Academic literature on the topic 'Organic reagent'

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Journal articles on the topic "Organic reagent"

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Jiang, Chao, Xiangbing Qi, and Chao Yang. "Alkylzirconocenes in Organic Synthesis: An Overview." Synthesis 53, no. 06 (2021): 1061–76. http://dx.doi.org/10.1055/s-0040-1706146.

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AbstractOrganozirconium chemistry has found extensive applications in organic synthesis since its discovery in the last century. Alkyl­zirconocenes, which are easily generated by the hydrozirconation of alkenes with the Schwartz reagent, are widely utilized for carbon–carbon­ and carbon–heteroatom bond formation. This short review summarizes the progress to date on the applications alkylzirconocenes in organic synthesis.1 Introduction2 General Methods for Generating Alkylzirconocenes3 Transformations of Alkylzirconocenes by Heteroatoms4 Insertion of Unsaturated Groups into Alkylzirconocenes5 T
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Krylov, Igor B., Vera A. Vil’, and Alexander O. Terent’ev. "Cross-dehydrogenative coupling for the intermolecular C–O bond formation." Beilstein Journal of Organic Chemistry 11 (January 20, 2015): 92–146. http://dx.doi.org/10.3762/bjoc.11.13.

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The present review summarizes primary publications on the cross-dehydrogenative C–O coupling, with special emphasis on the studies published after 2000. The starting compound, which donates a carbon atom for the formation of a new C–O bond, is called the CH-reagent or the C-reagent, and the compound, an oxygen atom of which is involved in the new bond, is called the OH-reagent or the O-reagent. Alcohols and carboxylic acids are most commonly used as O-reagents; hydroxylamine derivatives, hydroperoxides, and sulfonic acids are employed less often. The cross-dehydrogenative C–O coupling reaction
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TAGUCHI, Takeo. "New reagents. IX. Fluorinating reagents. Fluorinating reagent: DAST." Journal of Synthetic Organic Chemistry, Japan 48, no. 11 (1990): 1048–49. http://dx.doi.org/10.5059/yukigoseikyokaishi.48.1048.

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Degtjarjov, F. "Evaluation of mineral and organic inhibitor effects on bentonite clay." Georesursy 20, no. 4 (2018): 355–58. http://dx.doi.org/10.18599/grs.2018.4.355-358.

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The supra-salt complex of the oilfield of the Republic of Belarus is represented by high-colloidal multicolored clay deposits with layers of unstable sandstones and aleurolites evenly distributed throughout the section. Drilling of intervals which are represented by clay sediments is accompanied by complications caused by swelling of clays – stuck, tightening, sticking clay on the drilling tool. Swelling occurs during drilling of high-colloidal clays. As a result of the action of the drilling mud and its filtrate, the clay swells, narrowing the trunk and reducing the stability of the walls of
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Degtjarjov, F.V. "Evaluation of mineral and organic inhibitor effects on bentonite clay." Georesursy = Georesources 20, no. 4 (2018): 355–58. https://doi.org/10.18599/grs.2018.4.355-358.

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The supra-salt complex of the oilfield of the Republic of Belarus is represented by high-colloidal multicolored clay deposits with layers of unstable sandstones and aleurolites evenly distributed throughout the section. Drilling of intervals which are represented by clay sediments is accompanied by complications caused by swelling of clays – stuck, tightening, sticking clay on the drilling tool. Swelling occurs during drilling of high-colloidal clays. As a result of the action of the drilling mud and its filtrate, the clay swells, narrowing the trunk and reducing the stability of the wal
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WANG, NAI-XING, LEI-YANG ZHANG, YUE-HUA WU, and DUMITRA LUCAN. "Some sulphur - containing double combination reagents." Journal of Engineering Sciences and Innovation 8, no. 3 (2023): 269–76. http://dx.doi.org/10.56958/jesi.2023.8.3.269.

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Research and development of new reagents are very important for organic synthesis. In recent years, some new reagents with universal applicability have been reported, but new reagents of sulphur-containing are rarely reported. Wang’s group has developed several new sulphur-containing reagents which are called as Wang reagents: Sodium dithionite - tert-Butyl hydroperoxide (Na2S2O4-TBHP). The paper presents the reactions involved in the reagents obtaining and the associated mechanisms. Na2S2O4-TBHP is a new reagent for selective oxidation of aromatic alcohols to aldehydes. Wang reagents have uni
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M, Heravi; Majid, and L. Mohammadkhani. "Oxalyl Chloride: A Versatile Reagent in Organic Transformations." ChemistrySelect 4, no. 20 (2019): 6309–37. https://doi.org/10.1002/slct.201900120.

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Oxalyl chloride, (COCl)<sub>2</sub>, as an inexpensive commercially available chemical is one of the most versatile applicable organic reagents in chemical transformations. It is also employed extensively in various chemical industries. It is employed in various chemical transformations such as chlorination, oxidation, reduction, dehydration, decarboxylation, and formylation reactions as well as ring cleavage of epoxides. During the past decades, numerous procedures using (COCl)<sub>2</sub> as reagent have been developed and published. However, its importance has largely been overlooked by the
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SAKURAI, Hideki. "New reagents. V. Reducing reagents. Reducing reagent tris(trimethyl)silane." Journal of Synthetic Organic Chemistry, Japan 48, no. 11 (1990): 1012–13. http://dx.doi.org/10.5059/yukigoseikyokaishi.48.1012.

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SHIMIZU, Makoto, and Hirosuke YOSHIOKA. "New reagents. IX. Fluorinating reagents. Silicon tetrafluoride as monofluorination reagent." Journal of Synthetic Organic Chemistry, Japan 48, no. 11 (1990): 1054–55. http://dx.doi.org/10.5059/yukigoseikyokaishi.48.1054.

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KAJIGAESHI, Shoji, and Takaaki KAKINAMI. "New reagents. X. Reagents for functionalization. Iodinating reagent: Benzyltrimethylammonium dichloroiodate." Journal of Synthetic Organic Chemistry, Japan 48, no. 11 (1990): 1062–63. http://dx.doi.org/10.5059/yukigoseikyokaishi.48.1062.

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Dissertations / Theses on the topic "Organic reagent"

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Skinner, Christopher John. "Elemental fluorine as a valid synthetic reagent." Thesis, Durham University, 1994. http://etheses.dur.ac.uk/5141/.

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Chapter I Chapter I reviews the uses of elemental fluorine in selective organic synthesis and its use in the generation of selective electrophilic fluorinating agents. Chapter II Chapter II describes a systematic investigation into suitable solvents for the direct fluorination of deactivated aromatic systems. After highlighting 98% formic acid and 98 % sulphuric acid as excellent media for fluorinations, a number of other protonic acids were investigated. The work confirms the power of the resulting in situ fluorinating species is dependent on the pKa of the protonic acid. Chapter III Chapter
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Whittaker, David Thomas Edward. "Dimanganese decacarbonyl : a new reagent for radical organic synthesis." Thesis, University of York, 2000. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.341094.

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Walters, Jennifer Caroll. "NITROGEN-LIGATED (POLY)CATIONIC IODINE(III) REAGENTS: PLATFORMS FOR REAGENT DEVELOPMENT AND DIVERSE HETEROCYCLIC SYNTHESES." Diss., Temple University Libraries, 2019. http://cdm16002.contentdm.oclc.org/cdm/ref/collection/p245801coll10/id/558365.

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Chemistry<br>Ph.D.<br>Hypervalent iodine (HVI) reagents are easily accessed, highly tunable, mild, selective oxidants that are less toxic and more environmentally benign compared to their heavy metal counterparts. λ3-Iodanes, which possess an iodine center bound to one aryl substituent and two heteroatom ligands, have been the subject of recent interest due to their electrophilicity and hypernucleofugality. A central focus of the Wengryniuk laboratory has been the further development and application of a class of electrostatically activated (bis)cationic nitrogen-ligated HVI (N-HVI) reagents.
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Roberts, Richard Spurring. "Studies on the phenyldimethylsilyllithium reagent and its applications to organic synthesis." Thesis, University of Cambridge, 1997. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.627120.

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Massam, Jarrod. "The role of some aluminosilicates as catalyst and reagent supports for organic reactions." Thesis, Leeds Beckett University, 1995. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.306971.

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Li, Chao-Jun. "Part I: Barbier-grignard type reactions in aqueous media; part II: Development of a new tellurium reagent for organic synthesis." Thesis, McGill University, 1991. http://digitool.Library.McGill.CA:80/R/?func=dbin-jump-full&object_id=70267.

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Organometallic reactions, including allylation, alkylation, aldol and Reformatsky type reactions of carbonyl compounds in aqueous media mediated by Sn, Zn, Mn, and In were studied. The possible mechanism and stereochemistry of these reactions were investigated. The methodology has successfully been applied to the syntheses of 1,3-butadienes, vinyloxiranes, and methylenetetrahydrofurans; and the syntheses of natural product (+)-muscarine, (+)-epimuscarine, (+)-KDN and (+)-KDO.<br>A novel tellurium reagent, bis(triphenylstannyl)telluride, for organic synthesis was developed. Its application in t
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Gulati, Loveenia. "Characteristics and Treatment of Landfill Leachate and Optimization of Leachate Oxidation with Fenton's Reagent." Thesis, Virginia Tech, 2010. http://hdl.handle.net/10919/76771.

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The purpose of this study was to characterize the leachate from a landfill in Pennsylvania that had been pretreated by activated sludge and propose the most efficient treatment for this effluent. These samples had been pretreated in a sequencing batch reactor that also was operated to remove nitrogen by nitrification/denitrification. The SBR samples were found to have low BOD, high COD, high TOC and a very low BOD/COD ratio. These SBR decant samples have poor UV transmittance and hence quench UV light. Five treatment methods were evaluated, coagulation, ultrafiltration, combined coagulation/ul
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Easwar, S. "Enzymes as a reagent in organic synthesis: an efficient resolution of key intermediates of pharmaceutically important compounds and synthesis." Thesis(Ph.D.), CSIR-National Chemical Laboratory, Pune, 2006. http://dspace.ncl.res.in:8080/xmlui/handle/20.500.12252/2499.

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Goddard-Borger, Ethan D. "Some synthetic carbohydrate chemistry : natural product synthesis, rational inhibitor design and the development of a new reagent." University of Western Australia. School of Biomedical, Biomolecular and Chemical Sciences, 2008. http://theses.library.uwa.edu.au/adt-WU2009.0043.

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Earnest carbohydrate research was initiated in the nineteenth century by several talented organic chemists. Carbohydrates, now known to play essential roles in a range of fundamental biological processes, are presently studied by a throng of scientists from many fields, including: biochemistry, molecular biology, immunology, structural biology, medicine, agriculture, pharmacology and, of course, chemistry. Organic chemistry remains as relevant to carbohydrate research as it has ever been; its practitioners, with their skills in synthesis and fundamental understanding of molecules, are truly in
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Jonsson, Sofia. "The influence of soil and contaminant properties on the efficiency of physical and chemical soil remediation methods." Doctoral thesis, Umeå universitet, Kemi, 2009. http://urn.kb.se/resolve?urn=urn:nbn:se:umu:diva-21040.

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A vast number of sites that have been contaminated by industrial activities have been identified worldwide. Many such sites now pose serious risks to humans and the environment. Given the large number of contaminated sites there is a great need for efficient, cost-effective  remediation methods. Extensive research has therefore been focused on the development of such methods. However, the remediation of old industrial sites is challenging, for several reasons. One major  problem is that organic contaminants become increasingly strongly sequestered as they persist in the soil matrix for a long
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Books on the topic "Organic reagent"

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Cussion, Sylvia. Dissolved organic carbon and total organic carbon in reagent water and effluent: Report. Quality Management Office, Laboratory Services Branch, Ontario Ministry of the Environment, 1992.

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Cussion, Sylvia. Volatile organic parameters in reagent water and oil and grease in reagent water and effluent: Report. Ontario, Environment, 1990.

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Faĭnzilʹberg, A. A. Ftoristyĭ vodorod kak reagent i sreda v khimicheskikh reakt︠s︡ii︠a︡kh. Nauka, 2008.

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Cussion, Sylvia. Resin and fatty acids and adsorbable organic halides in reagent water and effluents: Report. Quality Management Office, Ontario Ministry of the Environment, 1992.

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Fieser, Mary. Reagents for organic synthesis. Wiley, 1990.

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Fieser, Mary. Reagents for organic synthesis. Wiley, 1989.

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Fieser, Mary. Reagents for organic synthesis. Wiley, 1990.

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Fieser, Mary. Reagents for organic synthesis. Wiley, 1986.

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Fieser, Mary. Reagents for organic synthesis. Wiley, 1992.

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Fieser, Mary. Reagents for organic synthesis. Wiley, 1989.

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Book chapters on the topic "Organic reagent"

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Andronov, Mikhail, Natalia Andronova, Michael Wand, Jürgen Schmidhuber, and Djork-Arné Clevert. "Curating Reagents in Chemical Reaction Data with an Interactive Reagent Space Map." In Lecture Notes in Computer Science. Springer Nature Switzerland, 2024. http://dx.doi.org/10.1007/978-3-031-72381-0_3.

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AbstractThe increasing use of machine learning and artificial intelligence in chemical reaction studies demands high-quality reaction data, necessitating specialized tools enabling data understanding and curation. Our work introduces a novel methodology for reaction data examination centered on reagents - essential molecules in reactions that do not contribute atoms to products. We propose an intuitive tool for creating interactive reagent space maps using distributed vector representations, akin to word2vec in Natural Language Processing, capturing the statistics of reagent usage within datas
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Han, Feng, Wei Sun, Chungu Xia, and Chao Liu. "Alcohol as a Reagent in Homogeneous Catalysis." In Solvents as Reagents in Organic Synthesis. Wiley-VCH Verlag GmbH & Co. KGaA, 2017. http://dx.doi.org/10.1002/9783527805624.ch10.

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Qi, Xinxin, Jin-Bao Peng, and Xiao-Feng Wu. "The Applications of Nitromethane as Reagent and Solvent in Organic Synthesis." In Solvents as Reagents in Organic Synthesis. Wiley-VCH Verlag GmbH & Co. KGaA, 2017. http://dx.doi.org/10.1002/9783527805624.ch9.

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Dickerson, Tobin J., Neal N. Reed, and Kim D. Janda. "Soluble Polymers as Catalyst and Reagent Platforms: Liquid-phase Methodologies." In Polymeric Materials in Organic Synthesis and Catalysis. Wiley-VCH Verlag GmbH & Co. KGaA, 2005. http://dx.doi.org/10.1002/3527601856.ch5.

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Bruni, P., L. Cardellini, L. Greci, and P. Stipa. "On the Radicalic Methylation. Unexpected Formation of Sulfones and Sulfonamides in the Reaction of Nitrosoarenes with Fenton’s Reagent in DMSO." In Organic Free Radicals. Springer Berlin Heidelberg, 1988. http://dx.doi.org/10.1007/978-3-642-73963-7_37.

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Bram, G. "Selectivity Induced by Heterogeneous Conditions in the Alkylation of Anionic Reagent." In Chemical Reactions in Organic and Inorganic Constrained Systems. Springer Netherlands, 1986. http://dx.doi.org/10.1007/978-94-009-4582-1_15.

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Nakamura, Eiichi. "Me3SiCl-accelerated conjugate addition reactions of organocopper reagents." In Organocopper Reagents: A Practical Approach. Oxford University PressOxford, 1995. http://dx.doi.org/10.1093/oso/9780198557579.003.0006.

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Abstract Conjugate addition to α,β-unsaturated carbonyl compounds represents an archetypical reaction of organocopper reagents (eqn 1). Various reagents including the classical Grignard-based catalytic copper reagent, the Gilman reagent (R2CuLi), and the ‘RCu•BF3’ reagent have been developed to improve the efficiency of the process by enhancing the reactivities of the reagents and by suppressing side-reactions such as 1,2-addition. Because of the paramount importance of the conjugate addition in organic synthesis, research efforts continue to make the reaction more versatile and more reliable.
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"Organometallic Addition Reactions to Ketones." In Greener Organic Transformations. The Royal Society of Chemistry, 2022. http://dx.doi.org/10.1039/9781837670895-00096.

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The formation of a carbon–carbon σ-bond via nucleophilic addition of an organometallic reagent to a carbonyl compound constitutes one of the most elementary transformations in organic synthesis. The great value of nucleophilic addition of organometallic reagents is its general applicability for the development of building blocks for an impressive range of different structures. This chapter looks at alternatives to the Grignard reaction, mechanochemical methods and the use of deep eutectic solvents.
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Rieke, R. D., and W. R. Klein. "Preparation of organocopper reagents using active copper." In Organocopper Reagents: A Practical Approach. Oxford University PressOxford, 1995. http://dx.doi.org/10.1093/oso/9780198557579.003.0003.

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Abstract Organocopper reagents have intensively been used in synthetic chemistry. The vast majority of organocopper reagents are prepared by a transmetallation reaction involving an organometallic reagent and a copper(I) salt. A variety of organometallic reagents, derived from metals more electropositive than copper, have been utilized in the preparation of organocopper reagents. The most common organometallic precursors have been organomagnesium and organolithium reagents. This approach severely limits the functionality that may be incorporated into the organocopper reagent. The use of tradit
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Clayden, Jonathan, Nick Greeves, and Stuart Warren. "Asymmetric synthesis." In Organic Chemistry. Oxford University Press, 2012. http://dx.doi.org/10.1093/hesc/9780199270293.003.0041.

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This chapter focuses on asymmetric synthesis. It begins by discussing chirality. A laboratory synthesis of a chiral compound from achiral or racemic starting materials alone always gives a racemic mixture of enantiomers. If we want to make just one enantiomer, we have to use a starting material or reagent which is also just one enantiomer. Nature provides a collection of ‘off the shelf’ enantiomerically pure compounds that we can exploit in various ways. This collection of natural, enantiomerically pure compounds is called the chiral pool. The chapter then looks at chiral auxiliaries and reage
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Conference papers on the topic "Organic reagent"

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Shaw, Robert W. "Supercritical Water Oxidation (SCWO) and the Army." In CORROSION 2009. NACE International, 2009. https://doi.org/10.5006/c2009-09246.

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Abstract During the mid 1980s, the problems of disposing of toxic military materials gained increasing attention. In response, the Army Research Office (ARO) expanded its basic research program on destruction of toxic materials. Previously focused on Chemical Warfare Agent (CWA) decontamination to protect the soldier under attack, the program changed to include weapon demilitarization. ARO reviewed those technologies in use and those in preparation to transform highly toxic organic compounds to relatively benign products and transformation chemistries that move completely to products with no p
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Almeida, Leonardo Silva de, Marcio C. S. de Mattos, and and Pierre M. Esteves. "Tribromoisocyanuric Acid: a Benzylic Brominating Reagent." In 14th Brazilian Meeting on Organic Synthesis. Editora Edgard Blücher, 2013. http://dx.doi.org/10.5151/chempro-14bmos-r0030-1.

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Salama, Tarek, Saad Elmorsya, and Mohamed Ismaila. "Tetrachlorosilane-A Versatile Reagent in Organic Synthesis." In The 12th International Electronic Conference on Synthetic Organic Chemistry. MDPI, 2008. http://dx.doi.org/10.3390/ecsoc-12-01199.

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Navarini, Jussara, Helio G. Bonacorso, Carson W. Wiethan, Rosália Andrighetto, Marcos A. P. Martins, and Nilo Zanatta. "Molecular Iodine - An Efficient Oxidative Reagent for Aromatization of Trifluoromethyl Substituted Chromenones." In 14th Brazilian Meeting on Organic Synthesis. Editora Edgard Blücher, 2013. http://dx.doi.org/10.5151/chempro-14bmos-r0009-2.

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Kalyakin, S. N., V. I. Kuzmin, and M. A. Mulagaleeva. "EXTRACTION OF HEAVY GROUP LANTHANIDES BY MIXTURES OF BINARY EXTRACTANTS AND SOLVATING REAGENTS." In XVI INTERNATIONAL CONFERENCE "METALLURGY OF NON-FERROUS, RARE AND NOBLE METALS" named after corresponding member of the RAS Gennady Leonidovich PASHKOVA. Krasnoyarsk Science and Technology City Hall, 2023. http://dx.doi.org/10.47813/sfu.mnfrpm.2023.140-147.

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Currently, phosphorus-containing cation-exchange organic extractants, due to their greatest selectivity, are the most commonly used reagents in the separation of rare earth metals (REM) by extraction methods. However, their use in the isolation and purification of individual REM is associated with high costs of reagents (mineral acids and bases). The addition of a cation-exchange extractant to a mixture of cation-exchange extractants makes it possible to change the nature of the process from cation exchange to extraction of the neutral salt, creating new opportunities for re-extraction of REM
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Taylor, Richard, and Jennifer Tesak. "Preparation of 4-Azido-2,6-diflurophenol Acetate, a Click Reagent." In The 15th International Electronic Conference on Synthetic Organic Chemistry. MDPI, 2011. http://dx.doi.org/10.3390/ecsoc-15-00700.

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Skulski, Lech, Barbara Krassowska-Swiebocka, and Grazyna Prokopienko. "Aromatic Iodination Method with Iodic Acid Used as the Iodinating Reagent." In The 8th International Electronic Conference on Synthetic Organic Chemistry. MDPI, 2004. http://dx.doi.org/10.3390/ecsoc-8-01957.

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Utaka, Aline, Lívia N. Cavalcanti, and Luiz F. Silva Jr. "Electrophilic alkynylation of ketones using hypervalent iodine reagent: a new approach to quaternary carbon formation." In 15th Brazilian Meeting on Organic Synthesis. Editora Edgard Blücher, 2013. http://dx.doi.org/10.5151/chempro-15bmos-bmos2013_201391510568.

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Kundu, Shrishnu Kumar. "“Combination of NaIO4 and NH2OH·HCl”: A new reagent in synthetic organic chemistry." In MODERN SYNTHETIC METHODOLOGIES FOR CREATING DRUGS AND FUNCTIONAL MATERIALS (MOSM2020): PROCEEDINGS OF THE IV INTERNATIONAL CONFERENCE. AIP Publishing, 2021. http://dx.doi.org/10.1063/5.0068475.

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Salama, T. A., S. S. Elmorsy, A. M. Khalil, M. A. Ismail, and A. S. El-Ahl. "Silicon Assisted Sulfuration: Tetrachlorosilane-Sodium Sulfide-A New Potent Thionating Reagent for Carbonyl Compounds." In The 11th International Electronic Conference on Synthetic Organic Chemistry. MDPI, 2007. http://dx.doi.org/10.3390/ecsoc-11-01317.

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Reports on the topic "Organic reagent"

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Moss, Robert A. Functional Micelles and Vesicles as Organic Reagents. Defense Technical Information Center, 1992. http://dx.doi.org/10.21236/ada253855.

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Banai, Menachem, and Gary Splitter. Molecular Characterization and Function of Brucella Immunodominant Proteins. United States Department of Agriculture, 1993. http://dx.doi.org/10.32747/1993.7568100.bard.

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The BARD project was a continuation of a previous BARD funded research project. It was aimed at characterization of the 12kDa immunodominant protein and subsequently the cloning and expression of the gene in E. coli. Additional immunodominant proteins were sought among genomic B. abortus expression library clones using T-lymphocyte proliferation assay as a screening method. The 12kDa protein was identified as the L7/L12 ribosomal protein demonstrating in the first time the role a structural protein may play in the development of the host's immunity against the organism. The gene was cloned fro
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