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Journal articles on the topic 'O-toluidine'

Author: Grafiati

Published: 28 May 2022

Last updated: 31 July 2025

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1

Jodynis-Liebert, Jadwiga, and Hassen A. H. Bennasir. "Effect of Dietary Fat on Selected Parameters of Toxicity Following 1- or 3-Month Exposure of Rats to Toluidine Isomers." International Journal of Toxicology 24, no. 5 (2005): 365–76. http://dx.doi.org/10.1080/10915810500210138.

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The aim of the study was to investigate the effect of the dietary fat on selected parameters of toluidines toxicity in rats during sub-chronic exposure. Three isomers of toluidine ( ortho, meta, and para) were administered to rats in the diet for 1 and 3 months at levels 40, 80, 160 mg/kg/day in two kinds of diet containing either 4% or 14% fat. All doses of toluidine isomers produced a 1.5- to 9.8-fold increase in methemoglobin (MetHb) level during both treatment periods. A distinct dose-response relationship was observed, especially for o- and m-toluidine; the effect was generally greater in

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2

Brock, Beate, Patricia Fuchs, Svend Kamysek, et al. "Non-Invasive O-Toluidine Monitoring during Regional Anaesthesia with Prilocaine and Detection of Accidental Intravenous Injection in an Animal Model." Metabolites 12, no. 6 (2022): 502. http://dx.doi.org/10.3390/metabo12060502.

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Regional anaesthesia is well established as a standard method in clinical practice. Currently, the local anaesthetics of amino-amide types such as prilocaine are frequently used. Despite routine use, complications due to overdose or accidental intravenous injection can arise. A non-invasive method that can indicate such complications early would be desirable. Breath gas analysis offers great potential for the non-invasive monitoring of drugs and their volatile metabolites. The physicochemical properties of o-toluidine, the main metabolite of prilocaine, allow its detection in breath gas. Withi

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3

Jiang, Yu Ling, Jin Jing Guo, and Hui Zhao. "Preparation and Cavilation Erosion Resistance of High Strength Nanocoating Cylinder Liner." Nano Hybrids and Composites 34 (February 23, 2022): 61–67. http://dx.doi.org/10.4028/p-y7gdd5.

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Using ammonium persulfate as an oxidant and nano-silica as dispersing medium,o-toluidine was oxidized to form a core-shell structure poly (o-toluidine)/nano-SiO2 particle. Investigation of particle yield by ICP-AES method, the adhesion method was used to study the adhesion between coating and cylinder liner. The cavitation resistance of the coating cylinder was studied by the vibration gas cavitation method. The results showed that poly(o-toluidine) was uniformly coated around the nano-silica particles to which forms stable poly (o-toluidine)/nano-SiO2 with core-shell structure, when m(SiO2):m

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4

Yoshioka, Hideki, Toru Nagasawa, Ryoichi Hasegawa, and Hideaki Yamada. "Conversion ofN-acetyl-o-toluidine into 4?-hydroxy-N-acetyl-o-toluidine byFusarium verticillioides." Biotechnology Letters 12, no. 9 (1990): 679–84. http://dx.doi.org/10.1007/bf01088193.

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5

Khan, Asif Ali, and Shakeeba Shaheen. "Preparations and characterizations of poly-o-toluidine/multiwalled carbon nanotubes/Sn(iv) tungstate composite ion exchange thin films and their application as a Pb(ii) selective electrode." RSC Adv. 4, no. 45 (2014): 23456–63. http://dx.doi.org/10.1039/c4ra01594k.

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Poly-o-toluidine (POT), poly-o-toluidine (POT)/multiwalled carbon nanotubes (MWCNTs), and poly-o-toluidine (POT)/multiwalled carbon nanotubes (MWCNTs)/Sn(iv) tungstate (ST) thin films were prepared by a solution casting method using polystyrene as a binder.

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6

Mortimer, Roger J. "Spectroelectrochemistry of electrochromic poly(o–toluidine) and poly(m-toluidine) films." J. Mater. Chem. 5, no. 7 (1995): 969–73. http://dx.doi.org/10.1039/jm9950500969.

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7

Sieńko, Dorota, Dorota Gugała, Jolanta Nieszporek, Joanna Jankowska, and Jadwiga Saba. "Studies of a Mixed Adsorption Layer of Butan-1-ol and o-Toluidine on Mercury Electrode." Collection of Czechoslovak Chemical Communications 67, no. 11 (2002): 1579–88. http://dx.doi.org/10.1135/cccc20021579.

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The results of thermodynamic analysis of o-toluidine adsorption on a mercury electrode in the presence of various butan-1-ol amounts complete our previous studies on properties of mixed adsorption layers of toluidine isomers-butan-1-ol. The values of the relative surface excess Γ'°T obtained for o-toluidine show that adsorption of this compound decreases with increasing of butan-1-ol concentration. Analysis of adsorption parameters derived from the Frumkin isotherm indicates that in the presence of 0.33 M BuOH in 1 M NaClO4 with adjusted pH 3 as supporting electrolyte, ∆G0 values for o-toluidi

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8

John, Honey, Rinku M. Thomas, K. T. Mathew, and Rani Joseph. "Studies on the dielectric properties of poly(o-toluidine) and poly(o-toluidine-aniline) copolymer." Journal of Applied Polymer Science 92, no. 1 (2004): 592–98. http://dx.doi.org/10.1002/app.20044.

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9

Liu, Jing, Xiaohong Wen, Zhanpeng Liu, Yi Tan, Shuangyan Yang, and Ping Zhang. "Electrorheological performances of poly(o-toluidine) and p-toluenesulfonic acid doped poly(o-toluidine) suspensions." Colloid and Polymer Science 293, no. 5 (2015): 1391–400. http://dx.doi.org/10.1007/s00396-015-3523-x.

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10

Pałaszewska-Tkacz, Anna, Anna Świdwińska-Gajewska, and Sławomir Czerczak. "o-Toluidine. Documentation of proposed values of occupational exposure limits (OELs)." Podstawy i Metody Oceny Środowiska Pracy 35, no. 3(97) (2018): 87–127. http://dx.doi.org/10.5604/01.3001.0012.4768.

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o-Toluidine is a substance produced in large amounts and used in rubber, dyeing and pharmaceutical industries and in the production of herbicide and other chemical compounds. The estimated number of people occupationally exposed to o-toluidine in EU is 5500, half of them is employed in chemical industry in the production of chemical fibers and rubber products. In the conditions of occupational exposure, o-toluidine is absorbed by skin and by inhalation. Regardless of route of exposure this compound is excreted in urine. The effects of acute inhalation exposure to high concentrations (>25 mg

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11

Bilal, Salma, and Rudolf Holze. "Electrochemical copolymerization of o-toluidine and o-phenylenediamine." Journal of Electroanalytical Chemistry 592, no. 1 (2006): 1–13. http://dx.doi.org/10.1016/j.jelechem.2006.03.039.

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12

Weber, Elisabeth, Elmar Richter, and Rudolf Holze. "o-Toluidine in electrochemistry – an overview." Journal of Solid State Electrochemistry 26, no. 4 (2022): 1097–114. http://dx.doi.org/10.1007/s10008-022-05128-8.

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AbstractThe substituted aromatic amine o-toluidine (2-methylaniline, 1-amino-2-methylbenzene) is frequently encountered in electrochemical research as a soluble corrosion inhibitor dissolved in aqueous media used e.g., in cooling systems, as a homomonomer for formation of intrinsically conducting poly-o-toluidine and as a comonomer in formation of respective copolymers and their composites. The obtained polymers are suggested as corrosion protection coatings, as active materials in devices for electrochemical energy storage, but more frequently, they are examined as active components in electr

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13

Brink, Alice, Hendrik G. Visser, and Andreas Roodt. "Tetraethylammonium dibromidotricarbonyl(o-toluidine)rhenate(I)." Acta Crystallographica Section E Structure Reports Online 67, no. 1 (2010): m32—m33. http://dx.doi.org/10.1107/s1600536810050038.

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14

Buzarovska, Aleksandra, Irena Arsova, and Ljubomir Arsov. "Electrochemical synthesis of poly(2-methyl aniline): electrochemical and spectroscopic characterization." Journal of the Serbian Chemical Society 66, no. 1 (2001): 27–37. http://dx.doi.org/10.2298/jsc0101027b.

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Poly(2-methyl aniline) or poly(ortho-toluidine), as ring substituted derivative of aniline, has been synthesized electrochemically in various concentrations of H2SO4 and HCl, and then characterized by cyclic voltammetry, as well as by impedance and Raman spectroscopy. The cyclic voltammograms of poly(o-toluidine) and poly(aniline) show that the electrochemical polymerization of these two polymers proceeds by almost identical mechanisms. The Raman spectroscopical measurements suggest that the redox reactions of poly(aniline) and poly(o-toluidine) are similar in the potential range between -0.2

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15

Bedekar, A. G., S. F. Patil, and R. C. Patil. "Comparative Studies of Electrochemically Deposited Poly(o-toluidine) and Poly(m-toluidine) Films." Polymer International 40, no. 3 (1996): 201–5. http://dx.doi.org/10.1002/(sici)1097-0126(199607)40:3<201::aid-pi548>3.0.co;2-0.

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16

ลาภวิบูลย์สุข, จุฑาทิพย์, พัฒน์นิภา วงศ์พิชัย та สมภพ ลาภวิบูลย์สุข. "การตรวจหาปริมาณสารไพมารีอะโรมาติกเอมีนใน วัสดุสัมผัสอาหารด้วยเทคนิคอัลตราไฮเพอร์ฟอร์แมนซ์ลิควิด โครมาโทกราฟี-แทนเดมแมสสเปกโทรเมตรี". วารสารวิทยาศาสตร์ประยุกต์ กรมวิทยาศาสตร์บริการ 13, № 1 (2024): 37–51. http://dx.doi.org/10.60136/bas.v13.2024.1129.

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การตรวจวัดสาร Primary aromatic amines (PAAs) ในวัสดุสัมผัสอาหาร จํานวน 10 ชนิด ได้แก่ Aniline (ANL), o-Anisidine (o-ASD), 4-chloro-aniline (4-CA), 4-chloro-o-toluidine (4-COT), 2,6-dimethylaniline (2,6-DMA), 4,4’-methylenedianiline (4,4’-MDA), 4,4-methylenedi-o-toluidine (4,4’-MDOT), 2-methoxy-5-methylaniline (2-M-5- MA), m-phenylenediamine (m-PDA) และ o-toluidine (o-T) ได้ดําเนินการโดยสกัดสาร PAAs ด้วยสารละลายตัวแทน อาหารเป็นกรดอะซิติก ความเข้มข้นร้อยละ 3 (น้ำหนักต่อปริมาตร) ที่อุณหภูมิ 100 องศาเซลเซียส แล้วทําการตรวจวัด โดยใช้เทคนิคอัลตราไฮเพอร์ฟอร์แมนซ์ลิควิด โครมาโทกราฟี-แทนเดมแมสสเปกโทรเม

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17

Hummer, Denise A. "Cytodiagnosis ofPneumocystis cariniiInfection Using Toluidine Blue O." Laboratory Medicine 19, no. 12 (1988): 821–23. http://dx.doi.org/10.1093/labmed/19.12.821.

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18

Wang, Y. Z., J. Joo, C. H. Hsu, J. P. Pouget, and A. J. Epstein. "Charge delocalization in poly(o-toluidine) fibers." Physical Review B 50, no. 23 (1994): 16811–16. http://dx.doi.org/10.1103/physrevb.50.16811.

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19

Kumar, D. "Poly(o-toluidine) polymer as electrochromic material." European Polymer Journal 37, no. 8 (2001): 1721–25. http://dx.doi.org/10.1016/s0014-3057(01)00018-0.

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20

Bel'skii, V. K., L. A. Chetkina, and V. A. Shuvaeva. "Structure of o-toluidine (C14H16N2). repeated determination." Journal of Structural Chemistry 28, no. 5 (1988): 803–5. http://dx.doi.org/10.1007/bf00752076.

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21

Lakshmi, G. B. V. S., Vazid Ali, Pawan Kulriya, Azher M. Siddiqui, M. Husain, and M. Zulfequar. "Electrical and spectroscopic characterization of p-toluene sulfonic acid doped poly(o-toluidine) and poly(o-toluidine) blends." Physica B: Condensed Matter 392, no. 1-2 (2007): 259–65. http://dx.doi.org/10.1016/j.physb.2006.11.045.

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22

Rajakani, P., and C. Vedhi. "Comparative Study: Synthesis, Characterization, and ORR Activity of Pot and TiO₂-Pot Nanocomposites." ECS Transactions 107, no. 1 (2022): 3945–52. http://dx.doi.org/10.1149/10701.3945ecst.

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o-toluidine was polymerized with the incorporation of different amount of titanium dioxide (TiO2) by chemical oxidation method using potassium perdisulphate as oxidizing agent. Comparative studies were carried out with different nanocomposites of varying compositions of TiO2/PoT against poly-o-toluidine (PoT). The resulting poly-o-toluidine – TiO2 nanocomposites (PoTTNCs) were characterized by UV–Vis and FTIR spectral studies. TiO2 has a deep influence in the crystallinity of PoT chains order in nanocomposite structure as observed in the XRD pattern. Electrochemical characterization studies we

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23

Zhu, Chao, Zarak Mahmood, Abdul Saboor Arshad, Jia Liu, and Hongrui Ma. "Recovery of o-toluidine and p-toluidine from wastewater by silicon rubber membrane extraction." Environmental Technology & Innovation 19 (August 2020): 100873. http://dx.doi.org/10.1016/j.eti.2020.100873.

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24

Zhang, Jiawei, Ying Li, and Sensen Zhang. "Preparation, Characterization and Corrosion Evaluation of Poly(o-toluidine), Poly(m-Toluidine), and Poly(p-Toluidine) Blended with Waterborne Polyurethane." JOM 70, no. 11 (2018): 2660–66. http://dx.doi.org/10.1007/s11837-018-3122-7.

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25

Shaji, S., Shibu M. Eappen, K. P. R. Nair, and T. M. A. Rasheed. "NIR vibrational overtone spectra of toluidines—evidence for steric and electronic effects in o-toluidine." Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy 60, no. 10 (2004): 2275–81. http://dx.doi.org/10.1016/j.saa.2003.11.026.

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26

Tanveer, Nelofar, and M. Mobin. "Corrosion Protection of Carbon Steel by Poly (aniline-co-o-toluidine) and Poly (pyrrole-co-o-toluidine) Copolymer Coatings." Journal of Minerals and Materials Characterization and Engineering 10, no. 08 (2011): 735–53. http://dx.doi.org/10.4236/jmmce.2011.108058.

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27

Dimple, J. S. Yadav, K. C. Singh, and V. K. Sharma. "Molecular interactions in binary mixtures containing o-toluidine." Thermochimica Acta 468, no. 1-2 (2008): 108–15. http://dx.doi.org/10.1016/j.tca.2007.12.006.

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28

Surwade, Sumedh P., Srikanth Rao Agnihotra, Vineet Dua, and Sanjeev K. Manohar. "Nitrogen dioxide vapor detection using poly-o-toluidine." Sensors and Actuators B: Chemical 143, no. 1 (2009): 454–57. http://dx.doi.org/10.1016/j.snb.2009.09.033.

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29

Slater, B. "Superior stain for Helicobacter pylori using toluidine O." Journal of Clinical Pathology 43, no. 11 (1990): 961. http://dx.doi.org/10.1136/jcp.43.11.961-b.

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30

Shinde, Vandana, S. R. Sainkar, and P. P. Patil. "Corrosion protective poly(o-toluidine) coatings on copper." Corrosion Science 47, no. 6 (2005): 1352–69. http://dx.doi.org/10.1016/j.corsci.2004.07.041.

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31

El-Zohary, Salah E., Mohamed A. Shenashen, Ashraf M. Abdel Haleem, Akinori Tsuji, Toshihiro Okamoto, and M. Haraguchi. "Heterojunction of poly (o-toluidine) and silicon nanowires." Journal of Nanophotonics 9, no. 1 (2015): 093093. http://dx.doi.org/10.1117/1.jnp.9.093093.

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32

Bilal, Salma, and Rudolf Holze. "Electrochemical copolymerization of m-toluidine and o-phenylenediamine." Electrochimica Acta 52, no. 3 (2006): 1247–57. http://dx.doi.org/10.1016/j.electacta.2006.07.024.

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33

Sánchez, Aurora, Aída Guzmán, Alma Ortiz, et al. "Toluidine blue-O staining of prion protein deposits." Histochemistry and Cell Biology 116, no. 6 (2001): 519–24. http://dx.doi.org/10.1007/s00418-001-0343-5.

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34

Elmansouri, A., A. Outzourhit, A. Oueriagli, et al. "Spectroscopic Characterization of Electrodeposited Poly(o-toluidine) Thin Films and Electrical Properties of ITO/Poly(o-toluidine)/Aluminum Schottky Diodes." Active and Passive Electronic Components 2007 (2007): 1–7. http://dx.doi.org/10.1155/2007/17846.

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Poly(o-toluidine) (POT) thin films were synthesized by electrochemical polymerization under cyclic voltammetric conditions from o-toluidine monomer in an aqueous solution of HCl as a supporting electrolyte. The electrosynthesized films were characterized by UV-Visible, FT-Raman, and FTIR spectroscopies. The optical transmissions of the as-deposited films were measured in the 400–900 nm wavelength range. These measurements showed that the optical band gap of the polymer films is in the order of 2.52 eV. The FT-Raman and FTIR measurements showed that the POT film is composed of imine and amine u

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35

Bilal, Salma, Anwar-ul-Haq Ali Shah, and Rudolf Holze. "Raman spectroelectrochemical studies of copolymers of o-phenylenediamine and o-toluidine." Vibrational Spectroscopy 53, no. 2 (2010): 279–84. http://dx.doi.org/10.1016/j.vibspec.2010.04.009.

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36

Dr., Prakash Pai G., Apoorva G. Dr., Dayakar MM Dr., and Devipriya B. Nayanar Dr. "Effect of Low-Level Laser of 650nm on Viability of Porphyromonas Gingivalis with and with Out Photosensitizers: An Invitro Study." International Journal of Innovative Science and Research Technology 8, no. 5 (2023): 1689–92. https://doi.org/10.5281/zenodo.7995080.

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Porphyromonas gingivalis is a major pathogen associated with initiation and progression of periodontitis.  Aim and Objective The aim of the study is to compare effect of lowlevel laser of wavelength 650nm on viability of porphyromonas gingivalis with and without photosensitisers.  Methods Thirty samples of bacterial suspensions (200µl) were prepared and divided into six groups .Group 1- laser group (low level laser with wavelength of 650nm, and irradiation time of 30 s), Group 2- Methylene blue + laser group (after pre-irradiation time of 10 min, laser was irradiated), and Group 3- Tol

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37

Leslie, Catherine, Gordon F. Reidy, Michael Murray, and Neill H. Stacey. "Induction of xenobiotic biotransformation by the insecticide chlordimeform, a metabolite 4-chloro-o-toluidine and a structurally related chemical o-toluidine." Biochemical Pharmacology 37, no. 13 (1988): 2529–35. http://dx.doi.org/10.1016/0006-2952(88)90242-0.

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38

Hwang, Jean J., Carlos Soto, Daniel Lafaurie, Moses Stephen, and David M. Sarno. "Porous microspheres of polyaniline, poly(o-toluidine), and poly(m-toluidine) prepared from double emulsions stabilized by toluidine isomers as the single surfactant." Journal of Colloid and Interface Science 513 (March 2018): 331–41. http://dx.doi.org/10.1016/j.jcis.2017.11.029.

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39

Li, Xin, Mei Xiang Wan, and Cong Ju Li. "Synthesis and Characterization of Alkyl-Substituted Polyaniline by Using Ammonium Persulfate as both Oxidant and Dopant." Advanced Materials Research 1096 (April 2015): 147–55. http://dx.doi.org/10.4028/www.scientific.net/amr.1096.147.

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Poly (o-toluidine) (POT), poly (m-toluidine) (PMT) and poly (p-toluidine) (PPT) were chemically oxidized by ammonium persulfate (APS) as both oxidant and dopant through a very simple self-assembly process. The structure characterizations by elemental analysis, XPS and FTIR demonstrated that APS is served as both oxidant and dopant due to the proton acid produced during polymerization, which is proven by the decreasing pH value of the reaction solution along with the increase of polymerization time. Besides, the influences of the alkyl-substitution position on the molecular structure, polymeriz

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40

Okuyama, Katsuhiko, Naohiko Mikami, and Mitsuo Ito. "Internal Rotation of the Methyl Group in the Electronically Excited State: o- and m-Toluidine." Laser Chemistry 7, no. 2-4 (1987): 197–212. http://dx.doi.org/10.1155/lc.7.197.

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The fluorescence excitation and dispersed fluorescence spectra of jet-cooled o- and m-toluidine were observed. Vibrational analysis of the spectra provided us with the potentials for the internal rotation of the CH3 group in both ground and excited states. In o-toluidine, a large potential barrier to the internal rotation in the ground state is practically removed in the excited state. On the other hand, a nearly free internal rotation of the CH3 group in the ground state of m-toluidine gains a large barrier by the electronic excitation. The great change in the barrier height upon the electron

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41

Kumari, Kiran, Vazid Ali, and Rajesh Gupta. "Spectral and Electrical Investigations of Cobalt-octoate Doped Poly (o-Toluidine) Films." Chitkara Chemistry Review 1, no. 1 (2013): 53–65. http://dx.doi.org/10.15415/ccr.2013.11004.

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42

Cappelletti, G., V. Pifferi, S. Mostoni, et al. "Hazardous o-toluidine mineralization by photocatalytic bismuth doped ZnO slurries." Chemical Communications 51, no. 52 (2015): 10459–62. http://dx.doi.org/10.1039/c5cc02620b.

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43

Jodynis-Liebert, J., and M. Murias. "Modulation of antioxidant defence system by dietary fat in rats intoxicated with o-toluidine." Human & Experimental Toxicology 21, no. 12 (2002): 659–65. http://dx.doi.org/10.1191/0960327102ht310oa.

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o-Toluidine was administered to rats in the diet for four weeks at levels approximately 40, 80 and 160 mg/kg b.w. per day. Two types of diet have been used, standard (4% fat) and high fat (14% fat). Activity of antioxidant enzymes, level of glutathione and thiobarbituric acid reactive substances were measured in liver. Glutathione peroxidase was significantly increased in all treated groups while glutathione S-transferase and glutathione reductase were elevated in rats fed high-fat diet. o-Toluidine slightly enhanced catalase activity regardless of the kind of diet. Superoxide dismutase was th

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44

Gafar, S. M., M. A. El-Kelany, M. A. El-Ahdal, and S. R. El-Shawadfy. "Toluidine Blue O-Gelatin Gel Dosimeter for Radiation Processing." Open Journal of Polymer Chemistry 04, no. 03 (2014): 56–61. http://dx.doi.org/10.4236/ojpchem.2014.43007.

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45

Katritzky, Alan R., and Kunihiko Akutagawa. "A PRACTICAL SYNTHETIC METHOD FOR N-METHYL-o-TOLUIDINE." Organic Preparations and Procedures International 21, no. 3 (1989): 340–41. http://dx.doi.org/10.1080/00304948909356389.

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46

Shimizu, H. "Liver dysfunction among workers handling 5-nitro-o-toluidine." Gut 50, no. 2 (2002): 266–70. http://dx.doi.org/10.1136/gut.50.2.266.

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47

Anand, R., R. Maheswari, S. G. Hegde, and B. S. Rao. "Alkylation of o-toluidine with methanol over acidic zeolites." Journal of Molecular Catalysis A: Chemical 192, no. 1-2 (2003): 253–62. http://dx.doi.org/10.1016/s1381-1169(02)00420-x.

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48

Bañón, M. L., V. López, P. Ocón, and P. Herrasti. "Poly(o-toluidine). Deposition of platinum and electrocatalytic applications." Synthetic Metals 48, no. 3 (1992): 355–62. http://dx.doi.org/10.1016/0379-6779(92)90238-e.

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Dubowski, Kurt M. "An o-Toluidine Method for Body-Fluid Glucose Determination." Clinical Chemistry 54, no. 11 (2008): 1919–20. http://dx.doi.org/10.1373/clinchem.2008.104844.

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Ekinci, Ergun. "Preparation and sensor properties of poly ( o -toluidine) film." Polymer Bulletin 42, no. 6 (1999): 693–99. http://dx.doi.org/10.1007/s002890050521.

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