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Journal articles on the topic 'O-Toluic Acid'

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Published: 2 June 2025

Last updated: 31 July 2025

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1

George, Roy. "Adsorption Equilibrium and Kinetic Studies of Effect of ortho-Substitution to Benzoic Acid in Aqueous Phase Using Granular Activated Carbon." Asian Journal of Chemistry 31, no. 8 (2019): 1667–74. http://dx.doi.org/10.14233/ajchem.2019.21938.

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Adsorption equilibrium and kinetics studies of effect of ortho-substituted benzoic acid in aqueous phase using granular activated carbon were investigated. The granular activated carbon (GAC) obtained from bituminous type coal having a surface area of 998 m2/g and loosely bounded and open pores morphology. The adorbates selected for this study was benzoic acid and its ortho-derivatives namely; salicylic acid, phthalic acid and o-toluic acid. The solubility of adsorbate in solvent affected the adsorption behaviour more pronouncly. The order of adsorption for adsorbates was found to be as: benzo

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2

Trivedi, Mahendra Kumar, Alice Branton, Dahryn Trivedi, Gopal Nayak, Gunin Saikia, and Snehasis Jana. "Quantitative Determination of Isotopic Abundance Ratio of 13C, 2H, and 18O in Biofield Energy Treated Ortho and Meta Toluic Acid Isomers." American Journal of Applied Chemistry 3, no. 6 (2015): 217–23. https://doi.org/10.11648/j.ajac.20150306.17.

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O-Toluic acid (OTA) and m-toluic acid (MTA) are two isomers of toluic acid that act as an important organic intermediates, mostly used in medicines and pesticides. The aim of the study was to evaluate the impact of biofield energy treatment on isotopic abundance ratios of 2H/1H, 13C/12C, (PM+1)/PM and 18O/16O, (PM+2)/PM, in toluic acid isomers using gas chromatography-mass spectrometry (GC-MS). The OTA and MTA samples were divided into two parts: control and treated. The control sample remained as untreated, while the treated sample was further divided into four groups as T1, T2, T3, and T4. T

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3

Trivedi, Mahendra Kumar, Alice Branton, Dahryn Trivedi, Gopal Nayak, Gunin Saikia, and Snehasis Jana. "Quantitative Determination of Isotopic Abundance Ratio of 13C, 2H, and 18O in Biofield Energy Treated Ortho and Meta Toluic Acid Isomers." American Journal of Applied Chemistry 3, no. 6 (2015): 217–23. https://doi.org/10.5281/zenodo.192636.

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O-Toluic acid (OTA) and m-toluic acid (MTA) are two isomers of toluic acid that act as an important organic intermediates, mostly used in medicines and pesticides. The aim of the study was to evaluate the impact of biofield energy treatment on isotopic abundance ratios of 2H/1H, 13C/12C, (PM+1)/PM and 18O/16O, (PM+2)/PM, in toluic acid isomers using gas chromatography-mass spectrometry (GC-MS). The OTA and MTA samples were divided into two parts: control and treated. The control sample remained as untreated, while the treated sample was further divided into four groups as T1, T2

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4

Schnitzler, Elijah G., Brandi L. M. Zenchyzen, and Wolfgang Jäger. "Rotational spectroscopy of the atmospheric photo-oxidation product o-toluic acid and its monohydrate." Physical Chemistry Chemical Physics 18, no. 1 (2016): 448–57. http://dx.doi.org/10.1039/c5cp06073g.

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5

Connolly, Terrence J., Michael Matchett, Patrick McGarry, Sunil Sukhtankar, and Jiang Zhu. "A Practical Synthesis of 3,4-Dimethoxy-o-toluic Acid." Organic Process Research & Development 8, no. 4 (2004): 624–27. http://dx.doi.org/10.1021/op049938t.

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6

Belonogov, Eduard V., Idris N. Muslimov, Ilya M. Zinoviev, and Vladimir Yu Guskov. "Kinetic features of the adsorption of menthol enantiomers on o-toluylic acid and CsCuCl3 crystals with supramolecular chirality." Сорбционные и хроматографические процессы 23, no. 4 (2023): 657–66. http://dx.doi.org/10.17308/sorpchrom.2023.23/11574.

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Chirality plays a key role in modern science because it is the distinguishing feature of molecules and crystals. The spontaneous emergence of chirality in the absence of detectable chiral physical and chemical sources has recently advanced significantly due to the deracemization of conglomerates through Viedma ripening. As a result, systems based on supramolecular chirality are obtained. Of particular importance to this type of chirality is the fact that supramolecular chirality underlies the formation of life on Earth. One manifestation of supramolecular chirality is enantiomorphic crystals.

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7

Shen, Zhipeng, Qinbo Wang, Linhui Chen, Xiaoxiao Sheng, and Yinchuan Pei. "Solubilities of Phthalic Acid and o-Toluic Acid in Binary Acetic Acid + Water and Acetic Acid + o-Xylene Solvent Mixtures." Journal of Chemical & Engineering Data 61, no. 9 (2016): 3233–40. http://dx.doi.org/10.1021/acs.jced.6b00324.

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8

Yu, Zhiqun, Qilin Xu, Linchang Liu, et al. "Dinitration of o-toluic acid in continuous-flow: process optimization and kinetic study." Journal of Flow Chemistry 10, no. 2 (2020): 429–36. http://dx.doi.org/10.1007/s41981-020-00078-6.

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9

Lakmuang, Chaiyaporn, Asja A. Kroeger, and Amir Karton. "Criegee intermediate decomposition pathways for the formation of o-toluic acid and 2-methylphenylformate." Chemical Physics Letters 748 (June 2020): 137399. http://dx.doi.org/10.1016/j.cplett.2020.137399.

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10

Besson, Michèle, Samuel Neto, and Catherine Pinel. "Diastereoselective hydrogenation of o-toluic acid derivatives over supported rhodium and ruthenium heterogeneous catalysts." Chemical Communications, no. 14 (1998): 1431–32. http://dx.doi.org/10.1039/a802822b.

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11

Zhukovetska, O. M., O. M. Guzenko, and D. V. Snigur. "LOW TEMPERATURE ANALYTICAL CLOUD POINT EXTRACTION. 1: PROTOLYTIC PROPERTIES OF ACIDIC EXTRACTION INITIATORS IN ORGANIZED MEDIA." Odesa National University Herald. Chemistry 28, no. 3(86) (2023): 62–71. http://dx.doi.org/10.18524/2304-0947.2023.3(86).297826.

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Cloud point extraction is a powerful tool for the analytical preconcentration of trace amounts of analytes. The standard cloud point extraction procedure requires prolonged heating of the solution, which is not always appropriate in the case of thermally unstable analytes or analytical forms and significantly limits the capabilities of the method. One of the ways to modify cloud point extraction is to find approaches to intensifying the process of analytical concentration. The main disadvantage of cloud point extraction is the need for thermal, ultrasonic, infrared or any other initiation of t

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12

Chuchani, Gabriel, та Rosa M. Domínguez. "Gas phase elimination kinetics of α-bromo-o-toluic acid. Participation of the COOH group". Reaction Kinetics & Catalysis Letters 59, № 1 (1996): 53–58. http://dx.doi.org/10.1007/bf02067992.

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13

De Suzzoni, S., and J. P. Noel. "Two-three steps syntheses of [14C-ring]o-xylene, [14C-ring]o-toluic acid; [14C-ring]-phthalic acid from [14C] barium carbonate." Journal of Labelled Compounds and Radiopharmaceuticals 34, no. 12 (1994): 1201–6. http://dx.doi.org/10.1002/jlcr.2580341209.

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14

Godin, Simon, Pawel Kubica, Anthony Ranchou-Peyruse, et al. "An LC-MS/MS Method for a Comprehensive Determination of Metabolites of BTEX Anaerobic Degradation in Bacterial Cultures and Groundwater." Water 12, no. 7 (2020): 1869. http://dx.doi.org/10.3390/w12071869.

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BTEX (benzene, toluene, ethylbenzene, and the different xylene isomers), known for carcinogenic and neurotoxic effects, are common environmental contaminants. The first step for the development of the bioremediation technologies is the detection of intense microbial degradation in contaminated waters in the quest for the most active bacterial strains. This requires the multispecies analysis for BTEX metabolites which are considered as markers of microbial degradation. A direct (50 µL injection) HPLC–electrospray MS/MS analytical method was developed for the simultaneous analysis of 11 BTEX met

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15

Guan, Aocong, Yucong Nie, Yue Shen, Sile Shi, and Weiping Luo. "Solubility of Phthalic Acid and o-Toluic Acid in Seven Organic Solvents: Experimental Measurement and Thermodynamic Modeling." Journal of Chemical & Engineering Data 66, no. 12 (2021): 4273–85. http://dx.doi.org/10.1021/acs.jced.1c00254.

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16

Bachiller-Baeza, B., I. Rodrı́guez-Ramos, A. Guerrero-Ruiz, M. Besson, and C. Pinel. "Diastereoselective hydrogenation of o-toluic acid coupled with (S)-proline and (S)-pyroglutamic acid methyl esters on ruthenium catalysts." Journal of Molecular Catalysis A: Chemical 164, no. 1-2 (2000): 147–55. http://dx.doi.org/10.1016/s1381-1169(00)00366-6.

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17

U., Arvind, and Kumar Sanjay. "Non-specific solvent effects on proton transfer equilibrium between toluic acids and carbinol base of crystal violet." Journal of Indian Chemical Society Vol. 87, Mar 2010 (2010): 361–63. https://doi.org/10.5281/zenodo.5779115.

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Department of Chemistry, Rajendra College, Chapra-841 301, Bihar, India Department of Chemistry, Jagdam College, Chapra-841 301, Bihar, India <em>Manuscript received 27 April 2009, accepted 20 August 2009</em> Acid-base reactions In apolar aprotic media provide a sufficiently close measure of intrinsic acid/base strengths. A study on reaction equilibria between <em>o</em>- and m-methyl benzoic: (toluic) acids with the carbinol base of crystal violet in five apolar aprotic solvents of similar Kirkwood polarity function (\(\in\) - 1)/(2\(\in\)+ 1) and significantly different Dimroth Reichar

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18

Yang, Hai-Jun, and Ming-Yu Ding. "DETERMINATION OF o -TOLUIC ACID AND ITS MICRO AMOUNTS OF IMPURITIES IN INDUSTRIAL PRODUCTS BY HPLC." Journal of Liquid Chromatography & Related Technologies 25, no. 17 (2002): 2709–15. http://dx.doi.org/10.1081/jlc-120014387.

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19

BESSON, M., P. GALLEZOT, S. NETO, and C. PINEL. "ChemInform Abstract: Diastereoselective Hydrogenation of o-Toluic Acid Derivatives over Supported Rhodium and Ruthenium Heterogeneous Catalysts." ChemInform 29, no. 43 (2010): no. http://dx.doi.org/10.1002/chin.199843036.

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20

Sunil, Abraham C., Ernst H. G. Langner, Charlene Marais, and Barend C. B. Bezuidenhoudt. "Thermo-analytical determination of intermediates in the copper catalysed rearrangement of o-toluic acid to meta-cresol." Catalysis Science & Technology 3, no. 9 (2013): 2227. http://dx.doi.org/10.1039/c3cy00119a.

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21

VARALE, YASHODHARA, and AMIT VARALE. "Oxidation of O-toluic Acid Hydrazide by Thallium (III) in Acidic Medium (A Kinetic and Mechanistic Study)." Oriental Journal Of Chemistry 29, no. 2 (2013): 667–72. http://dx.doi.org/10.13005/ojc/290239.

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22

Onyeke, Zamena Zion, Oladotun Paul Bolade, and Feyisayo Victoria Adams. "Optimization of the Removal of Naphthenic Acids from Crude Oil via Catalytic Esterification." Key Engineering Materials 917 (April 13, 2022): 241–49. http://dx.doi.org/10.4028/p-085907.

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This study was carried out to ascertain the optimum parameters for maximum total acid number (TAN) reduction via catalytic esterification using chicken eggshell ash as catalyst. A central composite design (CCD) was created to optimize TAN reduction by varying temperature and catalyst weight %. The chicken eggshell ash was calcined and reactivated in a furnace at 900 °C for an hour. An oil solution (referred to as synthetic solution) of diesel was adulterated with the organic acid m-toluic which served as a representation for highly acidic oil. Titration using alcoholic potassium hydroxide (KOH

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23

Pintar, Albin, Raluca Malacea, Catherine Pinel, and Michèle Besson. "Catalytic three-phase diastereoselective hydrogenation of o-toluic and 2-methyl nicotinic acid derivatives: In situ FTIR/ATR investigation." Vibrational Spectroscopy 45, no. 1 (2007): 18–26. http://dx.doi.org/10.1016/j.vibspec.2007.04.003.

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24

Trivedi, Mahendra Kumar, Alice Branton, Dahryn Trivedi, Gopal Nayak, Ragini Singh, and Snehasis Jana. "Characterization of Physical, Thermal and Spectroscopic Properties of Biofield Treated Ortho-Toluic Acid." Journal of Heterocyclics 1, no. 1 (2016): 1–8. https://doi.org/10.5281/zenodo.166328.

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Toluic acid isomers are widely used as a chemical intermediate in manufacturing of dyes, pharmaceuticals, polymer stabilizers, insect repellent and other organic synthesis. The aim of present study was to evaluate the impact of biofield treatment on physical, thermal and spectroscopic properties of ortho isomer of toluic acid (OTA). The OTA sample was divided into two groups, served as control and treated. The treated group received Mr. Trivedi’s biofield treatment. Subsequently, the control and treated samples were evaluated using X-ray diffraction (XRD), differential scanning calorimet

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25

Trivedi, Mahendra Kumar, Alice Branton, Dahryn Trivedi, Gopal Nayak, Ragini Singh, and Snehasis Jana. "Characterization of Physical, Thermal and Spectroscopic Properties of Biofield Treated Ortho-Toluic Acid." Journal of Heterocyclics 1, no. 1 (2016): 1–8. https://doi.org/10.5281/zenodo.193910.

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Toluic acid isomers are widely used as a chemical intermediate in manufacturing of dyes, pharmaceuticals, polymer stabilizers, insect repellent and other organic synthesis. The aim of present study was to evaluate the impact of biofield treatment on physical, thermal and spectroscopic properties of ortho isomer of toluic acid (OTA). The OTA sample was divided into two groups, served as control and treated. The treated group received Mr. Trivedi’s biofield treatment. Subsequently, the control and treated samples were evaluated using X-ray diffraction (XRD), differential scanning calorimet

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26

Ratna, Bandyopadhyay. "Oxo-peroxo vanadates(V): Synthesis, characterisation and uses in catalytic oxidation reactions." Journal of Indian Chemical Society Vol. 97, No. 11a, Nov 2020 (2020): 2166–71. https://doi.org/10.5281/zenodo.5653102.

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Department of Chemistry, Uluberia College, Howrah-711 315, West Bengal, India <em>E-mail</em>: ratna201200@yahoo.co.uk <em>Manuscript received online 12 October 2020, revised and accepted 27 November 2020</em> The reaction of V<sub>2</sub>O<sub>5</sub> with H<sub>2</sub>O<sub>2</sub> in a neutral medium can be utilised for the generation of an unknown and presumably binuclear oxo-bridged peroxovanadate(V), (PPh<sub>4</sub>)<sub>2</sub>[V<sub>2</sub>O<sub>2</sub>(μ<sub>2</sub>-O)(μ<sub>2</sub>-O<sub>2</sub>)(η<sub>2</sub>-O<sub>2</sub>)<sub>2</sub>] containing two triangular and one b

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27

Li, Xinbao, Mingju Wang, Cunbin Du, Yang Cong, and Hongkun Zhao. "Thermodynamic functions for solubility of 3-nitro- o -toluic acid in nine organic solvents from T = (283.15 to 318.15) K and apparent thermodynamic properties of solutions." Journal of Chemical Thermodynamics 110 (July 2017): 87–98. http://dx.doi.org/10.1016/j.jct.2017.02.017.

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28

Hajji, K. Tawfiki, F. Lépine, J. G. Bisaillon, and R. Beaudet. "Simultaneous removal of phenol, ortho- and para-cresol by mixed anaerobic consortia." Canadian Journal of Microbiology 45, no. 4 (1999): 318–25. http://dx.doi.org/10.1139/w99-003.

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Two different anerobic consortia, one removing phenol and ortho- (o-) cresol and the other removing para- (p-) cresol, were cultivated in serum bottles using whey as cosubstrate substitute for proteose peptone. Phenol and p-cresol removal with the phenol-removing consortium were the same with 0.0125% (w/v) whey as with 0.05% proteose peptone. For the other consortium, 8 days were required to decrease the p-cresol concentration from 35 to 2 mg/L with 0.025% whey, while 35 days were required to achieve a similar removal with 0.5% proteose peptone. The two consortia were mixed and cultivated with

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29

Kumar Trivedi, Mahendra. "Quantitative Determination of Isotopic Abundance Ratio of <sup>13</sup>C, <sup>2</sup>H, and <sup>18</sup>O in Biofield Energy Treated Ortho and Meta Toluic Acid Isomers." American Journal of Applied Chemistry 3, no. 6 (2015): 217. http://dx.doi.org/10.11648/j.ajac.20150306.17.

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30

KESSAR, S. V., Y. P. GUPTA, and S. SINGH. "ChemInform Abstract: Reactions of Dianions Derived from o-Toluic Acids: Facile Synthesis of 3-Phenyl-3,4-dihydroisocoumarins and 8-Oxotetrahydroprotoberberines." ChemInform 24, no. 20 (2010): no. http://dx.doi.org/10.1002/chin.199320155.

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31

Smeriglio, Antonella, Domenico Trombetta, Laura Cornara, et al. "Pharmacognostic Study of the Leaves of Ptilostemon greuteri Raimondo & Domina, a Rare Sicilian Paleoendemic Species." Plants 14, no. 3 (2025): 370. https://doi.org/10.3390/plants14030370.

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Ptilostemon greuteri Raimondo & Domina is a rare Sicilian paleoendemic species. The aim of study was to investigate the micro-morphological features of leaves by light and scanning electron microscopy, to elucidate the phytochemical profile of essential oil (EO), n-hexane (HE) and hydroalcoholic extract (HAE) by gas and liquid chromatographic methods, and antioxidant and anti-inflammatory properties by in vitro assays. Leaves had a large lanceolate blade, dark green on the upper side and greyish on the lower one with a dense tomentum. Epidermis showed many protruding stomata. By lipid-spec

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32

Mahendra, Trivedi, Branton Alice, Trivedi Dahryn, and Nayak Gopal. "Quantitative Determination of Isotopic Abundance Ratio of 13C, 2H, and 18O in Biofield Energy Treated Ortho and Meta Toluic Acid Isomers." Science Publishing Group, December 21, 2015. https://doi.org/10.5281/zenodo.813685.

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O-Toluic acid (OTA) and m-toluic acid (MTA) are two isomers of toluic acid that act as an important organic intermediates, mostly used in medicines and pesticides. The aim of the study was to evaluate the impact of biofield energy treatment on isotopic abundance ratios of 2H/1H, 13C/12C, (PM+1)/PM and 18O/16O, (PM+2)/PM, in toluic acid isomers using gas chromatography-mass spectrometry (GC-MS). The OTA and MTA samples were divided into two parts: control and treated. The control sample remained as untreated, while the treated sample was further divided into four groups as T1, T2, T3, and T4. T

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33

Dong, Mei, Wenjing Shi, Jian Chen, et al. "Solubilities of Phthalic Acid and o-Toluic Acid in Eight Alcohol Solvents: Experimental Measurement and Thermodynamic Modeling." Journal of Chemical & Engineering Data, April 13, 2023. http://dx.doi.org/10.1021/acs.jced.2c00764.

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34

Berniak, Tomasz, Piotr Łątka, Marek Drozdek, et al. "Covalent bonding of N‐hydroxyphthalimide on mesoporous silica for catalytic aerobic oxidation of p‐xylene at atmospheric pressure." ChemPlusChem, February 20, 2024. http://dx.doi.org/10.1002/cplu.202300631.

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The surface of SBA‐15 mesoporous silica was modified by N‐hydroxyphthalimide (NHPI) moieties acting as immobilized active species for aerobic oxidation of alkylaromatic hydrocarbons. The incorporation was carried out by four original approaches: the grafting‐from and grafting‐onto techniques, using the presence of surface silanols enabling the formation of particularly stable O‐Si‐C bonds between the silica support and the organic modifier. The strategies involving the Heck coupling led to the formation of NHPI groups separated from the SiO2 surface by a vinyl linker, while one of the develope

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35

Trivedi, Mahendra, Alice Branton, Dahryn Trivedi, and Gopal Nayak. "Characterization of Physical, Thermal and Spectroscopic Properties of Biofield Treated Ortho-Toluic Acid." Edelweiss Publication: Open Access, February 27, 2016. https://doi.org/10.5281/zenodo.813378.

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Toluic acid isomers are widely used as a chemical intermediate in manufacturing of dyes, pharmaceuticals, polymer stabilizers, insect repellent and other organic synthesis. The aim of present study was to evaluate the impact of biofield treatment on physical, thermal and spectroscopic properties of ortho isomer of toluic acid (OTA). The OTA sample was divided into two groups, served as control and treated. The treated group received Mr. Trivedi's biofield treatment. Subsequently, the control and treated samples were evaluated using X-ray diffraction (XRD), differential scanning calorimetry (DS

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36

Liu, Dan-Yang, and De-Cai Fang. "Theoretical Study on the Mechanism of Ru(II)-Catalyzed Intermolecular [3 + 2] Annulation between o-Toluic Acid and 3,5-Bis(trifluoromethyl)benzaldehyde: Octahedral vs Trigonal Bipyramidal." Journal of Organic Chemistry, September 23, 2024. http://dx.doi.org/10.1021/acs.joc.4c01461.

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