate shows potential for polluta

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