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Journal articles on the topic ']octane bis chloride'

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Published: 5 June 2025

Last updated: 1 August 2025

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1

Salmanpoor, Sadegh, Mahmood Tajbakhsh, Setareh Habibzadeh, Davood Azarifar, and Hassan Ghasemnejad-Bosra. "Chlorination of 3-substituted sydnones using 1,4-dichloro-1,4-diazoniabicyclo[2,2,2]octane bis-chloride." Journal of Chemical Research 2008, no. 11 (2008): 662–63. http://dx.doi.org/10.3184/030823408x375205.

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1,4-Dichloro-1,4-diazoniabicyclo[2,2,2]octane bis-chloride has been used as effective reagent for the chlorination of 3-arylsydnones to their corresponding 4-chloro derivatives in DMF-H2O at room temperature. The 1,4-diazabicyclo [2,2,2]octane was regenerated, rechlorinated and reused several times.

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2

Lahanas, Nicole, Pavel Kucheryavy, Roger A. Lalancette, and Jenny V. Lockard. "Crystallographic identification of a series of manganese porphyrin complexes with nitrogenous bases." Acta Crystallographica Section C Structural Chemistry 75, no. 3 (2019): 304–12. http://dx.doi.org/10.1107/s2053229619001232.

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Studying the axial ligation behavior of metalloporphyrins with nitrogenous bases helps to better understand not only the biological function of heme-based protein systems, but also the catalytic properties of porphyrin-based reaction sites in other biomimetic synthetic support environments. Unlike iron porphyrin complexes, little is known about the axial ligation behavior of Mn porphyrins, particularly in the solid state with Mn in the +3 oxidation state. Here, we present the syntheses and crystal and molecular structures of three new high-spin manganese(III) porphyrin complexes with the diffe

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3

Li, Qiang, Hui-Ting Wang, and Lin Zhou. "A new three-dimensional CdIIsupramolecular framework constructed from the 1-[(1H-tetrazol-5-yl)methyl]-1,4-diazoniabicyclo[2.2.2]octane ligand." Acta Crystallographica Section C Structural Chemistry 71, no. 2 (2015): 93–96. http://dx.doi.org/10.1107/s2053229614028009.

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A new tetrazole–metal supramolecular compound, di-μ-chlorido-bis(trichlorido{1-[(1H-tetrazol-5-yl-κN2)methyl]-1,4-diazoniabicyclo[2.2.2]octane}cadmium(II)), [Cd2(C8H16N6)2Cl8], has been synthesized and structurally characterized by single-crystal X-ray diffraction. In the structure, each CdIIcation is coordinated by five Cl atoms (two bridging and three terminal) and by one N atom from the 1-[(1H-tetrazol-5-yl)methyl]-1,4-diazoniabicyclo[2.2.2]octane ligand, adopting a slightly distorted octahedral coordination geometry. The bridging bicyclo[2.2.2]octane and chloride ligands link the CdIIcatio

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4

Tajbakhsh, Mahmood, and Setareh Habibzadeh. "Oxidative deprotection of tetrahydropyranyl and trimethylsilyl ethers in water using 1,4-dichloro-1,4-diazoniabicyclo[2,2,2]octane bis-chloride under neutral conditions." Journal of Chemical Research 2007, no. 7 (2007): 377–80. http://dx.doi.org/10.3184/030823407x218101.

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A facile oxidative deprotection of trimethylsilyl and tetrahydropyranyl ethers in water using 1,4-dichloro-1,4-diazoniabicyclo[2,2,2]octane bis-chloride as a new efficient reagent under neutral conditions is described. This methodology is ecofriendly and environmentally benign since it uses water as a solvent. In all reactions DABCO was regenerated, rechlorinated and reused several times.

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5

Setareh, Habibzadeh. "1,4-Dichloro-1,4-diazoniabicyclo[2,2,2]octane bis chloride a new and efficient catalyst for the synthesis of 14-aryl-14H-dibenzo[a,j]xanthenes in water as solvent." Journal of Indian Chemical Society Vol. 91, Jul 2014 (2014): 1341–45. https://doi.org/10.5281/zenodo.5726441.

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Babol University of Technology, Babol, Iran <em>E-mail </em>: habibzadeh@nit.ac.ir Fax : 98-111-3234203 <em>Manuscript received online 16 August 2013, revised 03 February 2014, accepted 24 February 2014</em> A new and green procedure for the synthesis of 14-aryl-14<em>H</em>-dibenzo[a,j]xanthenes through one-pot condensation of naphthalen-2-ol with benzaldehydes in the presence of 1,4-dichloro-1,4-diazoniabicyclo[2,2,2]octane bis chloride as catalyst in water as a solvent is described.

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6

Hou, Xue-Li, and Hui-Ting Wang. "Two different one-dimensional CdIIhalide coordination polymers constructed through bridging carboxylate ligands." Acta Crystallographica Section C Structural Chemistry 71, no. 11 (2015): 979–84. http://dx.doi.org/10.1107/s2053229615018264.

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Two cadmium halide complexes,catena-poly[[chloridocadmium(II)]-di-μ-chlorido-[chloridocadmium(II)]-bis[μ2-4-(dimethylamino)pyridin-1-ium-1-acetate]-κ3O:O,O′;κ3O,O′:O], [CdCl2(C9H12N2O2)]n, (I), andcatena-poly[1-cyanomethyl-1,4-diazoniabicyclo[2.2.2]octane [[dichloridocadmium(II)]-μ-oxalato-κ4O1,O2:O1′,O2′] monohydrate], {(C8H15N3)[CdCl2(C2O4)]·H2O}n, (II), were synthesized in aqueous solution. In (I), the CdIIcation is octahedrally coordinated by three O atoms from two carboxylate groups and by one terminal and two bridging chloride ligands. Neighbouring CdIIcations are linked together by chlo

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7

Noroozizadeh, Ehsan, Ahmad Reza Moosavi-Zare, Mohammad Ali Zolfigol, Abdolkarim Zare, and Mahmoud Zarei. "Friedel–Crafts alkylation of 4-hydroxycoumarin over silica-bonded 1,4-diaza-bicyclo[2.2.2] octane-sulfonic acid chloride as nanostructured heterogeneous catalyst." Canadian Journal of Chemistry 95, no. 1 (2017): 16–21. http://dx.doi.org/10.1139/cjc-2016-0258.

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A novel nanostructured heterogeneous catalyst, namely silica-bonded 1,4-diaza-bicyclo[2.2.2]octane-sulfonic acid chloride (SBDBSAC), has been synthesized and fully characterized by several techniques, including Fourier transform infrared spectroscopy (FTIR), X-ray diffraction (XRD), thermal gravimetric analysis (TGA), differential thermal gravimetric (DTG), scanning electron microscope (SEM), and energy dispersive X-ray analysis (EDX). Afterward, the nanostructured catalyst was utilized as an efficient catalyst for the synthesis of bis-coumarin derivatives by the condensation reaction of aryla

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8

Zhou, Qin-Qin, Lei Jin, Wei-Qiang Liao та Yi Zhang. "A potential molecular ferroelectric material: poly[[bis(1-aza-4-azoniabicyclo[2.2.2]octane)di-μ3-chlorido-tetra-μ2-chlorido-dichloridotricadmium(II)] dihydrate]". Acta Crystallographica Section C Crystal Structure Communications 69, № 3 (2013): 237–40. http://dx.doi.org/10.1107/s0108270113003892.

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The title compound, {[Cd3(C6H13N2)2Cl8]·2H2O}n, consists of pendant protonated cationic diamine ligands bonded to an anionic one-dimensional coordination polymer chloridocadmate scaffold. Each coordination chain features two kinds of CdIIcentre, each with distorted octahedral coordination geometry. One CdIIcation lies on a centre of inversion and is coordinated by six bridging chloride ligands, while the other is coordinated by four bridging chloride ligands, one terminal chloride ligand and a 1-aza-4-azoniabicyclo[2.2.2]octane aza N atom. This gives a reversible corner-sharing half-cubic line

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9

Tajbakhsh, Mahmood, and Setareh Habibzadeh. "1,4-Dichloro-1,4-Diazoniabicyclo [2,2,2] Octane Bis Chloride, a Useful and Reusable Electrophilic Chlorinating Agent." Letters in Organic Chemistry 4, no. 7 (2007): 512–14. http://dx.doi.org/10.2174/157017807782006344.

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10

Sumii, Sasaki, Tsuzuki, and Shibata. "Studies of Halogen Bonding Induced by Pentafluorosulfanyl Aryl Iodides: A Potential Group of Halogen Bond Donors in a Rational Drug Design." Molecules 24, no. 19 (2019): 3610. http://dx.doi.org/10.3390/molecules24193610.

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The activation of halogen bonding by the substitution of the pentafluoro-λ6-sulfanyl (SF5) group was studied using a series of SF5-substituted iodobenzenes. The simulated electrostatic potential values of SF5-substituted iodobenzenes, the ab initio molecular orbital calculations of intermolecular interactions of SF5-substituted iodobenzenes with pyridine, and the 13C-NMR titration experiments of SF5-substituted iodobenzenes in the presence of pyridine or tetra (n-butyl) ammonium chloride (TBAC) indicated the obvious activation of halogen bonding, although this was highly dependent on the posit

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11

Cefalì, Federica, Anna Iuliano, Federica Balzano, Gloria Uccello Barretta, Valerio Zullo, and Carlo Baldassari. "Isohexide-Based Tunable Chiral Platforms as Amide- and Thiourea-Chiral Solvating Agents for the NMR Enantiodiscrimination of Derivatized Amino Acids." Molecules 29, no. 6 (2024): 1307. http://dx.doi.org/10.3390/molecules29061307.

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New arylamide- and arylthiourea-based chiral solvating agents (CSAs) were synthesized starting from commercially available isomannide and isosorbide. The two natural isohexides were transformed into the three amino derivatives, having isomannide, isosorbide, and isoidide stereochemistry, then the amino groups were derivatized with 3,5-dimethoxybenzoyl chloride or 3,5-bis(trifluoromethyl)phenyl isothiocyanate to obtain the CSAs. Bis-thiourea derivative containing the 3,5-bis(trifluoromethyl)phenyl moiety with exo–exo stereochemistry was remarkably efficient in the differentiation of NMR signals

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12

Hintermann, Lukas, Mauro Perseghini та Antonio Togni. "Development of the titanium–TADDOLate-catalyzed asymmetric fluorination of β-ketoesters". Beilstein Journal of Organic Chemistry 7 (17 жовтня 2011): 1421–35. http://dx.doi.org/10.3762/bjoc.7.166.

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Titanium-based Lewis acids catalyze the α-fluorination of β-ketoesters by electrophilic N–F-fluorinating reagents. Asymmetric catalysis with TADDOLato–titanium(IV) dichloride (TADDOL = α,α,α',α'-tetraaryl-(1,3-dioxolane-4,5-diyl)-dimethanol) Lewis acids produces enantiomerically enriched α-fluorinated β-ketoesters in up to 91% enantiomeric excess, with either F–TEDA (1-chloromethyl-4-fluoro-1,4-diazoniabicyclo[2.2.2]octane bis(tetrafluoroborate)) in acetonitrile solution or NFSI (N-fluorobenzenesulfonimide) in dichloromethane solution as fluorinating reagents. The effects of various reaction p

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13

Habibzadeh, Setareh, and Mahmood Tajbakhsh. "Oxidation of alkyl benzenes to corresponding carbonyl compounds with 1,4-dichloro-1,4-diazoniabicyclo [2,2,2] octane bis-chloride in water." Journal of Chemical Research 2009, no. 11 (2009): 696–98. http://dx.doi.org/10.3184/030823409x12561451265580.

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14

Yang, Qiuqing, Qiong Zhou та P. Somasundaran. "Mixed micelles of octane-1,8 bis(dodecyl dimethyl ammonium chloride) and n-dodecyl-β-d-maltoside by 1H NMR study". Colloids and Surfaces A: Physicochemical and Engineering Aspects 305, № 1-3 (2007): 22–28. http://dx.doi.org/10.1016/j.colsurfa.2007.04.050.

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15

Tajbakhsh, Mahmood, and Setareh Habibzadeh. "Oxidative deprotection of tetrahydropyranyl and trimethylsilyl ethers in water using 1,4-dichloro-1,4-diazoniabicyclo[2,2,2]octane bis-chloride under neutral conditions." Journal of Chemical Research 2007, no. 5 (2007): 259–62. http://dx.doi.org/10.3184/030823407x209723.

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16

Chouri, Marwen, та Habib Boughzala. "Crystal structure of the new hybrid material bis(1,4-diazoniabicyclo[2.2.2]octane) di-μ-chlorido-bis[tetrachloridobismuthate(III)] dihydrate". Acta Crystallographica Section E Crystallographic Communications 71, № 11 (2015): 1384–87. http://dx.doi.org/10.1107/s2056989015019933.

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The title compound bis(1,4-diazoniabicyclo[2.2.2]octane) di-μ-chlorido-bis[tetrachloridobismuthate(III)] dihydrate, (C6H14N2)2[Bi2Cl10]·2H2O, was obtained by slow evaporation at room temperature of a hydrochloric aqueous solution (pH = 1) containing bismuth(III) nitrate and 1,4-diazabicyclo[2.2.2]octane (DABCO) in a 1:2 molar ratio. The structure displays a two-dimensional arrangement parallel to (100) of isolated [Bi2Cl10]4−bioctahedra (site symmetry -1) separated by layers of organic 1,4-diazoniabicyclo[2.2.2]octane dications [(DABCOH2)2+] and water molecules. O—H...Cl, N—H...O and N—H...Cl

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17

Habibzadeh, Setareh. "ChemInform Abstract: 1,4-Dichloro-1,4-diazoniabicyclo[2,2,2]octane Bis Chloride - A New and Efficient Catalyst for the Synthesis of 14-Aryl-14H-dibenzo[a,j]xanthenes in Water as Solvent." ChemInform 46, no. 10 (2015): no. http://dx.doi.org/10.1002/chin.201510191.

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18

Ben Rhaiem, Tarek, and Habib Boughzala. "Crystal structure of a new hybrid antimony–halide-based compound for possible non-linear optical applications." Acta Crystallographica Section E Crystallographic Communications 71, no. 5 (2015): 498–501. http://dx.doi.org/10.1107/s2056989015007379.

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The hybrid title compound,catena-poly[[[bis(1,4-diazoniabicyclo[2.2.2]octane) [tetraachloridoantimonate(III)]-μ-chlorido-[tetrachloridoantimonate(III)]-μ-chlorido]] monohydrate], {(C6H14N2)2[Sb2Cl10]·H2O}n, is self-assembled into alternating organic and inorganic layers parallel to thebcplane. The anionic inorganic layer consists of infinite zigzag chains of corner-sharing [SbCl6]3−octahedra running along thebaxis. The organic part is made up of 1,4-diazoniabicyclo[2.2.2]octane dications (dabcoH22+). The water molecules in the structure connect inorganic and organic layers. Hydrogen-bonding in

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19

Connor, Atkinson. "1-hexenes & 1-octenes Industrial Catalysis for Polymerization: A Brief Literature Review." Chemistry Research Journal 9, no. 2 (2024): 114–20. https://doi.org/10.5281/zenodo.11282296.

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<strong>Abstract </strong> 1-hexenes and 1-octenes are in growing demand, for the production of LLDPE and LDPE. Selective 1-hexene and 1-octene production is assessed via the catalyst/ligand design of Bis(imino) pyridine-chromium(III) chloride and chromium–bis(diarylphosphino)amine catalyst systems. 1-butene, 1-hexene, 1-octene and Polyethylene yields are reported and compared. Proposing the relative stability of 5-, 7-, and 9-member rings and the relative rates of competing processes such as alkene insertion or β-H elimination, control selectivity, with catalyst selection and their

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20

Ben Rhaiem, Tarek, Habib Boughzala та Ahmed Driss. "Bis(1,4-diazoniabicyclo[2.2.2]octane) di-μ-chlorido-bis[tetrachloridoantimonate(III)] dihydrate". Acta Crystallographica Section E Structure Reports Online 69, № 6 (2013): m330. http://dx.doi.org/10.1107/s160053681301307x.

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21

Khan, Muhammad S., Nawal K. Al-Rasbi, Edwin C. Constable, Adrian R. Dale, and Jack Lewis. "Derivatized Pentadentate Macrocyclic Ligands and Their Transition Metal Complexes." Sultan Qaboos University Journal for Science [SQUJS] 7, no. 2 (2002): 241. http://dx.doi.org/10.24200/squjs.vol7iss2pp241-249.

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The reaction of the pendant hydroxyethyl group in the planar pentadentate macrocyclic ligand,1,11-bis(2’-hydroxyethyl)-4,8;12,16;17,21-trinitrilo-1,2,10,11-tetraazacyclohenicosa- 2,4,6,9,12,14,18,20-octaene (L2), derived from the condensation of 2,6-pyridinedialdehyde with 6,6’-bis(2’ hydroxyethylhydrazino) -2,2’-bipyridine (L1), has been investigated. Esterification reactions are facile, and the reaction of the hydroxyethyl-substituted macrocycle with thionyl chloride yields a chloroethyl derivative. Metal complexes of the new derivatized macrocyclic ligands L3-6having general formula ML3-6X2

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22

(Miss), Megha K. Burghate, K. Burghate S., and N. Berad B. "Synthesis of novel bis-1,3,4-thiadiazoles, bis-1,2,4-triazoles and their antimicrobial activity." Journal of Indian Chemical Society Vol. 85, May 2008 (2008): 561–65. https://doi.org/10.5281/zenodo.5816535.

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P. G. Department of Chemistry, Shri Shivaji Science College, Amravati-444 603, Maharashtra, India <em>E-mail :</em> meghaburghate@rediffmail.com <em>Manuscript received 12 February 2007, revised 7 January 2008, accepted 6 March 2008</em> Condensation of sehacic acid dihydrazide (1) with aryl/alkyl isothiocyanates (2a-g) gives bis-(<em>N</em>-aryl/alkylthiocarbamido)-sebacic acid diamidcs (3a-g), which on reaction with <em>o</em>-phosphoric acid yields 1 ,8-bis-(2-aryl/alkylamino1,3,4-thiadiazol-5-yl)-octanes (4a-g). 1,8-Bis-(3-mcrcapto-4-aryl/alkyl-1,2,4-triazol-5-yl)-octanes (5a-g) were obtai

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23

Savard, Jacques, and Howard Alper. "Air-stable binuclear alkoxytungsten complexes as catalyst precursors for olefin metathesis." Canadian Journal of Chemistry 66, no. 10 (1988): 2483–86. http://dx.doi.org/10.1139/v88-390.

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The use of the air-stable complexes tetrachlorobis(μ-methoxy)bis(methanolo)dimethoxyditungsten (1) and tetrachlorobis(μ-ethoxy) tetraethoxyditungsten (2) as catalyst precursors for the metathesis of 1-octene is described. Using mild conditions, the latter was converted to 7-tetradecene (4) in fair yields when diethylaluminum chloride (3) was used as a cocatalyst. Product stereoselectivity was 4/1 in favor of the trans isomer. The reaction was also shown to be efficient for the production of 2-nonenes.

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24

Alinezhad, Heshmatollah, Mahmood Tajbakhsh, and Fatemeh Salehian. "Reduction of acid chlorides using dichloro bis[(1,4-diaza bicyclo [2.2.2] octane) bis(tetrahydroborato)] zirconium (IV)." Journal of Chemical Research 2004, no. 12 (2004): 814–15. http://dx.doi.org/10.3184/0308234043431249.

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25

Yan, Jing-Jing, Qi-Jian Pan та Li-Zhuang Chen. "Crystal structure of di-μ2-chlorido-bis[(1-aza-4-azoniabicyclo[2.2.2]octane-κN1)dichloridodicadmium]". Acta Crystallographica Section E Crystallographic Communications 71, № 12 (2015): m259—m260. http://dx.doi.org/10.1107/s2056989015023361.

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In the structure of the binuclear title compound, [Cd2(C6H13N2)2Cl6], two CdIIatoms are bridged by two Cl−ligands, defining a centrosymmetric Cd2Cl2motif. Each metal cation is additionally coordinated by two Cl−ligands and the N atom of a protonated 1,4-diazabicyclo[2.2.2]octane (H-DABCO)+ligand, leading to an overall trigonal–bipyramidal coordination environment with one of the bridging Cl−ligands and the N atom at the apical sites. In the crystal, the neutral dimers are linkedviaN—H...Cl hydrogen bonds, forming a two-dimensional network expanding parallel to (100).

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26

Chen, Changfu, Xingxing Zhang, Chenfei Ren, et al. "Synthesis and Photocatalytic Performance of Five Organic–Inorganic Hybrid Supramolecules with Chain-like Organic Cations for Tetracycline Degradation." Molecules 30, no. 4 (2025): 817. https://doi.org/10.3390/molecules30040817.

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In this paper, we synthesized a chain-like organic cation structure directing agent L·Cl2 by reacting triethylenediamine with 1,2-bis(2-chloroethoxy)ethane. We then used a room temperature volatilization method to react L·Cl2 with inorganic metal salts to synthesize five organic–inorganic hybrid supramolecules: {[L][HgI4]} (1), {[L][CdI4]} (2), {[(L)(Cu2I3)]·[CuI2]CH3CN}n (3) {[L][CoCl3]2} (4), and {[L][Ce(NO3)5·(H2O)2]} (5) (L=1,1′-((ethane-1,2-diylbis(oxy))bis(ethane-2,1-diyl))bis(1,4-diazabicyclo [2.2.2]octan-1-ium) chloride). The compounds were characterized by X-ray diffraction, infrared

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Xiao, Jing-Mei. "catena-Poly[bis[1-chloromethyl-1,4-diazoniabicyclo[2.2.2]octane] [cadmium(II)-tri-μ-chlorido-[chloridocadmium(II)]-di-μ-chlorido-[chloridocadmium(II)]-tri-μ-chlorido] tetrahydrate]". Acta Crystallographica Section C Crystal Structure Communications 66, № 11 (2010): m348—m350. http://dx.doi.org/10.1107/s0108270110040813.

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28

Tajbakhsh, Mahmood, and Setareh Habibzadeh. "Bis(chlorine)-1,4-diazabicyclo[2.2.2]octane: a novel and reusable oxidising agent for conversion of alcohols into their carbonyl compounds under microwave irradiation." Journal of Chemical Research 2006, no. 8 (2006): 539–41. http://dx.doi.org/10.3184/030823406778256487.

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Azarifar, Davood, Hassan Ghasemnejad-Bosra, Mahmood Tajbaksh, and Setareh Habibzadeh. "One-Pot Conversion of N-Arylglycines to Sydnones Efficiently Promoted by Bis-chlorine-1,4-diazabicyclo[2.2.2]octane Complex (Cl2-DABCO) in the Presence of NaNO2/Ac2O under Neutral Conditions." HETEROCYCLES 71, no. 8 (2007): 1815. http://dx.doi.org/10.3987/com-07-11033.

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Salmanpoor, Sadegh, Mahmood Tajbakhsh, Setareh Habibzadeh, Davood Azarifar, and Hassan Ghasemnejad-Bosra. "ChemInform Abstract: Chlorination of 3-Substituted Sydnones Using 1,4-Dichloro-1,4-diazoniabicyclo[2,2,2]octane Bis-Chloride." ChemInform 40, no. 15 (2009). http://dx.doi.org/10.1002/chin.200915134.

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Tajbakhsh, Mahmood, and Setareh Habibzadeh. "ChemInform Abstract: 1,4-Dichloro-1,4-diazoniabicyclo [2,2,2] Octane Bis Chloride, a Useful and Reusable Electrophilic Chlorinating Agent." ChemInform 39, no. 9 (2008). http://dx.doi.org/10.1002/chin.200809046.

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Tajbakhsh, Mahmood, and Setareh Habibzadeh. "Oxidative Deprotection of Tetrahydropyranyl and Trimethylsilyl Ethers in Water Using 1,4-Dichloro-1,4-diazoniabicyclo[2,2,2]octane Bis-chloride under Neutral Conditions." ChemInform 38, no. 47 (2007). http://dx.doi.org/10.1002/chin.200747053.

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Tajbakhsh, Mahmood, and Setareh Habibzadeh. "ChemInform Abstract: Oxidative Deprotection of Tetrahydropyranyl and Trimethylsilyl Ethers in Water Using 1,4-Dichloro-1,4-diazoniabicyclo[2,2,2]octane Bis-Chloride under Neutral Conditions." ChemInform 39, no. 3 (2008). http://dx.doi.org/10.1002/chin.200803037.

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34

Alinezhad, Heshmatollah, Mahmood Tajbakhsh, and Fatemeh Salehian. "Reduction of Acid Chlorides Using Dichloro Bis[(1,4-diazabicyclo[2.2.2]octane)bis(tetrahydroborato)] Zirconium(IV)." ChemInform 36, no. 24 (2005). http://dx.doi.org/10.1002/chin.200524083.

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35

"Developing Catalytic Enantioselective Fluorination." CHIMIA 55, no. 10 (2001): 801. http://dx.doi.org/10.2533/chimia.2001.801.

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The background that led to the development ofthe first catalytic and enantioselective carbon-fluorine bond-forming reaction is presented. Two different approaches, i.e. the use of nucleophilic and electrophilic fluorinating agents, respectively, have been pursued. Well-defined RU(II) 16-electron systems of the type [RuF(PP)2]+ (where PP is a chelating diphosphine), as well as analogous complexes containing tetradentate PNNP ligands, were found to catalyze the halogen exchange reaction of activated alkyl chlorides, bromides, and iodides in the presence of TIF as the fluorine source. Isolable cr

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Tajbakhsh, Mahmood, and Setareh Habibzadeh. "Bis(chlorine)-1,4-diazabicyclo[2.2.2]octane: A Novel and Reusable Oxidizing Agent for Conversion of Alcohols into Their Carbonyl Compounds under Microwave Irradiation." ChemInform 38, no. 3 (2007). http://dx.doi.org/10.1002/chin.200703042.

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Azarifar, Davood, Hassan Ghasemnejad-Bosra, Mahmood Tajbaksh, and Setareh Habibizadeh. "One-Pot Conversion of N-Arylglycines to Sydnones Efficiently Promoted by Bis-chlorine-1,4-diazabicyclo[2.2.2]octane Complex Cl2-DABCO in the Presence of NaNO2/Ac2O under Neutral Condition." ChemInform 38, no. 48 (2007). http://dx.doi.org/10.1002/chin.200748123.

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