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Dissertations / Theses on the topic 'Organic-Inorganic complexes'

Author: Grafiati

Published: 28 May 2022

Last updated: 31 July 2025

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1

Saleem, al-Shaqri Layla Mohammed. "Kinetic studies of inorganic and organic peroxo complexes /." free to MU campus, to others for purchase, 2003. http://wwwlib.umi.com/cr/mo/fullcit?p3099628.

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2

Khandelwal, Amit Harikant. "Lithium, sodium and lanthanide metal inorganic and organic salt complexes." Thesis, University of Cambridge, 1994. https://www.repository.cam.ac.uk/handle/1810/272664.

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3

Ll, Yanfen. "Synthesis, Structure, and Characterization of Hybrid Solids Containing Polyoxometalates and Ruthenium Polypyridyl Complexes." TopSCHOLAR®, 2012. http://digitalcommons.wku.edu/theses/1163.

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Polyoxometalates (POMs), which are inorganic metal oxide cluster anions with discrete structures, have been extensively studied in recent years due to their large variety of applications such as medicine, biology, catalysis, material sciences and chemical analysis. Ruthenium polypyridyl complexes have been extensively studied for their applications as photosensitizers in solar energy conversion and photoelectronic materials. Recently, ruthenium heterocyclic ligand complex-based building blocks have been used for the synthesis of hybrid organic-inorganic solids through the self-assembly. We are

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4

Kowalski, Vincent Michael. "Synthesis and Characterization of Dipyrromethene Complexes of Antimony." University of Toledo / OhioLINK, 2017. http://rave.ohiolink.edu/etdc/view?acc_num=toledo1493393079741153.

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5

Taha, Ziyad Ahmed. "Silica-supported vanadium complexes: Structure, characterization and reactivity, especially towards olefins." Thesis, University of Ottawa (Canada), 2004. http://hdl.handle.net/10393/29175.

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This thesis is divided into four major parts. The first part describes a simple method to measure the content of reactive hydroxyls of various amorphous silicas before and after thermal treatment. The reaction of excess VOCl3 vapor with surface OH groups of partially dehydroxylated silica is rapid and quantitative. Regardless of the degree of dehydroxylation, the stoichiometry of the reaction is invariable, as demonstrated by 51V magic angle spinning NMR spectroscopy and X-ray absorption spectroscopy (XAS). Using this method, we have quantified the reacive hydroxyls of fumed and precipitated

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6

Plouffe, Pierre-Yves. "The chemistry of cyclopentadienyl ruthenium complexes containing thiolato or catenated polysulfano ligands /." Thesis, McGill University, 1990. http://digitool.Library.McGill.CA:80/R/?func=dbin-jump-full&object_id=74679.

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The reactive complexes CpRu(PPh$ sb3) sb2$SR (Cp = $ eta sp5$-cyclopentadienyl; R = H, 4-C$ sb6$H$ sb4$Me, 1-C$ sb3$H$ sb7$, CHMe$ sb2$) were prepared by briefly heating CpRu(PPh$ sb3$)$ sb2$Cl with LiSR in refluxing THF. Treatment of the thiolates with CO gave CpRu(PPh$ sb3$)(CO)SR. The reaction of CS$ sb2$ with CpRu(PPh$ sb3) sb2$SR gave the thioxanthate complexes CpRu(PPh$ sb3$)(S$ sb2$CSR) (R = 4-C$ sb6$H$ sb4$Me, 1-C$ sb3$H$ sb7$, CHMe$ sb2$), wherein the CS$ sb2$ inserted into the Ru-S bond. A study of the kinetics of this reaction and the crystal structure of CpRu(PPh$ sb3$)(S$ sb2$CS(1

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7

Gundersen, Jennifer Lisa. "Peroxo Complexes of Molybdenum (VI) and Vanadium (V) with Imidazole and Histidine." W&M ScholarWorks, 1986. https://scholarworks.wm.edu/etd/1539625344.

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8

Granville, Stephanie L. "Studies of Iron Polyfluorometallacycle Complexes Enroute to the "Green" Catalytic Synthesis of Hydrofluorocarbons." Thesis, University of Ottawa (Canada), 2011. http://hdl.handle.net/10393/28894.

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Chlorofluorocarbons were once commonly used as propellants and refrigerants due to their stability, low toxicity and excellent physical properties. They were phased out, however, after being identified as ozone-depleters, and have been replaced by hydrofluorocarbons (HFCs) and other fluorocarbon derivatives (FCDs). The high temperature-resistant characteristic of these materials is beneficial for many applications; however, the robust nature of the C-F bonds leads to their persistence in the environment. Frequently, the synthesis of HFCs and FCDs involves energy-intensive processes and toxic p

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9

Boily, Hélène Louise. "The chemistry of platinum and ruthenium complexes containing a thiosulfonate ester ligans (-SO2SR)." Thesis, McGill University, 1994. http://digitool.Library.McGill.CA:80/R/?func=dbin-jump-full&object_id=28684.

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The study of catenated polysulfur oxide ligands as homogeneous models of possible species involved in the Claus reaction has led to the investigation of SO$ sb2$ complexes as precursors to the MSO$ sb2$SR moiety. In the first part of this study, cationic Cp-ruthenium complexes having a planar SO$ sb2$ ligand were treated with thiolate anions and thiols. When (CpRu(PPh$ rm sb3) sb2SO sb2 rbrack PF sb6$ was treated with LiSCHMe$ sb2$, no reaction occurred and the starting complex was recovered. Treatment with a weaker nucleophile $ rm LiSC sb6F sb5$ gave CpRu(PPh$ rm sb3) sb2SC sb6F sb5.$ Replac

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10

Sheffield, Sandra Jean. "Peroxo Complexes of Vanadium(V) and Molybdenum(VI) with Nicotine and Aspartic Acids." W&M ScholarWorks, 1986. https://scholarworks.wm.edu/etd/1539625346.

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11

Mason, Chris. "The search for low-valent transition metal complexes for oligomerization and polymerization of ethylene." Thesis, University of Ottawa (Canada), 2010. http://hdl.handle.net/10393/28515.

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Combination of the potassium salt of the triazenide anion (R)NNN(R) - with CrCl2(THF)2 leads to the formation of dimeric complexes {Cr[mu,eta,eta'-bis-1,3-(2',5'-diisopropylphenyl) triazenide]2}2(2.1), [Cr(mu,eta,eta')-1,3-diphenyltriazenide) 2]2 (2.2), {Cr[mu,eta,eta')-bis-1,3-(2'-methoxyphenyl)triazenide] 2}2 (2.3) which are paddlewheel type structures featuring bridging triazenide anions. These complexes led to very low activity for the polymerization and oligomerization of ethylene upon activation with known activators MAO, TIBAO. Combination of the potassium salt of the triazenide anion w

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12

Baldwin, Jean A. "High pressure vibrational spectroscopic studies of some organoplatinum complexes." Thesis, McGill University, 1992. http://digitool.Library.McGill.CA:80/R/?func=dbin-jump-full&object_id=56648.

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High pressure infrared and micro-Raman vibrational spectroscopy has been used to study the following organoplatium(II) complexes: Zeise's salt, K (Pt($ eta sp2$-C$ sb2$H$ sb4$)Cl$ sb3$); Zeise's dimer, (Pt($ eta sp2$-C$ sb2$H$ sb4) sb2$Cl$ sb2 rbrack sb2$; and dichloro(1,5-cyclooctadiene)platinum(II), Pt(COD)Cl$ sb2$. Pressure dependences of the vibrational modes have been used in the assignments of the $ upsilon$(C=C) modes and the ethylene and cyclic diene C-H stretching vibrations. Pressure increases the extent of $ pi$-backbonding, as shown by the negative pressure dependence of the $ upsi

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13

Reta, Mañeru Daniel. "Understanding and predicting magnetic coupling in complex systems: from inorganic complexes to organic polyradicals." Doctoral thesis, Universitat de Barcelona, 2016. http://hdl.handle.net/10803/380161.

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This thesis presents a theoretical and computational approach to the accurate description of magnetic exchange interactions in a variety of complex systems. These include two main families of compounds. The first family is formed by inorganic coordination complexes, presenting localized magnetic centres and well-defined crystal structures. The second family consists of purely organic, π−conjugated odd alternant neutral polyradicals, which display a much larger structural flexibility and greater delocalization of the unpaired electrons over the π system. The thesis has two main parts. The fi

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14

Bailey, Brad Cameron. "Synthesis, characterization, and reactivity of titanium-ligand multiply bonded complexes supported by sterically encumbering beta-diketiminate and PNP pincer-type ligands." [Bloomington, Ind.] : Indiana University, 2007. http://gateway.proquest.com/openurl?url_ver=Z39.88-2004&rft_val_fmt=info:ofi/fmt:kev:mtx:dissertation&res_dat=xri:pqdiss&rft_dat=xri:pqdiss:3283107.

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Thesis (Ph. D.)--Indiana University, Dept. of Chemistry, 2007.<br>Source: Dissertation Abstracts International, Volume: 68-09, Section: B, page: 5940. Adviser: Daniel J. Mindiola. Title from dissertation home page (viewed May 12, 2008).

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15

El-Bjeirami, Oussama. "Photochemical and Photophysical Properties of Gold(I) Complexes and Phosphorescence Sensitization of Organic Luminophores." Thesis, University of North Texas, 2006. https://digital.library.unt.edu/ark:/67531/metadc5375/.

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Two major topics that involve synthetic strategies to enhance the phosphorescence of organic and inorganic luminophores have been investigated. The first topic involves, the photophysical and photochemical properties of the gold (I) complexes LAuIX (L = CO, RNC where R = alkyl or aryl group; X = halide or pseudohalide), which have been investigated and found to exhibit Au-centered phosphorescence and tunable photochemical reactivity. The investigations have shown a clear relationship between the luminescence energies and association modes. We have also demonstrated for the first time that auro

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16

Al-Anber, Mohammed. "Organic and/or InOrganic Pi-Conjugated Units in the Synthesis of Multinuclear Transition Metal Complexes." Doctoral thesis, Universitätsbibliothek Chemnitz, 2003. http://nbn-resolving.de/urn:nbn:de:swb:ch1-200301585.

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Die heterobimetallischen Pi-Pinzetten können erfolgreich als Grundbaustein für die Darstellung von mehrkernigen Übergangsmetallkomplexen, in denen die Metallzentren M(I) (M = Cu, Ag) über unterschiedliche stickstoffhaltige organische sigma-Donor-Liganden verbrückt sind, verwendet werden. In Abhängigkeit von der Natur der korrespondierenden organometallischen Pi-Pinzetten und der organischen Brückeneinheiten konnten verschiedene mehrkernige Übergangsmetallkomplexe synthetisiert werden. Diese Komplexe wurden mittels IR, 1H- und 13C-NMR-Spektroskopie sowie MS charakterisiert. Die Festkörperstrukt

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17

Faust, Marcus Donovan. "Metal hydroquinone complexes : the physical properties and catalysis of rhodium & iridium quinonoids." View abstract/electronic edition; access limited to Brown University users, 2008. http://gateway.proquest.com/openurl?url_ver=Z39.88-2004&rft_val_fmt=info:ofi/fmt:kev:mtx:dissertation&res_dat=xri:pqdiss&rft_dat=xri:pqdiss:3318315.

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18

Hasan, Md Faruque. "Synthesis and Characterization of Cobalt-Based Coordination Complexes with Various Organic Linkers." Youngstown State University / OhioLINK, 2018. http://rave.ohiolink.edu/etdc/view?acc_num=ysu1532001654030436.

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19

Wiznycia, Alexander V. "The preparation and study of Bis(pyridyl-imine) and Monohelical salen-type complexes of iron and zinc." Diss., Manhattan, Kan. : Kansas State University, 2006. http://hdl.handle.net/2097/200.

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20

Anber, Mohammed al. "Organic and, or inorganic p-conjugated [pi-conjugated] units in the synthesis of multinuclear transition metal complexes." [S.l. : s.n.], 2003. http://deposit.ddb.de/cgi-bin/dokserv?idn=97031387X.

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21

任詠華 and Wing-wah Vivian Yam. "High-valent ruthenium and osmium oxo complexes for homogeneous and photochemical oxidations of inorganic and organic substrates." Thesis, The University of Hong Kong (Pokfulam, Hong Kong), 1988. http://hub.hku.hk/bib/B31231421.

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22

Yam, Wing-wah Vivian. "High-valent ruthenium and osmium oxo complexes for homogeneous and photochemical oxidations of inorganic and organic substrates /." [Hong Kong : University of Hong Kong], 1988. http://sunzi.lib.hku.hk/hkuto/record.jsp?B12361434.

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23

Kanyuk, M. I., and A. P. Demchenko. "Spectroscopic Studies of New Fluorescent Nanomaterial Composed of Silver Atoms and Organic Dye." Thesis, Sumy State University, 2013. http://essuir.sumdu.edu.ua/handle/123456789/35269.

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The novel fluorescent nanostructures are synthesized in a simple one-step process by UV light illumination of silver salt in a mixture with organic dye Thioflavin T. The latter serves both as a sensitizer in photoreaction and as molecular support. The most stable composite structures are obtained in 2-propanol. They are characterized by absorption spectra that are quite different from that of the dye and by strong excitation and emission bands with the maxima at 340 nm and 450 nm correspondingly. We suggest that this photoreaction product consists of two silver atoms and two dye molecules. We

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24

Shah, Sana. "Synthesis and Characterization of Manganese Pyridazyl Complexes." TopSCHOLAR®, 2013. http://digitalcommons.wku.edu/theses/1298.

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Heterocyclic’s and their fused-ring derivatives have been of interest for their use in electronic materials due to their ease of production, synthetic versatility, and low cost compared to traditional inorganic materials like silicon. Pyridazines have been found to be useful in catalysis gas storage, polymeric sensors and biological mimetics. When a transition-metal is fused into a synthesized pyridazine, unique properties such as conductivity and optics are allowed. In this work, synthesized pyridazine complexes will be analyzed by mass spectroscopy, elemental analysis, nuclear magnetic reson

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25

Das, Sanjit. "Enhanced Structural Support of Metal Sites as Nodes in Metal-Organic Frameworks Compared to Metal Complexes." DigitalCommons@USU, 2013. https://digitalcommons.usu.edu/etd/1736.

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Metal-organic frameworks are a new class of crystalline, porous solid-state materials with metal ions periodically linked by organic linkers. This gives rise to one-, two- or three-dimensional structures. Here, we compare the stability of similar metal sites toward external ligand (solvent) induced disruption of the coordination environment in metal complexes and in metal-organic frameworks. Our experimental results show that a metal site as node of a metal-organic framework retains much higher stability compared to a similar metal site in a metal complex.

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26

Hueting, Rebekka. "Radiolabelled copper complexes for cancer imaging." Thesis, University of Oxford, 2011. http://ora.ox.ac.uk/objects/uuid:47438968-6aa3-41f5-82b4-9121dc327b53.

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Chapter One introduces molecular irnaging and the modalities available for oncological irnaging. The radioisotopes and imaging agents for Positron Emission Tomography (PET) and Single Photon Emission Computed Tomography (SPECT) are discussed together with the bifunctional chelator approach for radio labelling of biomolecules. Finally, the chemistry and radioisotopes of copper are described, and copper bis(thiosemicarbazonato) complexes introduced in the context of PET irnaging. Chapter Two describes the synthesis and characterisation of novel carboxylate- and maleirnide- functionalised bis(thi

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27

Ogura, Hiroshi. "Probing the interactions between sterically demanding ferrihemes and histidine analogues. I. 2-D NMR studies of nonplanar ferriheme/bis(N-/2-methylimidazole) complexes; II. Synthesis of a trans-disubstituted tetraarylporphyrin with a bulky group near each potential axial ligation site." Diss., The University of Arizona, 2000. http://hdl.handle.net/10150/284178.

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In a hemoprotein, histidine and other aromatic amines that ligate to the heme may encounter steric interactions from the following: (1) the peptide chains that form the pocket; or (2) the porphyrin ring that may have been distorted by the protein matrix or a distal ligand. Models that mimic these steric interactions need to be synthesized and studied in detail. The results of two research projects---both dealing with porphyrins that interact sterically with the axially ligated aromatic amines--are presented in this dissertation. In the first part, variable-temperature 2-D NMR studies of nonpla

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28

Du, Guodong. "Group 4 Metalloporphyrin diolato Complexes and Catalytic Application of Metalloporphyrins and Related Transition Metal Complexes." Washington, D.C. : Oak Ridge, Tenn. : United States. Dept. of Energy. Office of Science ; distributed by the Office of Scientific and Technical Information, U.S. Dept. of Energy, 2004. http://www.osti.gov/servlets/purl/835301-irsXCw/webviewable/.

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29

Scheuermann, Margaret L. "Reactivity of PtII "Pincer" Complexes with Carbon Monoxide." Scholarship @ Claremont, 2008. https://scholarship.claremont.edu/scripps_theses/6.

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ABSTRACT Upon addition of carbon monoxide (CO) to a solution of (k-N, C, N-2, 6-bis(diethylaminomethyl)-phenyl)methyl platinum(II),[NCN]PtMe,(1), a ligand arm is displaced to form [SP-4-2] ((k-N,C-2,6-bis(diethylaminomethyl)-phenyl) carbonmethyl platinum(II), N[CN]Pt(CO)(Me),(2). Addition of CO to a THF solution of 2 results in the formation of [SP-4-3]((k-N,C-2,6-bis(diethylaminomethyl)-phenyl)acylcarbonyl platinum(II),N[CN]pt(Ac)(CO),(3). In THF ,2 partially isomerizes in the presence of CO to form [SP-4-4]((k-N,C-2,6-bis(diethylaminomethyl)-phenyl)carbonylmethyl platinum(II), N[CN]

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30

Sun, Dongyue. "Complexes diimine-dioxime de cobalt pour l'électrocatalyse de production d'hydrogène : étude mécanistique et optimisation par intégration d'un réservoir d'électron." Thesis, Université Grenoble Alpes (ComUE), 2017. http://www.theses.fr/2017GREAV062/document.

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La production de H2, à partir d'eau et d'énergie solaire, est probablement une solution d'avenir pour le stockage des énergies renouvelables. Pour éviter l’utilisation de platine, des catalyseurs à base de métaux abondants doivent être développés. Les complexes diimine-dioxime de cobalt sont parmi les catalyseurs bio-inspirés les plus performants. Dans ce travail, nous avons dans un premier temps élucidé le mécanisme de production d’hydrogène par ces complexes et extrait les paramètres cinétiques des différentes étapes en utilisant les méthodes et techniques électrochimiques les plus récentes.

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31

Nambukara, Wellala Nadeesha P. "Synthesis and Catalytic Activities of Nickel Complexes Bearing Flexible Tridentate Ligands." University of Cincinnati / OhioLINK, 2017. http://rave.ohiolink.edu/etdc/view?acc_num=ucin1491561548324255.

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32

Köhler, Christian [Verfasser]. "Spin crossover behavior of 1,3,4-oxadiazole based dinuclear iron(II) complexes und functionalized phosphonates as bridging ligands in inorganic-organic hybrid-materials / Christian Köhler." Mainz : Universitätsbibliothek Mainz, 2016. http://d-nb.info/1105589935/34.

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33

Saang'onyo, Daudi Sayialel. "CATALYTIC CONVERSION OF MONOSACCHARIDES INTO 5-(HYDROXYMETHYL)FURFURAL IN IONIC LIQUIDS USING ALUMINUM COMPLEXES BEARING BIDENTATE (AMINOMETHYL)PHENOLATE LIGANDS." UKnowledge, 2018. https://uknowledge.uky.edu/chemistry_etds/100.

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Currently, the major sources of fuel, energy, and chemicals are nonrenewable fossil resources such as petroleum, natural gas, and coal. Additionally, petroleum is used for the production of most transportation fuels and for the production of about 95% of organic chemicals. However, the production and use of non-renewable fossil fuels are unsustainable. For economic and environmental sustainability, there is a need to search for new and/or renewable resources and technologies for energy, fuels, and chemicals production that have the potential of effectively substituting fossil resources. In thi

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34

Kwong, Ka Wai. "Visible-Light Generation of High-Valent Metal-Oxo Intermediates and a Biomimetic Oxidation Catalyzed By Manganese Porphyrins with Iodobenzene Diacetate." TopSCHOLAR®, 2016. http://digitalcommons.wku.edu/theses/1743.

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High-valent iron-oxo intermediates play central roles as active oxidants in enzymatic and synthetic catalytic oxidations. Many transition metal catalysts are designed for biomimetic studies of the predominant oxidation catalysts in Nature, the cytochrome P450 enzymes. In this work, a new photochemical method to generate high-valent iron-oxo porphyrin models was discovered. As controlled by the electronic nature of porphyrin ligands, iron(IV)-oxo porphyrin radical cations (Compound I model) and iron(IV)-oxo porphyrin derivatives (Compound II model) were produced. These observations indicate tha

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35

Pullen, Sonja. "Mimicking the Outer Coordination Sphere in [FeFe]-Hydrogenase Active Site Models : From Extended Ligand Design to Metal-Organic Frameworks." Doctoral thesis, Uppsala universitet, Molekylär biomimetik, 2017. http://urn.kb.se/resolve?urn=urn:nbn:se:uu:diva-318975.

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Biomimetic catalysis is an important research field, as a better understanding of nature´s powerful toolbox for the conversion of molecules can lead to technological progress. [FeFe]-hydrogenases are very efficient catalysts for hydrogen production. These enzymes play a crucial role in the metabolism of green algae and certain cyanobacteria. Their active site consists of a diiron complex that is embedded in an interactive protein matrix. In this thesis, two pathways for mimicking the outer coordination sphere effects resulting from the protein matrix are explored. The first is the construction

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36

Urig, Christina S. "EVALUATION OF SINGLE MOLECULE DIODES FABRICATED VIA ELECTRON-BEAM LITHOGRAPHY AND METAL-ORGANIC FRAMEWORKS INCORPORATING TWO NOVEL LIGANDS, A TRIGONAL PLANAR CARBOXYLATE LIGAND AND A TETRAHEDRAL TETRAZOLATE-BASED LIGAND." Miami University / OhioLINK, 2007. http://rave.ohiolink.edu/etdc/view?acc_num=miami1176829199.

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Parker, Mariah L. "The Investigation of Oxidative Addition Reactions of Metal Complexes in Cross-Coupling Catalytic Cycles Based on a Unique Methodology of Coupled Ion/Ion-Ion/Molecule Reactions." VCU Scholars Compass, 2018. https://scholarscompass.vcu.edu/etd/5651.

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Popular catalytic cycles, such as the Heck, Suzuki, and Negishi, utilize metal centers that oscillate between two oxidation states (II/0) during the three main steps of catalysis: reductive elimination, oxidative addition, and transmetallation. There has been a push to use less toxic, cheaper metal centers in catalytic cycles, leading to interest in first-row transition metals, such as nickel and cobalt. With these metals, the cycles can potentially pass through the +1 oxidation state, which acts as reactive intermediates, undergoing oxidative additions to form products, potentially with radic

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38

Muizzi, Casanas Dayana Andreina. "Light Activated Nitric Oxide Releasing Materials." Bowling Green State University / OhioLINK, 2015. http://rave.ohiolink.edu/etdc/view?acc_num=bgsu1435581276.

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39

Knapp, Amanda R. "Antimicrobial and Antitumor Properties of Free and Poly(Ethylene Glycol)-Poly(Lactic Acid) Encapsulated Silver N-Heterocyclic Carbene Complexes." University of Akron / OhioLINK, 2011. http://rave.ohiolink.edu/etdc/view?acc_num=akron1309211795.

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40

Binding, Samantha Carys. "Synthesis and characterisation of permethylpentalene complexes and permethylpentalene derivatives." Thesis, University of Oxford, 2015. http://ora.ox.ac.uk/objects/uuid:7855e90d-7ce9-42eb-b962-b68606ade746.

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This thesis expands the scope for using the permethylpentalene ligand and its precursors in the synthesis of organometallic complexes. <strong>Chapter one</strong> begins with a brief review of linked metallocenes, with which multimetallic compounds bridged by pentalene ligands have often been compared, followed by a comprehensive review of the routes used to make pentalenes and substituted pentalenes. Organometallic compounds of pentalenes are introduced, with a focus on bimetallic systems. <strong>Chapter two</strong> explores the diversification of substituents added to the permethylpentale

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41

Mougenot, Pierre. "Etude theorique ab initio scf et ci de complexes organometalliques binucleaires." Université Louis Pasteur (Strasbourg) (1971-2008), 1988. http://www.theses.fr/1988STR13025.

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Analyse approfondie du spectre photoelectronique se(fe(c::(5)h::(5)))::(2)(no)::(2). Etude critique des resultats experimentaux anterieurs concernant le diamagnetisme suppose se(co(c::(5)h::(5)))::(2)(no)::(2). Bon accord avec l'experience dans l'etude theorique de l'etat fondamental du cation dirhodium tetraacetate dihydrate. Etude sur la nature de l'interaction metal-metal dans (v(c::(5)h::(5)))::(2) (c::(8)h::(8))

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42

Foulet-Fonseca, Gloria. "Etude par spectroscopie vibrationnelle des complexes méthylcarbyniques et méthylcarbéniques de chrome." Paris 13, 1987. http://www.theses.fr/1987PA132028.

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Etude en particulier de complexes, du type br(co)::(4)crcch::(3), br(co)::(4)crcchd::(2) et d'une série de mélanges isotopiques. Mise en évidence de la non-équivalence des liaisons c-h du groupe methyle. Etablissement d'un champ de forces pour les complexes méthylcarbyniques

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43

Bouet, Gilles. "Etude structurale et analytique de complexes d'halogénures d'éléments 3D : mx::(2) (M = co,ni,cu; X = cl,br) et de diverses aldoximes furanniques." Angers, 1987. http://www.theses.fr/1987ANGE0009.

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Vingt-quatre nouveaux complexes d'halogénures de métaux 3 D : mx::(2) (m = co,ni,cu; x = cl,br) sont préparés et caractérisés. Leurs structures sont déterminées par diffraction des rayons X pour deux des composés et, à partir de celles-ci, pour l'ensemble des complexes grâce à la spectroscopie infrarouge et à la spectroscopie électronique. Le calcul des constantes de stabilité et des paramètres thermodynamiques correspondants par titrimétrie thermométrique est décrit.

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44

Nemra, Ghinwa. "Comportement electrochimique de nouveaux complexes a liaison pd-pd et pt-pd stabilises par des ligands bidentates ph : :(2)pch::(2)pph::(2)." Strasbourg 1, 1986. http://www.theses.fr/1986STR13055.

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L'etude des proprietes redox d'une vingtaine de complexes mono-, di-, tri- et tetranucleaires du palladium et du platine a ete effectuee par des methodes electrochimiques (electrode a disque tournant, voltamperometrie cyclique et coulometrie) associees a des methodes spectroscopiques (spectrophotometrie d'absorption electronique, rpe et rmn). Les differents mecanismes des reactions redox ont ete etablis en fonction de la nature des metaux et des ligands dans le complexe. On montre qu'on peut modifier de maniere controlee les potentiels d'oxydoreduction et la reversibilite des transferts de cha

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Faulmann, Christophe. "Conducteurs derives de metaux de transition : complexes moleculaires, polymeres, oxydes de cuivre." Toulouse 3, 1988. http://www.theses.fr/1988TOU30160.

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Deb, Tapash K. "Bioinspired Redox Active Pseudotetrahedral Ni(II) Thiolate and Phenolate Complexes: Synthesis, Characterization, Alkylation Kinetics and Molecular Oxygen Activation." Ohio University / OhioLINK, 2013. http://rave.ohiolink.edu/etdc/view?acc_num=ohiou1377256181.

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Soules, Régis. "Proprietes cooperatives de complexes polymetalliques des ligands squarate et thiosquarate." Toulouse 3, 1987. http://www.theses.fr/1987TOU30178.

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Etude de l'emploi d'un coordinat assembleur qui puisse par coordination avec le centre metallique utilise (metaux de transition du groupe viii) aboutir a un agencement a une dimension des motifs moleculaires par empilement d'entites monomeres ou par formation de chaines. Par utilisation du coordinat squarate sous ses formes oxygenees et soufrees, obtention d'un certain nombre de complexes de pt, pd, ni et cu repondant aux criteres fixes. Etude des structures de ces composes, de leurs proprietes physiques et de la relation structure-propriete. La nature du coordinat comme le caractere specifiqu

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Conan, Françoise. "Contribution à l'élaboration de nouveaux squelettes organiques via l'étude de la réactivité d'un groupe disulfure de carbone coordine au molybdène." Brest, 1988. http://www.theses.fr/1988BRES2017.

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La reactivite du complexe du titre est etudiee vis a vis d'alcynes portant des groupes electroattracteurs. On obtient des complexes metallocycliques a liaison molybdene-carbone ou molybdene-soufre. On prepare un complexe original par addition de trois molecules de propiolonitrile. On etudie egalement la reactivite de ces composes heterocycliques vis a vis de ch::(3)i, nabh::(4) et de hc=c-cn

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Bouhrara, Mohamed. "Préparation de matériaux catalytiques bien définis à site unique de type complexe carbénique N-hétérocyclique d’Au(I) : application à la réaction d’addition des alcools sur les alcynes." Thesis, Lyon 1, 2010. http://www.theses.fr/2010LYO10193.

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Les ligands carbéniques N-hétérocycliques sont généralement décrits comme des analogues aux ligands phosphines car ils présentent des propriétés électroniques comparables, bien que leur caractère σ-donneur soit plus prononcé. Ils ont donc été utilisés pour la synthèse de complexes organométalliques en remplacement des ligands phosphines et un nombre très important de complexes métal-NHC ont été développés ces 15 dernières années. Toutefois, ces complexes bien que très actifs dans de nombreuses réactions catalytiques clefs (métathèse des oléfines, couplages C-C, échange H/D…), présentent des pr

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Bellamy, Dena. "Intermolecular interactions in transition metal complexes and analogous organic species." Thesis, University of Bristol, 1997. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.389380.

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