Academic literature on the topic 'Organic electron donors (OEDs)'

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Journal articles on the topic "Organic electron donors (OEDs)"

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Cha, Judy J. "Intercalation and Functionalization in 2D Materials." ECS Meeting Abstracts MA2023-01, no. 13 (2023): 1306. http://dx.doi.org/10.1149/ma2023-01131306mtgabs.

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The large surface areas and interlayer gaps of 2D materials enable surface functionalization and intercalation as effective post-synthesis design knobs to tune the properties of 2D materials using ions, atoms, and organic molecules. For complete engineering control, detailed understanding of the interactions between the 2D materials and the molecules adsorbed on 2D materials surface or between the 2D materials and the intercalants is necessary. I will first discuss surface functionalization to tune the electrical properties of 2D materials. We developed an experimental approach to quantitative
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Murphy, John A. "ChemInform Abstract: Organic Electron Donors." ChemInform 43, no. 37 (2012): no. http://dx.doi.org/10.1002/chin.201237244.

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Broggi, Julie, Marion Rollet, Jean-Louis Clément, et al. "Polymerization Initiated by Organic Electron Donors." Angewandte Chemie International Edition 55, no. 20 (2016): 5994–99. http://dx.doi.org/10.1002/anie.201600327.

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Broggi, Julie, Marion Rollet, Jean-Louis Clément, et al. "Polymerization Initiated by Organic Electron Donors." Angewandte Chemie 128, no. 20 (2016): 6098–103. http://dx.doi.org/10.1002/ange.201600327.

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Broggi, Julie, Thierry Terme, and Patrice Vanelle. "Organic Electron Donors as Powerful Single-Electron Reducing Agents in Organic Synthesis." Angewandte Chemie International Edition 53, no. 2 (2013): 384–413. http://dx.doi.org/10.1002/anie.201209060.

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Zhou, Shengze, Hardeep Farwaha, and John A. Murphy. "The Development of Organic Super Electron Donors." CHIMIA International Journal for Chemistry 66, no. 6 (2012): 418–24. http://dx.doi.org/10.2533/chimia.2012.418.

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Rohrbach, Simon, Rushabh S. Shah, Tell Tuttle, and John A. Murphy. "Neutral Organic Super Electron Donors Made Catalytic." Angewandte Chemie International Edition 58, no. 33 (2019): 11454–58. http://dx.doi.org/10.1002/anie.201905814.

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Lowe, Grace A. "Enabling artificial photosynthesis systems with molecular recycling: A review of photo- and electrochemical methods for regenerating organic sacrificial electron donors." Beilstein Journal of Organic Chemistry 19 (August 8, 2023): 1198–215. http://dx.doi.org/10.3762/bjoc.19.88.

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This review surveys advances in the literature that impact organic sacrificial electron donor recycling in artificial photosynthesis. Systems for photocatalytic carbon dioxide reduction are optimized using sacrificial electron donors. One strategy for coupling carbon dioxide reduction and water oxidation to achieve artificial photosynthesis is to use a redox mediator, or recyclable electron donor. This review highlights photo- and electrochemical methods for recycling amines and NADH analogues that can be used as electron donors in artificial photosynthesis. Important properties of sacrificial
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Murphy, John A. "Discovery and Development of Organic Super-Electron-Donors." Journal of Organic Chemistry 79, no. 9 (2014): 3731–46. http://dx.doi.org/10.1021/jo500071u.

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Rohrbach, Simon, Rushabh S. Shah, Tell Tuttle, and John A. Murphy. "Corrigendum: Neutral Organic Super Electron Donors Made Catalytic." Angewandte Chemie International Edition 58, no. 43 (2019): 15183. http://dx.doi.org/10.1002/anie.201910425.

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Dissertations / Theses on the topic "Organic electron donors (OEDs)"

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Zhao, Yuxi. "Synthèse de donneurs d’électrons organiques : application en synthèse organique et chimie des polymères." Electronic Thesis or Diss., Aix-Marseille, 2021. http://www.theses.fr/2021AIXM0156.

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Les donneurs d'électrons organiques (DEO), aux potentiels redox exceptionnellement négatifs, ont montré un intérêt particulier en synthèse organique du fait de leurs fortes propriétés réductrices. Ils sont capables de transférer spontanément un ou deux électrons à des substrats organiques, formant ainsi des intermédiaires radicalaires ou anioniques. Néanmoins, la diversité structurale des DEO est limitée et leur champ d'application assez restreint.Dans cette thèse, nous avons tout d'abord développé de nouvelles bibliothèques de DEO afin d'identifier de nouvelles familles de réducteurs organiqu
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Schonebeck, Franziska. "Super electron donors powerful reductions performed by neutral organic molecules." Thesis, University of Strathclyde, 2007. http://oleg.lib.strath.ac.uk:80/R/?func=dbin-jump-full&object_id=21732.

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This project aims to explore the ability of organic molecules to transfer electrons and is based on the recent development within the Murphy group of a novel organic molecule, called Super-S.E.T. reagent 1, that allows the reduction of unactivated aryl and alkyl iodides. My study investigates the scope of donor 1 as a reducing agent and extends the study to a more powerful donor 2. Chapter One provides an introduction to the world of electron transfer. After giving a theoretical background, synthetic applications of electron transfer are highlighted, in particular using metal chemistry, electr
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Cumine, Florimond. "Studies on organic electron donors and their applications in chemistry." Thesis, University of Strathclyde, 2017. http://digitool.lib.strath.ac.uk:80/R/?func=dbin-jump-full&object_id=29432.

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Electron transfer reactions using organic donors have been and are still successfully applied in the Murphy group to perform reductions usually requiring heavy metals. This thesis focuses on several organic electron donors used to: (i) promote the cross-coupling reaction between aryl halides and benzene, which was also studied with computational experiments, (ii) cleave carbon-oxygen bonds and (iii) reduce nitrobenzenes and azobenzenes. In addition, computational analysis of controversial literature proposals for a radical/electron transfer mechanism for ring-forming reactions of alkoxide alle
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Buker, Nicholas D. "Guanidine donors in nonlinear optical chromophores /." Thesis, Connect to this title online; UW restricted, 2006. http://hdl.handle.net/1773/8669.

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Chua, Jonathan. "Exploring new reactions with Organic Electron Donors and the complexities of the Birch reduction." Thesis, University of Strathclyde, 2016. http://oleg.lib.strath.ac.uk:80/R/?func=dbin-jump-full&object_id=26437.

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Reductive σ-bond cleavages of challenging substrates under metal-free, mild conditions have recently been achieved with photoactivated super-electron donor (SED). These include (but are not limited to) C-O bonds of benzylic ethers and esters, C-N bonds of benzylic sulfonamides and aromatic amides. This work has successfully widened the substrate scope of reduction by SED to include i) the C-O bond cleavages of phenolic esters and aryl ethers and ii) the C-S bond cleavages of aromatic sulfides, sulfoxides and sulfones. Previously it was also discovered that the X-N bond of several amides were r
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Anderson, Greg. "Towards the rational development of organic super electron donors for transition metal-free biaryl coupling." Thesis, University of Strathclyde, 2016. http://digitool.lib.strath.ac.uk:80/R/?func=dbin-jump-full&object_id=27424.

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Within both the industrial and academic laboratory, the coupling of two aryl moieties is a process of significant synthetic use. To achieve such transformations typically requires the use of expensive transition metal catalysts that cannot always be recovered from the reaction mixtures. Consequently, the investigation of biaryl coupling reactions without the requirement for any such catalysts has been of key interest amongst chemists. Throughout the literature, a variety of simple organic molecules have been incorrectly termed as “ligands” or “catalysts” with respect to their role in transitio
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Tyree, William Stuart. "Correlation of Structure and Magnetic Properties in Charge-Transfer Salt Molecular Magnets Composed of Decamethylmetallocene Electron Donors and Organic Electron Acceptors." Thesis, Virginia Tech, 2005. http://hdl.handle.net/10919/34436.

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Di-n-propyl dicyanofumarate (DnPrDCF) and di-isopropyl dicyanofumarate (DiPrDCF) have been used as one-electron acceptors in the synthesis of charge-transfer salt magnets with decamethylmetallocenes, MCp*2 (M = Mn, Cr). Salts of each acceptor with each metallocene have been characterized and the structures of the chromium analogues have been solved. The two acceptors are structurally similar to dimethyl dicyanofumarate (DMeDCF) and diethyl dicyanofumarate (DEtDCF), which have been previously studied and found to form charge-transfer salt magnets with the aforementioned decamethylmetallocenes
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Xu, Yunhua. "Synthesis and Photoinduced Electron Transfer of Donor-Sensitizer-Acceptor Systems." Doctoral thesis, Stockholm : Department of Organic Chemistry, Stockholm University, 2005. http://urn.kb.se/resolve?urn=urn:nbn:se:su:diva-411.

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Fall, Arona. "Donneurs d’électrons organiques : développement d’un nouveau système catalytique photoredox." Electronic Thesis or Diss., Aix-Marseille, 2021. http://www.theses.fr/2021AIXM0607.

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Durant ces dernières décennies, la réactivité des donneurs d’électrons organiques de type énamine (DEO) a été largement exploitée dans des réactions de réduction par transfert électronique. De part leurs forts pouvoir réducteur avec des potentiels redox exceptionellement négatifs, les DEOs sont capables de transférer spontanément un ou deux électrons à des substrats organiques, formant ainsi des intermédiaires radicalaires ou anioniques. Cependant, ces DEOs sont toujours utilisés en quantité stœchiométrique, ce qui limite leur compétivité face aux catalyseurs organométalliques et organiques.Le
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Aguiar, António Luís Gonçalves de. "New boron-dipyrromethene (BODIPY) molecules as suitable electron-donors for organic photovoltaic cells." Doctoral thesis, 2019. http://hdl.handle.net/10316/88807.

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Tese no âmbito do Doutoramento em Química, Ramo de Especialização em Química Macromolecular apresentada ao Departamento de Química da Faculdade de Ciências e Tecnologia da Universidade de Coimbra.<br>As células fotovoltaicas orgânicas (OPVs) têm surgido como uma das alternativas mais apelativas às células fotovoltaicas baseadas em semicondutores inorgânicos (essencialmente silício), devido ao baixo custo de produção, leveza, flexibilidade dos dispositivos e versatilidade na integração em edifícios. As moléculas de boro-dipirrometeno (BODIPY) são fotossensibilizadores muito promissores para apl
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Books on the topic "Organic electron donors (OEDs)"

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Ogura, F., and Y. Aso. Design of Novel Chalcogen-Containing Organic Metals: Extensively Conjugated Electron Donors and Acceptors with Reduced On-site Coulomb Repulsion. Taylor & Francis Group, 1992.

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Book chapters on the topic "Organic electron donors (OEDs)"

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Clark, K. F., D. Dimitrova, and J. A. Murphy. "2.1 Organic Electron Donors in Electron-Transfer Reactions." In Free Radicals: Fundamentals and Applications in Organic Synthesis 2. Georg Thieme Verlag KG, 2021. http://dx.doi.org/10.1055/sos-sd-233-00233.

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AbstractThe field of organic electron donors is large and diverse, both in terms of the structures of the donors and the structures of the acceptors. In the past 15 years, organic donors have been developed that show remarkable strength, with ground-state or excited-state oxidation potentials rivalling even the most reactive metals. At the other end of the scale of reactivity, highly reactive oxidizing agents are now available upon photoactivation of a number of organic structures. The first part of this chapter reviews organic electron donors that are based upon an alkene that is activated by
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"Conjugated Polymers as Electron Donors in Organic Solar Cells." In Organic Solar Cells. CRC Press, 2017. http://dx.doi.org/10.1201/b18072-5.

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Ogura, Fumio, and Kazuo Takimiya. "Preparation of organic conductors." In Organoselenium Chemistry. Oxford University PressOxford, 1999. http://dx.doi.org/10.1093/oso/9780198501411.003.0014.

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Abstract Since the striking discovery of the charge-transfer (CT) complex of tetrathiafulvalene (TTF, 1) and 7,7,8,8-tetracyanoquinodimethane (TCNQ, 2) as the first synthetic metal, the development of novel electron donors and acceptors and the synthesis of organic metals and superconductors from them have aroused great interest among not only organic chemists but also scientists in many other interdisciplinary areas.
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Cook, Michael, and Philippa Cranwell. "Nucleophilic substitution." In Organic Chemistry, edited by Elizabeth Page. Oxford University Press, 2017. http://dx.doi.org/10.1093/hesc/9780198729518.003.0003.

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This chapter examines nucleophilic substitution. It begins by defining electrophiles and nucleophiles. An electrophile is a neutral or positively charged species with an empty orbital (or an energetically accessible anti-bonding orbital) which can accept electrons. Lewis acids can also be considered electrophiles as they have an empty orbital that can accept an electron pair. Meanwhile, a nucleophile contains a pair of electrons that can be used to form a new chemical bond. Nucleophiles thus act as electron donors. The chapter then looks at Lewis acids/bases.. The chapter then looks at Lewis a
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Leonties, Anca R., Ludmila Aricov, and Adina Raducan. "Electron Transfer." In Fundamental and Biomedical Aspects of Redox Processes. IGI Global, 2023. http://dx.doi.org/10.4018/978-1-6684-7198-2.ch016.

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Oxidoreductases are a special class of enzymes that use the redox mechanism for the efficient transformation of organic substrates. Most oxidoreductases contain metals in the active site and, for optimal functioning, require the participation of a small co-substrate with the ability to donate electrons. From the multitude of enzymes with economic and applicable potential, the authors focused their attention on three particular classes: catalases, peroxidases, and laccases. Catalases and peroxidases contain heme iron in their active sites and most often require electron donors such as oxygen or
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Pope, Martin, and Charlese E. Swenberg. "Electronic processes in polyaniline (PAni)." In Electronic Processes in Organic Crystals and Polymers. Oxford University PressNew York, NY, 1999. http://dx.doi.org/10.1093/oso/9780195129632.003.0010.

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Abstract Among the most important polymeric conductors from the technological standpoint (as distinct from molecularly doped polymer films, which constitute the much more commercially important materials used in electrophotography) are the polyanilines. Polyanilines are a family of polymers of the general formula shown in Fig. X. l. These compounds have been known for more than 100 years as aniline blacks and are important dyestuffs. The great interest in these polymers at present is due to their ability to behave either as semiconductors or as metals, depending on the degree and type of dopin
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Zaier, Rania, and Sahbi Ayachi. "Designing Well-Organized Donor-Bridge-Acceptor Conjugated Systems Based on Cyclopentadithiophene as Donors in Bulk Heterojunction Organic Solar Cells: DFT-Based Modeling and Calculations." In Solar Cells - Theory, Materials and Recent Advances. IntechOpen, 2021. http://dx.doi.org/10.5772/intechopen.94874.

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Two host materials based on CPDT as donors in bulk heterojunction organic solar cells were designed and investigated by means of DFT calculations. The first one (P-CPDTBT3) is a copolymer with D-A configuration and the second one (SM-CPDTDPP) is a D-π-A-π-D type small molecule. The investigated materials exhibited interesting structural properties with high planarity and rigidity originated from intra-molecular non-covalent interactions between the different building blocks. Thanks to their narrow band gaps, the optical absorption spectra have covered the main part of solar spectrum of interes
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Devikala, Sundaramurthy, and Johnson Maryleedarani Abisharani. "Addition of Organic Compounds in Gelatin-biopolymer Gel Electrolyte for Enhanced Dye-sensitized Solar Cells." In Advances in Solar Photovoltaic Energy Systems. IntechOpen, 2024. http://dx.doi.org/10.5772/intechopen.1003045.

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This chapter introduced a new series of organic compound additives like thiophene 2,5-dicarboxylic acid (TDA), sulfanilamide (SAA), 2,6-diamino pyridine (DAP), dibenzo-18-crown-6 (DBC) and 2,6-pyridine dicarboxylic acid (PDA) with gelatin/KI/I2 consist gel polymer electrolytes for dye-sensitized solar cells (DSSCs) application. Nowadays, it is focusing on biopolymers for preparing gel electrolytes for DSSCs application which is a conventional renewable energy source. Biopolymers are abundant in nature, and they are non-toxic, thermally stable, environmentally friendly, low-cost, and have good
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Conference papers on the topic "Organic electron donors (OEDs)"

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Esmaeely, Saba Nava, Sarah Hopkin, Johannes Sonke, and Shane Finneran. "Storage Area Assessment for Underground Hydrogen Storage (UHS) - Material Integrity Concerns." In CONFERENCE 2025. AMPP, 2025. https://doi.org/10.5006/c2025-00164.

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Abstract As hydrogen is becoming a key source for transitioning the existing energy system toward decarbonized sources, one of the remaining challenges for the large-scale deployment of hydrogen is the development of safe and efficient storage systems. Geological reservoirs, such as depleted oil and gas fields or saline aquifers, have been discussed as a large-scale storage option that could provide the volume capacity needed for large-scale underground hydrogen storage (UHS). While underground gas storage (UGS) has been safely used for CH4 storage for decades, the experience is not directly t
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Gu, Qinying, and Dan Credgington. "Organic Photovoltaics Incorporating Electron Donors with Small Exchange Energy." In 1st International Conference on Advances in Organic and Hybrid Electronic Materials. Fundació Scito, 2019. http://dx.doi.org/10.29363/nanoge.aohm.2019.040.

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Sheats, John E., Andrew Jones, Albert Lang, Felicia Bland та Elizabeth Hernandez. "Organotransition Metal Complexes as π Acceptors in Non-linear Optical Materials". У Organic Thin Films for Photonic Applications. Optica Publishing Group, 1993. http://dx.doi.org/10.1364/otfa.1993.wd.22.

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Previous investigators 1-4 have employed ferrocenyl derivatives as strong π-electron donors in the preparation of highly conjugated organic molecules such as Ia-c with high values of the second order hyperpolarizability, β.
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Ahrens, Michael J., Michael J. Fuller, and Michael R. Wasielewski. "Aminated and cyanated perylene mono- and diimides: Liquid crystalline electron donors and acceptors for organic photonics and electronics." In Frontiers in Optics. OSA, 2003. http://dx.doi.org/10.1364/fio.2003.tuj5.

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Tian, Mingzhen, Baozhu Luo, Wenlian Li, Shihua Huang, and Jiaqi Yu. "Persistent Photon-gated Spectral Holeburning In A New Donor-Acceptor Electron Transfer System." In Persistent Spectral Hole Burning: Science and Applications. Optica Publishing Group, 1991. http://dx.doi.org/10.1364/pshb.1991.fa7.

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Due to the interest in the frequency-domain optical storage application, recent researches on spectral holeburning concentrated on the two-colour photon-gated persistent holeburning[1,2]. Some organic systems have been investigated [3-7]. A representative one is TZT as a donor and CHCl3 as an acceptor in PMMA film undergoing donor-acceptor electron transfer, which offered a significant mechanism for persistent holeburning in organic system [4,5]. But there is an insurmountable problem in the system. As CHCl3 is volatile at room temperature, its concentration can not be controlled and the sampl
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Ehrlich, J., A. Heikal, Z. Y. Hu, et al. "Nonlinear Spectroscopy and Applications of Two-Photon Absorbing Molecules." In Organic Thin Films for Photonic Applications. Optica Publishing Group, 1997. http://dx.doi.org/10.1364/otfa.1997.tha.3.

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Molecules exhibiting strong two-photon absorption hold great potential for a wide range of applications including: two-photon fluorescence microscopy, three-dimensional (3D) optical data storage, 3D microfabrication, and optical limiting. (1-4) From a fundamental point of view, knowledge of molecular two-photon spectra and structure/property relationships are also important for a more complete understanding of the third order polarizabilities of conjugated molecules. However, very little is known or understood about two-photon states and spectra of conjugated molecules or how they correlate wi
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Rovira, C., J. Veciana, J. Tarres, et al. "Towards tridimensional organic metals. synthesis and study of mlrlti sulfur /spl pi/-electron donors and their charge transfer complexes and salts." In International Conference on Science and Technology of Synthetic Metals. IEEE, 1994. http://dx.doi.org/10.1109/stsm.1994.835659.

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Jiang, Min-hua, Xu-tang Tao, Duo-rong Yuan, Nan Zhang, and Dong Xu. "The Exploration of New Organic Crystals for Semiconductor Laser Second-Harmonic Generation." In Nonlinear Optics. Optica Publishing Group, 1992. http://dx.doi.org/10.1364/nlo.1992.md31.

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The demand for miniature blue and violet laser applications has stimulated the research on nonlinear optical crystals for semiconductor laser (800-1000nm) second-harmonic generation (SHG).This paper summarized our recent development on the exploration of new organic nonlinear optical (NLO) materials for such purposes. Based on the features of organic crystals and the requirements of semiconductor lasers to the corresponding SHG materials. The relations between the crystal sturcture and the spectral characteristics as well as the NLO properties of the organic corjugated molecules were investiga
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Adhikarya, Keshab Kumar, and Philippe M. Heynderickxa. "Structure and Properties of Stacking-type Complexes of Triazin at Graphene Surface: A Theoretical Assessment." In 5th World Conference on Chemistry and Chemical Engineering and 5th World Conference on Advanced Materials, Nanoscience and Nanotechnology. Eurasia Conferences, 2024. https://doi.org/10.62422/978-81-970328-7-5-024.

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In recent decades graphene immersed into the technology and industry with its various derivatives including with its immense functionality by making a complex, combination with other organic molecules, atoms and the combination of the both. Noncovalent functionalization creates a wide range of applications for these graphene complexes. Our intention was to characterize the stacking-like two-layered graphene nanoparticles. We selected triazin and its substituted derivatives ((1) 2,4,6-tris(dimethylamine)-1,3,5-triazine (TDA); (2) 2,4,6-triamino-1,3,5-triazine (TAM); (3) 2,4,6-trihydroxy-1,3,5-t
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Patel, J. "Role of Plasma-Induced Liquid Chemistry for the Reduction Mechanism of Silver Ions to form Silver Nanostructures." In Functional Materials and Applied Physics. Materials Research Forum LLC, 2022. http://dx.doi.org/10.21741/9781644901878-7.

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Abstract. There exists a variety of reports on the synthesis of silver nanostructures by plasma-liquid interactions; however seldom are those that discusses the underlying reaction kinetics. The present study focuses in such direction where the role of plasma-induced chemistry has been analysed in detail with the reports on the influence of radicals on the formation of silver nanostructures. The silver nanostructures are synthesized from various precursor concentrations of silver and characterized byultraviolet-visible spectroscopy and transmission electron microscopy analysis. Further, experi
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Reports on the topic "Organic electron donors (OEDs)"

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Chefetz, Benny, Baoshan Xing, Leor Eshed-Williams, Tamara Polubesova, and Jason Unrine. DOM affected behavior of manufactured nanoparticles in soil-plant system. United States Department of Agriculture, 2016. http://dx.doi.org/10.32747/2016.7604286.bard.

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The overall goal of this project was to elucidate the role of dissolved organic matter (DOM) in soil retention, bioavailability and plant uptake of silver and cerium oxide NPs. The environmental risks of manufactured nanoparticles (NPs) are attracting increasing attention from both industrial and scientific communities. These NPs have shown to be taken-up, translocated and bio- accumulated in plant edible parts. However, very little is known about the behavior of NPs in soil-plant system as affected by dissolved organic matter (DOM). Thus DOM effect on NPs behavior is critical to assessing the
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