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Relevant bibliographies by topics / Organic eutectics

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Journal articles

Academic literature on the topic 'Organic eutectics'

Author: Grafiati

Published: 6 September 2023

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Journal articles on the topic "Organic eutectics"

1

Rai, Uma Shanker, Manjeet Singh, and Rama Nand Rai. "Crystal growth and some physicochemical studies on an organic intermolecular compound of anthranilic acid and N,N-dimethylamino benzaldehyde." European Journal of Chemistry 9, no. 4 (2018): 303–10. http://dx.doi.org/10.5155/eurjchem.9.4.303-310.1720.

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The phase diagram of anthranilic acid and N,N-dimethylaminobenzaldehyde system gives two eutectics (E1 and E2) and a 1:1 intermolecular compound with congruent melting point. The mole fractions of anthranilic acid at E1 and E2 are 0.10 and 0.95, respectively. The negative values of heat of mixing of eutectics suggest that there is clustering of molecules in their eutectic liquid melt. The positive values of excess free energy for eutectics indicate that the interactions between the like molecules are stronger than those of unlike molecules. It can be inferred from single crystal X-ray analysis

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2

Yoshikawa, Shinichi, Shimpei Watanabe, Yoshinori Yamamoto, and Fumitoshi Kaneko. "Binary Phase Behavior of 1,3-Distearoyl-2-oleoyl-sn-glycerol (SOS) and Trilaurin (LLL)." Molecules 25, no. 22 (2020): 5313. http://dx.doi.org/10.3390/molecules25225313.

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This paper reports the precise analysis of the eutectic mixing behavior of 1,3-distearoyl-2-oleoyl-sn-glycerol (SOS) and trilaurin (LLL), as a typical model case of the mixture of cocoa butter (CB) and cocoa butter substitute (CBS). SOS was mixed with LLL at several mass fractions of LLL (wLLL); the mixtures obtained were analyzed for polymorphic phase behavior using differential scanning calorimetry (DSC) and synchrotron radiation X-ray diffractometry (SR-XRD). In melt crystallization with constant-rate cooling, SOS and LLL formed eutectics in their metastable polymorphs, allowing the occurre

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3

Araya-Sibaja, Andrea, José Vega-Baudrit, Teodolito Guillén-Girón, Mirtha Navarro-Hoyos, and Silvia Cuffini. "Drug Solubility Enhancement through the Preparation of Multicomponent Organic Materials: Eutectics of Lovastatin with Carboxylic Acids." Pharmaceutics 11, no. 3 (2019): 112. http://dx.doi.org/10.3390/pharmaceutics11030112.

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Lovastatin (LOV) is a drug used to treat hypercholesterolemia. Recent studies have identified its antioxidant effects and potential use in the treatment of some types of cancer. However, the low bioavailability related to its poor water solubility limits its use in solid oral dosage forms. Therefore, to improve the solubility of LOV three eutectic systems of LOV with the carboxylic acids benzoic (BEN), salicylic (SAL) and cinnamic (CIN) were obtained. Both binary phase and Tammann diagrams were constructed using differential scanning calorimetry (DSC) data of mixtures prepared from 0.1 to 1.0

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4

Gupta, R. K., S. K. Singh, and R. A. Singh. "Some physicochemical studies on organic eutectics." Journal of Crystal Growth 300, no. 2 (2007): 415–20. http://dx.doi.org/10.1016/j.jcrysgro.2006.12.017.

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5

Rai, U. S., and K. D. Mandal. "Some physicochemical studies on organic eutectics and 1:1 addition compound; p-phenylenediamine – benzoic acid system." Canadian Journal of Chemistry 67, no. 2 (1989): 239–44. http://dx.doi.org/10.1139/v89-039.

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The phase diagram of p-phenylenediamine – benzoic acid system, determined by the thaw–melt method, shows the formation of two eutectics and a 1:1 addition compound. The linear velocity of crystallization of pure components, eutectics and addition compound, determined by measuring the movement of growth front in a capillary, suggests that crystallization data obey the Hillig–Turnbull equation. Using experimental values of heats of fusion, entropy of fusion and excess thermodynamic functions were calculated and the results are explained on the basis of cluster formation in the melts. X-ray diffr

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6

Nahar, Yeasmin, and Stuart C. Thickett. "Greener, Faster, Stronger: The Benefits of Deep Eutectic Solvents in Polymer and Materials Science." Polymers 13, no. 3 (2021): 447. http://dx.doi.org/10.3390/polym13030447.

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Deep eutectic solvents (DESs) represent an emergent class of green designer solvents that find numerous applications in different aspects of chemical synthesis. A particularly appealing aspect of DES systems is their simplicity of preparation, combined with inexpensive, readily available starting materials to yield solvents with appealing properties (negligible volatility, non-flammability and high solvation capacity). In the context of polymer science, DES systems not only offer an appealing route towards replacing hazardous volatile organic solvents (VOCs), but can serve multiple roles inclu

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7

Pramanik, Titas, Ashish Anand, Janaky Sunil, et al. "Organic eutectics: characterization, microstructural evolution and properties." Acta Crystallographica Section A Foundations and Advances 77, a2 (2021): C121. http://dx.doi.org/10.1107/s0108767321095593.

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8

Rai, U. S., and H. Shekhar. "Some physicochemical studies on binary organic eutectics." Thermochimica Acta 175, no. 2 (1991): 215–27. http://dx.doi.org/10.1016/0040-6031(91)80068-t.

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9

Rai, U. S., and Santhi George. "A physicochemical study on organic eutectics and addition compound; benzidine–pyrogallol system." Canadian Journal of Chemistry 70, no. 12 (1992): 2869–74. http://dx.doi.org/10.1139/v92-366.

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The phase diagrams of the binary organic system of benzidine–pyrogallol was determined by the thaw–melt method. The solidification behaviour of the pure components, their eutectics, and the addition compound were studied by measuring the movement of growth front in a capillary. From the data on X-ray diffraction, thermal and microscopic investigations it can be inferred that the eutectics are not simple mechanical mixtures of the components involved. The IR and NMR spectral investigations were carried out to throw light on the nature of bonding between the two components forming the addition c

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10

Alhadid, Ahmad, Liudmila Mokrushina, and Mirjana Minceva. "Design of Deep Eutectic Systems: A Simple Approach for Preselecting Eutectic Mixture Constituents." Molecules 25, no. 5 (2020): 1077. http://dx.doi.org/10.3390/molecules25051077.

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Eutectic systems offer a wide range of new (green) designer solvents for diverse applications. However, due to the large pool of possible compounds, selecting compounds that form eutectic systems is not straightforward. In this study, a simple approach for preselecting possible candidates from a pool of substances sharing the same chemical functionality was presented. First, the melting entropy of single compounds was correlated with their molecular structure to calculate their melting enthalpy. Subsequently, the eutectic temperature of the screened binary systems was qualitatively predicted,

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