Academic literature on the topic ']octane bis chloride'

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Journal articles on the topic "]octane bis chloride"

1

Salmanpoor, Sadegh, Mahmood Tajbakhsh, Setareh Habibzadeh, Davood Azarifar, and Hassan Ghasemnejad-Bosra. "Chlorination of 3-substituted sydnones using 1,4-dichloro-1,4-diazoniabicyclo[2,2,2]octane bis-chloride." Journal of Chemical Research 2008, no. 11 (2008): 662–63. http://dx.doi.org/10.3184/030823408x375205.

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1,4-Dichloro-1,4-diazoniabicyclo[2,2,2]octane bis-chloride has been used as effective reagent for the chlorination of 3-arylsydnones to their corresponding 4-chloro derivatives in DMF-H2O at room temperature. The 1,4-diazabicyclo [2,2,2]octane was regenerated, rechlorinated and reused several times.
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2

Lahanas, Nicole, Pavel Kucheryavy, Roger A. Lalancette, and Jenny V. Lockard. "Crystallographic identification of a series of manganese porphyrin complexes with nitrogenous bases." Acta Crystallographica Section C Structural Chemistry 75, no. 3 (2019): 304–12. http://dx.doi.org/10.1107/s2053229619001232.

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Studying the axial ligation behavior of metalloporphyrins with nitrogenous bases helps to better understand not only the biological function of heme-based protein systems, but also the catalytic properties of porphyrin-based reaction sites in other biomimetic synthetic support environments. Unlike iron porphyrin complexes, little is known about the axial ligation behavior of Mn porphyrins, particularly in the solid state with Mn in the +3 oxidation state. Here, we present the syntheses and crystal and molecular structures of three new high-spin manganese(III) porphyrin complexes with the diffe
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Li, Qiang, Hui-Ting Wang, and Lin Zhou. "A new three-dimensional CdIIsupramolecular framework constructed from the 1-[(1H-tetrazol-5-yl)methyl]-1,4-diazoniabicyclo[2.2.2]octane ligand." Acta Crystallographica Section C Structural Chemistry 71, no. 2 (2015): 93–96. http://dx.doi.org/10.1107/s2053229614028009.

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A new tetrazole–metal supramolecular compound, di-μ-chlorido-bis(trichlorido{1-[(1H-tetrazol-5-yl-κN2)methyl]-1,4-diazoniabicyclo[2.2.2]octane}cadmium(II)), [Cd2(C8H16N6)2Cl8], has been synthesized and structurally characterized by single-crystal X-ray diffraction. In the structure, each CdIIcation is coordinated by five Cl atoms (two bridging and three terminal) and by one N atom from the 1-[(1H-tetrazol-5-yl)methyl]-1,4-diazoniabicyclo[2.2.2]octane ligand, adopting a slightly distorted octahedral coordination geometry. The bridging bicyclo[2.2.2]octane and chloride ligands link the CdIIcatio
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Tajbakhsh, Mahmood, and Setareh Habibzadeh. "Oxidative deprotection of tetrahydropyranyl and trimethylsilyl ethers in water using 1,4-dichloro-1,4-diazoniabicyclo[2,2,2]octane bis-chloride under neutral conditions." Journal of Chemical Research 2007, no. 7 (2007): 377–80. http://dx.doi.org/10.3184/030823407x218101.

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A facile oxidative deprotection of trimethylsilyl and tetrahydropyranyl ethers in water using 1,4-dichloro-1,4-diazoniabicyclo[2,2,2]octane bis-chloride as a new efficient reagent under neutral conditions is described. This methodology is ecofriendly and environmentally benign since it uses water as a solvent. In all reactions DABCO was regenerated, rechlorinated and reused several times.
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Setareh, Habibzadeh. "1,4-Dichloro-1,4-diazoniabicyclo[2,2,2]octane bis chloride a new and efficient catalyst for the synthesis of 14-aryl-14H-dibenzo[a,j]xanthenes in water as solvent." Journal of Indian Chemical Society Vol. 91, Jul 2014 (2014): 1341–45. https://doi.org/10.5281/zenodo.5726441.

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Babol University of Technology, Babol, Iran <em>E-mail </em>: habibzadeh@nit.ac.ir Fax : 98-111-3234203 <em>Manuscript received online 16 August 2013, revised 03 February 2014, accepted 24 February 2014</em> A new and green procedure for the synthesis of 14-aryl-14<em>H</em>-dibenzo[a,j]xanthenes through one-pot condensation of naphthalen-2-ol with benzaldehydes in the presence of 1,4-dichloro-1,4-diazoniabicyclo[2,2,2]octane bis chloride as catalyst in water as a solvent is described.
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Hou, Xue-Li, and Hui-Ting Wang. "Two different one-dimensional CdIIhalide coordination polymers constructed through bridging carboxylate ligands." Acta Crystallographica Section C Structural Chemistry 71, no. 11 (2015): 979–84. http://dx.doi.org/10.1107/s2053229615018264.

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Two cadmium halide complexes,catena-poly[[chloridocadmium(II)]-di-μ-chlorido-[chloridocadmium(II)]-bis[μ2-4-(dimethylamino)pyridin-1-ium-1-acetate]-κ3O:O,O′;κ3O,O′:O], [CdCl2(C9H12N2O2)]n, (I), andcatena-poly[1-cyanomethyl-1,4-diazoniabicyclo[2.2.2]octane [[dichloridocadmium(II)]-μ-oxalato-κ4O1,O2:O1′,O2′] monohydrate], {(C8H15N3)[CdCl2(C2O4)]·H2O}n, (II), were synthesized in aqueous solution. In (I), the CdIIcation is octahedrally coordinated by three O atoms from two carboxylate groups and by one terminal and two bridging chloride ligands. Neighbouring CdIIcations are linked together by chlo
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7

Noroozizadeh, Ehsan, Ahmad Reza Moosavi-Zare, Mohammad Ali Zolfigol, Abdolkarim Zare, and Mahmoud Zarei. "Friedel–Crafts alkylation of 4-hydroxycoumarin over silica-bonded 1,4-diaza-bicyclo[2.2.2] octane-sulfonic acid chloride as nanostructured heterogeneous catalyst." Canadian Journal of Chemistry 95, no. 1 (2017): 16–21. http://dx.doi.org/10.1139/cjc-2016-0258.

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A novel nanostructured heterogeneous catalyst, namely silica-bonded 1,4-diaza-bicyclo[2.2.2]octane-sulfonic acid chloride (SBDBSAC), has been synthesized and fully characterized by several techniques, including Fourier transform infrared spectroscopy (FTIR), X-ray diffraction (XRD), thermal gravimetric analysis (TGA), differential thermal gravimetric (DTG), scanning electron microscope (SEM), and energy dispersive X-ray analysis (EDX). Afterward, the nanostructured catalyst was utilized as an efficient catalyst for the synthesis of bis-coumarin derivatives by the condensation reaction of aryla
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8

Zhou, Qin-Qin, Lei Jin, Wei-Qiang Liao та Yi Zhang. "A potential molecular ferroelectric material: poly[[bis(1-aza-4-azoniabicyclo[2.2.2]octane)di-μ3-chlorido-tetra-μ2-chlorido-dichloridotricadmium(II)] dihydrate]". Acta Crystallographica Section C Crystal Structure Communications 69, № 3 (2013): 237–40. http://dx.doi.org/10.1107/s0108270113003892.

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The title compound, {[Cd3(C6H13N2)2Cl8]·2H2O}n, consists of pendant protonated cationic diamine ligands bonded to an anionic one-dimensional coordination polymer chloridocadmate scaffold. Each coordination chain features two kinds of CdIIcentre, each with distorted octahedral coordination geometry. One CdIIcation lies on a centre of inversion and is coordinated by six bridging chloride ligands, while the other is coordinated by four bridging chloride ligands, one terminal chloride ligand and a 1-aza-4-azoniabicyclo[2.2.2]octane aza N atom. This gives a reversible corner-sharing half-cubic line
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9

Tajbakhsh, Mahmood, and Setareh Habibzadeh. "1,4-Dichloro-1,4-Diazoniabicyclo [2,2,2] Octane Bis Chloride, a Useful and Reusable Electrophilic Chlorinating Agent." Letters in Organic Chemistry 4, no. 7 (2007): 512–14. http://dx.doi.org/10.2174/157017807782006344.

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10

Sumii, Sasaki, Tsuzuki, and Shibata. "Studies of Halogen Bonding Induced by Pentafluorosulfanyl Aryl Iodides: A Potential Group of Halogen Bond Donors in a Rational Drug Design." Molecules 24, no. 19 (2019): 3610. http://dx.doi.org/10.3390/molecules24193610.

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The activation of halogen bonding by the substitution of the pentafluoro-λ6-sulfanyl (SF5) group was studied using a series of SF5-substituted iodobenzenes. The simulated electrostatic potential values of SF5-substituted iodobenzenes, the ab initio molecular orbital calculations of intermolecular interactions of SF5-substituted iodobenzenes with pyridine, and the 13C-NMR titration experiments of SF5-substituted iodobenzenes in the presence of pyridine or tetra (n-butyl) ammonium chloride (TBAC) indicated the obvious activation of halogen bonding, although this was highly dependent on the posit
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